SAFETY DATA SHEET

ABNT NBR 14725 Standard

Sanolin Tartrazin X 90 Page 1(12)

Substance key: SXR091103 Revision Date: 02.06.2021
Version : 4 - 10 / BR Date of printing : 07.12.2021

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Substance or preparation name (trade name)

Sanolin Tartrazin X 90

Internal substance key for identification of product

Material number : 107594
Substance key : SXR091103

Major recommendable usage for substance or preparation

Industry sector : Industrial Performance Chemicals
Personal Care
Detergents Intermediates
Paints, lacquers and varnishes industry
Type of use : Colorant/organic pigment

Name of company / address

Colorants Solutions Deutschland GmbH
Brüningstraße 50
65929 Frankfurt am Main
Telephone no. : +49 6196 757 0

Information about the substance / preparation

BU Pigments
Product Stewardship
e-mail : SDS.PI.Europe@clariant.com

Emergency telephone number : 00800-5121 5121 (24 h)

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification in accordance with ABNT NBR 14725 Standard

Not a hazardous substance or mixture.
GHS label elements in accordance with ABNT NBR 14725 Standard
Not a hazardous substance or mixture.
Other hazards which do not result in classification
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Substance

Chemical nature : C.I. Acid Yellow23, (C.I. 19140) Monoazo Dye, soluble in
water

CAS-No. : 1934-21-0

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Substance key: SXR091103 Revision Date: 02.06.2021
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Components
No hazardous ingredients

SECTION 4. FIRST AID MEASURES

General advice : Get medical advice/ attention if you feel unwell.

If inhaled : Remove to fresh air.

Get medical attention if symptoms occur.

In case of skin contact : IF ON SKIN: Wash with plenty of soap and water.

In case of eye contact : In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
In case of irritation consult an occulist

Rinse immediately with plenty of water, also under the eyelids,

for at least 15 minutes.
Get medical attention immediately if irritation develops and
persists.

If swallowed : Rinse mouth with water.

Get medical advice/ attention if you feel unwell.

Most important symptoms : No symptoms known currently.

and effects, both acute and No hazards known at this time.
delayed

Notes to physician : Treat symptomatically.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water spray

Carbon dioxide (CO2)
Foam
Dry chemical

Unsuitable extinguishing : High volume water jet

media Carbon dioxide (CO2)
Dry powder

Specific hazards during : In case of fire hazardous decomposition products may be

firefighting produced such as:
Carbon dioxide (CO2)
Carbon monoxide
Nitrogen oxides (NOx)
Sulphur dioxide

Special protective equipment : Wear suitable protective equipment.

for firefighters

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Substance key: SXR091103 Revision Date: 02.06.2021
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SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Wear suitable protective equipment.

protective equipment and
emergency procedures

Environmental precautions : The product should not be allowed to enter drains, water
courses or the soil.

Methods and materials for : Avoid dust formation.

containment and cleaning up Take measures to prevent the build up of electrostatic charge.
Risk of dust explosion.
Treat recovered material as described in the section "Disposal
considerations".

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Take precautionary measures against build-up of electrostatic

fire and explosion charges, e.g earthing during loading and off-loading
operations.
Keep away sources of ignition.

Advice on safe handling : When used and handled appropriately no special measures
are needed

Avoid inhalation, ingestion and contact with skin and eyes.

Wash thoroughly after handling.

Hygiene measures : Do not eat, drink or smoke when using this product.
Wash hands before breaks and at the end of workday.
Take off immediately all contaminated clothing and wash it
before reuse.

Conditions for safe storage : Keep only in the original container.

Further information on : Keep containers tightly closed in a cool, well-ventilated place.

storage conditions Store at room temperature.

Materials to avoid : No conditions to be specially mentioned.

Further information on : no data available

storage stability

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Contains no substances with occupational exposure limit values.
Personal protective equipment
Respiratory protection : Use respiratory protection in case of insufficient exhaust
ventilation or prolonged exposure

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Substance key: SXR091103 Revision Date: 02.06.2021
Version : 4 - 10 / BR Date of printing : 07.12.2021

Respirator with a dust filter

Wear NIOSH approved particulate filtering respirator rated N,

R, or P95 or 100 or equivalent in the absence of proper
environmental control. Type of respirator depends on level of
exposure.

Hand protection
Remarks : Butyl Rubber, PVC Or Neoprene.

Eye protection : Safety glasses with side-shields

Skin and body protection : working clothes

Protective measures : Observe the usual precautions for handling chemicals.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : powder

Colour : yellow-orange

Odour : not specified

Odour Threshold : not available

pH : approximately 7 (20 °C)

Concentration: 10 g/l 0,1 %

Melting point : 350 °C

Boiling point : Not applicable

Flash point : Not applicable

Evaporation rate : Not applicable

Self-ignition : 260 °C
Method: VDI 2263 (Grewer)
Information refers to the main component.

280 °C
Method: VDI 2263 (Grewer)
The sample was mixed 1:1 with diatomaceous earth. The
substance or mixture is not classified as self heating. The
substance or mixture is not classified as pyrophoric.

Burning number : 2 (100 °C)

Method: VDI 2263, ESCIS, Vol. 1

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Substance key: SXR091103 Revision Date: 02.06.2021
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Short flaring up without spreading

Upper explosion limit / upper : not available

flammability limit

Lower explosion limit / Lower : not available

flammability limit

Vapour pressure : Not applicable

Relative vapour density : Not applicable

Relative density : not available

Density : 1,7660 g/cm3

Bulk density : 600 kg/m3

Solubility(ies)
Water solubility : 50 g/l (20 °C)

Partition coefficient: n- : log Pow: -2,2 (20 - 25 °C)

octanol/water
Method: OECD Test Guideline 107

Auto-ignition temperature : not available

Decomposition temperature : 240 - 350 °C

Heating rate: 3 K/min
Decomposition energy (mass): 270 kJ/kg
Method: DSC
closed cup
Exothermic reaction

380 - 430 °C
Heating rate: 3 K/min
Decomposition energy (mass): 40 kJ/kg
closed cup
Exothermic reaction

250 - 500 °C
Heating rate: 3 K/min
Decomposition energy (mass): 4.300 kJ/kg
Method: DSC
Exothermic reaction
open cup

The substance or mixture is not classified self-reactive.

Viscosity
Viscosity, dynamic : Not applicable

Flow time : Not applicable

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Substance key: SXR091103 Revision Date: 02.06.2021
Version : 4 - 10 / BR Date of printing : 07.12.2021

Explosive properties : Not explosive

Not explosive

Oxidizing properties : not available

Molecular weight : 534,4 g/mol

Dust explosion class : St1

Minimum ignition energy : > 10 J

Particle size : 64 µm
Method: ISO 13320-1

SECTION 10. STABILITY AND REACTIVITY

Reactivity : See section 10.3. "Possibility of hazardous reactions"

Chemical stability : Stable

Possibility of hazardous : None known.

reactions Stable

Conditions to avoid : None known.

Incompatible materials : not known

Hazardous decomposition : When used and handled as intended, none.

products

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity
Product:
Acute oral toxicity : LD50 (Rat, female): > 2.000 mg/kg
Method: OECD Test Guideline 423
GLP: no
Assessment: The substance or mixture has no acute oral
toxicity

Acute inhalation toxicity : Remarks: no data available

Acute dermal toxicity : Method: Expert judgement

Assessment: The substance or mixture has no acute dermal
toxicity
Remarks: no data available

Skin corrosion/irritation
Product:
Species : reconstructed human epidermis (RhE)

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Substance key: SXR091103 Revision Date: 02.06.2021
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Exposure time : 18 h
Method : OECD Test Guideline 439
Result : No skin irritation
GLP : yes

Serious eye damage/eye irritation

Product:
Species : Rabbit
Result : No eye irritation
Method : Draize Test
GLP : no

Respiratory or skin sensitisation

Product:
Test Type : Local lymph node assay (LLNA)
Exposure routes : Dermal
Species : Mouse
Method : OECD Test Guideline 429
Result : Not a skin sensitizer.
GLP : yes

Germ cell mutagenicity

Product:
Genotoxicity in vitro : Test Type: Ames test
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
GLP: yes

Test Type: In vitro mammalian cell gene mutation test

Test system: mouse lymphoma cells
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: negative
GLP: yes

Test Type: Chromosome aberration test in vitro

Metabolic activation: without
Method: OECD Test Guideline 473
Result: positive
GLP: yes

Genotoxicity in vivo : Test Type: Unscheduled DNA synthesis test (UDS) in

testicular cells
Species: Rat (male)
Strain: Sprague-Dawley
Application Route: oral (gavage)
Dose: 500 mg/kg bw/day (nominal)
Method: OECD Test Guideline 486

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Substance key: SXR091103 Revision Date: 02.06.2021
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Result: negative
GLP: No information available.

Germ cell mutagenicity - : Weight of evidence does not support classification as a germ
Assessment cell mutagen.

Carcinogenicity
Product:
Species : Rat, male and female
Application Route : oral (feed)
Exposure time : 2 years
Dose : 0,1 %, 1 %, 2 %, 5 % in diet
Control Group : yes, concurrent no treatment
: 2.641 mg/kg bw/day
Method : OECD Test Guideline 453
Result : no increase in tumors observed
GLP : no

Carcinogenicity - : No evidence of carcinogenicity in animal studies.

Assessment

Reproductive toxicity
Product:
Effects on fertility : Test Type: One generation study
Species: Rat, male and female
Strain: CD1
Application Route: oral (gavage)
Dose: 0,1 %, 1 %, 2 %, 5 % in diet
General Toxicity - Parent: NOAEL: 2.641 mg/kg body weight
General Toxicity F1: NOAEL: 2.641 mg/kg body weight
Method: OECD Test Guideline 415
GLP: No information available.
Remarks: By analogy with a product of similar composition
Fertility and developmental toxicity tests did not reveal any
effect on reproduction.

Effects on foetal : Test Type: Pre-natal

development Species: Rat, female
Strain: Other
Application Route: oral (gavage)
Dose: 0, 60, 100 - 1000 mg/kg bw/da
Duration of Single Treatment: 19 d
Frequency of Treatment: 1 daily
General Toxicity Maternal: NOAEL: 1.000 mg/kg body weight
Developmental Toxicity: 1.000 mg/kg body weight
Embryo-foetal toxicity: NOAEL: 1.000 mg/kg body weight
Method: OECD Test Guideline 414
GLP: No information available.

Reproductive toxicity - : No evidence of adverse effects on sexual function and fertility,

Assessment or on development, based on animal experiments.

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Substance key: SXR091103 Revision Date: 02.06.2021
Version : 4 - 10 / BR Date of printing : 07.12.2021

STOT - single exposure

Product:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, single exposure.

STOT - repeated exposure

Product:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, repeated exposure.

Repeated dose toxicity

Product:
Species : Rat, male and female
NOAEL : 8103 mg/kg bw/day
Application Route : oral (feed)
Exposure time : 104 weeks
Number of exposures : daily
Dose : 0,5%, 1,5%, 5 % in diet
Control Group : yes
Method : OECD Test Guideline 453
GLP : No information available.
Remarks : No adverse effect has been observed in chronic toxicity tests.

Aspiration toxicity
Product:
no data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Product:
Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 120 mg/l
End point: mortality
Exposure time: 96 h
Test Type: static test
Method: OECD Test Guideline 203
GLP: yes
Remarks: By analogy with a product of similar composition

Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): > 125 mg/l
End point: mortality
Exposure time: 48 h
Analytical monitoring: yes
Method: OECD Test Guideline 202
GLP: No information available.

Toxicity to algae/aquatic : EC50 (Desmodesmus subspicatus (green algae)): > 125 mg/l
plants End point: Growth rate

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Substance key: SXR091103 Revision Date: 02.06.2021
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Exposure time: 72 h
Test Type: static test
Analytical monitoring: yes
Method: OECD Test Guideline 201
GLP: no

Toxicity to fish (Chronic : Remarks: no data available

toxicity)

Toxicity to daphnia and other : Remarks: no data available

aquatic invertebrates
(Chronic toxicity)

Toxicity to microorganisms : IC50 (activated sludge): ca. > 1.000 mg/l

End point: Bacteria toxicity (respiration inhibition)
Exposure time: 3 h
Test Type: static test
Method: OECD Test Guideline 209
GLP: yes

Persistence and degradability

Product:
Biodegradability : Test Type: aerobic
Inoculum: activated sludge
Concentration: 24,6 mg/l
Result: Not readily biodegradable.
Biodegradation: 30 - 40 % (Carbon dioxide (CO2))
Exposure time: 28 d
Method: OECD Test Guideline 301B
GLP: yes
Remarks: By analogy with a product of similar composition

Bioaccumulative potential
Product:
Bioaccumulation : Remarks: not tested.

Mobility in soil
Product:
Distribution among : adsorption
environmental compartments Medium: Other
log Koc: ca. -4,228
Method: estimated

Other adverse effects

Product:
Environmental fate and : Remarks: no data available
pathways

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Substance key: SXR091103 Revision Date: 02.06.2021
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SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues
: Product should be taken to a suitable and authorized waste
disposal site in accordance with relevant regulations and if
necessary after consultation with the waste disposal operator
and/or the competent Authorities

Contaminated packaging : Packaging that cannot be cleaned should be disposed of as

product waste

SECTION 14. TRANSPORT INFORMATION

Terrestrial (railways, not restricted

highways) - ANTT:
Air - ANAC: not restricted
Ship (sea, rivers, lakes) - not restricted
IMDG:
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or

mixture
The product is classified and labelled in accordance with GHS regulation and the relevant
national laws.

International Regulations

SECTION 16. OTHER INFORMATION

Further information
Other information
: Microbiological purity of this powder dye is ensured by low
dose gamma irradiation. According to present regulations, the
irradiated substances cannot be used for the coloration of
foodstuff.

Full text of other abbreviations

AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with

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Substance key: SXR091103 Revision Date: 02.06.2021
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x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized
System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer;
IATA - International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No
Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level;
NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National
Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines
Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity
Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals;
SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan
Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TECI - Thailand
Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United
Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials
Information System

This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application.
Nothing included in this information waives any of Clariant's General Terms and Conditions of
Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial
property rights must be observed. Due to possible changes in our products and applicable
national and international regulations and laws, the status of our products could change. Material
Safety Data Sheets providing safety precautions, that should be observed when handling or
storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.

BR / EN

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