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plantedtank.net/threads/testing-for-calcium.1264234
Grobbins48
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#1 · May 15, 2018
I have looked through my water quality report and it does not list anywhere thr Ca ppm. How
are people getting this reading? The only test kits I see are for saltwater.
On the same note, how would one test for Mg? Or do you use Gh test combined with some
Ca test and do some math?
1 - 13 of 13 Posts
@Grobbins48 best info I can offer is what I have been doing lately.
Get an API CA test kit. This kit is definitely designed for the salt water crowd but can be
useful for us with a little modification.
First, find a container that will hold a little more than 10ml. Get a 10ml sample of tank water
and add 20 drops of bottle 1 (10 drops in 5ml is normal). Now, each drop of bottle 2 roughly
equals 10ppm calcium.
Once you get a good reading (takes a bit of practice / good observation to see color change),
now you need to test the GH of your tank water. More or less, GH is made up of CA and MG.
So, 10ppm CA is equal to 1.4 dGH. In my case, I have a CA reading of 50ppm or 1.4 * 5 =
7dGH. My tank GH equals 11dGH. So, 11 - 7 equals 4dGH.
That means of the 11 dGH total, CA makes up 7dGH and MG makes up 4dGH.
1/15
MG equals 0.23dGH per 1ppm. So, 4dGH/0.23 equals 17.4ppm MG
I had great difficulty trying to make the API kit work. I found that the Elos Aqua Calcium Test
Kit (Amazon) is much easier.
For magnesium, I use the JBL kit from Germany (JBL Mg Magnesium Test Set Freshwater). I
got it via Ebay from one of several British sellers. Make sure you get the FW version and not
the SW version.
API Ca test kit can detect 0, 5, 10, 15, 20, … ppm Ca.
2/15
#7 · May 16, 2018 (Edited by Moderator)
So the API marine will work, just with a diluted (10-20 ml) as my scale? The math and all that
is fine, and I understand. I just was not sure on the reliability of API Ca test for freshwater.
Okay, now I understand why it is a saltwater kit. One drop is 20mg/L, so using a larger ratio
of water to solution yields a finer scale. Ie. 20ml of water. Thanks for the advice everyone.
I guess the question comes, with a gh of 8, does it matter? I mean to really hone in on things
I suppose. I might just grab the test anyways to have and know!
Thanks again for the help and hopefully this helps someone else out too.
FYI, look at post 139 in this thread Joe's tap water is 8.75:1 to 10:1 Ca:Mg
See more
Ah wow that is interesting. Funny enough when I started dry dosing, I ordered Mg, and
dosed at EI levels. I guess part of me thought that our water here was lacking- with
absolutely no scientific backup! HA!
I just ordered the API test kit from Amazon, so I'll post results when it comes in. Good info on
the ratios, I'll keep reading on that topic.
3/15
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Recently been watching a bunch of YouTube’s on calcium and magnesium titration tests. It
has been enlightening to say the least. Seems there is a whole lot of 1st year chemistry out
there that applies directly to what we are all doing lol. The dance that occurs between these
basic chemicals of life is pretty humbling in its simple complexity. I just got a salifert
magnesium. And a seachem iron. I have been fight omg algae with sick plants and I have a
suspicion that it is the lack of mg that is causing the carbonates to be sucked up and lost to
something like calcium carbonate. At any rate a little hard science backed data front the test
should tell a tale. Oh and also take a look at Dennis Wongs website
advancedplantedtanks.something. Just found it last week it has really cleanly explained
documents and videos about all of this.
Cheers
11/15
Kit came in today, but I'm reading some conflicting info. To get a higher resolution, I
understand adding more water, ie. 10ml. Would I not want to then keep bottle 1 at 10 drops,
making every drop of bottle two equal 10ppm. Or to get a 5ppm resolution, use 20ml of water
and still 10 drops of solution 1?
I might be missing something but it seems the titration should be the reaction of bottle 1 and
bottle 2 due to the Ca concentration in the water. With a diluted solution it would take more
drops to get the reaction, thus a finer redolution.
Thoughts?
1- The normal 5ml test with 10 drops solution 1 (normal saltwater test). I got to the 2nd drop
of bottle 2 and water went from pink to blue. This would indicate ~40ppm, low resolution of
20ppm.
2- Did the test with 5ml of water and 5 drops of solution 1. Again, it only took two drops to get
to blue. So does this mean 20ppm, or is the test flawed? not sure how I feel about this test
3- Did the test with 10ml of water, and all 10 drops of solution 1. It took 4 drops of solution 2
to change from pink to blue, so this would indicate ~40ppm Ca, with a resolution of 10ppm.
So with the assumption right now (I know, assumption... yikes...) that I have 40ppm Ca, I
tested tap GH, where I got 8 drops. Plug these two numbers into the Mg formula and I get:
(17.86*8)-(2.5*40)/4.1 or (142.88-100)/4.1 which equals 10.46ppm Mg. This makes the ratio
roughly 4:1, so not too far off, but could continue to dose Mg at 1/2 EI levels it seems to add
~7ppm Mg/ week.
Thoughts on this method? Am I going about this with the right idea, or way off base?
See more
#12 · May 20, 2018
The API Ca test kit was designed for reef keeping with 400 ppm Ca levels in 5 ml, 10 drops
#1, 20 drops #2.
12/15
So when we pick the best 5 ppm resolution then it takes 4 drops of #2. By changing #1 from
10 drops to 5 drops, we are doubling the test kit value otherwise it runs dry. I have verified it
with Ca solutions to be sure.
See more
Okay thanks for helping to clear that up for me. So for our use, solution 1 at 5 or 10 drops
yields the same results. What gives me resolution is increasing the sample size of the water
by a factor.
So 20ml of water, 5 drops solution 1, will give us a resolution of 5ppm for each drop of
solution 2.
I'll do the test again with the description above and see what results I get.
Test completed, results are in. Using the 20ml of water, 5 drops solution 1, I added 8 total
drops of solution 2 in order to turn blue. That would give me 5ppm * 8 drops = 40ppm.
So I guess validated a few ways, I am fairly confident my tap is at ~40ppm Ca right now,
which by the math gives me the ~10ppm Mg.
Unless anyone can advise otherwise, I'll probably add ~7ppm of Mg weekly, as I am EI
dosing on my tank.
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