o2/172023, 12:18 aboutblank ‘abouttblank 183o2/172023, 12:18 ey e 2 aboutblank Time allowed: 2:35 Hours _.\ ‘NOTE: Answer any FOURTEEN pate fom Section’ and attempts any TWO questions from Section ©" on ‘abouttblank CHEMISTRY HSSC-)\ \\ aC \ abba ds Sections B and C: 68 the separately provided answer book. Wrile your answers neatly and legibly. SECTION ~ B (Marks 42) any FOURTEEN parts from the following. All parts carry equal marks. (14x3= 42) The liquid CliBr, has 2 density of 2.89@ / cn”. What volume ofthis Nquic should be measured to contain a total of 48x10" molecules of CH; (MWR, C=12, H=1, Br=80) (i) Point out the three defects of Bohr’s mode! (ii) How dipole moment help to determine the polarity of molecules? Apply this concept to determine the nature of CO, and Cis-1, 2-clehioro ethene, tiv) Predict and draw the shape and bond angles of following molecules on the basis of VSEPR theory: 0 8 @ SCL) PCL (¥) Bley explain azimuthal quantum number. How it helps to determine number of ein @ subshell? (vi) Prove that absolute temperature of a gas is the measure of average kinetic energy of ts molecules. K-EveT (vi) How the molar mass and density of @ ges can be determined with the help of general gas equation? (vii) Why butene is gas at room temperature while hexane is Iquid? (ix) Differentiate between Isomorphism and polymorphism with sultable examples. (%) Describe electron sea theory, How it explains the properties of metals? (i) Nj+3,==22NH, — K, = 6x10" at $00°C Predict the direction in which the system wl shift to align equilbrium when concentrations of #7,, N, and NH, are L.0x10" M, 10x10? Af 10x10? 4f respectively (34) Calulate the pit ofa buffer when molar concentrations of N#/,OH and NH,CI ie Oar 0.14 respectively, PK, of NH,OH is 4.75 Gai) Explain with chemical equation vy on 530) eo a. basit\ \\\ @ NHC sacks) eer j)| —Ka,80, is neutral (iv) Consider the. fo vi rep0toh Ul EN, 22H, r= KUH,}INO} if this reeetion occurs intwo steps Guile ieee predict the reaction intermaciate ow) What is aio? (ot stale Graham's law of effusion and ciffusion with mathematical expression. oe abit ne moat ot 30% © cout of rutose (6,0, Way \ Define system, surtoundings and boundary wih a sutable example (oui) Predict the feasibly of the folowing reaction Sng” —oSn «Ag By, =-0.14Y , Fy, (x) sian under reduced pressure i offen used for purcation of sensitive inuids. Describe the process giving reason (6%) Apply n-+1 rule and pick the orsital with the lower energy from each of the given pairs Sas W) 2pas (i) 6p.as ‘SECTION ~ 6 (Marks 25 ‘Attempt any TWO questions. All questions carry equal marks. (2x13=26) Consider tne folowing reaction CH, + #,0 —»COs3H, (08) (9 Whats the amount of CO produced if 30g of CH, and s0y of H1,0 is used (i) Inanexperiment 22¢ of CO were produced, what is percentage yield? >. Deserve constuction of eas storage battery and reaction aking pace during charging ard daiscnarging (07) 3. Whats oral hybridization? Explain the structure of HC= CH , Bh and Ci, onthe basis of hybridization. (08) b. Slate Le-Chateliers principle. Briefly discuss the effect of increase in pressure, increase in oncentation of SO, inorease in emparature anc increase in 10, catalyst when felowing reacton is Ks \\\\ 7) (08) at equilibrium. 250, +0, #+280,,, all a ‘Drew complete Born Haber cycle forthe formation of Net Fee the bonny oatae 28112023, 12:13 aboutblank ‘aboutblank AFH OF MgO = -€02 kT mol Be Of Ma = ISDA tN Qf Mg) = 2180 / mol AWE of 0, 2244 /mal aH FO" (OR of OF = S78LI/mol 5 OF O, = 244y /mol aH OF OLIN ies ot mo Why accion af shite increases the boiling point of solution? Explain quantitative aspects of elevation of boing pot ie brave thatA7, is inversely propertonal to molar mass of solute (07) a rIN] 2 ais