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Airbus Industries Lithium Batteries
Airbus Industries Lithium Batteries
OPERATIONS
Lithium batteries: safe to fly?
Lithium batteries:
visible cases of cell phones or laptops self-igniting and burning.
Likewise, several events have occurred on aircraft, ranging from
localized and limited fires to large, uncontrolled in-flight fires
safe to fly?
resulting in hull losses and fatalities.
The air industry has become more aware of the specific
characteristics of Lithium batteries and the associated risks can
now be mitigated. Procedures have been developed to address
Today, Lithium batteries play a barely visible, yet essential the risks for Lithium batteries being part of the aircraft design,
role in both our daily life and aviation alike. Manufactured and those belonging to passengers or crews carry-on items, or indeed
procedures linked to the shipping of Lithium batteries as cargo.
handled correctly, Lithium batteries are safe. But production
failures, mishandling, or not being aware of their specific
characteristics can have serious repercussions.
LITHIUM BATTERIES:
A POWERFUL AND VERSATILE
TECHNOLOGY, ASSOCIATED
WITH A COMMON RISK
Lithium is the metal with the lowest den- intrinsic risk is the same for all applica-
sity, but with the greatest electrochemi- tions, different solutions and procedures
cal potential and energy-to-weight ratio, exist to mitigate this common risk
meaning that is has excellent energy depending on where and how the Lith-
CHRISTINE BEZARD IAN GOODWIN PEIMANN PAUL ROHRBACH storage capacity. These large energy ium battery is used (i.e. part of the aircraft
Head of Human Factors Director Flight Safety - TOFIGHI-NIAKI Fire Protection - density and low weight characteristics design, transported as cargo or in pas-
& Ergonomics in design - Safety Enhancement Flight Safety Project leader Lithium make it an ideal material to act as a sengers and crews luggage and PED).
power source for any application where This section will highlight the benefits of
Safety advisor Enhancement - batteries as cargo
weight is an issue, aircraft applications this new technology irrespective of its
Flight Operations being a natural candidate. use in applications, and describe the
and Training Support While the technology used and the associated risk of “thermal runaway”.
Safety First #21 | January 2016 025
OPERATIONS
Lithium batteries: safe to fly?
16,000
Consumption t Li-contained
14,000
Batteries
12,000
10,000
Different technologies
8,000
Glass Direct
The term “Lithium battery” actually refers to a family of batteries that can be
6,000
Alloy & Other
Other divided into two categories:
4,000
Ceramics Glazing
2,000
Primary: Lithium-metal, non-rechargeable batteries (fig.4)
Lithium-metal batteries
0
2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020
These include coin or cylindrical Lithium-metal batteries have a higher
Year
batteries used in calculators, digital specific energy compared to all other
cameras and emergency (back-up) batteries, as well as low weight and a
Batteries Air Conditioning Al Process Add Ceramics Glazing Glass Direct applications for example (fig.4). long shelf and operating life.
Lubricants Pharmaceuticals Polymer Process Synthetic rubber Alloy & Other
Today, Lithium batteries are progres- The Lithium battery market is extremely Key current applications for this type of The advantages of the Lithium-ion
sively replacing previous technology dynamic and expanding fast, with batteries are in powering cell phones, or Lithium-polymer battery are its
batteries – e.g. Nickel-Cadmium, a growing application as the power laptops or other hand held electronic ability to be recharged in addition to (fig.5)
Lead-acid – and can be found in most source for a wide range of electric vehi- devices, as well as electric/hybrid cars its higher energy density and lighter Lithium-ion / Lithium-polymer batteries
of electronic and autonomous electric cles. In fact, no level off is foreseen in and power stores (fig.5). weight compared to nickel-cadmium
systems or equipment. Development the coming years. In 2014, 5.5 billion and nickel-metal hybrid batteries.
and applications are evolving with Lithium-ion batteries were produced
latest uses including ultrathin (down to (fig.2).
0.5 mm) and flexible technologies.
(fig.2)
Worldwide batteries production (Source:
Christophe PILLOT, Avicenne Energy)
Safety First #21 | January 2016 027
OPERATIONS
Lithium batteries: safe to fly?
One main intrinsic risk to tackle: the thermal Cathode Electrolyte Anode
runaway current current
collector collector
As with every new technology, poorly manufactured, they can suffer
Lithium batteries offer a number of stability issues and be subject to
advantages, but they also come what is called a “thermal runaway”.
with limitations. Although previous This phenomenon is well recognized
batteries technologies were not risk- now, and it can be mitigated providing
free, Lithium based batteries have awareness and prevention actions are
a larger electrochemical potential; taken.
Lithium therefore if damaged, mishandled or
batteries can Cathode Anode
A self-ignited and highly propagative phenomenon Passivating
be both a source
Layer
of fire through In case of internal degradation or Both the primary and secondary types of
self-ignition and damage, a battery cell rapidly releases
its stored energy (potential and chemical)
batteries are capable of self-ignition and
thermal runaway. And once this process
Separator
thermal runaway, through a very energetic venting reaction, is initiated, it easily can propagate
and a cause which in turn can generate smoke, because it generates sufficient heat to
flammable gas, heat (up to 600°C and induce adjacent batteries into the same
of fire by igniting 1000°C locally), fire, explosion, or a spray thermal runaway state.
surrounding of flammable electrolyte. The amount of Lithium batteries can be both a source
Abuse
condition
Thermal Runaway
FIRE
energy released is directly related to the of fire through self-ignition and thermal
flammable electrochemical energy stored and the runaway, and a cause of fire by igniting
+
EXPLOSION
material. type of battery (chemic and design). surrounding flammable material. Exothermic reaction and pressure built up
Internal degradation:
breakdown of the thin Breakdown
passivating layer in the electrolyte Internal damages:
INSIGHT INTO THE THERMAL RUNAWAY PHENOMENON releasing flammable short circuits between
hydrocarbon gases the electrodes
DISCHARGE CHARGE
V
External Heating
In-service experience
FAA tests show that even a small hazardous materials, therefore par- Lithium
number of overheating batteries emit ticular care and consideration must
gases that can cause explosions and be taken to ensure safe operations in batteries
ELT 21 1 2 3 4 5 6 7 8 9 10 11 12 fires that cannot be prevented by relation to use and transport of Lithium are classified
traditional fire suppression systems. batteries (or devices containing
In view of the possible consequences, Lithium batteries) when in an aircraft
as hazardous
Lithium batteries are classified as environment. materials.
Cordless devices
20 4 8 9 (fig.7)
12
21 2 5 10 Consequences of Lithium batteries
19 7
18 20 16 thermal runaway
14
19 1 3 6 11 13
17 15
CVR/DFDR 18
are subject to runaway or a fire starts with securing common sense precautions, such
the batteries that form part of the aircraft as using only the Original Equipment
strict development design. In this respect, the Lithium Manufacturer (OEM) parts. The use
and integration batteries embedded in the aircraft design of counterfeit or non-authorized parts 1 3 6 11
are subject to strict development and increases the risk of fire and explosion.
requirements, integration requirements, complying with Consequently, complying with the
complying with the highest safety standards. The intrinsic Airbus Parts Catalogue and exclusi-
the highest safety risk of this new generation of Lithium vely using Airbus or OEM catalogue Cordless devices
based batteries is acknowledged at all references for spare batteries is key.
standards. levels of the aircraft design phase, as Similarly, before installing spare
19
early as from the inception of the pro- batteries in Buyer Furnished Equipment
duct and its systems. It is then mitigated (BFE) or in aircraft, operators should
thanks to acceptability justification ensure the parts are genuine spare 19 1 3 6 11
based on each battery location, and a parts, that they have been stored and
17 15
thorough review of installation, ensur- handled appropriately and present no
ing that no heat source and hazardous mark of overheat or damage.
material or fluids are in the vicinity.
impact of different characteristics of tems are not capable of containing What the regulations say
the batteries (e.g. chemistry, state of these accumulated gases.
charge, size), cargo compartments
types and loading configurations make
The passive protection standards are
designed to withstand heat sources for
In the light of the risks identified, in
January 2015, the ICAO Dangerous
non-rechargeable and rechargeable
batteries alike. At time of publication
Primary
it very difficult to define a quantity up to 5 minutes and are not resistant Goods Panel took the position to ban of this article, these discussions are (non-rechargeable)
limitation that could be recommended against the characteristics of a Lithium the carriage of Lithium-metal batteries on-going. At their last meeting in Lithium-metal
at aircraft level, for all operational battery fire. The temperature, duration of all types, as cargo on passenger October 2015, the ICAO Dangerous
situations. Tests have demonstrated and intensity of such a fire will quickly aircraft. Goods Panel (DGP) proposed a 30% batteries are
that some configurations, involving only overwhelm the passive protections. State of Charge (SoC) limit as an interim forbidden for
one item of the regulated packaging In addition, the quantity and continuing However, whilst this was an important measure aiming to reduce the risk of fire
size, has the potential to lead to production of smoke produced is development, Lithium-metal batteries propagation to adjacent batteries and
transportation
significant damage of an aircraft. likely to overwhelm the passive and only account for a small proportion of thereby improve aviation safety. aboard passenger-
Irrespective of the size of the shipment,
active smoke barriers that protect the
occupied compartments.
all Lithium batteries carried annually as
air cargo. Consequently, research into
At the same time, discussions in
ICAO are focussing on establishing
carrying aircraft.
research into the impact of both Lith- the impact of a Lithium-ion batteries appropriate packaging and shipping
ium-metal and Lithium-ion batteries With these findings, the aviation fire has continued. As already noted, requirements to ensure safer shipment
Today’s cargo fire has demonstrated that the existing industry came to the conclusion that this research has demonstrated that of Lithium-ion batteries. Airbus is also
cargo compartment fire suppression today’s cargo compartments, which Lithium-ion batteries themselves involved in the Civil Aviation Safety
compartments do systems – namely Halon 1301 (class are certified to US CFR Part 25.857 and represent a significant threat due to the Team (CAST) investigating overall
not demonstrate C) or oxygen starvation (class E) – are EASA CS 25.857, do not demonstrate fact that the existing cargo compartment approaches from the battery itself to
resistance to unable to stop a thermal runaway
and prevent propagation to adjacent
resistance to a fire involving Lithium-
metal and Lithium-ion batteries. For
fire suppression functions are ineffective
against a Lithium-ion battery fire.
a combination of packaging / container
and the aircraft itself.
a fire involving cells. If a thermal runaway is initiated, this reason, the inability to contain a The importance of correct trans-
Lithium-metal heat and flammable gases coming Lithium battery fire for sufficient time As a result, regulatory authorities are port and shipping of Lithium batte-
from the degradation of the hydro- to secure safe flight and landing of the now heading towards a larger ban on ries therefore becomes key, and
and Lithium-ion carbon electrolyte will be emitted. aircraft, is an identified risk to the air Lithium battery shipments as cargo on the involvement of the shipper and
batteries. The existing fire protection cargo sys- transport industry. passenger planes that would include operator is crucial.
What shippers and operators can do: risk assessment and best practices
1. Check the latest industry available cable regulations (ICAO and/or local
information and guidance regulations)
• Overall capability of the aircraft and
Air transport of Lithium batteries is its systems
controlled by international and local • Segregation possibilities of Lithium
regulations. If transporting Lithium batteries from other flammable/
batteries, operators need to first explosive dangerous goods.
check the latest instructions for the Cameras Spare batteries Laptops Tablets, MP3
safe transport of dangerous goods 3. Ensure safe packaging and
by air, be they provided through shipping
Airworthiness Authorities or local
regulations, and/or the ICAO. Local and/or international regulations
provide the applicable set of rules 2 4 5 7 10 12
2. Perform a risk assessment that need to be complied with
when transporting Lithium batteries.
In the end, the responsibility for the Attention should be given to:
safe carriage of dangerous goods Cordless devices
(including Lithium batteries) lies • Training and awareness of employ-
with the shipper and operator. It is ees regarding: 20 4
12
recommended that if carriage of - The aircraft limitations against a 2 5 10
20 16 7
dangerous goods is pursued, then Lithium battery fire and existing
a safety risk assessment of cargo mitigation means. 14
operations should be performed to - Regulations, handling procedures,
determine if battery shipments can the dangers of mishandling, and
be handled safely. methods to identify Lithium battery
With respect to Lithium batteries, shipments.
guidelines for the assessment should • Packaging:
16 14
consider factors such as: - Clearly identify shipments of
Lithium batteries by information on Cell Phones
• The quantity and density of Lithium airway bills and other documents.
battery shipment - Make sure that the packaging is
• The type of Lithium batteries to be correctly labelled and identified
shipped as dangerous goods according
• Who the supplier/shipper of Lithium to ICAO technical instructions.
batteries is and their quality control - Do not ship damaged packages.
• The identification and notification of • Cargo loading: segregate any
all shipments of Lithium batteries Lithium battery shipments from
(also Section II Lithium batteries) other dangerous goods that present
• Accepting only Lithium battery a fire hazard (flammable and explo-
shipments that comply with appli- sive goods).
Raising passengers awareness before boarding Mitigating the risks posed by Lithium batteries:
summary
Recommendations have been • Consider the quantity carried by
developed with respect to what can individuals. Whilst there is no limit Lithium battery thermal runaways can • Ensure that loads conform with
or cannot be carried in passenger on the number of PEDs or spare be caused by design / manufacturing ICAO / IATA labelling, packaging and
baggage. ICAO and IATA regulated and batteries, below a specified size quality / integration shortcomings handling recommendations.
recommended general requirements (normally 100 Watt-hour) that a or by inadequate compliance with a
with regards to carrying and managing passenger or crew member may number of basic rules. The following • Ensure compliance to the Airbus
what is carried in passenger baggage carry, but they must be for personal principles should be adhered to in Parts Catalogue when replacing
is that: use. order to minimize the risk of Lithium batteries.
battery fires and explosions:
• Batteries carried should have been The key however is making both the • Ensure that ground, flight and cabin
appropriately tested (e.g. should customer facing representatives and • Ensure that Lithium cells/batteries crews are trained and passengers
be manufactured by the original the passenger themselves aware of shipped comply to international are aware of Lithium batteries spe-
manufacturer). the risks presented by the incorrect standards. cificities.
carriage of Lithium batteries, and
• PEDs containing Lithium batteries making sure that they know the regu-
should be carried in carry-on lations. To increase the awareness
baggage. to the travelling public, posters and HOW TO MANAGE THE
Lithium battery pamphlets can be a
• Spare batteries (i.e. those not con- useful option and are widely used by CONSEQUENCES OF A LITHIUM
tained in a PED), regardless of size, air carriers and authorities around the
MUST be in carry-on baggage. They world alike. As an example, FAA have BATTERY FIRE
are forbidden in checked baggage issued Safety Alerts for Operators
and should be appropriately pro- (SAFO) number 15010, which deals
tected against short circuit, e.g. by with “Carriage of Spare Lithium
leaving the batteries in its original Batteries in Carry-on and Checked As detailed previously, proactive action fire is essential. The key principles to Halon can
retail packaging. Baggage”. by making passengers and airline safely and efficiently tackling a Lithium
personnel aware of the risks posed battery fire, whether it is in the cabin of suppress open
Raising passengers awareness on-board by Lithium batteries is preferable than flight deck, being: flames, but it
reacting to a fire caused by a Lithium • Keep people away from the fire
A key aspect to mitigating the risk subsequent crushing of PEDs during battery. Therefore knowing what to do • Minimize risks of fire propagation
is ineffective in
is making the owner, namely the adjustment of the seat can lead to in the unlikely event of a Lithium battery • Apply specific firefighting principles. addressing the
passenger, aware of the risks inherent overheat and thermal runaway. source of fire. Use
to Lithium batteries being used in Making passengers aware of this Apply specific firefighting principles of water is the best
an aircraft environment. Make sure inherent risk can help reduce this
passengers are aware of what is scenario. For example, including a option to allow
allowed in the terms of Lithium note in the pre-flight briefing to ensure Classical firefighting procedures and fire Halon can suppress open flames, but
batteries in carry-on baggage, and the that in case a PED is lost, then the seat extinguishing means are not efficient to it is ineffective in addressing the source
cooling and limit
requirement for correct storage, but is not moved until the component is stop a lithium battery fire. of fire. Use of water is the best option to the propagation to
also impact of a PED getting trapped
in the movable seat mechanism.
retrieved is an option. Likewise, making
cabin and flight crew aware of this
allow cooling and limit the propagation
to adjacent cells.
adjacent cells.
potential failure mode is key to quick
Due to their small size, PEDs can easily and efficient action when addressing Once a lithium battery cell has ignited
be trapped in seat mechanisms. The a fire caused by a PED. then the effort must concentrate on
cooling the surrounding cells by use of
water (or other non-alcoholic liquid) and
preventing deterioration of the situation
to avoid any fire propagation to the
INFORMATION adjacent battery cells.
Cabin crew procedures a Lithium battery powered device may of Halon and liquid to tackle the fire,
be at the origin of the fire. and makes reference to the other two
Isolate the source of fire Therefore the overhead bin smoke/ cabin crew procedures to address a
fi re procedure now covers the use Lithium battery fire.
In the cabin, Reacting to a Lithium battery fire in the a device that is emitting smoke.
(fig.9)
cabin starts with isolating the source Prevent propagation by ensuring
do not try to pick of fire. Indeed, a smoking battery may that no fl ammable material (fl uids, Overhead bin smoke/ fire CCOM
up and attempt to explode at any time, due to the highly gas, devices) are near the smoking
procedure
This procedure (fig.8) proposes the merse the device in a suitable con-
use of Halon to extinguish open tainer (such as a waste bin, or stand-
ABNORMAL/EMERGENCY PROCEDURES
flames, and water (or a non-alcoholic ard galley container) to secure against
FIRE PROTECTION
liquid) to cool the device down. thermal runaway (refer to the third
A330/A340
(fig.8) The recommendation
CABIN CREW OPERATING MANUAL is then to im- step below).
Lithium battery fire CCOM procedure
LITHIUM BATTERY FIRE
Ident.: 09-020-00015205.0001001 / 28 JAN 14
Criteria: LR
Applicable to: ALL
The roles of the firefighter, assistant firefighter and communicator must be distributed according to
the basic firefighting procedure.
In the case of PED or spare lithium battery fire in the cabin or when notified by the flight crew:
If there are flames:
FIREFIGHTING EQUIPMENT.............................................................................................. TAKE
Consider the use of a PBE and fire gloves.
HALON EXTINGUISHER..........................................................................................DISCHARGE
Halon extinguisher must be discharged to suppress the flames prior to cool down the PED or
the Spare lithium battery.
When the flames are suppressed or If there are no flames:
ON PED or spare lithium battery.........................POUR WATER OR NON-ALCOHOLIC LIQUID
The PED or Spare lithium batteries must be cooled down by pouring water or non-alcoholic
Liquids
STORAGE PROCEDURE AFTER A LITHIUM BATTERY FIRE ...................................... APPLY
WARNING ‐ Do not attempt to pick up and move a smoking or burning device
‐ Do not cover the device or use ice to cool down the device. Ice or other
materials insulate the device increasing the likelihood that additional battery
cells will ignite.
‐ Do not use fire resistant burn bags to isolate burning lithium type batteries.
Transferring a burning appliance into a burn bag may be extremely hazardous.
END OF PROC
Lithium battery fires may sometimes not occurred in service, the procedure
easily be identified, and considering the for fire in the overhead compartment
specific cases when fires have actually (fig.9) now considers as a base that
Safety First #21 | January 2016 041
OPERATIONS
Lithium batteries: safe to fly?
Storage procedure after a Lithium battery fire • Once there are no more open flames: aimed at the device is sufficient to cool
- If it is not possible to remove the it and mitigate the consequences of
As referenced in the first step above, subject it to regular monitoring. burning/heating device from flight the thermal runaway.
this procedure (fig.10) is called at the The lavatory is proposed as it contains deck, pour water or non-alcoholic - If it is possible to move the device:
end of the two previous procedures. a means of smoke detection, but is liquid on the device to cool it down. transfer it to the cabin and use the
Once the fire has been contained also a location that can secure the Be aware of possible explosion. Cabin Crew Lithium battery procedures
and the device can be safely moved, device away from
ABNORMAL/EMERGENCY the passengers and
PROCEDURES Tests completed by Airbus have con- to secure it, by immersion in water or
this procedure recommends to place provides waterproof
FIRE PROTECTION
floor designed firmed that a small quantity of water non-alcoholic liquid.
receptacle where the burning/heating to receive water in case of turbulent
A330/A340
device was
CABIN CREW immersed
OPERATING MANUALin a lavatory and conditions. (fig.11)
Smoke/fire from Lithium battery QRH
(fig.10) procedure
STORAGE PROCEDURE AFTER A LITHIUM BATTERY FIRE
Storage after a Lithium battery fire CCOM
procedure Ident.: 09-020-00015206.0001001 / 28 JAN 14
Criteria: LR
Applicable to: ALL