Name ____________________________ Date Submitted: ____________

Lab Schedule: _____________________ Date Performed: ____________

Experiment No. 2
Differences between Organic & Inorganic
Compounds and Tests for Element Found in Organic Compounds

I. OBJECTIVES

Results Inference
1. Test for Elements Present in Organic Compound

A. Elements detected by combustion

Test Sample Visible Result Structure/Formula of Cpd responsible Element

for the visible result Detected

A1. LPG ______________ ________________________ ________

A2. LPG ______________ ________________________ ________

A3. breath/Ca(OH)2

______________ ________________________ ________

CH4 + O2 ________________________
incomplete combustion

CH4 + O2 ________________________
complete combustion

CO2 + Ca(0H)2 ________________________

B. Elements detected by addition of strong base and heating

Test Sample Visible Result Structure/Formula of Cpd responsible Element
for the visible result Detected

1. Urea a. ____________ __________________________ __________

b. ____________ __________________________ __________

egg white

ttunheated_______________ __________________________ __________

theated ________________ __________________________ __________

Reactions:

Co(NH3)2 + NaOH ________________________

S-2 (from albumin) + Pb(OAc)2 _______________________

C. Beilstein Test

Test Sample Color Flame Element Detected

HCl(3M) _______________ _______________

KI _______________ _______________

CHCl3 _______________ _______________

KBr) _______________ _______________

Saliva _______________ _______________

II. Differences in Properties of Organic and Inorganic Compounds

A. Effect of Heating

Test Sample Observations

NaCl __________________________________

___________________________________
 Sucrose _____________________________________

_____________________________________

Reaction:

C12H22O11 + O2 ________________________

B. Conductivity

Test Sample Conductor Noncondutor

NaCl slution _______________ _______________

Benzene _______________ _______________

KI solution _______________ _______________

Sucrose _______________ _______________

C. Ionization

Observation Explanation

NaCl + 1% AgNO3 __________________ ___________________

CHCl3 + 1%AgNO3 __________________ ___________________

Name ____________________________ Date Submitted: ____________
Lab Instructor: _____________________ Date Performed: ____________

Experiment No. 2
Differences between Organic & Inorganic
Compounds and Tests for Element Found in Organic Compounds

I. OBJECTIVES

Results Inference
1. Test for Elements Present in Organic Compound
A. Elements detected by combustion
Name ____________________________ Date Submitted: ____________
Lab Schedule _____________________ Date Performed: ____________

Experiment No. 3
Extraction of Caffeine from Tea

I. OBJECTIVES

Results Inference

1. Weight of tea + beaker = ___________________

Weight of beaker = ___________________

Weight of tea = ___________________

2. Weight of Erlenmeyer flask + crude caffeine

= ________________________

Weight of Erlenmeyer flask = _______________________

Weight of crude caffeine = _______________________

% Recovery = _______________________
Name ____________________________ Date Submitted: ____________
Lab Schedule _____________________ Date Performed: ____________

Experiment No. 4
Sublimation of Crude Caffeine

I. OBJECTIVES

Results Inference

1. Weight of crude caffeine = ___________________

2. Weight of paper + sublimed caffeine

= ________________________

Weight of paper = _______________________

Weight of sublimed caffeine =_______________________

3. % Recovery = _______________________

4. Color of caffeine = _______________________

Name ____________________________ Date Submitted: ____________
Lab Schedule _____________________ Date Performed: ____________

Experiment No. 5
Recrystallization and Melting Point Determination

I. OBJECTIVES

Results Inference

A. Selection of Solvent for Recrystallization

OBSERVATION

Solvents Room Temp Higher T (if insoluble)

H 2O _____________ ___________

CHCl3 _____________ ___________

CCl4 _____________ ___________

B. Recrystallization

wt. of impure benzoic acid _____________

wt. of recrystallized benzoic acid _____________

% recovery _____________

C. M.P. Determination

crude benzoic acid _____________

recrystallized benzoic acid _____________

Name ____________________________ Date Submitted: ____________
Lab Schedule _____________________ Date Performed: ____________

Experiment No. 6
Volatility: Distillation and Determination of Boiling Point

I. OBJECTIVES

Results Inference

A. Comparison of Volatility by Rate of Evaporation

Compounds tested Time Exposed Time completely Minutes
Evaporated Elapsed
O
1. Acetone, CH3 – C-CH3 _______________ _______________ __________

2. Methanol, CH3 - OH __________ __________ _______

O
3. Ethylacetate, CH3C-O-CH2CH3 __________ __________ _______

4. 1-butanol, CH3CH2CH2CH2OH __________ __________ _______

5. Water, HOH __________ __________ _______

B. Distillation of Water and Boiling Point Determination

Description Vol. Distillate T(°) Remarks
Ordinary 1 drop
Tap water 3 mL
6 mL
9 mL
12 mL
15 mL

Residue After
Distillation

Distillate
Name ____________________________ Date Submitted: ____________
Lab Schedule _____________________ Date Performed: ____________

Experiment No. 7
Solubility Classification

I. OBJECTIVES

Results
Solvent System
Sample Water 2.5M NaOH Conc. H2SO4
1.5M HCl 5% NaHCO3
Alanine
Aniline
Chlorobenzene
Cyclohexane
Hexane
α-napthol
Phenol
Salicylic acid
Sulfanilic acid

Inference
Name ____________________________ Date Submitted: ____________
Lab Schedule _____________________ Date Performed: ____________

Experiment No. 8
Hydrocarbons

I. OBJECTIVES

Results Inference

A. Ignition Test
Samples Chem. Formula Description of Observation during
sample Ignition test

Cyclohexane

Cyclohexene

Benzene

Toluene

B. Reaction with Bromine in CCl4

Samples Wrapped Test w/ Unwrapped Test w/
test tube litmus test tube litmus

Cyclohexane

Cyclohexene

Benzene

Toluene

Acetylene
C. Reaction with Potassium Permanganate
Samples Observation

Cyclohexane

Cyclohexene

Benzene

Toluene

Acetylene

D. Reaction with Ammoniacal AgNO3

Samples Observation

Cyclohexane

Cyclohexene

Benzene

Toluene

Acetylene

Name ____________________________ Date Submitted: ____________

Lab Schedule _____________________ Date Performed: ____________
 Experiment No. 9a
Classification Test for Functional Groups
a. Aromatic Hydrocarbons

I. OBJECTIVES

Results Inference
A. Tests for Aromaticity
Test Reagent Visible Result Structure/Formula
of cpd responsible
for visible result

Nitration

Le Rosen

B. Ignition Test
Test Sample Observation

Hexane

Benzene

Aniline

Phenol

C. Reaction with AlCl3/HCCl3

Test Sample Color Reaction

Benzene
Toluene

Chlorobenzene

Hexane
Name ____________________________ Date Submitted: ____________
Lab Schedule _____________________ Date Performed: ____________

Experiment No. 9b
Classification Test for Functional Groups
b. Alcohols and Phenols

I. OBJECTIVES

Results Inference
1. Reaction of Alcohols

C. Reaction with Potassium Dichromate

D. Iodoform Reaction

Acetone __________ ______________________

Ethyl alcohol __________ ______________________

Methyl alcohol __________ ______________________

Isopropyl alcohol __________ ______________________

n-propyl alcohol __________ ______________________

2. Reaction of Phenols
A. Ferric Chloride Test

Phenol __________ ______________________

-naphthol __________ ______________________

Cathecol __________ ______________________

Resorcinol __________ ______________________

B. Bromine Test

Phenol __________ ______________________

-naphthol __________ ______________________

Cathecol __________ ______________________

Resorcinol __________ ______________________

Name ____________________________ Date Submitted: ____________

Lab Schedule _____________________ Date Performed: ____________

Experiment No. 9c
Classification Test for Functional Groups
b. Carbonyl Compounds

I. OBJECTIVES

Results Inference
1. Test for Aldehydes and Ketones

2. Test for Carboxylic Acid