[Versatie Waster Rey (241) Solved Chemistry 7 Year notespk.com ce of Knowledge | notespk.com WWW. Notespk com Excellence of Knowledge ANNUAL BOARD PAPERS 2022 notespk.com OF ._... ‘Www.notespk.com > Excellence of Knowledge _ ALL PUNJAB BOARD'S com motespk.com notespk, wavw. notes ok.com Excellence ci Knowiedge ! notespk.com Notesn o, 'www.notespk.com Excelience of KnowledgeVersatile Master Key (212) Solved Chemistry 1, Year FAISALABAD BOARD 2022 PAPER CHEMISTRY PART-I (G - 1) Time: 20 Min. (Objective Part) Marks: 17 Note:You have four choice for each objective type question as A, B, C and @ (i) (iii) (iv) (vy) (vi) D. The choice which you think is correct; fill that circle in front of that question number. Use marker or pen to fill the circles. Cutting or filling two or more circles will result in zero mark in that question. The molecules of CO, in dry ice form the: (a) Ionic crystals (b) Molecular crystals (c) Metallic crystals “ (d) Covalent crystals Density of ice is minimum at 4°C due to: (a) Empty spaces in structure of ice “ resp com (>) Tetrahedral shape of crystal of ice we (c) Large bond lengths (d) Large bond angles The temperature of a natural plasma is about: (a) 20000°CY(b) 1000°C (c) S000°C (d) 10000°C The deviation of a gas from ideal behaviour is maximum at: (a) 0°C and 2.0 atm (b) -10°C and 5 atm ¥ (c) 100°C and 2 atm (d) -10°C and 2 atm The technique of chromatography is useful in organic synthesis for: : notespk.com (a) Separation(b) Isolation (c) Purification(d) All these” Separating funnel s used in the technique-of analysis: (a) Crystallization (b) Filtration (c) Solvent extraction ~ (d) Sublimation (vii) Nickel has number of isotopes: notespk.com (a) 2 (@) 3 () 5Y "7 (viii) The number of moles of CO, , which contain 8.0g of oxygen: (ix) () (xi) (a) 0.25Y (b) 0.50 (c) 10 (d) 1.50 If rate equation of reaction 24+ 8- Product, is rate = k[4][B] and A is present in large excess, then order of reaction is: notespk.com (@y 1v (b) 2 () 3 (d) 4 The oxidation state of 'Mn' in KMnO, is: (a) +74 (b) +6 (c) +2 (d) +5 18g glucose dissolved in 90gm of 1,0 has relative lowering of vapour Pressure equal to: Notespk ¢[versatile Master Key (ha) Solved Chemistry ZL, Year 8 1 Ow 6 OF OH (xii) pH of human blood is: notesp.com (a) 7.35% — (b) 6.35 (ce) 5.35 (d) 4.35 (xiii) For a given process, the heat changes at constant pressure (9,) and at constant volume (4,) are related to each other as: Heb) He arava 4=% (xiv) Which of the hydrogen halides has the highest percentage ionic character? (a) HCL (bt) HBC (ce) HFY (d) HI (av) lonization energy for Mg Mg' +12 has «H =? (a) 738KJ mol! ¥ (b) 238 KJ molt (c) 448 KJ mot™ - (4) 138 KJ mol (xvi) Splitting of Spectral lines when atoms are subjected to strong electrical field is called: (a) Zeeman effect __ (b) Stark effect (c) Photoelectric effect (@ Compton. neem (xvii)De-Brogli equation is represented as: : (a) aoe (b) m= fae O mz -@ MY vy Section] —jotespk.com 2. Attempt any EIGHT short questions. (8 x 2 = 16) “(iJ Magnesium atom is twice heavier than that of carbon atom. Justify it. (ii) Many chemical reactions taking place in our.surrounding involve . the limiting reactants. Give examples. (iii) Molecular formula is multiple of empirical formula. Give an example, notespk.com (iv) How is chromatography classified on the basis of stationary phases? notespk.com * (v) Define sublimation. Give two examples (vi) Write names of four steps of crystallization. (vii) Calculate the value of general gas constant (R) sep baie of pressure and volume. “www.notes (viii) What is Joule-Thomson effect? Excellence ot Know (ix) Write quantitative definition of Charles's law.Soived Chemistry 1, Year yspk.com Versatile Master Key (x) State Le-Chatelicr’s principle, (xi) How does equilibrium constant tell about direetion of reaction? (xin) What is the effet of common ion on solubility? Give an example. 3. Attempt any EIGHT short questions, (8 x 2= 16) (i) Amorphous solid like glass is also super cooled liquid. Why? (ii) Cleavage of erystal is itself anisotropic behaviour. Jus ty it (ui) Water and ethanol can mix easily in all proportions. Give reason. oy) Ina cold winter the fish in garden ponds owe their lives to U-bonding. Explain. Notespk.com (vy) Detine Hunds rule with an example. (v1) Give out (wo detects,of Rutherford Model of an atom (ii) Difterentiate between Zeeman. and Stark effect. (viii) Define continuous spectrum with an example tive? tive properties? (ix), Why some of propetties are called colli (a) What are the conditions to obey col (xi) Define half life time (period) with an example (xii) How the surface area affect the rate of reaction? 4. Attempt any SIX short questions. (OX 2= 12) atomic radius cannot be determined precisely? (ii) How ionization energy changes in periodic table? (iii), What is coordinate covalent bond? Give one example. (iv) Why bond order of Helium molecule ts zero” (vy) Why enthalpy of neutralization is called enthalpy of formation of H,0? notespk.com (vi) Define heat capacity of a body. Give its mathematical expressions (vii) What is enthalpy of reaction? Give example. (viii) What is oxidation number? Give example. (ix) Write the product obtained during electrolysis of PbBr2 notespk. com om noresPh“ 5. (a) Describe combustion analysis. Also write formula to calculate percentage af carbon, hydrogen and oxygen. 2) State Mosley's law. What is its importance? 6.4 (a) 250cm" of hydrogen gas is cooled from 127°C to -27¢ é keeping the pressure constant. Calculate the new volume of the gas at low temperature. notespk.com (b) Explain the construction and working of fuel cells. 7. (a) Give the assumptions and postulates of VSEPR theory {b) Define and explain Hess's law of constagt heat summats eens sane ecsranrnnns sen eeenssessesecsccssiasiansinacabh NoteVersatile Maste [versatile Master Key (218') Soved Chemistry L, Year with an example. 8. (a) Write (b) notespk.com the structure of ice Why ice floats on water? The solubility product of Ag,CrO, is 2.6x107 at 25°C. Calculate the solubility of the compound. 9% (a) How lowering of vapour pressure as colligative property is used to find out molecular mass of solute? : ___(b) Explain any four ¢ Notespk. com of a catalyst, FAISALABAD BOARD 2022 _ PAPER CHEMISTRY PART-I (G - I!) Time: 20 Min, (Objective Part) Marks: 17 ‘ou have four choice for each objective type question as A, B, C and D. The choice which you think is correct; fill that circle in front of that question number. Use marker or pen to fill the circles, Cutting or filling two or more circles will result in zero mark in that question. ° () The volume occupied by 1.4g of N, at S.T.P. is: (a) 224d (by 22.4dm? (ec) 112d? (d) 112d" (ii), Many elements have fractional atomic masses. This is because: notespk.con) (a) masses of atom is itself fractional (b) Atomic masses are average masses of isobars (c) Atomic masses are average masses of isotopes (d) Atomic masses are average masses of isotopes proportional to their relative abundance. ¥ (iii) A technique in which a solute distribute itself in stationary phase and mobile phase is called: notespk.com (a) Sublimation (b) Solvent extraction (c) Chromato-graphy “ (d)_ None of these (iv) Coloured impurities appear during crystallization are removed by boiling the substance in the solvent with: (a) Silica gel - (b) Benzonic acid (c) Powdered anima charcoal¥ (d) CaCé, (v) Gases deviate from ideal behaviour at high pressure because: (a) . At high pressure, the gas molecule move in one direction only. (b) At high pressure, the gas molecules move in all direction.” (c) Athigh pressure, there are significant attractive forces (d) All these my oe a (vi) Value of Rat stp. WWW.notespk oo 1 Excellence of K..o. 2 EEEVersatile Master Key (216) Solved Chemistry 1, Year (a) R.21dm'aimK ‘mot! (b) 0.0821dm' atmK 'mol' (©) 0.0082tdm'atmK 'mot! (d) 0.00082 1dm'armK ‘mol ' (vii) London dispersion forces are present among the: (a) Molecules of liquid water notespk.com (b) Molecule of hydrogen chloride gas (c) Molecule of solid iodine ¥(d) ‘All these (vill) Lonic solids are characterized by: (a) Low melting point (b) Good conductors in solid state (c) High vapour pressure (d) Solubility in polar solvents” (ix) In the ground state of an atom, the electron is present: (a) In the nucleus (b) In the second shell (c) Nearest to the nucleus” (d)__Farthest from the nucleus (x) Quantum number value for 2p orbitals are: (a) a=2,0=1V (b) n=1,f=2 (c) m=l,l=0 (d) =2,b=0 (xi) Ethyne molecule have: notesp«. con (a) Three n bonds between carbon atom (b) There a bonds between atom (c) Onea and two 2 bonds between carbon atom ¥ (d) One n and two a bonds between carbon atom (xii) Bond order for He, is: notespk.com (a) 0V (b) 1 (c) 2 (d) 3 (xiii) For the reaction NaOH + HCI -» NaCl+H,0 the change in enthalpy is: notespk.cor (a) Heat of reaction (b) Heat 6f formation (c) Heat of neutralization ¥ (d) Heat of combustion (xiv) pH of 10% mol dm” of HClis: Nnotespk co... (a) 1 (b) 2 (c) 3 (d) 44% (xv) 18gram glucose is dissolved in 90gram of water. The relative Jowering of vapour pressure equal to: ~— notespk.com 1 1 a) zg =v (a) 5 (b) 5.1 (c) 51 (d) 6 (xvi) Oxidation number of 'Mn'in KMn0, is: (a) 3 (b) 5 (c) 7¥ (d) 9 (xvii)The catalytic activity of enzyme is greatly enhanced by the presence of: teen com (a) Inhibitors nee (b)- Coenzymes (c) Activators ~ (d) Coenzymes & activators EEESection I com 2 Attempt any EIGHT short questions, nevese (8X 2=16) (i) Define isotopes: Write isotopes of carbon. (ii) Mg atom is twice heavier than carbon atom. Justify. (iii) What is macro molecule? Give example. : (iv) Define partition chromatography. with example. (vy) State distribution law, wiww.rotespk.com (vi) How fluted filter paper is prepared? Nene of Knowiedae (vii) State Charles law. Write its mathematical form. (viii)Define criticat temperature and critical Pressure of a substance. (ix) Differentiate between natural and artificial plasma. (x) Differentiate between reversible and irreversible reactions. (xi) Define Buffer capacity. notespk.com (xii) What is the effect of common ion on solubility? 3. Attempt any EIGHT short questions. (8 x 2 = 16) (i) Why is boiling point of H,0 greater than that of HF? (ii) What are London forces? Give an example. (iii) Define lattice energy. Give one example. (iv) What are molecular solids? What type of interactions hold them together? (v) Define spectrum. Give its two types. (vi) The e/m values of positive rays for different gases are different but those for cathode rays, the e/m values are same. Why? notespk.com (vii) How are the neutrons involved .in the conversion of 3CH into «an fwww.ncte pk.com , Excellence 0° r nowledg (viii) What are x-rays? How are they produced? (ix) Aqueous solution of CuSO, is acidic in nature. Give the reason. (x) Why are NaCl and KNO, used to lower the melting point of ice? (xi) What are Pseudo first order reactions? Give one example (xii) How does the surface area of reactants affect the rate of reaction’ Give un example. 4, Attempt any SIX short questions. (6*2=12) (i) How does the electronegativity difference decide the nature of ionic bond? (ii) Why an ionic bond is stronger than covalent bond? (iii) Why the atomic radii increase down the group?Versatile Master Key (218) Solved Chemistry 1. Year| (iv) How the bond length is affected by hybridization? (v) What is state and state function? (vi), What do you mean by internal energy of chemical system? (vii) Define surroundings and give examples. pk.com (viii) Write the cathodic reaction in fuel cells. (ix) Give the structure of anode and cathode in lead acid battery ar ets Write various steps to calculate the empirical formula of a compound. (b) What is Plank's Quantum Theory? Write its main points. 6. (a) 250cm’ of the sample of hydrogen effuses four times as rapidly as 250cm° of an unknown gas. Calculate the molar mass of unknown gas. notespk.con” | (b) Describe fuel cells. Give theif uses. 7. {a) Write postulates of M.O.T. and explain oxygen molecule by this theory. Notespk.com (b) Explain first law of thermodynamics. 8. (a) What are liquid crystals? Give their uses (b) The solubility of CaF, in water at 25°C is found to be 2.05x10 moldm®. What is the value of A, at this temperature? notespk.com 9. (a) Give applications of elevation of boiling point and depression of freezing point. (>) Explain rat e determining step in detail .o™ LAHORE BOARD 2022 eo? ae PAPER CHEMISTRY PART-I Time: 20 Min. (Objective Part) Marks: 17 Note:You have four choice for each objective type question as A, B, C and D. The choice which you, think is correct; fill that circh in front of that question number. Use marker or pen to fill the circlem Cutting or filling two or more circles will result in zero mark in that question. (i) According to VSEPR theory, the shape of PH, moleucle is: (a) Trigonal pyramidal” (b) Tetragonal (c) Linear yatesnk om (d) Trigonal planer (ii) When water freezes at 0°C, its density decreases due to: (a) Cubic structure of ice (b) Empty spaces present in structure of ice¥ (c) Change of bond lengths (d) Change of bond angles en ey notes!—_ Versatile Master Key (219) Solved Chemistry 1, Year (ii) An excess of silver nitrate ij aqueous barium chloride an filtration. What are main ions ij (a) 4g” and NO; only (b) 4g* and Ba** and NO, (©) Ba** and NO; only (4) Ba and NO; and C/ iv) 1 gram formula of NaC is equal to: notespk.com (a) 58.5g¥ (b) 23g (c) 355g (d) 12g os) The unit of rate constant is the same as that of rate of reaction in: Notespk.com (a) First order reaction (b) “Second order reaction (©) Zero order reaction” (d)_ Third order reaction (vi) Balmer series in hydrogen spectrum lies in the region: (a) Ultraviolet (b) Visible” (c) . Infrared (qd) Microwave (vii) If absolute temperature of a gas is doubled and the pressure is reduced to one half, the volume of the gas will: (a) Remain unchanged {b) Increase four times” (c) Reduce to 1/4 (d) Be dotibled (viii) Many elements have fractional atomic masses, thi: 's because (a) The mass of-an atom is itself fractional (b) Atomic masses are average masses of isobars © (ce). Atomic masses are averiige masses of isotopes (d) Atomic masses are average misses of isotopes proportional to their relative abundance” (ix) In endothermic reactions, the heat content of-the: (a) Products is more than that of reactantsY (b) Reactants is more than that of products (c) Surraunding increases notespk.com (d) Reactants and prodycts are equal (x) A thermometer used in Landsberger's method can read upto: iM aqueous form is added to 'd precipitate is removed by in the filtrate: (a) O1K , (6) 0.01F (©) 0.01 KY (d) 0.4) °C (xi) Which of the following species has unpaired ee antibonding molecular orbitals: notespk.co (a) OF (b) NP (c) B: @ (xii) Density of an ideal gas can be calculated by the formula: PM (a) F=RT yy 425. iy 4 dae (xiii) If a salt bridge is not used between two half ceils, then the voltage: a eeVersatile Master Key (220) _Solved Chemistry 1, Year (a) Decreases rapidly (b) Decreases slowly (c) Does not change (d) Drops to zeroY (xiv) Orbitals having same energy are called: (a) Hybrid orbitals (b), Valence orbftals (c) Degenerate orbitals” (d)_ d-orbitals (xv) Which of the following compounds do not show f sublimation? comp notspe: cAW Process o (a) Ammonium chloride¥ — (b)_odine (c) Naphthalene (d) Carbon tetra chloride (xvi) In the monoclinic crystal system, bond axes are: (@) a=b=c (b) a=b¥cY (0) atb=c (i) azbec (xvii) The pH of mixture of CH,COONa and CH,COOH is: (a) 7 (bt) >7 @ @ 1 tnd notespk.com Section I - notespk.com™ . Attempt any EIGHT short questions, (8 x 2 = 16) (i) How is the law of conservation of mass obeyed during stoichiometric calculations? notespk.com (ii) Why 4, and CO have same number of electrons, protons and ___ Reutrons? Justify. notespk.com (iii) Define mole. Calculate the gram atoms (moles) in 0.1 g of sodium: (iv) Draw the beautiful diagram of sublimation process. (v) Write down the uses of chromatography. (vi) What is the physical meaning of R? notespk.com (vii) Prove Boyle's law in the light of K.M.T. . (viii) What are the two characteristics of plasma? (ix) Write down the quantitative statement of Charles's law. (x) Define heat of solution. notespk.com (xi) How will you justify that the lowering of vapour pressure is a colligative property? notespk.com (xii) Differentiate between ideal and non-ideal solutions. 3. Attempt any EIGHT short questions. - (8x2=16) (i) Ethyl alcohol is soluble in water. Why? (ii) Explain H-bonding in deoxyribonueleic acid (DNA). (iii) What do you know about anisotropy, explain with example? (iv) What is allotropy, give one example? (v) Write two nuclear reactions for production of gamma (7) radiations and A -particle.[Versatile Master Rey (221) Solved Chemistry 4, Year| (vi) Write defect of Rutherford Atomic Model. (vii) Define Heisenberg's uncertainty principle and write its mathematical equation. notespk.com (viii) Write name of different quantum numbers. (ix) Write Henderson's equation for acidic and basic buffer. (x) Why do we need buffer solution? (xi) Explain specific rate constant briefly. (xii) What is zero order reaction, give one example? 4, Attempt any SIX short questions. (6% 2=12) (i) Define bond order and give one example. (ii) Draw diagram for formation of bonding and antibonding molecular orbitals for H, molecule. (iii) Define sigma bond and pi-bond. notespk.com (iv) Define atomic orbital hybridization. (v) What is first law. of thermodynamics, give its mathematical equation? (vi) Define enthalpy of combustion AH? . (vii) How anodized aluminium is prepared in an electrolytic cell? notespk.com notespk.com (viii)Draw a diagram of standard hydrogeh electrode (SHE). (ix) Define electrochemical series. 5. (a) NH, gas can be produced by heating together ni Ce and Ca(OH),. Ifa mixture containing 100g of each splid is heated then calculate the number of grams of NH, produced. 2NH,CE +Ca(OH), — CaCt, +2NH,+2H,O (b) Explain isomorphism with examples. 6. (a) Give postulates of kinetic molecular theory. (b). Derive an expression to determine radius of an orbit using Bohr's model. : 7. (a) What is sp? hybridization, how it explains structure of ethene? (b) What is Hess's law? Explain by giving two examples. 8. (a) Calculate the pH of a buffer solution in which 0.11 molar CH,COOH and 0.09 molar acetic acid solutions are present. K, for the CH,COOH is 1.85x10°. (b) Define half life period. How order of reaction can be determined by knowing half life of a reaction? 9. (a) What are colligative properties of solutions? Explain elevation of boiling points. notespk.com CeeeeneeeeenenVersatile Master Key (222) Solved Chemistry 1, Year (b) Describe the construction and working of standard hydrogen electrode. GUJRANWALA BOARD 2022 PAPER CHEMISTRY PART-I (G - !) Time: 20 Min, (Objective Part) Marks: 17 Note: You have four choice for each objective type question as A, B, C and ai) (vy) (vip (vii) D. The choice which you think is correct; fill that circle in front of that question number. Use marker or pen to fill the circles. Cutting or filling two or more circles will result in zero mark in that question. Amorphous solids (a) have sharp melting points (b) undergo clean cleavage when cut with knife (c) have perfect arrangement of atoms ~ (d) cam possess small regions of orderly arrangement of notesnk.com atoms ¥ notespk.com BF, shows. hybridization. ‘ (@) pv (b) (©) Spd (d) sp’d VSEPR theory was developed by (a) Sidgwick and Powell“ (b) . Sidgwick and Nylholm (c) Powell and Gillespie (d) Nylholm and Gillespie An aqueous solution of ethanol in water may have vapour pressure: notespk.com (a) equal to that of water (b) | equal to that of ethanol (c) more than that of water “(d),_ less than that of water The mass of one mole of electrons is: (a) 1.008mg (b) 0.55mgv(c) 0.184mg (d) 1.673 mg An excess of aqueous silver nitrate is added to aqueous barium chloride and precipitate is removed by filtration. ‘What are main ions in the filtrate? = notespk:com (a) Ag’ and NO™,only (b) Ag’ and Ba" and NO only ¥ (c) Ba" and NO only (a) Ba"? and NO°, and CI If the salt bridge is not used between two half cells, then the voltage (a) decreases rapidly (b) decreases slowly (c) does not change. (d) drops to zero (viii) The deviation of a gas from ideal behaviour is maximum at: (a) -10°C and 5.0 atmy’(b) -10°C and 2.0 atm (c) 100°C and 2.0 atm (d) 0°C and 2.0 atm SSVersatile Master Key (223) Solved Chemistry 1, Year (ix) is not used as drying agent in a desiccator. (a) Water (b) Cac, v (c) silica gel (4) phosphorus pentoxide (x) The unit of the rate constant is the same as that of the rate of reaction order. (a) First (b) second (ec) , zerov (a) third (xi) *__ is a pseudo solid. (a) CaF, (b) glass“ (c) NacI no (a) sugar (xii) Solvent extraction is controlled by. OF Spy (a) distribution law = = ¥ (6) Newton's law °°m (c) law of mass action (@)_ Graham's law (xiii) A limiting reactant is the one which (a) is taken in lessér quantity in gm as compared to other reactants (b) is taken in lesser quantity in volume as compared to the other reactants (c) _ gives the maximum amount of the product which is required (da) gives the minimum amount of the product under consideration ¥ notespk.com (xiv) In endothermic reactions, the heat content of the a (a) products is more than that of reactants (b) reactants is more than that of products (c) surroundings increases notespk.com (d) reactants and products is equal (xv) Orbitals having same energy are called 5 (a) hybrid orbitals (b) valence orbitals (c) degenerate orbitals V (d) d-orbitals (xvi) When 6d orbital is completed, the entering electron goes into . \ (a) 7£ (b) 7sv (c) Tp (d) 74 (xvii)Equal masses of methane and oxygen are mixed in an empty container at 25° The fraction of total pressure exerted by oxygen is. - (a) 13% ~~ (b) 89 (c) 1/9 (4) 16/17 2. Attempt any EIGHT short questions. (8 x 2=16) (i) What is molecular ion? Write down formulas of any two of these 6 lons, SEU UU EEEEEEESEEEEEEnee[Versatile Master Key "~~" 234 Solved Chemistry 1, Year (ii) Differentiate between empirival and molecular formula. (iit) Mg (Magnesium) etom ix twice heavier than C (Carbon) atom. Justify, (iv) How crystals are dried in vacuum desiccator? (vy) What is 8, vatue? Why does it has no units? com (vi) What is partition chromatography? “tester (vit) Convert 40 °C into Fahrenheit scale. (viii) Define absolute zero temperature. (ix) "Water vapours do not behave ideally at 273 K". Explain it < (x) What is Le-chatelier's principle? 50) (xi) Define solubility product. noreshk oge [2,0 Jar] ar 8G noe (xii) Prove that & = ~THay xeon 3. Attempt any EIGHT short questions. (8 x2 = 16) (i) Boiling needs a constant supply of heat. Give reason. (ii) The vapour pressures of solids are far less than those of liquids. Why? - (ii) Define symmetry. Give its elements. notespk.com (iv) What are ionic solids? Give two examples. (v)_ Whichever gas is used in the discharge tube, the nature of cathode Tays remains the same. Why? ‘ (vi) What is the origin of line spectrum? (vii) State Pauli's exclusion principle. (viii) Write down names of two spectral series alongwith their regions. (ix) The concentration in terms of molality is independent of temperature but molarity depends upon temperature. Why? (x) Define hydrolysis. Give an example. ‘notespk.com (xi) What is activated complex? (xii) What is half-life period? Give an example. zi 4. Attempt any SIX short questions. (6x 2=12) (i) Write Lewis structures of (i) CCI, (ii) HCN (ii) Why Noble gases don't form chemical bonds? (iii) O, shows paramagnetic behaviour; why? (iv) Why CH, does not form co-ordinate covalent bond but -H,0 can form? i (v) Is it true that non spontaneous process never happens in the universe? (vi) What does the symbol AH? denote? Define this quantity. (vii) Burning of candle is spontaneous process; brief it? —_—_—_—_————— aiyield. How theoretical and Practica} yield can be calculated? notespk.co (b) Define quantum numbers. Explain azimuthal quantum number in detail 6 (a) Calculate the density of CH,(g) at 0°C and 1 atm pressure What happens to thedensity if the pressure is increased to 2 atm at 0°C? notespk.com plain the construction of lead accumulator. Give its discharging process. (a) Draw the molecular orbital diagram for O, and explain its paramagnetic behaviour. (b) How the enthalpy of a reaction can be measured by using glass calorimeter? 8. (a) What are London forces? Write down factors affecting them. (b) Calculate the pH of a buffer solution in which 0.11 molar CH,COONa and 0.09 molar acetic acid solution are present. K, for CH,COOH is 185x105. 9. (a) Differentiate between Note i) Ideal and non-ideal solutions. ‘SDA, Con, ii) Hydration and hydrolysis (b) Define catalysis. Explain its types with suitable examples. GUJRANWALA BOARD 2022 PAPER CHEMISTRY PART-I (G - Il) Time: 20 Min. (Objective Part) Marks: 17 Note:You have four choice for each objective type question as A, B, C and D. The choiée which you think is correct; fill that circle in front of that question number. Use marker or pen to fill the circles. Cutting or filling two or more circles will result in zero mark in that question. (i) The pH of 10° mol.dm®” of an aqueous solution of H,S0, (b) is__- notespk.com™ (a) 15 (b) 2.0 (c) 3.0 (@) 2.74 (ii) ___ Substance is used as decolourizing agent in crystallization process. notespk.co (a) silica gel (b) animal charcoal ¥ (c) CaCl, (d) #,SO, EE(iii) Bohr model of atom is contradicted by: (a) planks quantum theory (b) dual nature of matter (©) Heisenberg's uncertainty principle “ (ad) allofthese * potesp.com (iv) When water freezes at 0°C its density decreases due to___. (a) cubic structure of ice (b) , changes bond length (c) empty spaces present in structure of ice ¥ (d) changes bond angles notespk.com (v) The largest number of molecules are present in. (a) 3.6gof H,0 v (b) 4.8 gof C,H,OH (c) 2.8g0fCO - @) 54g of NO, (vi) An aqueous solution of ethanol in water may have vapour pressure___. notespk.cor (a) equal to that of water (b) more than that of water ¥ (c) equal to that of ethanol (d) _ less than that of water (vii) is a pseudo solid. notespk.com (a) glass¥ (b) Ca (c) NaCl = (d)_ “HCI (viii) Orbitals having same energy are called__. (a) degenerate orbitals“ © (b) Sand P orbitals (c) molecular orbitals (d) valence orbitals (ix) In Sp’ hybrid orbital "S" character is___. (a) 2% (b) 50% (©) 75% (d) 100% (x) Number of molecules in one dm of water is close to___. 6.02 * 3 « 12.04 @ mar age 18 o © FgrXt” (@) 586x6.02x10" Vv (xi) Solvent extraction is an equilibrium process and is controlled by. notespk- (a) law of mass action (b) amount of solvent used (c) distribution law Vv (d) amount of solute (xii) If the rate equation of a reaction 2 A+B— products is, rate = K[A]’[8] and A is present lin large excess then order of reaction is__. (@) iv (b) 2 () 3 d) 4 (xiii) The nfmber of bonds in nitrogen molecule is (a) one 9 and one 7- (b) one 9 and two 7 ¥Versatile Master Key ‘Solved Chemistry 1, Ye (c) three sigma only (d) two % and one 7 (xiv) How many subatomic particles are thought to exist in an atom. notespk.com (a) 3 (b) 20 (c) 50 (d) 100V (xv) Stronger the oxidizing agent greater is the___. (a). redox potential (b) EMF. of cell (c) oxidation potential (d) reduction potential ¥ (xvi) The molar volume of CO, is maximum at__. (a) STP (b) 127°C and 1 atm ¥ (©) O°Cand2atm (d) 273°C and 2 atm (xvii)For the reaction NaOH + HCI NaCl+H,0 the enthalpy change is called: notespk.com (a) _ heat of reaction (b) heat of formation (c) heat of neutralization “ (d) heat of combustion SectionT — notespk.com 2. Attempt any EIGHT short questions. (8 x2 = 16) (i) What is mass spectrum? (ii) One mole of 4,50, should completely réact with two moles of NaOH. How does Avogadro's number help to explain it? (iii) Define limiting reactant. Give an example. (iv) Write down the names of any four major steps involved in crystallization. www.notespK.co! (v) What is ether extraction? Excellence of Know! (vi) What is paper chromatography? Name its two types. (vii) What is mean square velocity? (viii) Where is plasma found? (ix) Derive Charle's law from kinetic molecular theory of gases. (x) What is common ion effect? Give an example. (xi) Write down’ the Henderson's equation to determine the pH of a buffer solution. notespk.com (xii) Define solubility product, Give an example. 3. Attempt any EIGHT short questions. (8 x2 = 16) (i) lonic crystals are highly brittle. Justify it. (ii). Cleavage of the crystals is itself anisotropic behaviour. Justify it. (iii) Diamond is hard and an electrical insulator. Justify it. RS UU EEE EEE EERIEVersatile Master Key (228) * Solved Chemistry 1, Year (iv) Boiling needs a constant supply of heat. Justify it. “ “ (y) How the Cu can be converted into Zt ov » 0 pk © (vi) What is Zeeman effect? (vii) Define Moseley's law and give its relationship/equation. (viii) Define Pauli's exclusion principle. (ix) Define parts per million (PPM) and give its expression. (%)_ Define critical solution temperature and give an example. (x1) What is catalytic poisoning? Give an example. . (xii) Define catalysis and give two examples of catalysed reactions. 4. Attempt any SIX short quéstions. Nota (6 ¥ 2= 12) (i) Why the molecules of BF, are triangular planar? “SPk.co, (ii) Define covalent radius. Give one example. (iii) Define shielding effect. How it varies across the period? (iv) Define coordinate covalent bond. Give one example. (vy) Differentiate between endothermic and exothermic reaction. (vi) What is lattice energy? Give one example. (vii) Enthalpy of neutralization of a strong acid and a base is always - -5.75Keal mole” . Why? (viii)Calculate the oxidation number of chromium in the following compounds: a) Cr, ——b) Cr, notespk.co™ (ix) Define oxidation state. Give example. 7 s. (a) Explain the concept of limiting reactant with a suitable example. Also write down steps to identify a limiting reactant. * (b) Define quantum numbers and explain in detail azimuthal quantum number. notespk.com 6. (a) 250cm’*of the sample of hydrogen effuses four times as rapidly as 250cm’ of an unknown gas. Calculate the molar mass of unknown gas. (b) Discuss any two industrial importance of electrolytic process. 7. (a) Explain the geometry of NH, using hybridization. (b) State and explain Hess's.law of constant heat summation with an example. notesp< 8. (a) Brief about structure of ice. (b) Calculate the pH of buffer solution in which 6.1LM rer ge eeepc emmaVersatile Master Fey (238) Soned chemistry 4, Year] CH,COONa and 0.09 M CH,COOH solutions are present while ka for CH,COOH is 185-10 9. (a) What is solubility curve? Discuss its types with examples. (b) What in catalysis? Give any three characteristics of catalyst with examples. notespk.com RAWALPINDI BOARD 2022 ; PAPER CHEMISTRY PART-I (G -1) Time: 20 Min. (Objective Part) Marks: 17 Note:You have four choice for each objective type question as A, B, C and D. The choice which you think is correct; fill that circle in front of that question number. Use marker or pen to fill the circles. Cutting or filling two or more circles will result in zero mark in that question. (i) Quantum number value for 2S orbitals are: (a) n=2,1 (b) n=l, 72 (c) n=l, 0 (d) n=2,-0 Vv (ii) Which of the following species has unpaired electrons in the antibonding bonding molecular orbitals? a 4.c ow @ 8 ow Mv | &O WF (iii), Geometry:of 1,0 on the basis of VSEPR theory. (a) Linear (b) Trigonal planer (c) Tetrahedral (d) Bent ¥ (iv) The net heat change in a chemical reaction is same, whether it is brought about in two or different ways in one or several steps. It is known as. (a) Henry law “ (b) Joul's law (c) Hess's law ¥ (d) Law of conservation of energy (v) For which system, does the equilibrium constant Ice has no units. (a) N,+3H,—==2NH, (b) 4H, +1, 2H v —_— a (c) 2No,===N,O, — -(d) None of these eS yy (vi) Colligative properties are the properties of: On, (a) Dil solution which behave as nearly ideal solutions V (b) Concentrated solution which behave as nearly non ideal solution (c) Both (A) and (B) (d) None of these (vii) If the salt bridge is not used between half cells, then the voltage. (a) Decrease rapidly (b) Decrease slowlyVersstie Master Rey (230) Solved Chemistry i Year] (c) Does not change (d) Drops to Zero ¥ (viii) If the equation at reaction A is present in large excess, then order of reaction is: notespk.com (a) iv (b) (c) 3 (d) 4 (ix) One mole of So, contain: (a) 6,02x10" atoms of oxygen (b) 1.81x10* molecule of So, (©) 6.0210” atoms of Sulphur V (d) 4 gram atoms of So, A limiting reactant is one which is: (a) Taken is small amount in gram as compared to other 2, Spy £0, ny z reactant notespk.com (b) Taken in lesser amount in volume as compared to other reactant. notesok.com (c) Give the maximum amount of product (d) Give minimum amount of product ¥ A filtration process could be very time consuming if it were not aided by suction which is developed: (a) If the paper covers the funnel up to the circumference ¥ (b) If the paper has got small sized pores in it (c) If the stem at the funnel in large so that it dips'into the filtrate : (d) If the paper fits tightly (xii) Solvent extraction is an equilibrium process and is controlled snteapk.com& "otespk com by. espk.com (a) Law of Mass action (b) Amount of solvent used (c) Partition law ¥ (d) Amount of solute (xiii) Pressure remain constant, at which temperature the volume of gas will becom® twice of what it is at 0°C, (a) 546°C Y “(b) 200°C (c) 546K (d) /273K (xiv) The order of rate of diffusion of gases NH,,5o,,Cl, and Co, is: notespk.com (a) NH,>So,>Cl,>Co, (b) NH,>Co, >So, >Cl, ¥ (c) Ch>So,>Co,>NH, — (d)’ NH, >Co, > Cl, > So, (xv) 1n order to raise the building point at H.O up to 110°C, the external pressure should be. (a) Between 760 torr and 1200 torr “ (b) Between 200 torr and 760 torr (c) 576 torr (d) At any pressure[Versatile Master Key (331. Sowved Chemistry 3, Year] (xvi) Amorphous solids: (a) Have shape melting point (b) Under go clean cleavage when cut with knife (c) Have perfect arrangement of atoms (a) Have small region of orderly arrangement of atom ~ (xvii) The value of charge on electron is: notespk.com (a) 2.602x10'" Coulombs — (b) 1.60210" Coulombs (ce) 1.6023x10'" Coulombs ¥ (d) 1.602x10 " Kg ae al Marks: 68 Section —_yatesd*-°% 2. Attempt any EIGHT short questions. (8 x 2 = 16) Q) How molecular ions are formed? Give example. (ii) Define Mole and Avogadro's Number. (iti) What is percentage yield? Write its formula. (iv) - Write down two phases of chromatography. ¢ (¥) Define solvent extraction. ° (vi) Why fluted filter paper in more useful than ordinary filter paper for filtration? ; notespk.com (vii) Convert 30° centigrade into Fahrenheit scale. (viii) What is Joule Thomson effect? (ix) Write down any two applications of plasma. (x) Calculate PH of 10“ moledm™ of HCI solution. (xi) What are the optimum conditions of tempe: huge and pressure to get maximum yield of ammonia? notespr. N, +3Hy == 2.NH, + 92.46Kj (xii) State Le-chatelier’s principle. notespk.com 3. Attempt any EIGHT short questions. (8 x 2 = 16) (i) What do you mean by Habit of a crystal? Give an example. (ii) Define molar heat of vaporization and Molar heat of sublimation. (iii) Boiling points of halogens increase down the group. Give the reason. notespk.com (iv) Ide floats on water. Give the reason. (v) What do you mean by Line Spectrum? (vi), What is n + [ nule? Give an example. (vii) Why is the elm value for positive rays obtained from hydrogen gas Also 1836 times less than that of cathode rays? (viii)State Heisen berg's Uncertainty Principle. write its mathematicalVersatile Master Key (232) Solved Chemistry 2, Year] form. « (ix) What are conjugate solutions? Give an example. o (x) What are hydrates? How are they formed? ag“ (xi) What is auto-catalysis? Give an example. or’ (xii) A catalyst is specific in its action. Give one example. 4, Attempt any SIX short questions. (6x 2=12) (i) Bond distance is the compromised distance between two atoms. (ii) A bonds are more diffused than sigma bonds. Justify (ii) What are bonding and antibonding molecular orbitals? Give examples, notespk "7 (iv) Define non polar covalent bond. Give examples. (v)_ Define a spontaneous reaction. (vi) Why the temperature of the system changes during exothermic and endothermic reactions. (vii) Burning of Candle is a sportaneous process. Justify it (viii)A salt bridge maintains the electrical neutrality in the cell. Give reasons, notespk.com (ix) Write anodic reaction in alkaline battery. 5. (a) What is the difference between actual yield and theoretical yield. Why actual yield is less than the theoretical yield. (b) What is spectrum? Explain Atomic Emission and Atomic 6 absorption spectrum. 6. (a) 250cm’ of hydrogen is cooled from 127°C to 27° by S maintaining the pressure constant. Calculate the new volume of the gas at this low temperature. otecnk com (b) Define electrochemical series. Discuss calculation of the voltage of cell, giving one example. 7. (a) Explain structure of water and boron trifluoride by hybridization. f b) Explain measurement of eiialpy of a reaction by glass calorilmeter. How is the vapour pressure of a liquid measured using Manometric method? 'b) The solubility of PbF, at 25°C is 0.64gdm” . Calculate Ksp of POF,. notespk.com 9. (a) Explain Beckmann method to determine depression of ‘ Freezing point. (b) How order of reaction can be measured by half life method. notespk sgom = ———Versatile Master Key (233°) Solved Chemistry 1, Year RAWALPINDI BOARD 2022 PAPER CHEMISTRY PART-1 (G - II) Time: 20 Min. (Objective Part) Marks: 17 Note:You have four choice foreach objective type question as A, B, C and D. The choice which you think is correct; fill that circle in front of that question number. Use marker or pen to fill the circles. Cutting or Filling two or more circles will result in zero mark in that question. (i) Which of the following Statements is not correct about galvanic cell? Vy, (a) Reduction occurs at cathode ” “on Ney (b) Anode is negatively charged Ce SESp ‘ (©) Cathode is positively charged Hog) Cop: (d) Reduction occurs at anode if, 9 (ii) Oxidation of nitric oxide with ozone has been shown to b (a) First order reaction ¥ —(b)_ Pseudo first order reaction (c) Second order reaction (d) Third order reaction (iii) A.solution of glucose is 10%W/v. The volume in which Ig mole of it is dissolved will be: “(ay 90cm’ —(b)-200em?—(c) 1.8m’ V (dd) Adm (iv) The aqueous solution of BiCI, is cloudy. The cloudness of solution can be vanished by: (a) Addition of BiCl, (b) Addition of H,0 (c) Addition of HCI rote spy (d) Addition‘of both BiCl, and H,O ¥ com (v) 22g of CO, sample has: (a) %mole of atoms . (b) 1 mole of atoms ¥ (c) 1.5 moles of O atoms —— (d) 6.02 x1023 molecules of CO, teSpk.com (vi) Which one of the following maybe employed as drying agent in a desiccator? co™ (a) POY ese (b). Animal charcoal (c) KMno, * (d) NH,CI (vii) In endothermic reactions, the heat contents of: (a) Products is more than that of reactants v (b) Reactants is more than that of products (c) Both (A) and (B) 70teSDk com (a) Reactants and products are equal —__(viii) The volume occupied by 16g of O, at S.T.P is: (a) 22.4dm* (b) 2.24dm' (c) 11.2dm' V (d) (ix) According to VSEPR theory, the shape of SO,.molecule is. (a) Trigonal pyramidal (b) Bent or angular (c) Triangular planer ¥ (d) Tetrahedral (xX) A filtration process could be very time consuming if were not aided by a gentle suction which is developed. (a) If the paper covers the funnel up to its circumference V (b) Ifthe paper has got small sized pores in it (c) Ufthe stem of the funnel is large so that it dips into the filtrate {d) Ifthe paper fits tightly spy ¢ (xi) When 6d orbital is complete, the entering electron goes into. (a) 7s Vv" (b) 7p () 7f (d) 7d (aii) Which one of the following hydrocarbons has shortest C-C bond length? notespk.com (a) Ethyne v (b) Ethene (c) Ethane (d) Benzene (xiii) NH, shows a maximum boiling point among the hydrides of € Vth group elements due to: & (a) Enhanced electronegative character of nitrogen ¥ % (b) Pyramidal structure of NH, 1.A2dm? SO k cam NOt a © (c) Lone - pairs of electrons present on nitrogen & (d) Very small size of nitrogen notespk.com (xiv) If the absolute temperature of a gas is doubled and the pressure is reduced to one half, the volume of the gas will. (a) Remains unchanged _(b) Reduced tol/4 (c) Increases four times“ (d) Be doubled (xv) Splitting of spectral lines when atoms, are subjected to strong magnetic field is called: {a) Zeeman effect ¥ (b) Stark effect (c) Photoelectric effect (d) Compton effect (xvi) Gases deviate from ideal behaviour at high pressure. Which of the following is correct for non-ideality? (a) Athigh pressure, the gas molecules move in one direction (b) At high pressure, the intermolecular attractions only becomes significant ¥ (c) Athigh pressure, the collisions between the gas molecules are (d) At high pressure, the volume of the gas becomes much CeeVersatile Master Key (235°) Solved Chemistry 4, Year increased insignificant notespk.com (xvit) Dipote - dipole forces are present among the. (a) Atoms of helium gas (b) Molecules of CCI, (©) Molecules of solid 4, . (d)- Molecules of HCI ¥ notespk.com Attempt any EIGHT short questions. (8 x 2 = 16) (1) Write the formulas to determine the percentage of carbon and hydrogen in combustion analysis, Gi) How the molecular and empirical formulas are related to each other? notespk.com (it) Define gram molecule by giving two examples. (iv) Define sublimation and give examples. Differentiate between. adsorption and partition chromatography. (w) Define qualitative and quantitative analysis: (vil) Detine Avogadro's Law and give two examples. (viiOne dm? of H, and O, have different masses but occupy same volumes. Give reason (ix) Why the sum of mole fraction: always equal to unily?) (x) Define law of mass action and give the equilibrium constant ww) expression. notespk.com (xi) Write the formula to calculate the percentage ionization of weak acids. notespk.com (xdi) Define Lowry Bronsted acid base concept. 3. “Attempt any EIGHT short questions, (8 X2= 16) () Ina very cold winter fish in the garden ponds owe their lives due to H-bonding. Justify. (ii) Water and ethanol can mix easily and in all proportions. Justify. (iii) Cleavage of the crystals is itself anisotropic behaviour. Justify: (iv) London dispersion forces are weaker than n dipole dipole forces. Why? notesp! (vy) Differentiate between frequency and wave number. (vi) Write two importance of Mosely's law. (vii) What is Zeeman effect? (viii) Write down any two postulates of plank's quantum theory. (ix) Differentiate between Molarity and Motality. (x). What is ‘fractional crystalization?Versatile Master Key (236) Solved Chemistry 1, Year (xi) The radio active decay is always first order reaction. Give reason. (xii) Differentiate between homogeneous and Heterogeneous catalysis. 4. Attempt any SIX short questions. 0tes, (6 * 2 = 12) (i) Name the factors influencing the electron affinity. "2 (i) Define orbital hybridization and name its types. (iii) Explain bond order for Helium and why it does nét exist as Hez molecule? notespk.com (iv) Tonization energy decreases down the group. Why? (v)_ Define internal energy and point out; is it a state function or not? (vi) What do you mean by heat of solution; give asuitable example. (vii) Define state function, write names of two such functions. (vit) What do you mean by Standard Hydrogen Electrode (SHE). Ux) _Impure Cu can be purified by electrolytic process, justify? sp What is ig reactant, give examples and how i identified, - notespk.com (b) Explain measurement of elm value of electron. 6 (a) Describe the charging and discharging of Lead Accumulator. (b) Calculate the mass of 1dm’ of NH, gas at 30°C and 1000mm Hg pressure, considering that NH, is behaving ideally. notespk.com 7. (a) Discuss Geometry of ethene (CH) according to Sp’ hybridization. (b) How can you measure enthalpy of reaction by glass calorimeter. notespk.com 8. (a) What is hydrogen bonding. Give its three applications. (b) The solubility of CaF, in water at 25°C is found to be 2.05x10‘moldm®. What is value of Ksp at this temperature? 9. (a) Explain graphically depression of freezing point of a solvent by solute. Also write down’its mathematical form. (b) Clearly differentiate between Homogeneous and Heterogeneous catalysis. Give two examples of each. www.notespk.co Excellence of Knowledge