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DEGAROUTE® Designing Safe Traffic
DEGAROUTE® Designing Safe Traffic
Apart from visual information depending on their shape and structure, road
Safe, durable and eco-friendly— markings can also provide an audible and haptic signal. Profiled road mark-
The systems‘ longevity makes them markings also provide other in-built safety features to the road, such as a
well-adjusted level of skid resistance.
reliable, environmentally friendly and
cost-effective. Thus, making them 6
FORMULATION
As authority representatives, road designers, formulators or contractors,
you are facing the challenges of change every day. Therefore, we would like
an innovative solution which decision- to support you with our inventive skills and know-how, which has evolved
makers, contractors, formulators and over the last 50 years. DEGAROUTE® based road markings provide you
with a particularly long-lasting, resource saving and cost-effective option.
all road users can depend on. 10 Low VOC, low microplastic emission, fast curing in a wide range of tempera-
APPLICATION tures and versatility in any shape or color count among the many advantages
of DEGAROUTE® resins. Numerous certifications and applications around the
For more than 50 years, Röhm has world demonstrate the contribution of DEGAROUTE® to the improvement of
with methacrylate reactive resins to ROAD SAFETY On the following pages we would like to show you exactly how DEGAROUTE®
continuously enhance performance evolves from raw material to application and what makes our resin so sus-
tainable and a true milestone on the road. Please join us as we explore all
and safety features of DEGAROUTE® that DEGAROUTE® has to offer.
3
DEVELOPMENT PRODUCTION AND DISTRIBUTION
1988
The first profile markings increase visibility in
wet conditions and produce warning sounds 2011
1982 when being crossed over by vehicles
The introduction of fast curing
1966 For the first time, bicycle lanes are DEGAROUTE® resins
marked in color with cold plastic area (curing time within 2 minutes)
Market launch of the first 2-component
cold plastics extrusion machines with markings based on DEGAROUTE®
powered, speed-proportioned pumps
1990 2019
The introduction of structure The start of Röhm GmbH with high
markings offers high visibility focus on methacrylate chemistry
in darkness and rain
4 5
FORMULATION FORMULATION
FORMULATION
Road marking materials are formula- • thermoplastics that, after being DEGAROUTE® RESINS ty to formulate cold plastics for al- used for spray application. Resins
tions consisting of binders, fillers, heated to 200 to 220 °C (390 to FOR COLD PLASTICS most all tasks without using external such as DEGAROUTE® 655 or
pigments and additives. Modern road 430 °F) are sprayed on or extruded plasticizers. Structured road mark- DEGAROUTE® 661 provide fast cur-
marking systems also comprise glass as a melt, and cure by solidifica- The program of DEGAROUTE® resins ings made of DEGAROUTE® 465 ing, even at thin layers. DEGAROUTE®
beads to ensure wet-night visibility. tion (VOC free); thin and thick is designated by three-digit numbers. have proven their durability in the 655 is particularly suitable for appli-
There are many decisive factors for layers feasible The numbers 401–499 represent extremely cold climate of Alaska cation at elevated temperatures.
defining the right formulation, among • cold plastics that, mixed with a resins with higher viscosity used for as well as in the Brazilian heat. These grades are suitable for 98:2-
others traffic flow, road surface, curing component (hardener), are thick-layer cold plastics. Materials DEGAROUTE® 465 is also suitable to machines and in combination with
climatic conditions and traffic load. sprayed on or extruded at ambient that are made with these resins can formulate materials for area mark- their accelerator-free resin-version
The choice of the resin as binding temperatures and cure chemically be applied manually, by means of ings that provide enough flexibility to (e.g. DEGAROUTE® 655 with
agent is important for the applica- by polymerization (almost no VOC push-cart road marking units or by cover larger surface areas such as DEGAROUTE® 659) for 1:1-machines
tion characteristics of the road emission); thin and thick layers automatic extrusion machines. bicycle lanes or zebra crossings. as well.
marking material and the durability feasible
of the final road marking system State-of-the-art reactive resins like DEGAROUTE® RESINS FOR COLD
under traffic wear. DEGAROUTE® FOR COLD PLASTIC DEGAROUTE® 465 provide good SPRAY PLASTICS
ROAD MARKINGS wetting properties for fillers and can
The main binder-based road For decades, DEGAROUTE® reactive be processed easily. Furthermore, The numbers between 601 and 699
marking systems in use today are: Cold plastics are reactive two- or resins have been used to manufac- this resin has a high in-build flexibili- represent resins with low viscosity
• solvent-based paints of high solids multicomponent systems formulated ture high performance road marking
content that are sprayed on and with DEGAROUTE® binders and materials. Cold plastic road markings
dry physically by evaporation of brought to polymerization by adding based on DEGAROUTE® binders
the solvent (emission of VOC); a curing component prior to applica- provide long lasting functionality,
only thin layers (< 1mm) feasible tion. The system cures chemically a variety of colors and shapes, and
• water-based paints that are after a certain lapse of time (pot make our daily way safer and more
sprayed on and dry physically by life), when the volatile resin compo- lively, too. Due to the high durability,
evaporation of the water and a nents are chemically bound in the DEGAROUTE® based cold plastics
small solvent and ammonia com- resulting inert polymer. Thus, the provide most resource efficient and
ponent (almost no VOC emission); application can be considered as environmentally friendly road mark-
only thin layers (< 1mm) feasible almost free from VOC emission. ing solutions.
* With addition of accelerator down to – 10° C/14 F on dry and clean substrate
6 7
FORMULATION FORMULATION
FORMULATION OF DEGAROUTE® should be adjustable. Long stirring migrate to the surface. In this case, container with a separate steerer thoroughly tested pigments with Cold plastic is typically broadcasted
BASED COLD PLASTIC times and heating of the material the paraffin must be homogenized to avoid contamination with the good UV stability shall be used. with approx. 150 to 400 g/m² and
READY-TO-USE MATERIAL over 40 °C/104 °F must be avoided. with an explosion-proof (e. g. air- accelerated component. Our DEGAROUTE® technical service cold spray plastic typically with 400
• The respective DEGAROUTE® driven) barrel mixer to guarantee team will help you determine and to 600 g/m² of reflective drop on
Cold plastic road marking materials binder is poured into the mixer. equal distribution in the individual Additives testing suitable pigments. beads. Drop on beads may contain a
based on DEGAROUTE® binders are Subsequently additives, pigments batches. Carefully selected thixotropic agents smaller fraction of anti-skit aggre-
formulated by the respective binder and fine fillers are added while (e. g. Byk® D410) and thoroughly test- Fillers gates to adjust skit resistance. If too
type, pigments, fillers, additives and stirring. Finally, coarse fillers and DEGAROUTE® resins should be ed wetting agents (e. g. Disperbyk® Commercially available fire-dried many or too fine glass beads and
glass beads. Coarse fillers and inter- intermix beads are stirred in. stored at maximum 30 °C/86 °F 163) may be used to adjust viscosity. fillers in various sizes can be used for anti-skid aggregates are applied on
mix beads may also be added. A for- • Adjustment of viscosity is depend- without direct exposure to sunlight. Other additives, such as solvents the formulation such as quartz pow- a road marking, an excessive soiling
mulation for cold spray plastics con- ing on wetting properties of fillers, In general, the storage stability of and air release agents (e. g. silicone der, dolomite, feldspar, calcined flint of the surface could happen.
sists of binder, pigments, additives pigments and used additives. This DEGAROUTE® ready-to-use materi- oil), should be avoided as they have or quartz (cristobalite), calcite and
and fine fillers. must be considered regarding the al is very good especially if the ma- a negative impact on curing of the heavy spar. Fine fillers with large Intermix and reflective glass beads
sedimentation and flow behavior terial contains titanium dioxide. cold plastic material and may pre- surface or high oil absorption and with silane treatment provide im-
During the preparation of as well as for the application of For ready-to-use materials prepared vent tack-free hardening. Our hydrophobic qualities are not suit- proved adhesion to cold plastic
DEGAROUTE® cold plastic ready- broadcast material (reflective without titanium dioxide, an early DEGAROUTE® technical team will be able. Depending on the formulation, materials. Uncoated or glass beads
to-use material, the following basic beads). gelling may occur under unfavorable glad to help you determine suitable intermix beads with a size of 0,05 to coated with silicon treatment should
precautions must be taken: • The bottom outlet should have a conditions (e. g. high storage tem- additives for your cold plastic for- 0,8mm may be used as fillers to con- not be used since they provide only
• Equipment must be diameter of at least 5 cm (2 inch) perature). Therefore, we recommend mulation. trol rheology of the formulation. poor adhesion to cold plastic materi-
explosion-proof. to allow discharge of high viscose adding a small amount of titanium als. Silicone treated glass beads
• Barrels or containers must only be cold plastic material. dioxide (approx. 1 wt %) to yellow Pigments Drop on beads must not be used as drop on beads
opened with non-sparking tools. marking materials. Besides, heavy Mostly titanium dioxide (rutile) is Reflective drop on glass beads must for cold plastic since they cannot
MMA evaporates when the resin is FURTHER RECOMMENDATIONS spar should not be used as filler in used. Please be aware of moisture be broadcast to the applied road provide long-lasting retro-reflectiv-
stirred or filled into other contain- these cases. that will cause thickening of the RTU marking to achieve the required day ity in road service.
ers. The evaporation loss should be DEGAROUTE® binders contain par- material and organic post treatment and night visibility. Much larger
kept as low as possible. The mixing affin which is necessary for tack-free In case of a 1:1 system, the non- agents that may cause yellowing or reflective beads (up to 2,5mm) are
container must be closed or at hardening. After long storage periods accelerated component must be tackiness of the pigments. Only used for improved wet-night visibility.
least covered. The stirring speed at lower temperature, paraffin can processed in a separate mixing
8 9
APPLICATION APPLICATION
10 11
APPLICATION APPLICATION
HARDENER DOSAGE AND ing, 4 wt % of hardener powder (3rd desired thickness with the catalyzed manually by means of a system of large batches, e. g. on highways and
APPLICATION CONCEPTS component) is mixed to the accel- marking material (smoothing trowel). levers. When using these units, the national roads. For these purposes,
erator free component off-line on beginning and end of the line must machines that are working according
BPO hardener (dibenzoyl peroxide) – the job site. The inactive cold plastic The tape should be removed before be marked off beforehand. to the 98:2 system and 1:1 system
mostly as powder with 50 wt % BPO component requires an accelera- the curing is completed. Additional- are available.
(hardener powder) or in liquid form tor-free DEGAROUTE® grade provid- ly, reflective beads and an antiskid FULLY AUTOMATIC APPLICATION
containing typically 40-50 wt % ing enough stability to the premix agent may be sprinkled over the All equipment contaminated with
BPO (liquid hardener or liquid BPO) with the hardener. We recommend freshly marked surface. So-called For thick layer (flat-, profile- as well catalyzed cold plastic (e.g. appli-
– serves as hardening agent for clear marking of the containers with draw boxes can be used for stop- as structure marking) as well spray cation head) must be purged with
cold plastics or cold spray plastics. the two components to avoid confu- ping lines and nontraffic zones. Such applications, self-driven machines suitable solvent during interruption
Typically, 1-2 wt % hardener is used sion. The two components (reactive applicators consist of variously with automatic line length device of application process.
for application in a wide range of component and premix with hard- constructed metal frames with a are used for the application of
temperatures. For application at ener) are then poured into separate slit to release marking compound at
extreme temperatures, the mixing tanks and machine fed, mixed and the rear. The width of the draw box
ratio may be adjusted to control pot sprayed or extruded in a ratio of 1:1. determines the width of the marking
life and curing speed. Guidelines for line. The release slit height deter-
adjustment of hardener dosage are 1:1 spray applications are also typ- mines the layer thickness.
given in the technical data sheets of ically used in smaller walk behind
the respective DEGAROUTE® resins. spray equipment for legend as well APPLICATION BY MEANS
as striping applications. OF ROLLERS
Manual or semi-automatic
application: Caution: Flexible DEGAROUTE® resins are
Hardener powder is most suitable, • Once the hardener has been add- offered especially for area markings.
whereby the powder is manually feed ed, the stability of the “non-accel- Usually, the material is applied in 1
and mixed with a stirrer to the cold erated” component may be limited or 2-layers by means of rollers as
plastic before charging it to a screed to 1 to 2 hours only depending on colored area markings or anti-skid
box, for instance. temperature. marking for bike and walk ways,
• Even slight contamination of the bridges, bus lanes and hazardous
Machine application with reactive component with Dibenzo- points like school zones or round-
fully-automatic dosage and mixing: yl peroxide (BPO) hardening agent abouts. To mask the edges, tem-
Liquid BPO is used for fully auto- must be avoided. In case of a 1:1 plates or tape can be used.
matic machines operating with a system, the non-accelerated com-
fixed mixing ratio, whereby two major ponent must be processed in a APPLICATION BY MEANS
machine concepts (mixing ratios) separate mixing container with a OF HAND GUIDED MACHINES
are used: separate steerer to avoid contami-
nation with the accelerated com- Various favorable marking devices
98:2 system ponent. for flat-, profile-, as well as for struc-
98 wt % reactive cold plastic to 2 wt ture markings that can be transport-
% liquid hardener with direct liquid MANUAL APPLICATION ed easily have been developed for
BPO metering. the application of center and side
Direction arrows, symbols as well lines as well as for pedestrian cross-
1:1 system as letters and numbers are drawn ings with widths of 10-50 cm.
This 3-component system requires on the pre-cleaned road surface,
one reactive cold plastic ready-to- typically using templates and chalk. All these marking devices function
use component and one inactive Templates are removed and edges according to the draw box principle.
accelerator free cold plastic ready- masked with tape. The masked area The catalyzed material flows into
to-use component. Prior to process- will be filled and smoothed to the the box which is opened and closed
12 13
ROAD SAFETY SUSTAINABILITY
About one third of all road accidents CO2 emissions and posing major road markings cost-effective and
happen at night and in wet condi- safety hazards. The application of resource-saving, since they need to
tions, which is exactly when many DEGAROUTE® based road markings be renewed less often.
types of road markings lose their requires minimal road closure time.
visibility. Due to integrated glass Since the marking is fast curing, Traffic all around the world is get-
beads and the three-dimensional roads can be reopened for traffic ting more and more complex. This DEGAROUTE® based road
structure, road markings based on
DEGAROUTE® provide the advan-
within a short period of time and
the risks that are typically present
requires new solutions for safety on
the roads. Whether flat, structure,
markings lead the way for
tage of a significantly higher wet- during the application process are profile or area markings are con- more than 50 years.
night visibility. Therefore, they offer
the best performance when road
drastically reduced. cerned, cold plastic markings based
on DEGAROUTE® can be applied
They are highly visible even
users need guidance the most. Cold plastic markings can cope with to the road in any shape, color and at night and wet, thus they
Even in hot and dry climates where
extreme traffic and climatic condi-
tions, as well as with high snowplow
grip, both mechanically and manu-
ally. Thus, DEGAROUTE® based road
help to prevent accidents
traditional road markings turn black activity. Confirmed by indepen- markings contribute to innovative and save lives. They are
under traffic DEGAROUTE®-based
road markings stay clearly visible
dent wear simulation tests of the
German Federal Road Research
guidance systems which enhance
safety for pedestrians, cyclists and
extremely durable, ecofriendly,
thanks to anti-dirt pick-up technology. Institute (BASt), cold plastics have drivers. cost-efficient and easy to apply.
been found to be far more resistant
Especially on highly traveled roads, against wear than other markings.
any interference with traffic flow Furthermore, their outstanding lon-
can cause delays, thus increasing gevity makes DEGAROUTE® based
14 15
Röhm GmbH Roehm Chemical (Shanghai) Co., Ltd. Roehm America LLC
Deutsche-Telekom-Allee 9 7F, Westlink Tower A, 2337 Gudai Road, 299 Jefferson Road
64295 Darmstadt Minhang District Parsippany NJ 07054
Germany 201100 Shanghai, P. R. China USA
Phone: +49 6151 863-7000 Phone: +86 21 6759 1000 Phone: +1 800 225-0172
degaroute@roehm.com
www.degaroute.com
www.roehm.com
This information and all further technical advice is based on our present knowledge and experience. However, it implies no liability or other
legal responsibility on our part, including with regard to existing third party intellectual property rights, especially patent rights. In particular,
no warranty, whether express or implied, or guarantee of product properties in the legal sense is intended or implied. We reserve the right to
make any changes according to technological progress or further developments. The customer is not released from the obligation to conduct
careful inspection and testing of incoming goods. Performance of the product described herein should be verified by testing, which should be
carried out only by qualified experts in the sole responsibility of a customer. Reference to trade names used by other companies is neither
a recommendation, nor does it imply that similar products could not be used.
07/2021/HSP