Hybridization and Bonding in Organic Molecules

1. How many nand o bonds present inNC-C=N?

a) n =4, o= 4 (b) n=4, g=5 (c) T =4, G=3d) =2, o=1
2. Number of sp -sp o-bonds present in given compound is:

(a) 1 (b) 2 (c) 3 (d) 4

3. How many o-bonds are present in the given compound ?

(a) 6 (b) 12 (c) 18 (d) 24

4. What is the hybridization of carbon in compound HC=N?
(a) sp (b) sp² (c) sp (d) All of these
5. What is the hybridization of C1,C2,Ca carbon in the
following compound?
CH3CH2-CH=CH-C=CH
1 2 3

(a) sp,sp,sp? (b) sp,sp, sp? (c) sp, sp, sp () sp, sp,sp2
6. What is the hybridization of carbon in the following
compounds ?
CH, -F, CH3Cl
(a) sp²,sp? (b) sp, sp (c) sp (a) spsp2
7. In which of the following carbon is sp hybridized state?

(a) CH3-Cl (b) NH,- NH, (C) H C=N (d) CH3-NH,

8. What type of bonding is most important in CH,CH,CH,CH,CH,CH3?
(a) ionic (b) hydrogen (c) covalent (d) polar
9. Which carbon(s) in the following molecule is(are) sp hybridized?

CH3-C-CH,-C=C-H
1 2 3 4 5

(a) carbon 1 (b) carbon 2 (c) carbons 1,3 (d) carbon4 (e) carbons 4, 5
10. Which of the following has the strongest van der Waals' interaction between molecules of the
same kind?
(a) CH3CH-CH,CH, (b) CH CH,CH,CH3
CH,
CH3
(c) CH, -CHg () CH,CH,CH,CH2CH, (e) CH3 CHCH
CH3 CH3
11. What is the hybridization of the carbon atoms numbered 1 and 2 respectively in
the following structure?
-CH=CH 2C=CH
(a) sp,sp (b) sp,sp? (c) Sp,Sp (d) sp, sp (e) sp,sp
12. The carbon-carbon triple bond of an alkyne is composed of ...
(a) three o bonds (b) two o bonds and one n bond
(c) one o bond and two n bonds (d) three bonds
Bond (1) Bond (2)
Bond (3)

13.

Rank the indicated bonds in each compounds in order of increasing bond strength :
(a) 1<2<3 (b) 3<1<2 (c) 1<3<2 (d) 2<3<1

14.

How many *-electrons are contained in given molecule?

(a) 6x (b) 8r (c) 10r (d) 12rn
 IUPAG Nomenclature of Alkanes
1. How many carbons are present in longest chain of given compound?
C-C-G G C C
C-C-GC
(a) 6 (b) 7 () s (d) 9
2. How many carbons are present in longest carbon chain of given compound ?
C-C

C-C- C C
(a) 4 (b) 5 (c) 6 (d) 7
3. How many carbons are present in nonane ?
(a) 7 (b) 8 (c) 9 (d) 10
4 What is the common name for the following structure?

CH-CH-CH3

CH,
(a) isobutane (b) t-butane (c) n-butane () secbutane
5. How many carbon atoms are present in parentcarbon chain in the given following compound?

(a) 6C (b) 7C (c) sC (d) 9C

6. Which of the folowing alphabet have a five membered chain as a longest chain?
A,E, F, H, I, K, M, T, V, W, X, YZ
(a) A E.H (b) E, M, W (c) K, M, X (d) F,WN, Z
7. Give the complete IUPAC name for the structure below. Be careful to identify longest carbon
chain:
CHCH CH CH CHÊ
CHCH, CH CH
CH, CH,
(a) 3,5,6-trimethyl octane (b) 3,4,6-trimethyl octane
() 12.3.6-tetramethyl heptane (d) none of these
8. Give the IUPAC name for the following structure:
 Elementary Organic Chemist y
(a) 2-methyl-3-ethylheptane (b) 3-ethyl-2-methylheptane
(c) S-isopropyloctane (d) 4-isopropyloctane
(e) 2-methyl-3-propylheptane
9. Give the IUPAC name for the following
compound:

(a) isoprene (b) 3-methyl-1,3-butadiene

(c) 2-methyl-1,3-butadiene (a) 2-methyl-2,3-butadiene (e) isobutadiene
10. ; How many methyl -CH3 group are present in given alkane?

(a) 4 (b) 5 (c) 6 (d) 7

11. ; How many 2° carbon present in above compound?

(a) 4 (b) 5 (c) 6 (d) 7

CHg
12. The structure shown
CH,CH,CHÇHCH,CH,CHCH,
CH,CH, CH,CHg
(a) 1° 2°, and 3° carbon atoms (b) 1° and 2° carbon atoms only
(c) 1° and 3° carbon atoms only (d) 2° and 3° carbon atoms only
13. How many 1° carbon atom will be present in a simplest hydrocarbon having two 3° and One
carbon atom ?
(a) 3 (b) 4 (c) 5 (d) 6
14. 1°, 2°, 3° and 4° carbon atoms are present in:
(a) 2, 2, 3-rimethyl pentane (b) 2, 3, 4-trimethyl pentane
(c) both (a) and (b) (d) none of these
15. Corect IUPAC name of the following compound is:

(a) 4-(1,1-dimethylethyl)-5-ethyloctane (b) S-ethyl-4-(1,1-dimethylethyl) octane

(c) 5-(1,1-dimethylethyl) 4-ethyloctane (d) 4-ethyl-5-(1,1-dimethylethyl) octane
 IUPAC Nomenclature of Alkynes/Alkenes
1. Which of the following name will be incorrect ?

(a) 6-Dimethyl cyclohexene (b) 1,6-Dimethyl cyclohexene

(c) |6,6-Dimethyl cyclohexene 1,5-Dimethyl cyclohexene

2. Which pair of names refers to the same compound ?

(a) Ethyne and Acetylene (b) Ethyne and Ethene
(c) Ethane and Acetylene (d) Ethane and Ethene
3. What is the IUPAC name for the following compound?
CH, = C-CH,
|
CH,
CH,
(a) 2-methyl-1-butene (b) isopentene
(c) 2-methybutene (d) 2-ethylpropene (e) 3-methyl-3-butene
4. What is the IUPAC name for the following compound?

CH3
(a) 5-methylcyclohexene (b) 4-methylcyclohexxene
(c) 1-methyl-3-cyclohexene (d) 1-methyl-4-cyclohexene (e) methyleyclohexene
5. What is the IUPAC name for the following alkyne?
Br

CH -C=C-CH,-C-CH
CH3
(a) 5-bromo-2-heptyne (b) 3-bromo-5-heptyne
(c) 2-bromo-2-methyl-4-hexyne (d) 5-bromo-5,5-dimethylhexyne
(e) 5-bromo-5-methyl-2-hexyne
6. What is the common name for the following alkyne?
CH,
CH,-C-CaCH

CH4
 (a) neohexyne
(c) trimethylacetylene
(b) trimethylpropyne
(d) tert-butylacetylene
Chemlstry
(e) isopropylacetylene

7. The IUPAC name of is:

-Br

(a) 2-bromo-3-methylbut-3-ene (b) 4-bromo-3-methylpent-2-ene

(c) 2-bromo-3-methylpent-3-ene (d) 4-bromo-2,3-dimethylbut-2-er
8. The IUPAC name of the compound CH,CH=CHCH = CHC = CCH, is :
(a) Octa-4,6-dien-2-yne (b) Octa-2,4-dien-6-yne
(c) Oct-2-yne-4,6-diene (d) Oct-6-yne-2,4-diene
9. The molecular formula of the first member of the family of alkenynes and its name is given b.
the set:
(a) CzHz, alkene (b) CçH6, pent-1-en-3-yne
(c) GgHg, hex-1-en-5-yne (d) C4H4, butenyne
10. The correct IUPACname of H,C=CHCHCH,C=CH
|
CH3
(a) 3-methyl-1-hexen-5-yne (b) 4-methyl-5-hexen-1-yne
(c) 4-(ethenyl) 1-pentyne (d) 3-(2-propenyl) butene-1

IUPAC Nomenclature of Alcohols/Aldehydes/Ketones/Acids

1. Which of the following compounds does not have the molecular formula C&H1,0 ?
(a) 1-hexanol (b) 2-hexanol
(c) 3-methyl-2-pentanol (d) 3-methyl-3-pentanol (e) cyclohexanol
2. Which of the followingOH
compound have 4 carbon atom in the parent chain?
OH
(a) OH (b) /
CHO

(c) (d) -Br

3. what is the common nane of the following compound ?

ÇH,CHCH,COH