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Question

Answer Notes Marks


number
1 (a) (i) B box 2 1
The only correct answer is B because box 2 contains
two different particles in the same space that are
not chemically joined

A is not correct because box A shows an element


C is not correct because box C shows an element
D is not correct because box 4 shows a compound

(ii) C Boxes 1 and 3 1


The only correct answer is C because boxes 1 and 2
contain one type of atom only.
A is not correct because box 2 shows a mixture
B is not correct because box 2 shows a mixture
D is not correct because box 4 shows a compound

(iii) M1 (box 5 shows) two (different) elements ALLOW two (different) 2


types of atoms

REJECT mixture for M1

M2 (chemically) bonded (together) ALLOW (chemically)


combined/joined
(together)

M2 DEP on mention of
elements/atoms in M1

(b) (i) C number of protons 1

The only correct answer is B because the elements


in the periodic table are arranged in order of
proton number
A is not correct because elements are not arranged
in order of mass number
B is not correct because elements are not arranged
in order of the number of neutrons
D is not correct because elements are not arranged
in order of reactivity

(ii) A electrons in the outer shell 1

The only correct answer is A because elements in


the same group of the periodic table have the same
number of electrons in the outer shell.
B Is not the correct answer because elements in the
same period have the same number of shells
C elements in the same group do not have the same
number of neutrons
D is not the correct answer because elements in the
same group do not have the same number of
protons
Question
Answer Notes Marks
number
2 (a) (i) (pale/light) yellow 1

(ii) The correct answer is B 1 as bromine is the 1


only liquid at room temperature (20 °C)

A 0 is incorrect because bromine is a liquid at


room temperature (20 °C)

C 2 is incorrect because bromine is the only liquid


at room temperature (20 °C)

D 3 is incorrect because bromine is the only liquid


at room temperature (20 °C)

(iii) At2 1

(b) (i) explanation including 2

M1 oxidising agent is chlorine/Cl2

M2 because chlorine/Cl2 gains electron(s)/is ACCEPT because


reduced bromide ions/Br– lose
electrons/are oxidised
REJECT bromine ions

M2 DEP M1 correct or
missing
Question
Answer Notes Marks
number
2 (b) (ii) explanation containing three of following points 3

M1 bromine and chlorine react by gaining


electron/forming 1- or negative ion

M2 bromine atom larger (than chlorine atom) ALLOW bromine has


larger atomic radius
ALLOW bromine outer
(electron) shell further
from nucleus
ALLOW bromine atom
has more (electron)
shells (than chlorine)
M3 bromine (atom) has smaller/weaker attraction
(from nucleus) for (outer shell) electrons (than
chlorine) OWTTE

M4 so (bromine has) less tendency to gain


electron/form negative ion (so less reactive than
chlorine) OWTTE ALLOW reverse
argument for chlorine
in M2 M3 M4

(c) The correct answer is D K+ and Cl– because both 1


have electronic configuration of 2.8.8

A is not correct because Li+ does not have


electronic configuration of 2.8.8

B is not correct because F– does not have


electronic configuration of 2.8.8

C is not correct because neither Li+ nor F– have


electronic configuration of 2.8.8

(Total for Question 2 = 9)


Question
Answer Notes Marks
number
3 (a) (i) magnesium ALLOW Mg 1
cler

(ii) explanation including the following points 2


grad
M1 silver

M2 because it is the least reactive (of the metals) ALLOW it is very


unreactive

(b) explanation including the following points: 3


exp
M1 Method 1/ heating the metal oxide/lead(II)
oxide with carbon

M2 (because) lead is less reactive than iron (and ALLOW carbon is more
iron is obtained from iron oxide by carbon reactive than lead
extraction)
ACCEPT reverse
arguments

M3 2PbO + C 2Pb + CO2 ALLOW PbO + CO Pb


+ CO2
ALLOW PbO + C Pb
+CO
Question
Answer Notes Marks
number
3 (c) Explanation containing the following points 4
exp
Pure metal: REJECT molecules once
only
M1 (particles/ions/atoms are same size in a regular
arrangement so) layers can easily slide over each
other

Alloy:

M2 diagram of alloy structure showing minimum of


three layers with at least one different sized circle

M3 (having different sized particles/ions/atoms) ALLOW disrupts the


disrupts/breaks up regular arrangement OWTTE lattice / layers / rows
(of particles/ions
/atoms)

M4 so hard(er) for layers to slide over each other ALLOW layers cannot
slide over each other

IGNORE references to
strength/breaking of
forces/(metallic) bonds

Total for Q3 = 10
Question Answer Additional guidance Marks
number

M1

M2 M1 IGNORE

M3
M1

M2
ACCEPT
Question
Answer Additional guidance Marks
number

IGNORE

IGNORE

IGNORE

M1

M2
reactants
M3 products

Total 10
Question
Answer Notes Marks
number
6 (a) M1 mix / stir / add (silver nitrate and copper (II) IGNORE references 4
chloride) to heating

M2 filter (the silver chloride)

M3 wash with (deionised / distilled) water

M4 dry in a warm oven or dry with filter paper or


leave / allow to dry (on a windowsill) or dry in a
desiccator
If evaporation is
mentioned to form
crystals max = 1

(b) (i) M1 and M2 all points correctly plotted to ± half a Deduct 1 mark for 2
square every incorrect point.
1
(ii) M3 two straight lines of best fit which must meet
at
3 cm and 6 cm3

(iii) Any one from: 1

the precipitate wasn’t left to settle (for long ALLOW measured


enough) the height too early

the tube was on a slant

not enough / less than 3.0 cm3 of silver nitrate IGNORE references
added to human error
unqualified

(iv) all the copper [(II)] chloride has reacted ALLOW the silver 1
nitrate is in excess /
not all the silver
nitrate has reacted
Question
Answer Notes Marks
number

(c) (i) Any one from: 1

burette ALLOW measuring


cylinder

(volumetric) pipette REJECT beaker

(ii) Example calculation 3

M1 moles of coper chloride = (25 x 0.50) ÷ 1000 OR


0.0125 moles

M2 moles of silver chloride = 0.0250 ALLOW answer to M1


x2

M3 mass of silver chloride = 3.59 g ALLOW answer to M1


or M2 × 143.5
ALLOW 2 or more
significant figures

Correct answer of 3.59


g scores 3 marks

(iii) M1 (0.744 ÷ 0.850) × 100 2

M2 87.5(%) ALLOW 2 or more


significant figures
15 marks

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