PHYSICS 8.

(b)Time of flight – T =
2u
g
(SECTION-A)
1. (b)
u2
maximum height H = = 20m
2g
u = 20 m/s T = 4 sec
Time gap between each ball = 1 sec
1 1
Form figure, h1 = ut1 – gt12 = 20 × 1 – × 10 (a)2 = 20 – 5 = 15m
2 2
2R E 1 1 180°
θ= = rad = × = 2° 1 2
60R E 30 30 π h2 = ut2 – gt
2 2
∴ Diameter of the earth as seen from the moon is about 2° . 1
= 20 × 2 – × 10(b)2 = 40 – 20 = 20m
2
2. (c) Radius of the sphere, r = 1.41cm 1
h3 = ut3 – gt 2
4 3 2 3
(3 significant figures Volumes of the sphere, V = πr
3 1
= 20 × 3 – × 10(c)2 = 60 – 45 = 15 m
4 2
= × 3.14 × (1.41) 3 cm 3
3
= 11.763cm 3 𝒗𝒗𝟐𝟐 𝒗𝒗𝟐𝟐
9. (c) − 𝒔𝒔𝒔𝒔𝒔𝒔 𝜽𝜽 𝒊𝒊̂ − 𝒄𝒄𝒄𝒄𝒄𝒄 𝜽𝜽 𝒋𝒋̂
𝑹𝑹 𝑹𝑹
Rounded off upto 3 significant figures = 11.7cm 3

3. (c)
1 1 1
VC = × (value of 1 MSD) = × = 0.001cm
50 50 20

4. (c) 𝑣𝑣 2 ∝ 𝑔𝑔𝑔𝑔
Let 𝑣𝑣 𝑥𝑥 = 𝑘𝑘𝑔𝑔 𝑦𝑦 𝜆𝜆𝑧𝑧 𝜌𝜌𝛿𝛿 . Now by substituting the
dimensions of each quantities and equating
the powers of M, L and T we get 𝛿𝛿 = 0 and x =
2,y=l,z=l . 2ux uy
10. (c) R =
g
  A 1
5. (b) | A |= 5 , | B |= 10 ⇒ =
B 2
6. (b) 11. (b)
Distance covered in total 7 seconds
1
= Area of trapezium ABCD = (2 + 6) × 10 = 40 m 12. (a) m
28
2 9
Distance covered in last 2 second = area of triangle CDQ Initial velocities of the particle
1 ux= 10 cos 53 = 6 m/s
= × 2 × 10 = 10 m uy = 10 sin 53 = 8 m/s
2 3
10 1 6t = 1 + t + x. [where x is the length of the
5
So required fraction = =
hypotenuse of the wedge]
40 4
3𝑥𝑥
5t = 1 + (in x - direction)
5
𝑥𝑥
7. (b)With respect to lift initial speed = ν0 8t - 5t2= 4. (in y - direction)
5
35
x= m
acceleration = – 2g 9
35 4 28
displacement = 0 Height = × = m
9 5 9
1 2
∴ S = ut + at 13. (b)
2
1
0 = ν0T' + × 2g × T'2
2
ν0 1 2ν0 1
∴ T' = = × = T
g 2 g 2
14. (c): If a is downward acceleration of 4 kg block, the upward = 2 × 10 × 10–3 × 5
acceleration of 1 kg block must be 2a = 10–1
Let T be tension in each part of string. The equation of motion
on 4 kg block is ∆t = 10–2
∆P
F =
∆t
10−1
=
10−2
= 10 N

4 g − 2T = 4a ….. (i)
The equation of motion or 1 kg block is
T − 1g =1 × 2a …(ii)
Or 2T − 2 g = 4a ….(iii)
Adding (i) and (iii) we get
g 19. (c)
2 g = 8a or a =
4
∴ Acceleration of 1 kg block For Remaining is Equilibrum
g Fs = Mg sin θ
= 2a = upwards.
2 µN ≥ Mg sin θ
µ mg cos θ mg cos θ
15. (a) : figure shows that slope of x-t graph changes from positive
to negative at t = 2 s and it changes from negative to positive at µ ≥Tan θ
t = 4s and so on. Thus direction of velocity is reversed after Tan θ ≥ µ
every two seconds. Hence, the body must be receiving (Tan θ)max = µ = 0.5
consecutive impulses after every two seconds.
x 2 dy x
y= = = (Tanθ)
m 20 dx 10
16. (d): Here mA = , mB = m
2  x
  = (Tanθ)max (Tanθ)vf/kdre
 10 max
(X)vf/kdre = 0.5 × 10
µ A = 0.2, µ B = 0.1 =5
Let both the blocks are moving with common acceleration a then (X vf/kdr e )2 25
(y)vf/kdr= = = 1.25m
µ AmA g e
20 20
a= = µ A g = 0.2 g
mA
F − µ B (mB + mA ) g = (mB + mA )a
20. (c)When friction is absent tc ?
F = (mB + mA )a + µ B (mB + mA ) g
 m  m a1 = g sin θ
And =  m +  (0.2 g ) + (0.1) m +  g
 2  2 1 2
∴ s1 = a1t1 ........ (i)
3  3  0.9 2
=  m (0.2 g ) +  m (0.1g ) = mg = 0.45mg
2  2  2 When friction is present tc ?
a2 = g sin θ – µ g cos θ
17. (d)
64
1
Limiting friction = Fl = µ s R ⇒ 64 = 0.6 m g ⇒ m = . ∴ s2 = a2t22 ........ (ii)
0.6 g 2
Applied force – Kinetic friction
From Eq. (i) and (ii) (i) o (ii) ls
Acceleration = = 1 2 1 2
Mass of the body
a1t1 = a2t2
64 2 2
64 − 0.4 ×
64 − µ K mg 0.6 = 0.2g or ;k a1t12 = a2 (nt1)2 (∴ t2 = nt1)
=
m 64
or ;k a1 = n2a2
0.6 g
a2 g sin θ − µ g cos θ 1
=
or ;k = 2
18. (b) ∆P = 2mv a1 g sin θ n
 g sin 45º − µ g cos 45º 1 mv 2
or ;k = 2 mg cos θ =
g sin 45º n R
h
1 cos θ =
or ;k 1 – µk = 2 R
n Energy conservation
1 1
or ;k µk = 1 – 2 mg { R − h} =mv 2
n 2
 h  2mg { R − h}
from (1) & (2) ⇒ mg   =
(SECTION-B) R R
2R
1. 82 =h = 2m
3

5. 2

Component along 𝐴𝐴𝐴𝐴

2
= 100cos⁡35∘ N 𝐻𝐻1 = �√2� = 2𝑚𝑚
= 100 × 0.819N 𝐻𝐻2 = (1)2 = 1𝑚𝑚
= 81.9N
≈ 82N ∴ 𝑣𝑣 = �2 × 𝑔𝑔 × (𝐻𝐻2 − 𝐻𝐻1 )
𝑣𝑣 = √20𝑚𝑚𝑠𝑠 −1
𝑑𝑑𝑑𝑑
2. (36) 𝑡𝑡𝑡𝑡𝑡𝑡 𝜃𝜃 = � = 2𝑥𝑥|𝑥𝑥=1 = 2
𝑑𝑑𝑑𝑑 𝑥𝑥=1
𝑔𝑔𝑑𝑑 2
−𝐻𝐻2 = 𝑑𝑑 𝑡𝑡𝑡𝑡𝑡𝑡 𝜃𝜃 − 2𝑢𝑢 2 𝑐𝑐𝑐𝑐𝑐𝑐 2 𝜃𝜃
10𝑑𝑑 2
−1 = 2𝑑𝑑 − 2 1 2
2�√20� � �
√5
5 2
𝑑𝑑
− 2𝑑𝑑 − 1 = 0
4
On solving we get d = 2m

6. 45.00
6mg 6 g 3 g Length of each train,
=
a = =
10m 10 5 𝑙𝑙 A= 𝑙𝑙 B= 400m
5
𝑢𝑢𝐴𝐴 = 72 × 𝑚𝑚/𝑠𝑠
taking 8,9,10 together 18
T = 3 ma
=20m/s
Distance travelled by train A in 50 s
3g
= 3mx sA = uAxt
5 (As for unaccelerated motion, distance =
= 36N Speed x Time)
SA= 20 x 50
3. (6) = 1000m
2 Mg − T =4ma Distance travelled by train B in 50 s, 𝑠𝑠𝐵𝐵 =
  T − Mg = 1
Using F net = µ a,
Ma 𝑢𝑢𝐵𝐵 𝑡𝑡 + 𝑎𝑎𝐵𝐵 𝑡𝑡 2
2
g (As motion of train B is an accelerated motion)
⇒a=
5 1
𝑠𝑠𝐵𝐵 = 20 × 50 + × 1 × (50)2
Mg 6 2
T = Mg + Ma = Mg + = Mg = 1000+1250
5 5 = 2250 m
relative distance between the two trains =SB-
4. (2) SA
= 2250-1000
= 1250m
we should subtract 2𝑙𝑙from it where 𝑙𝑙is length
of train so final answer will be 450 m

7. (5)
v2 = u2 + 2as
 100 = 0 + 2(10)s
S=5m
Height from ground = 10 - 5 = 5m

8. 180
If �P⃗ × �Q⃗ = Q
�⃗ × P̄
Only if �P⃗ = 0
Or Q �⃗ = 0
The angle b/wP �⃗ is 𝜃𝜃(0∘ < 𝜃𝜃 < 360∘ )
�⃗&Q
So 𝜃𝜃 = 180∘

9. Ans. 0030

10. (412)
10 VSD = 9 MSD
1 VST = .9MSD
L.C. = .1 mm =.01 cm
+ve zero error = .4mm
= 0.04 cm
Negative zero error = 4.1cm + 6x.01
= 4.12 cm
= 412 x 10-2 cm
 CHEMISTRY
(SECTION-A)
21. (c)
For the given reaction:
2C57 H110 O6 (s) + 163 O2 (g) → 114CO2 (g) + 110 H2 O(1)
445
𝑛𝑛 = = 0.5
890
110
Now, moles of water = × 0.5 = 27.5
2
∴ Mass of water = 27.5 × 18 = 495 g

22. (c)

Average molar mass

23. (b) Li+

24. (c) Electron

25. (d)
Given mass of organic compound =120
mass of CO2(g) = 330g
mass of H2O( l ) = 270g
mass of carbon = nCO2 x12
330
= × 12 = 90 g
44
90
% of carbon = x 100 = 75%
120
mass of hydrogen = nH 2O x 2
270
= x2 = 30g
18
30
% of hydrogen = x 100 = 25%
120

26. (d)

74 6.16
C 74% = 6.16 =5
12 1.23
17.3 1.23
N 17.3% = 1.23 =1
14 1.23
8.7 8.7
H 8.7 = 8.7 =7
1 1.23

Emperical formula = C5NH7

Emperical weight = 81
162
Multiplying factor = =2
81
Molecular formula = C10N2H14

27. (d) As we know that,

1 1
𝑣𝑣̅ = −𝑅𝑅𝐻𝐻 � − � 𝑍𝑍 2 (where, 𝑍𝑍 = 1)
𝑛𝑛 22 𝑛𝑛 22
After putting the values, we get
 1 1
𝑣𝑣̅ = −𝑅𝑅𝐻𝐻 � − 2�
𝑛𝑛2 8
𝑅𝑅𝐻𝐻 𝑅𝑅𝐻𝐻
⇒ 𝑣𝑣̅ = −
64 𝑛𝑛2
Comparing to 𝑦𝑦 = 𝑚𝑚𝑚𝑚 + 𝑐𝑐, we get
1
𝑥𝑥 = and𝑚𝑚 = −𝑅𝑅𝐻𝐻 (slope)
𝑛𝑛 2

28. (d) 0

29. (d)
In photoelectric effect,
ℎ𝑐𝑐
= 𝑤𝑤 + 𝐾𝐾𝐾𝐾 of electron
𝜆𝜆
Given that KE of ejected photoelectron is very high in comparison to work function 𝑤𝑤.
ℎ𝑐𝑐 ℎ𝑐𝑐 𝑃𝑃2
= 𝐾𝐾𝐾𝐾 ⇒ =
𝜆𝜆 𝜆𝜆 2𝑚𝑚
New wavelength
ℎ𝑐𝑐 (1.5𝑃𝑃)2 4
= ⇒ 𝜆𝜆1 = 𝜆𝜆
𝜆𝜆1 2𝑚𝑚 9

30. (b)
𝑣𝑣̅ ∝ ∆𝐸𝐸
For H-atom
1 1
𝑣𝑣̅ = 𝑅𝑅 � 2 − 2 �
𝑛𝑛1 𝑛𝑛2
For Lyman series,
1
𝑣𝑣̅ (𝑚𝑚𝑚𝑚𝑚𝑚) = 13.6 �1 − �
∞
1
𝑣𝑣̅ (𝑚𝑚𝑚𝑚𝑚𝑚) = 13.6 �1 − �
4
1
∴ 𝑣𝑣̅𝑚𝑚𝑚𝑚𝑚𝑚 − 𝑣𝑣̅𝑚𝑚𝑚𝑚𝑚𝑚 = 13.6 � �
4
For Balmer series,
1 1
𝑣𝑣̅ (𝑚𝑚𝑚𝑚𝑚𝑚) = 13.6 � − �
4 ∞
1 1
𝑣𝑣̅ (𝑚𝑚𝑚𝑚𝑚𝑚) = 13.6 � − �
4 9
1
∴ 𝑣𝑣̅𝑚𝑚𝑚𝑚𝑚𝑚 − 𝑣𝑣̅𝑚𝑚𝑚𝑚𝑚𝑚 = 13.6 � �
9
∆𝑣𝑣̅𝑚𝑚𝑚𝑚𝑚𝑚 9
=
∆𝑣𝑣̅𝑚𝑚𝑚𝑚𝑚𝑚 4

31. (a)
Atomic numbers of N, O, F and Na are 7, 8, 9 and 11 respectively. Therefore, total number of electrons in each
of 𝑁𝑁 3−, 𝑂𝑂2− , 𝐹𝐹 − and 𝑁𝑁𝑎𝑎+ are 10 and hence they are isoelectronic.

32. (d)
Under hypothetical situation, the value of 𝐼𝐼 is greater than 𝑛𝑛 which varies from 0 to 𝑛𝑛 + 1
𝑛𝑛 for 𝑛𝑛 = 1,1 = 0,1,2
Elements follow the following electronic configuration
1s1p1d2s2p2d2f
Atomic number(𝑍𝑍) = 9
1𝑠𝑠 2 1𝑝𝑝6 1𝑑𝑑1
Atomic number 6
1𝑠𝑠 2 1𝑝𝑝4
Atomic number 8
1s 2 1p6
 Atomic number 13
1s 2 1p6 1d5
Here atomic number of first noble gas will be 18

33. (c)
2𝜋𝜋𝜋𝜋 = 𝑛𝑛𝑛𝑛
𝑛𝑛2
2𝜋𝜋 × 𝑎𝑎0 = 𝑛𝑛𝑛𝑛
𝑍𝑍
42
2𝜋𝜋 × 𝑎𝑎0 = 𝑛𝑛𝑛𝑛
1
𝜆𝜆 = 8𝜋𝜋𝑎𝑎0

34. (a)
Reaction involved:

∴ The number of electrons involved in producing one mole of CO2 is 1.

35. (d)
Bunsen Burner and measuring cylinder is not required for titration.

36. (c)
H3 PO3 + 2NaOH → Na 2 HPO3 + 2H2 O
1MV =?

nH3PO3 × M1V1= nNaOH × M2 V2 ;

n-n factor
H3PO3 – dibasic (nf = 2)
NaOH – monobasic (nf = 1)

⇒ 2 × 1× 50 = 1× 1× V2

⇒ VNaOH = 100ml
H3 PO2 + 2NaOH → NaH2 PO3 + H2 O
100ml
2M
V =?
nH3PO2 × M1V1= nNaOH × M2 V2
H3PO2 → monobasic (nf = 1)
1× 2 × 100 = 1× 1× V2
⇒ VNaOH = 200ml

37. (d)

38. (a)
2Cu +2 + 4 I − (excess ) → Cu2 I 2 ( s ) + I 2
2Cu +2 + 3I − (limited) → 2CuI + I 2

39. (a)
3MnO42 − + 4 H + → 2 MnO4− + MnO2 + 2 H 2O
+6 +7 +4
 So, it is disproportionation reaction.

40. (a)
2KMnO4 + 16HC1 → 2MnCl2 + 2KC1 + 8H2O +C12
HC1 gets oxidised by KMnO4 into C12

(SECTION-B)
1. (12)
millimole of NaOH = 0.24 x 25
∴millimole of acid = 0.24x25
⇒ mass of acid = 0.24 x 25 x 24.2 mg
for pure acid,
w
V= ;(d = 1.21kg/L =1.21 g/ml)
d
0.24 × 25 × 24.2
=∴V × 10−3
1.12
= 120 × 10−3 ml
= 12 × 10−2 ml

2. (15)
0.69
Mole of Na= = 3x10-2
23
1
Na + H2O → NaOH + H2
2
By using POAC
Moles of NaOH = 3 x 10-2
NaOH reacts with HC1
No. of equivalent of NaOH = No. of equivalent of HC1
73
3x10-2x1 = xV (in L)x 1
36.5
V=1.5 x 10-2L
Volume of HC1 = 15 ml

3. (3)
+7 +4
MnO4− + 4 H + + 3e− → MnO2 + 2 H 2O

4. (3)

At equivalence point,
mmole of KC1 = mmole of AgNO3
=20mmole
Volume of solution = 25 ml
Mass of solution = 25 gm
Mass of solvent
= 25-mass of solute
= 25-[20x l0-3x74.5]
= 23.51 gm
 mole of KCl
Molality of KC1 =
mass of solvent in kg
20 × 10−3
= 0.85
23.51 × 10−3
i of KC1 = 2 (100% ionisation)
∆ Tf=i x Kf x m
= 2 x 2 x 0.85
= 3.4
 3

5. (270)
n2
r∝
Z
n2
rHe=
+ rH ×
Z
( 3)
2

rHe=
+ 0.6 ×
2
0
= 2.7 A
rHe+ = 270 pm

6. (798)
For one photon E = hv
For one mole photon,
E = 6.023x1023x6.626x10-34x2x1012
= 798.16 J
≈ 798J
7. (2)
(A) Ve = 1000 m/s ; h = 6 x 10-34Js ;
me=9 x 10-31 Kg
h 6 × 10−34
λ
= = = 666.67 × 10−9 m
mv 9 × 10−31 × 1000
= 666.67 nm
(B) The characteristic of electrons emitted is independent of the material of the electrodes of the
cathode ray tube.
(C) The cathode rays start from cathode and move towards anode.
(D) The nature of the emitted electrons is independent on the nature of the gas present in cathode
ray tube.

8. (4)
A : Fe0.93 O → Fe2O3
 200 
nf =
3 −  × 0.93
 93 
nf=0.79
B : 2x + (0.93 - x) x 3 =2
x = 0.79
Fe2+ = 0.79,Fe3+ = 0.14
C : fact
0.79
D : %Fe2+ = x 100 = 85%; Fe3+ = 15%
0.93

9. (4)
 Zn + 2HC1 → ZnCl2 + H2 ↑
11.5
Moles of Zn used = = Moles of H2 evolved
65.4
11.5
Volume of H2 = x 22.7L = 3.99L
65.4
Ans : 4

10. (364)
1000 × M
m=
1000 × d − M × M.W of solute
1000 × 3
= 3.64
1000 × 1 − ( 3 × 58.5 )
= 364 × 10−2
MATHEMATICS
SECTION-A
41 D
42 B
43 C
44 C
45 A
46 C
47 B
48 A
49 C
50 A
51 C
52 D
53 B
54 B
55 A
56 C
57 B
58 D
59 B
60 C
SECTION-B
1 4
2 4
3 3
4 129
5 197
6 2
7 310
8 0
9 900
10 3417