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    İbrahim İbrahimli
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    Chem leak shady

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    223 views20 pages

    Chem Leak Shady

    Uploaded by

    İbrahim İbrahimli

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    9 O, Substa ance | Serie FF Wate 4.18 Ethanol 2.44 Tye@ identical insulated containers hold equal masses of liquid at the same temperature; one contains water and the other contains ethanol: Two identical cubes of Fe(s) are heated to the same temperature, one cube is placed in each container, and both systems are allowed.to reach thermal equilibrium. Based gsi tiie information in the table shown, whigh béthe following best predicts what will be observed? (A) Both systems, will have the same final temperature because the mass and initial temperature of the liquids are the same. (8Y"' Both systems will have the same final temperature because the Fe(s) cubes will transfer the same amount of heat to ‘both liquids. (C) The ethanol system will have the higher final temperature because the Specific heat of ethanol is loygpthan that of water. (D) The ethanol sygt#nv will have the lower final temperature because the specific heat of ethanol is lower than that of water, Pe wo ms ot # A,(g) ot wosCls) ¥ Als) - ol s 2 \ ae? i The single-step reaction at sin om oa place in a sealed container Whah of the. following wiff reduce the value of keke rate re 1 reaction? a ~ ot a aS (A) Decreasing the unica Ree ®) Increasing the teenpleratare z oo (0) Decrease te sie of the seat “ ) oweasng the sine of the seated, ei grr? iS a oe on , ap Ww x er ay gor 0 al ’ pe oe eal 3, 108 ans of 0 on: oie oft KOM _ Stew aa suecanad wn pe 1A) 2 ow ms we ww P pit . ; * on a 2 ow or an porn oe as wee a_i oe Pe ee B ih rhs i :O: is ws | " ¥ a os h uw io H—C—N=“y gi a ae : oe ier ae we eer ee” H a ot HONE L€éwis electron-dot diagram for YHs"is shown above. Idenitify the i hybridization of the valence orbitals for the carbon atom and the approximate od gen bond angle according AS) _eolVdrogen-carbon-ni : “to VSEPR theory. ye ald i § : of ee e or ae : (A) sp hybridized and 180 eo 0° os (B) sp hybridized and 12 Kote a: sho iF (CG) sp* hybridized andt8 sone oi a ot W “4: Oi (D) sp? hybridized and 120° he ent fh we x yo a aps we * Qh RX)! s APS x or ee ance = ; Relative Ab got téiis are it S er \* , no" or" as i - fe a ae? S W yo" 4 ee on ChO(g) + He O(s) @ oe a co = + 13kJ/mOlpxn wee . achemigat hem at equilib | sceni ae Bemis represented abbve ai of the OE ee h ill increase the ee (¢) present inthe system? 7 3 i Increasing the temperature wor if ) Decreasin, - : ie the volumestthe G (C) Addi e reaction vesse ; ai a : se 5 1 es «el one ) Removing Cl Lore) ¥ st e eo eS : w ae : oil i pe wey? oe c or oe ; “ yor en sp poe be - a soe ra ae oe ( att Questions nditions gi Three equimolar g4s samples al re at aie col we F yw 10. Which gas, if any, has mol 12. The number of moles of No(g) is closest to greatest average kinetic energy? aatianott the followin g? ot sor oY 0.10 mol a “ ae™ os (B) 1.2 mol ee (D) The molecules in all three samples have the © 22 mol . Sathe ineti "i ae average kinetic energy, (D) 28 mol ae a 11. Which ay ra #2 if any, has the Steatest density? aoe” yt (A) F, (B) N. he : ve ae ae ©) 0, po por »o @) Ay es ra. Khe loss of “nltopy is tooPreat to Maké‘molecular Collisions like]. Half-Reaction 16. The standard reductio te eatals of the re half-reactions associated with a galvanic cell ie listed in the table “above. Which of the followi statement® identifies the electrode that ificreases in mass as the cell operates, and correctly explaitis why? we § oe : A) The Ag electrode“ because Ag (aq) in the solution is reduced to form Ag(s). (B) The Ag eleéirode, because greater molar mass than Nj (C) The Ni electrode, because emically more et 3 Ag hasia” has, ep e Nivis Teactive | than Ag i Hy or ‘ ae iC ww ye EP nS at “( er en sap ea so eo. @ por 2Cu(s) + One 2 Cu0(s) AH? = 31210 Fi er 2Cu(s) + 508) -» Cu,O(s) AH? = —\71kI/ mol -xn al a” saps we Pa < xe al a ao a? sor . et 17. Based on the ee above, what is the ae ne AH? for the following FeACHOW AS on ee as 9p" Beers = ge Pom oor” (A)ge483 kJ/mol,+n be % eB) “141M gt 0 so ¢! se ot wi? (C) +141 kJ/mol, xs a we : ne” a oe (D) +483kI/mol,n, < ae Ke aw gh we yner® aor oe es f ao Sate roe rmation in the table. which of tures forms ‘ buffer with a pH ao" 1S) ge k 19, Based on the ‘inte the following mix sap ns closest to 3 ? ss ao (A) 50.0 mL of 0.10M HCIO3(aq) and 25.0 mbt 0.1 ) mbof 0.10 M NaOH(aq), oe (B) 50:0 mL of 0.20 M HNO, (tif) and _,50.0 mL of 0.10 M NaQH (aq) Poe “50.0 mL of . of 0. 10 M.. 5Hs0,(aq) and | oe ® 3 5 ee “@) 50 oe ee NaOH (aq) 250 of 240M HOCI(ag) oe RBE"o of 0.10. M NaOH (ag an aor ‘Ss cal K pO gs ot Bond ndaerey | ot mol) 4. 2°" value of AH for the reaction Hy + Clh =2\2HICI te ae value o} ‘or the reaction H + Cl, = “Wu pexic . Which of the following diagrams best eo is closest to which of the followings)” represents the mixture if the reaction goes to » completion? (A) —244kI/mol aot EenvA Energy 5 ep Ni (A) of a) Larger Larges Ris 3 er? (B) Small sno as” Smaller 0 (C) Sma 7 Nic] an or hanged oe ye or Unchan gv? er ged Smaller spo ae yal or ao rw eet et we pe {i 92K, 8) +Br, ae 32, The two mechanisms j sells NoBr(g) aor \S) hen Fal er mate ble below have been ; “tes Proposed for shefehction Tepresented above. Step 1: NO(g)gpNO(g) > N,05(g) Step 2 slow N=O3(g) + Br 2 eb 2(g) > 2 NOBr(g) fast 96) tep 2: NOBn(g) + NO(g) > 2 NOBr(s) 1 | rcs ich of the followi ati a M qgahich of the following observations woulesupport mechanism | but not mechanism race 3 pe (A) The reaction rate is independent of [NO]. (“= (g)_ The reaction rate is indepepdesit [Bry]. ot (C) The reaction is exothg@inic. of (D) The reaction,jgs#¥ond order overall. ar eal rca s r sp? of soe! ele Ss Ae iS ) aoe ae se . ee - —10 ¥ + CN (a K,=62% fo HCN(a gy gto? 2 H,0 (aq) + (aq) si ee A ! (aq) + OH (aq). gifs 1 * goo BO +1,0() 2 HOD Po i ts is correct? e A which of the following statemen . Based mical equations given. 33. Based on shes i " , y HCN is a weaker acid than H,0-

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