yaa! UL__iwja0 U—oid GEMS OUR OWN INDIAN SCHOOL Anchored'n Bxeellence MIDTERM EXAMINATION 2022-2023 Subject: CHEMISTRY Grade: XII Date: 7-11-2022 General Instructions: Read the following instructions carefully. a) There are 35 questions in this question paper with internal choice. b) SECTION A consists of 18 multiple-choice questions carrying 1 mark each. c) SECTION B consists of 7 very short answer questions carrying 2 marks each. d) SECTION C consists of 5 short answer questions carrying 3 marks each. €) SECTION D consists of 2 case-based questions carrying 4 marks each. f) SECTION E consists of 3 long answer questions carrying 5 marks each. 8) All questions are compulsory. h) Use of log tables and calculators is not allowed. Maximum Marks: 70 Duration: 3 hours 1 SECTIONA 1. The compound that reacts fastest with Lucas reagent at room temperature is ) butan-1-ol (b) butan-2-o1 (c) 2-methypropan-1-ol (d) 2-methypropan-2-ol 2, _ The IUPAC name of CHs-CH=CHCHsBr Is a) 1-Bromobut-2-ene (by1-Bromobut-3-ene (c) 2-Butene-1-bromide cares Re. 3. The best reagent for converting 2-phenyl propanamide into 1-phenylethanamine is (hy excess He/Pt (b) NaOH/Br2 (c) NaBHe/methanol (o/Lialtis/ether 4. Nucleic acids are the polymers of (a) nucleosides (sfnucleotides (c) bases (d) sugars Page 1¢ Scanned with CamScanner10. aa. An electrochemical cell can behave like an electrolytic cell when W) Econ Eo , (2) Ecan=0 (6) Eeae > Eee (4) Ecet = Eo ff The reaction given below is called as t R-CH,-CooH —1%/Red phosphors _, p.cH-COOH n Ww #0 T ua \ x (a) Reimer Tiemann reaction wh Hell Volhard Zelinsky reaction : (c) Cannizaro’s reaction (4) Sandmeyer’s reaction Which of the following has highest pks value? A (a) CHsCHaNH2 {b) NH * (c) CHSNH (6) CoHsNHz The stabilization of coordination compounds due to chelation is called the chelate effect. Which of the following is the most stable complex species? (a) [Fe(CO)s] (b) [Fe(CN)e]>= (c) [Fe(C204}3] (4) [Fe(H20)<}** Monochlorination of toluene in sunlight followed by hydrolysis with aq. NaOH yields ho-cresol (b) m-Cresol (c) 2,4-Dihydroxytoluene (d) Benzyl alcohol Which one of the following amines cannot be prepared by Gabriel phthalimide synthesis? (a) Ethyl amine (b) lsopropylamine ty (c) n-Propylamine (d) Ethylmethylamine + ‘The correct order of increasing acidic strength is (a) Phenol < Ethanol < Chloroacetic acid < Acetic acid re (b) Ethanol < Phenol < Chloroacetic acid < Acetic acid ‘ (ef ethanol < Phenol < Acetic acid < Chloroacetic acid (d) Chloroacetic acid < Acetic acid < Phenol < Ethanol The electrolyte used in the mercury cell is (a) paste of NHaCl and ZnCl2 (8) paste of HgO and carbon (c) paste of KOH and ZnO (a) paste of PbO and H2S0, Scanned with CamScanner2B. 4. 16. i 18. 19. Indicate the complex ion which shows geometrical isomerism. (a) [Cr(H20)sCla}” {b) (Pt(NH3)3Cl]" (€) [Cotnts)}* {d) [Cofen)stnc)}* An organic compound ‘x’ of molecular formula C3HeO did not give silver mirror test with Tollen’s reagent but gives an oxime with hydroxylamine. The compound ‘x’ is (a) GH=CH-CH20H (b) CHaCHCHO aes (d) CHy=CH-OCH3 Question No. 15 to 18 consist of two statements Assertion (A) and Reason (R). Answer these questions selecting the appropriate option given below: i ‘A. Both A and Rare true and Ris the correct explanation of A. B. Both A and R are true and R is not the correct explanation of A. C Ais true but R is false. D. Ais false but Ris true. Assertion (A): An ether is more volatil than an alcohol of comparable molecular mass. Reason (R): Ethers are polar in nature. Assertion (A): Glucose reacts with hydroxylamine to form an oxime and also adds a molecule of hydrogen cyanide to give cyanohydrin. cy 7 Reason (R): The carbonyl group is present in the open chain structure of glucose. ©“ Assertion (A): Conduct decrease in concentration. ity decreases for weak electrolyte and increases for strong electrolyte with Reason (I On dilution, the number of ions per unit volume that carry the current decreases. Assertion (A): Acetanilide is less basic than aniline. Reason (R): Acetylation of aniline results in decrease of electron density on nitrogen. “SECTION B At 25°C, the saturated vapour pressure of water is 3.165 kPa (23.75 mm Hg). Find the saturated vapour pressure of a 5% aqueous solution of urea (carbamide) at the same temperature. (Molar mass of urea = 60.05 g mol) Page 3 of 8 Scanned with CamScanner20, / (a) Define the term Glycosiic linkage — (b) Vitamin € cannot be stored in our body. Give reasons. i) \Q OR (a) Define the term Invert sugar. (b) Give one structural difference between amylose and amylopectin. (2) Name the suitable alcohol and reagent from which 2-Chloro-2-methyl propane can be prepared. | a. (b) Out of Chioromethane and Fluoromethane, which one has higher dipole moment and why? oR "3 2-Bromopentane, 2-Bromo-2-methy{pdtane, 1-Bromopentane . dy (a) Write the compound which is most reactive towards Su2 reaction. . et (b) Write the compound which is most reactive towards B-elimination reaction. =r [Give the mechanism for the formation of Ethene from Ethanol. Dy 33.) A metal ion M™ having d valence electronic configuration combines with three bidentate ligands to form a complex compound. Assuming Ms > P. {a) Draw and explain orbital splitting during this complex formation. (b) Write the electronic configuration of the valence electrons of the metal M** jon in terms Of try and eg. 24, Write the major product(s) in the following react (a) CHsCH = C(CHs)2 + HBr > (o) CHSCHLG Se Ter ®) Give a simple test to distinguish between the following pairs of compounds. (2) CoHsCOCHs and CcHsCOCH:CHs 240m — {Yetleu? Qvekne**« (b) Benzoic acid and Phenol e ») nyooye As) SECTION C > 26. Give reasons for the following. (2) Phenol is more acidic than methanol. (b) The C-O-H bond angle in alcohols is slightly less than the tetrahedral angle. Scanned with CamScanner(c) (CHs)sC-OCHs on reaction with Hi gives (CH3)3C-I and CH3OH as the main products and not (CH3)sC-OH and CHs-I. Write the anode half reaction, cathode half reaction and overall cell reaction occurring during the discharge of a lead storage battery. > © 28. Give reasons. (a) Cooking is faster in pressure cooker than in cooking pan. {b) Red blood cells (RBC) shrink when placed in saline water but swell in distilled water. (c) An increase in temperature is observed on mixing chloroform and acetone. oR (a)\state Henry's law. 18) Gas (A) is more soluble in water than Gas (B) at the same temperature. Which one of the two gases will have the higher value of Kx (Henry's constant) and why? {(c) In non-ideal solution, what type of deviation shows the formation of maximum boiling azeotropes? ‘ 29. Answer any three. How will you carry out the following conversions in not more than two steps? Sy “(aly aniline to benzene ® € @ Toluene to p-Toluidine . ge tah 7 3 we & (c) N-phenylethanamide to p-bromoaniline ~ ay @Penzene diazonium chloride to nitrobenzene — ‘3% (2) Identify the major product formed when 2-cyclohexylchloroethane undergoes a \ z,, dehydrohalogenation reaction. Name the reagent which is used to carry out the reaction. {b) Why are haloalkanes more reactive towards nucleophilic substitution reactions than haloarenes and vinylic halides? SECTION D (CASE-BASED QUESTIONS) 31. Proteins are high molecular mass complex biomolecules of amino acids. The important proteins required for our body are enzymes, hormones, antibodies, transport proteins, structural proteins, contractile proteins etc. Except for glycine, all a-amino acids have chiral carbon atom and have L- ‘configuration. The amino acids exist as dipolar ion called zwitter ion, in which a proton goes from the Page 5 of 8 Scanned with CamScanner32. ‘carboxyl group to the amino group. A large number of a-amino acids are joined by peptide bonds forming polypeptides. The peptides having very large molecular mass (more than 10,000) are called Proteins. The structure of proteins is described as primary structure giving sequence of linking of amino acids, secondary structure giving sequence of folded polypeptide chains and tertiary structure iving sequence of folding, coiling or bonding polypeptide chains producing three dimensional structures and quaternary structure giving arrangement of sub-units in an aggregate protein molecule. {a) What type of bonding helps in stabilizing the a-helix structure of proteins? (b) Give one example each for fibrous protein and globular protein. (c) a-amino acids have relatively higher melting points than the corresponding halo acids. Explain. oR \ (€) Give any two properties of amino acids. Boiling point or freezing point of liquid solution would be affected by the dissolved solids in the liquid has the effect of raising its boiling point and depressing its freezing phase. A soluble solid in sol point. The addition of non-volatile substances to a solvent decreases the vapour pressure’ and the added solute particles affect the formation of pure solvent crystals. According to many researches, the decrease in freezing point s directly correlated to the concentration of solutes dissolved in the solvent. This phenomenon is expressed as freezing point depression and it is useful for several applications such as freeze concentration of liquid food and to find the molar mass of an unknown solute in the solution. Freeze concentration is a high quality liquid food concentration method where water is ice crystals. This is done by cooling the liquid food below the freezing point of the removed by formi solution. The freezing point depression is referred as a colligative property and itis proportional to the 1 (m), along with vapour pressure lowering, boiling point elevation, molar concentration of the solu ‘and osmotic pressure. These are physical characteristics of solutions that depend only on the identity Of the solvent and the concentration of the solute. The characters are not depending on the solute’s. identity. (a) Why is glycol and water mixture used in car radiators in cold countries? (b) Which one of the following has the highest freezing point? ()1MGlucose (ti) 1MNacl (ii) 1M Cac Scanned with CamScanner33. (c) Calculate the mass of NaCl (Molar mass = 58.5 g/mol) to be dissolved in 37.2 g of water to lower the freezing point by 2°C, assuming that NaCl undergoes complete dissociation. (Ks for water = 1.86 K Kg mol) OR (c) Derive the relationship between depression in freezing point and molar mass of solute. SECTION E (a) Represent the cell in which the following reaction takes place. 2A\(s) + 3Ni?* (0.1 M) -> 2AP*(0.01) + 3Ni(s) Calculate the emf if E%au = 1.41 V. {(b) State Kohlrausch law of independent migration of ions and calculate A°m for acetic acid. Given that \°m (HCl) =426 S em? mol", A°m (NaCl) =126 S em? mol and A%m (CHsCOONa) = 91S cm? mol oR (a) Calculate €°eu for the following reaction at 298 K. 2Al(s) + 3Cu?(0.01M) > 2AP*(0.01) + Cuts) Given: Ege = 1.98 V (b) Using the E® values of A and B, predict which is better for coating the surface of iron to prevent corrosion and why? Given: ({E°(Fe?*/Fe)= -0.44 VJ , E°(A?/A) = - 2.37 V, E°(B**/B) = - 0.14 V] 34. Ahydrocarbon (A) with molecular formula CsHxo on ozonolysis gives two products (B) and (C). Both ¢ , {B) and (C) give a yellow precipitate when heated with iodine in presence of NaOH while only (Bygivey a silver mirror on reaction with Tollen’s reagent. iS (a) Identify (A), (B) and (C). && - (b) Write the reaction of B with Tollen’s reagent. 7 (c) Write the equation for iodoform test for C. = uf {d) Write down the equation for aldol condensation reaction of B and C. = \ Scanned with CamScannerwt ‘Aketone (A) which undergoes haloform reaction, gives compound (B) on reduction, (B) of heating with Sulphuric acid gives compound (C), which forms mono-ozonide {D). The compound. (D) on hydrolysis in presence of zinc dust gives only acetaldehyde. Write the structures and IUPAC names of (A), (B) and (C). Write down the reactions involved. 135. CoSOxCI.SNH3 exists in two isomeric forms ‘A’ and ‘B’. Isomer ‘A’ reacts with AgNOs to give white: precipitate but does not react with BaCla. Isomer ‘8’ gives white precipitate with BaCl but does not react with AgNOs. = (2) Identify ‘a’ and ‘8’ and write their structural formulae. =X (b) Name the type of isomerism involved. es (c) Give the IUPAC name of ‘A’ and ‘8’. 5) 4 Sn xb ~8~-| aexT¢buro : Chee 41 rr TO. He ffl +Hr0 ALO, si RHR Tex2 43247 Par Scanned with CamScanner