rs (@ 188M a (4425 (@) Sacem en i eee a Reason () Select the correct ee satements G9) Hah aero od easy NO joth Assertion (A) and Reason (I) vec’ ae @and {@_Astertion (A) is true, but Reason (fs (9) Assertion (4) sale, but Renn OO se ie oacde w. so Renae perteaet a wet ean mica, ca Uptccre a aaneme Peep on -SECTION-B_ 5) Wiest hw ars ceceereenee ee Oe reetyendet>s*7erene ronan (i) State Faraday's first law of electrolysis, vw. OR (#) Calculate the emf ofthe following cell at 288 K ey) | Fe™* (001M) gag | Hay (1 bar), Phy Given Blog = 044 V. 20, What happens to the rate constant k and activation energy E, as the te increased? Justify. 21, (a) Which of the following species cannot act as a ligand? Give reason. OH, NHj, CH, NH, H,O (0) The complex [Co(NH,)s(NO;)] Ci; is red in colour. Give TUPAC name Why is boiling point of o-dichlorobenzene higher than p-dichlorobenzene higher than ortho isomer? 23, For the pair phenol and cyclohexanol, answer the following (a) Why is phenol more acidic than cyclohexanol ? (®) Give one chemical test to distinguish between the two. 4. (a) (i) Draw the zwitter ion structure for sulphanilic acid. OR ©) @ Complete the reaction with the main product formed: Nice ;CH; (CH;CH; OH. (i) Convert Bromoethane to Propanamine. * Give the reaction of glucose with hydrogen cyanide. Presence of w 26. (a) For the reaction 404 4NO sy + Oye at 318K (ty ble the rate 6 reaction if rate of disappearance ofN, a first order reaction derive the relationship tymai cnse sample Question Papert, CHEMISTRY, Clase XI e ete eletoniconfguraton or on With stony, a Bang try while [NWCN),)* has square planar yet both exh 1%" t bot ana Ma) Onthe basic of crystal field theory wri 2. which dy > P Ey; (&) INNCO}] has tetrahedral geo abc number: Ni er. Blast Santee) NH is more basic than (CH) N in aqueous sottion ia! a ©) Expl She rescons for any 3 ofthe following observations: 29. Give Pemracetate of glucose does nat react with hydroxylamine. ‘Amino acids behave like sats. ‘Water soluble vitamins must be taken regularly in diet. ©) {9 Thetwo srandsin DNA are complimentary to each other. 1. (a) G@) Whyis the C—O bond length in phenols less than that in methanol? (i) Arrange the following in order of increasing boiling point: Ethoxyethane, Butanal, Butanol, n-butane (éi)How can phenol be prepared from anisole? Give reaction. ‘OR (©) @) Give mechanism of the following reaction : (CH3- CH OH HE CH3CH, ~~ CH CHy+ H,0 (i) Mlustrate hydroboration - oxidation reaction with an example. Questions hy {ie following questions are case - based! questions. Read the passage carefully and answer the : Nucleophilic Substitution Si {e°Philic Substitution reaction of haloalkane can be conducted according to both Sy! and § Sais a two step reaction while S,2.is a single step reaction. For any ie which mec Gepends on factors such as structure of haloalkane, properties of leaving group, nucleophilic exe Influences of solvent polarity: In Sy1 reaction, transition sate, Because a polar solvent hos Why racemisation occurs in $1? Why is ethanol less polar than water? Which one of the following in each pais, : “ @ CH,—CH, - Tor CH, CH, — Cl ‘more reactive towards Sy2 reaction? CO)Why. does condense souvnp ) Of KClis 150.08 45 ; © d 7 degree of dig we pee of dissociation of Oi tthe, values tobe © Amita classmate of Rahul repeateg oe aha Point that would be similar ana PEtiMent with cy oe and one that woald be eco aia SECTION -E 34 (6) Why's boling point of 1M NaCI stati (i) A nonvolatile solute 'X' (molar , more than the pressure to 90% Ealetlate the mass of X dissolved inthe alate eng ea assuming MgChis completely dissociscn ‘on Prepared by adding (K, for Water = 0.512 K kg mol'!, Mola 7 at OF IM glucose 5 mol") when dissolved in 78 of bam ’ Molar mass MgCt (bDetermine te oomote pe eo rear acnbenaene ne solution at 25 SC; assuming that KSO, is completely aeesey Seg 238 jf 0062 L atm KY mot" Molarmass 50, apna 4 (ii)When 25.6g of sulphur was dissolved in 1h00¢ ge) na Calculate the formula of sulphur (S,) of benzene, the ree amy (K for benzene = 5.12 K kg mol" Atomic mass of Sulphur = 32g mot 44. (@) (i) Write the reaction involved in Cannizaro's reoctone oa {i) Why are the boiling point of aldehydes and ketones ower than that of (Gi)An organic compound 'A’ with molecular formula CYOr mos followed by heating with NaOH and Glycol formsactioeinsnaea Todoform and Tolle’ test Identify ‘A’ and give its reaction ov lear OR = 95g mor x (©) @) Give a chemical test to distinguish between ethanol acid and ethanoie (i) Why is the a-hydrogens of aldehydes and ketones are acidic in natune? i)An organic compound 'A’ with molecular formula CyH,0, under ‘compounds'B' and’'C’. Oxidation of 'C'with acidified potassium perm salt of 'B' on heating with soda lime gives methane. (1) Identify ‘A’, 'B' and 'C. @) Out of 'B' and 'C, which will have higher boiling point? Give reason. 3. (a) Why is chemistry of actinoids complicated as compared to Janthanoids? 1+2+2= (©) Complete the following reaction and justify that it is a disproportionation reaction: une + ait". + +2H,0. 6 The given graph shows the trends in melting points of transition ‘metals; Explain the reason why Cr has highest melting point and manganese (Mn) a lower melting point.