The document describes experiments to identify the cation and anion in a blue crystalline salt. Tests were conducted to determine the anion was sulfate (SO42-) and the cation was copper (Cu2+). Specifically, barium chloride solution produced a white precipitate when added to the salt and hydrochloric acid, confirming the presence of sulfate. Additional tests on the salt showed the presence of copper including forming a black precipitate with hydrogen sulfide gas and producing characteristic color changes in solutions.
The document describes experiments to identify the cation and anion in a blue crystalline salt. Tests were conducted to determine the anion was sulfate (SO42-) and the cation was copper (Cu2+). Specifically, barium chloride solution produced a white precipitate when added to the salt and hydrochloric acid, confirming the presence of sulfate. Additional tests on the salt showed the presence of copper including forming a black precipitate with hydrogen sulfide gas and producing characteristic color changes in solutions.
The document describes experiments to identify the cation and anion in a blue crystalline salt. Tests were conducted to determine the anion was sulfate (SO42-) and the cation was copper (Cu2+). Specifically, barium chloride solution produced a white precipitate when added to the salt and hydrochloric acid, confirming the presence of sulfate. Additional tests on the salt showed the presence of copper including forming a black precipitate with hydrogen sulfide gas and producing characteristic color changes in solutions.
AIM: TO IDENTIFY ONE CATION AND ONE ANION IN THE GIVEN SALT.
APPRATUS: TEST TUBE, TEST TUBE HOLDER, BURNER
CHEMICAL REQUIRED:- NH4OH, NaOH, HCl, BaCl2, H2SO4, HNO . PHYSICAL APPEARANCE: STATE: CRYSTALLINE COLOUR: BLUE ODOUR: ODOURLESS SOLUBILITY: SOLUBLE IN WATER TEST FOR ANION S.NO EXPERIMENT OBSERVATION INFERENCE 01 SALT + DIL.HCl + BaCl2 SOLUTION WHITE PPT FORMED WHICH SO42- PRESENT & IS INSOLUBLE IN CONC. CONFERIMED HNO3 TEST FOR CATION S.NO EXPERIMENT OBSERVATION INFERENCE 01 SALT + NaOH + HEAT NO AMMONICAL SMELL O GROUP ABSENT 02 OS. OF SALT + DIL. HCl NO PPT FORMED 1 GROUP ABSENT 03 DIVIDE THE ABOVE SOLN. IN 2 PARTS BLACK PPT FORMED 2 GROUP PRESENT ST & PASS H2S TO I PART Cu2+ SUSPECTED CONFERMATORY TEST 06 DISSOLVE THE BLACK COLOURED LIGHT BLUE COLOUR PPT IN 50% NITRIC ACID SOLUTION FORMED DIVIDE THE ABOVE SOLUTION IN Cu2+ ION PRESENT & TWO PART CONFIRMED IST PART + NH4OH DEEP BLUE IIND PART + ACETIC ACID + CHOCLATE BROWN PPT K4[Fe(CN)6] RESULT: - THE GIVEN SALT CONTAINS Cu2+ AS CATION AND SO42- AS CATION. CHEMICAL REACTION INVOLVED SO42- CuSO4 + 2HCl CuCl2 + H2SO4 H2SO4 + BaCl BaSO4 + 2HCl WHITE PPT BaSO4 + CONC. HNO3 PPT REMAINS UNDISSOLVED Cu2+ CuSO4 + H2S CuS + H2SO4 BLACK PPT CuS + 2HNO3 Cu(NO3)2 + H2S LIGHT BLUE COLOUR Cu(NO3)2 + 4NH4OH [Cu(NH3)4](NO3)2 + 4H2O DEEP BLUE SOLUTION 2Cu(NO3)2 + K4[Fe(CN)6] Cu2[Fe(Cu)6] + 4KNO3
Coordination Chemistry—XIV: Plenary Lectures Presented at the XIVth International Conference on Coordination Chemistry Held at Toronto, Canada, 22—28 June 1972
Critical Evaluation of Equilibrium Constants Involving 8-Hydroxyquinoline and Its Metal Chelates: Critical Evaluation of Equilibrium Constants in Solution: Part B: Equilibrium Constants of Liquid-Liquid Distribution Systems
XXIVth International Congress of Pure and Applied Chemistry: Plenary and Main Section Lectures Presented at Hamburg, Federal Republic of Germany, 2–8 September 1973