Professional Documents
Culture Documents
SUBMITTED BY-
GROUP 148
GAURAV SHARMA (2505399)
HARENDRA KALYAN (2503791)
JOBIN GEEVARGHESE JOY (2506187)
TABLE OF CONTENTS
1. Abstract..........................................................................................2
2. Introduction...................................................................................2
3. Working Principle of Solar Cell..................................................3
4. Efficiency of Solar Cell.................................................................4
5. External and Internal Quantum Efficiency................................5
6. Tandem Solar Cells.......................................................................6
7. Measurement Setup......................................................................7
8. Results............................................................................................8
9. Conclusion....................................................................................15
10. References....................................................................................15
Our report highlights the importance of quantum efficiency measurements and distinguishes
different types of cells based on the observations. The valuable findings presented in this
report contribute significantly to ongoing efforts aimed at unlocking the full potential of
solar energy for a greener and more sustainable future.
2. Introduction
Photovoltaic Cells, commonly known as Solar Cells, are used in converting sunlight into elec-
trical energy. To maximize the efficiency and performance of solar cells, understanding their
Quantum Efficiency (QE) is important. In order to measure QE, first the bandgap needs to be
analysed. The Valence Band represents the lower energy levels where electrons are bound,
while the Conduction Band allows their free movement. The energy bandgap between them
determines photon absorption; photons with energy matching the gap are absorbed, influ-
encing the wavelength range a solar cell can effectively convert into electricity.
In this report, we present our results and evaluations to measure quantum efficiency, in-
cluding External Quantum Efficiency (EQE) and Internal Quantum Efficiency (IQE) measure-
ments. It measures the efficiency with which a device can convert incident photons into
charge carriers (electrons and holes) contributing to the device's electrical output. The EQE
is typically expressed as a percentage and represents the ratio of collected charge carriers to
the number of incident photons at a specific wavelength or energy. Internal Quantum Effi-
ciency is another critical parameter used to characterize the performance of photovoltaic
devices. Unlike EQE, which measures the efficiency of external charge carrier collection, IQE
assesses how efficiently photons are converted into charge carriers within the active mater-
ial of the device itself. IQE is also expressed as a percentage and represents the ratio of gen -
erated charge carriers to the number of absorbed photons. IQE is essential because not all
absorbed photons in a device result in the generation of charge carriers. Some may be lost
as heat or wasted as non-productive processes. A higher IQE value indicates a more efficient
device at converting absorbed photons into charge carriers.
Different types of solar cells have different QE characteristics because of the change in
structure and material. We observe these characteristics for different solar panels provided
to us and try to figure out the type of cells used in these panels.
A solar cell is a device that converts sunlight into electricity using a special effect called the
photovoltaic effect. When sunlight hits the surface of the solar panel, it generates both
current and voltage, which results in electricity. This conversion process needs two
important things: a material that can absorb light and make an electron go to a higher
energy level, and the movement of this energized electron from the solar cell to an outside
circuit. Once in the circuit, the electron releases its energy and completes the circuit,
eventually going back to the solar cell. There are different materials and methods that can
be used for solar energy conversion, but the most common way is by using semiconductor
materials arranged in a specific way called a p-n junction.
The efficiency and performance of a solar cell are influenced by a variety of factors, ranging
from local properties and the presence of metal contacts and gaps in multi-cell modules to
optical and electrical losses. Furthermore, manufacturing processes, storage conditions,
handling procedures, and the aging of the cell can also contribute to additional losses and
decreased performance. Continuous advancements in materials, manufacturing techniques,
and quality control are pursued to minimize these losses and improve the overall efficiency
of solar cells.
Figure 3: Maximum Power Point with a V-I curve (Alternative Energy Tutorials, n.d.)
Pmp is the maximum power that can be extracted by the solar cell.
The power conversion efficiency (PCE) of a solar cell is given by:
Quantum efficiency is a critical measure that quantifies the ratio between collected carriers
and incident photons in a solar cell, reflecting its efficiency. All photons of particular
wavelength would be absorbed, generating minority carriers which then got collected and
resulting in a quantum efficiency of unity at that wavelength. However, real solar cells
experience recombination effects, leading to reduction in quantum efficiency. Factors such
as front surface passivation and diffusion length impact different regions of the quantum
efficiency curve.
and the Internal Quantum Efficiency represents the percentage of incident photons that
generate charge carriers within the material. IQE focuses on intrinsic material performance,
disregarding charge collection efficiency.
7. Measurement Setup
8. Results
Task A: EQE Measurement Setup
Xenon Lamp: It is used as the setup's light source. The Xenon Lamp produces broad-
spectrum light, which is essential for precisely determining the device's external quantum
efficiency over a wide spectral range.
Monitor Diode: It is used to measure the QE by offering a consistent and known light source.
This helps in precise calibration and standardization of the measurements. It basically acts
like a benchmark against which the QE of the devices being tested are be evaluated.
8.00E+01
6.00E+01
4.00E+01
2.00E+01
0.00E+00
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
3 0 3 4 3 8 4 2 4 6 5 0 5 4 5 8 6 2 6 6 7 0 7 4 7 8 8 2 8 6 9 0 9 4 9 8 1 02 1 06 1 10
WAVELENGTH (nm)
EQE IQE=EQE/1-R
Recombination Loss: The presence of defects and dangling bonds in the amorphous
structure causes a higher rate of electron-hole recombination, which reduces the carrier
lifetime.
Transport Loss: Slow carrier mobility in amorphous silicon limits the efficient movement of
charge carriers to the respective places.
Microcrystalline Silicon Pin solar cell: For Microcrystalline Silicon Cells, external
quantum efficiency at wavelength 700-800 nm starts declining as the absorption is
not optimum. The primary reason for that could be assumed due to the energy levels
of the material and the absorption characteristics of the microcrystalline silicon
structure.
WAVELENGTH (nm)
EQE IQE=EQE/1-R
Absorption Loss: While microcrystalline silicon has better light absorption than amorphous
silicon, it still faces some absorption losses due to its inherent material properties.
Defect-Related Recombination: The presence of defects and grain boundaries in
microcrystalline silicon leads to non-radiative recombination, reducing the charge carrier
lifetime.
Transport Loss: The carrier mobility in µC-Si:H is higher than a-Si:H but lower than crystalline
silicon, causing some limitations in charge carrier movement.
Crystalline Silicon Single-Junction Solar Cell : The Quantum Efficiency is uniform
almost all over our spectrum range meaning that the absorption changes very little.
Although we can observe that at around 380 nm there’s a small decrease in efficiency
which can be concluded because of photons not being collected properly at this
wavelength.
1.00E+02
8.00E+01
6.00E+01
4.00E+01
2.00E+01
0.00E+00
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
3 0 3 4 3 8 4 2 4 6 5 0 5 4 5 8 6 2 6 6 7 0 7 4 7 8 8 2 8 6 9 0 9 4 9 8 1 02 1 06 1 10
Wavelength (nm)
EQE IQE=EQE/1-R
Absorption Loss: Crystalline silicon has excellent light absorption properties, its thickness
may not fully capture all the incident photons, leading to some absorption losses.
Auger Recombination: At high carrier densities, Auger recombination can become a
significant loss mechanism in c-Si solar cells, particularly under high illumination levels.
EQE & IQE vs Wavelength (Cell-5: Tandem Cell under Blue filter)
1.00E+02
9.00E+01
8.00E+01
Quantum Efficiency (%)
7.00E+01
6.00E+01
5.00E+01
4.00E+01
3.00E+01
2.00E+01
1.00E+01
0.00E+00
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
3 0 3 4 3 8 4 2 4 6 5 0 5 4 5 8 6 2 6 6 7 0 7 4 7 8 8 2 8 6 9 0 9 4 9 8 1 02 1 06 1 10
Wavelength (nm)
EQE1 IQE1
EQE & IQE vs Wavelength (Cell-5: Tandem Cell under Red filter)
9.00E+01
8.00E+01
7.00E+01
Quantum Efficiency (%)
6.00E+01
5.00E+01
4.00E+01
3.00E+01
2.00E+01
1.00E+01
0.00E+00
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
3 0 3 4 3 8 4 2 4 6 5 0 5 4 5 8 6 2 6 6 7 0 7 4 7 8 8 2 8 6 9 0 9 4 9 8 1 02 1 06 1 10
Wavelength (nm)
EQE2 IQE2
Absorption Loss: Each sub-cell absorbs specific parts of the solar spectrum, and any
mismatch in their absorption spectra can lead to sub-optimal photon utilization.
Recombination Loss: The presence of defects and grain boundaries in both a-Si:H and µc-Si:H
layers can contribute to recombination losses, impacting the overall efficiency of the tandem
cell.
We then integrate it over the wavelength of range from 300nm to 1100nm with the help of
trapezoidal rule in MS Excel and calculate JSC for all the observed Solar cells in the
experiment.
For AM (Extraterrestrial Irradiance) we have,
1. Microcrystalline Silicon pin solar cell (Cell1): JSC= 26.2 mA/cm2
2. Crystalline Silicon Single-Junction Solar Cell (Cell2): JSC= 35.8 mA/cm2
3. Amorphous Silicon pin solar cell: JSC= 17.4 mA/cm2
4. Amorphous Silicon/Microcrystalline Silicon Tandem Solar Cell:
JSC (under blue filter) = 13.6 mA/cm2
Jsc (under red filter) =14.1 mA/cm2
For AM (1.5)
1. Microcrystalline Silicon pin solar cell (Cell1): Jsc= 21.6 mA/cm2
2. Crystalline Silicon Single-Junction Solar Cell (Cell2): Jsc= 29.4 mA/cm2
3. Amorphous Silicon pin solar cell: Jsc= 13.9 mA/cm2
4. Amorphous Silicon/Microcrystalline Silicon Tandem Solar Cell:
Jsc (under blue filter) = 11.6 mA/cm2
Jsc (under red filter) = 11 mA/cm2
10. References
(n.d.). Retrieved from https://www.pvsyst.com/help/pvmodule_model.htm
D.K. Sharma, G. P. (2014). Analysis of the Effect of Fill Factor on the Efficiency of Solar PV System for
Improved Design of MPPT. The 6th World Conference on Photovoltaic Energy Conversion (p.
1281). WCPEC.
Matevž Bokalič, M. J. (2009). Solar Cell Efficiency Mapping by LBIC. 45th International Conference on
Microelectronics, Devices and Materials & The Workshop on Advanced Photovoltaic Devices
and Technologies, (p. 270). Postojna.
Lab Manual provided by the Supervisors- J. Roger, Prof. Ulrich W. Paetzold Light Technology Institute
(LTI), KIT
Sinicco, I. (2020). Re: How to calculate the current density (Jsc) from EQE for DSSC? Retrieved from
ResearchGate:
https://www.researchgate.net/post/How_to_calculate_the_current_density_Jsc_from_EQE_
for_DSSC/5e7a1e4325dedb5bf177b935/citation/download.