A.

Ketidakpastian Asal Konsentrasi Cu dalam Air Bersih dan Kurva (regresi linier)
Pengukuran Sampel Air Limbah =
Abs (Y sampel) =

Deret Standar xi = (mg/L) yi (absorban) xiyi xi2 yc

1 0.00 -0.0008 0.0000 0.0000 -0.0004

2 0.20 0.0253 0.0051 0.0400 0.0247
3 0.40 0.0497 0.0199 0.1600 0.0498
4 0.60 0.0745 0.0447 0.3600 0.0749
5 0.80 0.1005 0.0804 0.6400 0.1000
6 1.00 0.1248 0.1248 1.0000 0.1251
Intercept -0.0004 Jumlah
Slope (b) 0.1255
∑(xi-xr)2 0.70
∑(yi-yc)2 0.000001028
n 6
∑(yi-yc) / (n-2)
2 2.5705E-07
Sy/x=√∑(yi-yc)2 / (n-2) 0.000507
(Sy/x)/b 0.00404028969
xr 0.50
yo 0.0633
yr 0.0623
yo-yr 0.0009
(yo-yr)2 0.00000084
(b2∑(xi-xr)2) 0.01102267
(yo-yr)2/(b2∑(xi-xr)2) 0.0000762318
1+1/n 1.16666666667
1+(1/n)+(((yo-yr)2/(b2∑(xi-xr)2 1.16674289848
√1+(1/n)+(((yo-yr)2/(b2∑(xi-xr)2 1.08015874
μreg 0.0044
0.0633

(yi-yc)2 xi-xr (xi-xr)2

0.000000152 -0.50 0.25 Ulangan Abs Sampel

0.000000375 -0.30 0.09 1 0.0630
0.000000007 -0.10 0.01 2 0.0635
0.000000146 0.10 0.01
0.000000271 0.30 0.09
0.000000076 0.50 0.25
0.000001028 0.70
sampel

50 ml LT 50 ml

5 ml 50 ml ukur AAS

Hasil Pengukuran
Deret Standar Cu
konsentrasi abs ulangan abs Sampel
0.00 -0.0008 1 0.0630
0.20 0.0253 2 0.0635
0.40 0.0497 rata-rata 0.0633
0.60 0.0745
0.80 0.1005
1.00 0.1248

SD 0.0685
%Recovery 97.60%
SD 4.75%
Labu Takar 50±0,06 suhu 20℃
Pipet 5 ml 50±0,015 suhu 20℃
Suhu Lab 23℃

LT 50
sumber Nilai KP µBaku k µ baku²
Spesifikasi Pabrik 0.05 0.0288675135 1.732050808 0.000833333 SUM 0.001164083
efek suhu 0.0181865335 1.732050808 0.00033075 SQRT 0.034118665

Pipet Volume 5 mL
sumber Nilai KP KP Baku k µ baku²
Spesifikasi Pabrik 0.015 0.008660254 1.732050808 0.000075 SUM 7.83075E-05
efek suhu 0.0018186533 1.732050808 3.3075E-06 SQRT 0.008849153

FP
Alat Volume Ketidakpastian µ/V µ/V²
LT 50 0.0341186655 0.000682373 4.656333E-07 SUM 3.597933E-06
Pipet Volume 5 0.0088491525 0.001769831 3.1323E-06 SQRT 0.001896822

PM
SD 0.0685
% Recovery 4.75%
 Fish Bone Kadar Cu mg/L

V Pipet Cx
PM
µkalibrasi µreg
µT

µKalibrasi
µ Kalibrasi µ Kalibrasi
µT
µLT µPV
Rec
LT 1 µT µT

FP

Deret Standar Cu mg/L

0.14
0.12
f(x) = 0.125485714285714 x − 0.000409523809523811
0.1 R² = 0.999906729038526
Absorbansi

0.08
Column B
0.06
Linear (Column B)
0.04
0.02
0
-0.020.00 0.20 0.40 0.60 0.80 1.00 1.20
Konsentrasi
Kadar Cu mg/L
 Sampel 50 mL Disaring Filtrat

(m1-m0) PM
µ kal µ kal

µm0
µm1

µT
µ kal
µT µ Kal

Vol. pipet oven

pipet volume
sumber satuan volume nilai KP k µ KP baku µ^2 µVs
spesifikasi pabrik mL 50 0.05 1.73205081 0.02886751 0.000833 0.041858
efek suhu (ET) mL 50 1.73205081 0.03031089 0.000919

massa cawan kosong+TDS (m1)

sumber satuan nilai KP k µ KP baku µ^2
spesifikasi pabrik g 0.0007 2 0.00035 1.225E-07

massa cawan kosong (m0)

sumber satuan nilai KP k µ KP baku µ^2
spesifikasi pabrik g 0.0007 2 0.00035 1.225E-07

komponen satuan µ KP baku µ^2

massa cawan
g 0.00035 1.225E-07
kosong+TDS (m1)

massa cawan
g 0.00035 1.225E-07
kosong (m0)
(µm1-µm0)^2 0.000000245
µm1-µm0 0.000494975

oven
sumber satuan nilai KP k µ kp baku
sertif kalib ℃ 3 1.732050808 1.73205081
 tes pengaruh suhu pada hasil TDS
suhu (℃) SD (mg/L) efek suhu µ efek suhu
180 9.46 0.1020 0.176669182
185 9.97

PM
pengukuran
simbol keterangan satuan
simplo duplo
massa
m1 cawan + g 50.3798 50.3812
TDS
massa
m0 g 50.3656 50.3672
cawan
V sample vol, sampel mL 50 50
TDS kadar tds mg/l 284 280
Rata-rata 282
SD 2.83
m0 bobot m1 bobot bobot TDS
ulangan V sampel Total Solid
kosong (g) cawan+tds (m1-m0)
1 50.3656 50.3798 0.0142 50 284
2 50.3672 50.3812 0.0140 50 280
Rata-rata 0.0141 282

Gabungan
(µ/x) kp
komponen satuan nilai x µ kp baku µ/x^2
baku relatif
Vs mL 50 0.041857895 0.00083716 7.0083E-07
u (m1-m2) g 0.0141 0.000494975 0.03510459 0.00123233
u ET oven mg/L 282 0.176669182 0.00062649 3.9249E-07
uPM mg/L 282 2.83 0.01002988 0.0001006
Kadar TDS mg/L 282
(uCs/Cs)^2 = akar (Vs)^2+(u(m1-m0))^2+(uEToven)^2+(uPM)^2 0.00133402
uCs/Cs = akar (Vs)^2+(u(m1-m0))^2+(uEToven)^2+(uPM)^2 0.0365243
uCs=Cs x akar (Vs)^2+(u(m1-m0))^2+(uEToven)^2+(uPM)^2 10.2998517

faktor cakupan, k 2
KP diperluas, U 21

pelaporan hasil
kadar TDS ± U
282 ± 21 mg/L

cv hitung
7.4468085106369
 CV Horwith
c 0.000282
log c -3.54975089
0,5 log c -1.77487545
1-0,5 log c 2.77487545
2^1-0,5logc 6.84416929
Cawan Kosong Oven Timbang
(m0) (m1)

kadar TDS

suhu normal 25℃ beda suhu 5

suhu pipet 20℃
koef.muai 0.00021