Dmapa MSDS

Safety data sheet
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 07.03.2012 Version: 8.0
Product: 3-(Dimethylamino)propylamine
(ID no. 30036797/SDS_GEN_EU/EN)
Date of print 08.03.2012
1. Identification of the substance/mixture and of the company/undertaking

Product identifier
3-(Dimethylamino)propylamine
Chemical name: 3-aminopropyldimethylamine
CAS Number: 109-55-7
REACH registration number: 01-2119486842-27-0000, 01-2119486842-27-0001,

01-2119486842-27-0003
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Chemical used in synthesis and/or formulation of industrial products
For the detailed identified uses of the product see appendix of the safety data sheet.
Details of the supplier of the safety data sheet
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Operating Division Intermediates
Telephone: +49 621 60-42259

E-mail address: product-safety.intermediates@basf.com
Emergency telephone number
International emergency number:

Telephone: +49 180 2273-112
2. Hazards Identification
Label elements
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Globally Harmonized System, EU (GHS)
Pictogram:
Signal Word:
Danger
Hazard Statement:
H314 Causes severe skin burns and eye damage.
H311 Toxic in contact with skin.
H331 Toxic if inhaled.
H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H226 Flammable liquid and vapour.
Precautionary Statements (Prevention):

P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face
protection.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P260i Do not breathe dust/gas/mist/vapours.
P243 Take precautionary measures against static discharge.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P272 Contaminated work clothing should not be allowed out of the workplace.
P264 Wash with plenty of water and soap thoroughly after handling.
P270 Do no eat, drink or smoke when using this product.
P233 Keep container tightly closed.
P242 Use only non-sparking tools.
P240 Ground/bond container and receiving equipment.
Precautionary Statements (Response):

P311 Call a POISON CENTER or doctor/physician.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for
breathing.
P303 + P361 + P352 IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Wash with plenty of soap and water.
P361 Remove/Take off immediately all contaminated clothing.
P301 + P330 IF SWALLOWED: rinse mouth.
P362 Take off contaminated clothing and wash before reuse.
P370 + P378.14 In case of fire: Use water spray, dry powder, foam or carbon dioxide for
extinction.
Precautionary Statements (Storage):

P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P403 + P235 Store in a well-ventilated place. Keep cool.
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Precautionary Statements (Disposal):
P501 Dispose of contents/container to hazardous or special waste collection
point.
According to Regulation (EC) No 1272/2008 [CLP]
Hazard determining component(s) for labelling: 3-AMINOPROPYLDIMETHYLAMINE
According to Directive 67/548/EEC or 1999/45/EC
as in Annex VI REGULATION (EC) No 1272/2008 and Annex VI of Directive 67/548/EEC
Hazard symbol(s)
C Corrosive.
R-phrase(s)
R10 Flammable.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R34 Causes burns.
R43 May cause sensitization by skin contact.
S-phrase(s)
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S24 Avoid contact with skin.
Self classification
Hazard determining component(s) for labelling: 3-AMINOPROPYLDIMETHYLAMINE
Classification of the substance or mixture
Flam. Liq. 3
Acute Tox. 3 (Inhalation - vapour)
Acute Tox. 4 (oral)
Acute Tox. 3 (dermal)
Skin Corr./Irrit. 1B
Skin Sens. 1
According to Directive 67/548/EEC or 1999/45/EC
Possible Hazards:
Flammable.
Harmful by inhalation, in contact with skin and if swallowed.
Causes burns.
May cause sensitization by skin contact.
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For the classifications not written out in full in this section the full text can be found in section 16.
Other hazards
If applicable information is provided in this section on other hazards which do not result in classification
but which may contribute to the overall hazards of the substance or mixture.
3. Composition/Information on Ingredients
Substances
Chemical nature
Contains:
Hazardous ingredients (GHS)

according to Regulation (EC) No. 1272/2008
3-aminopropyldimethylamine; N,N-dimethyl-1,3-diaminopropane
Content (W/W): >= 99.8 % Flam. Liq. 3
CAS Number: 109-55-7 Acute Tox. 3 (Inhalation - vapour)
EC-Number: 203-680-9 Acute Tox. 4 (oral)
INDEX-Number: 612-061-00-6 Acute Tox. 3 (dermal)
Skin Corr./Irrit. 1B
Skin Sens. 1
H314, H311, H331, H302, H317, H226
Hazardous ingredients
according to Directive 1999/45/EC
3-aminopropyldimethylamine; N,N-dimethyl-1,3-diaminopropane
Content (W/W): >= 99.8 %
CAS Number: 109-55-7
EC-Number: 203-680-9
INDEX-Number: 612-061-00-6
Hazard symbol(s): C
R-phrase(s): 10, 20/21/22, 34, 43
For the classifications not written out in full in this section, including the indication of danger, the hazard
symbols, the R phrases, and the hazard statements, the full text is listed in section 16.
4. First-Aid Measures
Description of first aid measures
First aid personnel should pay attention to their own safety. If the patient is likely to become
unconscious, place and transport in stable sideways position (recovery position). Immediately remove
contaminated clothing.
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If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately inhale corticosteroid dose
aerosol.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Most important symptoms and effects, both acute and delayed

Symptoms: Overexposure may cause:, bronchospasm, tightness in the chest, coughing
Indication of any immediate medical attention and special treatment needed

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
5. Fire-Fighting Measures
Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide
Special hazards arising from the substance or mixture

nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain
conditions in case of fire other hazardous combustion products may be generated.
Advice for fire-fighters

Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up

For small amounts: Pick up with absorbent material (e.g. sand, sawdust, general-purpose binder).
For large amounts: Pump off product.
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For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder,
kieselguhr).
Cleaning operations should be carried out only while wearing breathing apparatus. Collect waste in
suitable containers, which can be labeled and sealed. Clean contaminated floors and objects
thoroughly with water and detergents, observing environmental regulations. Incinerate or take to a
special waste disposal site in accordance with local authority regulations.
Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be found
in section 8 and 13.
7. Handling and Storage

Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Product should be worked up in closed
equipment as far as possible.
Protection against fire and explosion:

Vapours may form explosive mixture with air. Prevent electrostatic charge - sources of ignition should
be kept well clear - fire extinguishers should be kept handy.
Conditions for safe storage, including any incompatibilities:Segregate from acids and acid forming
substances.
Suitable materials for containers: Stainless steel 1.4541

Further information on storage conditions: Keep container tightly closed in a cool, well-ventilated
place.
Storage stability:
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the
warrantee of application properties can be deduced.
Specific end use(s)

See exposure scenario(s) in the attachment to this safety data sheet.
8. Exposure Controls/Personal Protection

Control parameters
Components with workplace control parameters
109-55-7: 3-aminopropyldimethylamine; N,N-dimethyl-1,3-diaminopropane
PNEC
freshwater: 0.0535 mg/l
marine water: 0.00535 mg/l
intermittent release: 0.535 mg/l

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sediment (freshwater): 0.585 mg/kg
sediment (marine water): 0.0585 mg/kg
soil: 0.0854 mg/kg
STP: 69.5 mg/l
DNEL
worker:
Long-term exposure - systemic and local effects, Inhalation: 4.9 mg/m3
Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Gas filter for gases/vapours of organic
compounds (boiling point >65 °C, e. g. EN 14387 Type A) Consider the risk management measures as
outlined in the exposure scenario.
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
fluoroelastomer (FKM) - 0.7 mm coating thickness
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2,
corresponding > 30 minutes of permeation time according to EN 374)
butyl rubber (butyl) - 0.7 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in practice
may be much shorter than the permeation time determined through testing.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of
dust).
General safety and hygiene measures

Avoid inhalation of vapour. Avoid contact with the skin, eyes and clothing. Handle in accordance with
good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to
the stated personal protection equipment. Take off immediately all contaminated clothing. Store work
clothing separately.
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9. Physical and Chemical Properties
Information on basic physical and chemical properties
Form: liquid
Colour: colourless to yellow
Odour: amine-like
pH value: 12.7
(100 g/l, 20 °C)
Melting point: < -50 °C
Boiling point: 135.1 °C (measured)
(1,013 hPa)
Flash point: 30 °C (DIN 51755)
Lower explosion limit: 2.3 %(V)
Upper explosion limit: 12.3 %(V)
Ignition temperature: 215 °C (DIN 51794)
Vapour pressure: 5.9 hPa (measured)
(20 °C)
static
Density: 0.820 g/cm3
(15 °C)
0.818 g/cm3
(20 °C)
0.785 g/cm3
(50 °C)
Solubility in water: miscible
(20 °C)
Partitioning coefficient n-octanol/water (log Kow): -0.352 (OECD Guideline 107)
(25 °C)
Self ignition: Temperature: 20 °C
not self-igniting
Thermal decomposition: 680 kJ/kg (DSC (DIN 51007))

If product is heated above decomposition temperature toxic vapours
may be released. No decomposition if used as directed.
Viscosity, dynamic: 1.6 mPa.s
(20 °C)
Other information
pKA: 9.33
(35 °C)
Hygroscopy: hygroscopic
Surface tension:
Based on chemical structure, surface
activity is not to be expected.
Grain size distribution: The substance / product is marketed or used in a non solid or
granular form.
Molar mass: 102.18 g/mol
10. Stability and Reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
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Formation of Remarks: Forms no flammable gases in the

flammable gases: presence of water.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions

Strong exothermic reaction with acids.
Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame.
Incompatible materials
Substances to avoid:
Copper, strong acids, oxidizing agents, brass
Hazardous decomposition products
Hazardous decomposition products:

carbon monoxide, Carbon dioxide
nitrous gases
11. Toxicological Information

Information on toxicological effects
Acute toxicity
Assessment of acute toxicity:

Of moderate toxicity after single ingestion. Virtually nontoxic by inhalation. Of moderate toxicity after
short-term skin contact.
Experimental/calculated data:
LD50 rat (oral): 410 mg/kg (OECD Guideline 401)
LC50 rat (by inhalation): > 4.3 mg/l 4 h (OECD Guideline 403)
No mortality was observed. The vapour was tested.
LD50 rabbit (dermal): 2,139 mg/kg (OECD Guideline 402)
Irritation
Assessment of irritating effects:

Corrosive! Damages skin and eyes. May cause severe damage to the eyes.
Skin corrosion/irritation rabbit: Corrosive. (BASF-Test)
Serious eye damage/irritation rabbit: irreversible damage (BASF-Test)

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Respiratory/Skin sensitization
Assessment of sensitization:
Sensitization after skin contact possible.
Guinea pig maximization test guinea pig: skin sensitizing
Germ cell mutagenicity
Assessment of mutagenicity:
Most of the results from the available studies show no evidence of a mutagenic effect.
Carcinogenicity
Assessment of carcinogenicity:
No data available concerning carcinogenic effects.
Study not necessary due to exposure considerations.
Under certain conditions the substance can form nitrosamines. Nitrosamines are carcinogenic in
animal studies.
Reproductive toxicity
Assessment of reproduction toxicity:

The results of animal studies gave no indication of a fertility impairing effect.
Developmental toxicity
Assessment of teratogenicity:
No indications of a developmental toxic / teratogenic effect were seen in animal studies.
The results were determined in a Screening test (OECD 421/422).
Experiences in humans
Lung function impairment:
Specific target organ toxicity (single exposure)
Assessment of STOT single:

The available information is not sufficient for evaluation.
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Assessment of repeated dose toxicity:

After repeated administration the prominent effect is the induction of corrosion.
Aspiration hazard
No aspiration hazard expected.

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12. Ecological Information

Toxicity
Assessment of aquatic toxicity:

Acutely harmful for aquatic organisms. The inhibition of the degradation activity of activated sludge is
not anticipated when introduced to biological treatment plants in appropriate low concentrations.
Toxicity to fish:
LC50 (96 h) 122 mg/l, Leuciscus idus (DIN 38412 Part 15, static)
The details of the toxic effect relate to the nominal concentration.
Aquatic invertebrates:
EC50 (48 h) 59.5 mg/l, Daphnia magna (Directive 79/831/EEC, static)
Aquatic plants:
EC50 (72 h) 53.5 mg/l (biomass), Scenedesmus subspicatus (DIN 38412 Part 9, static)
Microorganisms/Effect on activated sludge:

EC50 (17 h) 94.5 mg/l, Pseudomonas putida (DIN 38412 Part 8, aerobic)
Chronic toxicity to fish:

Study scientifically not justified.
Chronic toxicity to aquatic invertebrates:

Assessment of terrestrial toxicity:

Persistence and degradability
Assessment biodegradation and elimination (H2O):

Readily biodegradable (according to OECD criteria).
Elimination information:
60 - 70 % BOD of the ThOD (20 d) (OECD 301D; EEC 92/69, C.4-E) (aerobic, activated sludge,
domestic, adapted)
Literature data.
90 - 100 % BOD of the ThOD (28 d) (OECD 301 A (new version)) (aerobic, activated sludge,
domestic, adapted)
The product has not been tested. The statement has been derived from products of a similar structure
or composition.
Information on Stability in Water (Hydrolysis):

According to structural properties, hydrolysis is not expected/probable.
Bioaccumulative potential
Bioaccumulation potential:
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Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is not to
be expected.
Mobility in soil (and other compartments if available)
Assessment transport between environmental compartments:

The substance will not evaporate into the atmosphere from the water surface.
Adsorption to solid soil phase is not expected.
The data refer to the uncharged form of the substance.
Results of PBT and vPvB assessment
According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): Not fulfilling PBT
(persistent/bioaccumulative/toxic) criteria. Self classification
According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH): Not fulfilling vPvB (very persistent/very
bioaccummulative) criteria. Self classification
Additional information
Adsorbable organically-bound halogen (AOX):

This product contains no organically-bound halogen.
13. Disposal Considerations
Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to
dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in
cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling
after being thoroughly cleaned.
14. Transport Information
Land transport
ADR
Hazard class: 8
Packing group: II
ID number: UN 2734
Hazard label: 8, 3
Proper shipping name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (contains
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3-AMINOPROPYLDIMETHYLAMINE)
RID
Hazard class: 8
Packing group: II
ID number: UN 2734
Hazard label: 8, 3
Inland waterway transport

ADN
Hazard class: 8
Packing group: II
ID number: UN 2734
Hazard label: 8, 3
Sea transport
IMDG
Hazard class: 8
Packing group: II
ID number: UN 2734
Hazard label: 8, 3
Marine pollutant: NO
Air transport
IATA/ICAO
Hazard class: 8
Packing group: II
ID number: UN 2734
Hazard label: 8, 3
15. Regulatory Information

Safety, health and environmental regulations/legislation specific for the substance or
mixture
If other regulatory information applies that is not already provided elsewhere in this safety data sheet,
then it is described in this subsection.
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16. Other Information
Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases,
and the hazard statements, if mentioned in section 2 or 3:
C Corrosive.
10 Flammable.
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
34 Causes burns.
43 May cause sensitization by skin contact.
Flam. Liq. Flammable liquid
Acute Tox. Acute toxicity
Skin Corr./Irrit. Skin corrosion/irritation
Skin Sens. Skin sensitization
H314 Causes severe skin burns and eye damage.
H311 Toxic in contact with skin.
H331 Toxic if inhaled.
H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H226 Flammable liquid and vapour.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of
the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.
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Annex: Exposure Scenarios

Index
1. Formulation & (re)packing of substances and mixtures
SU3; ERC2; PROC3, PROC5, PROC8a, PROC8b, PROC9
2. Use as an intermediate
SU3; ERC6a; PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC9
3. Use in laboratories
SU3; ERC4, ERC6a; PROC15
4. Use as a Process chemical, Production of Polymers and Synthetic Fibres

SU3; ERC3, ERC5; PROC7, PROC14, PROC21, PROC24; PC32
5. Use as a Process chemical, Rubber production and processing

SU22; SU12, SU19; ERC8c, ERC8f; PROC10, PROC11, PROC13; PC32
6. Use in coatings
SU3; ERC5; PROC7, PROC8a, PROC8b, PROC10, PROC13; PC9
7. Use in coatings
SU22; ERC8c, ERC8f; PROC8a, PROC8b, PROC10, PROC11, PROC13; PC9
8. Road and construction applications

SU22; ERC8f; PROC5, PROC8a, PROC10, PROC13, PROC19, PROC21, PROC24; PC0
9. Use as Monomer
SU22; ERC8c, ERC8f; PROC14; PC9, PC32
10. Use as Monomer

SU3; ERC6c; PROC14; PC9, PC32
11. Polymer processing

SU22; ERC8c, ERC8f; PROC2, PROC14, PROC15
****************
1. Short title of exposure scenario

Formulation & (re)packing of substances and mixtures
SU3; ERC2; PROC3, PROC5, PROC8a, PROC8b, PROC9
Control of exposure and risk management measures

Contributing exposure scenario
ERC2: Formulation of preparations
As no environmental hazard was identified no
Use descriptors covered environmental-related exposure assessment and risk
characterization was performed.

Use descriptors covered PROC3: Use in closed batch process (synthesis or
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formulation).
Use domain: industrial
Operational conditions
3-aminopropyldimethylamine;
N,N-dimethyl-1,3-diaminopropane
Concentration of the substance
Content: >= 0 % - <= 100 %
Physical state Liquid, moderate fugacity

480 min 5 days per week
Duration and Frequency of activity
Indoor/Outdoor Indoor
Exposed skin area Palm of one hand (240 cm²)
Risk Management Measures
Avoid frequent and direct contact with
substance. Supervision in place to
check that the RMMs in place are
being used correctly and OCs
followed. Clean equipment and the
work area every day. Ensure
minimization of manual phases
Wear chemically resistant gloves in
combination with specific activity
training Use suitable eye protection.
Wear suitable coveralls to prevent
exposure to the skin.
Risk Management Measures are
based on qualitative risk
characterisation.
Provide extract ventilation to points
Effectiveness: 90 %
where emissions occur (LEV).
Wear suitable respiratory protection. Effectiveness: 90 %
Reduce concentration to less than
45%, In case no respiratory protection
is used:
Exposure estimate and reference to its source
Assessment method ECETOC TRA v2.0 Worker
Worker - inhalative, long-term - local und systemic
Exposure estimate 1.065 mg/m³
Risk Characterization Ratio (RCR) 0.217
The short-term exposure value corresponds to the
long-term value multiplied by a factor of 2.
Assessment method Qualitative assessment
Worker - dermal
Guidance to Downstream Users
For scaling see: http://www.ecetoc.org/tra

PROC5: Mixing or blending in batch processes for
formulation of preparations and articles (multistage and/or
Use descriptors covered significant contact).
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Content: >= 0 % - <= 100 %

Exposed skin area Palm of both hands (480 cm²)
Use suitable eye protection. Wear
chemically resistant gloves in
training Wear suitable coveralls to
prevent exposure to the skin.
characterisation.
Effectiveness: 90 %
In case no respiratory protection is
used:, Reduce concentration to less
than 20%
Worker - dermal

PROC8a: Transfer of substance or preparation
(charging/discharging) from/to ves-sels/large containers at
Use descriptors covered non-dedicated facilities
Content: >= 0 % - <= 100 %
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Exposed skin area Both hands (960 cm²)
substance. Clean equipment and the
work area every day. Supervision in
place to check that the RMMs in place
are being used correctly and OCs
followed. Ensure minimization of
manual phases
characterisation.
Effectiveness: 90 %
Worker - dermal

PROC8b: Transfer of substance or preparation
(charging/discharging) from/to vessels/large containers at
Use descriptors covered dedicated facilities
Content: >= 0 % - <= 100 %

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characterisation.
Effectiveness: 97 %
used:, Reduce duration of activity to
less than 60 min
Worker - dermal

PROC9: Transfer of substance or preparation into small
containers (dedicated filling line, including weighing).
Use descriptors covered
Content: >= 0 % - <= 100 %

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characterisation.
Effectiveness: 90 %
than 20%
Worker - dermal
****************

Use as an intermediate
SU3; ERC6a; PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC9

ERC6a: Industrial use resulting in manufacture of another
substance (use of intermediates)
environmental-related exposure assessment and risk

PROC1: Use in closed process, no likelihood of exposure.
Use descriptors covered Use domain: industrial
Content: >= 0 % - <= 100 %

Duration and Frequency of activity 480 min 5 days per week
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combination with intensive
management supervision control.
characterisation., Personal measures
have to be applied in case of potential
exposure only.
Worker- inhalative, short-term - local und systemic
Worker - dermal

PROC2: Use in closed, continuous process with occasional
controlled exposure.
Content: >= 0 % - <= 100 %

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characterisation.
Effectiveness: 90 %
Worker - oral, long-term - local und systemic
Worker - dermal

PROC3: Use in closed batch process (synthesis or
formulation).
Content: >= 0 % - <= 100 %

characterisation.
Effectiveness: 90 %
45%, In case no respiratory protection
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is used:
Worker - dermal

PROC4: Use in batch and other process (synthesis) where
opportunity for exposure arises.
Content: >= 0 % - <= 100 %

characterisation.
Effectiveness: 90 %
less than 60 min, Alternatively:,
50%
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ECETOC TRA initial exposure value multiplied by a factor of
2.
Worker - dermal

Content: >= 0 % - <= 100 %

manual phases
characterisation.
Effectiveness: 90 %
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Worker - dermal

Content: >= 0 % - <= 100 %

characterisation.
Effectiveness: 97 %
less than 60 min
Worker - dermal
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PROC9: Transfer of substance or preparation into small
containers (dedicated filling line, including weighing).
Content: >= 0 % - <= 100 %

characterisation.
Effectiveness: 90 %
than 20%
Worker - dermal
****************

Use in laboratories
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SU3; ERC4, ERC6a; PROC15

ERC4: Industrial use of processing aids in processes and
products, not becoming part of articles

ERC6a: Industrial use resulting in manufacture of another
substance (use of intermediates)

PROC15: Use a laboratory reagent.
Content: >= 0 % - <= 100 %

characterisation.
Effectiveness: 97 %
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Worker - dermal
****************

Use as a Process chemical, Production of Polymers and Synthetic Fibres
SU3; ERC3, ERC5; PROC7, PROC14, PROC21, PROC24; PC32

ERC3: Formulation in materials
Use descriptors covered environmental-related exposure assessment and risk

ERC5: Industrial use resulting in inclusion into or onto a
matrix

PROC7: Industrial spraying
Content: >= 0 % - <= 100 %

Room size 1,000 m3
Page: 29/57
characterisation.
Ensure that a spraying booth is used.
Assessment method Stoffenmanager v4.0
Exposure estimate 0 mg/m³
Risk Characterization Ratio (RCR) 0
Worker - dermal
For scaling see: https://www.stoffenmanager.nl/default.aspx

Content: >= 0 % - <= 100 %

Room size 1,000 m3
characterisation.
Effectiveness: 97 %
Page: 30/57
2.
Worker - dermal

Content: >= 0 % - <= 100 %

Room size 1,000 m3
characterisation.
Effectiveness: 97 %
Ensure that the worker is in a
seperated (control) room with
independent air supply
Page: 31/57
2.
Worker - dermal

PROC14: Production of preparations or articles by
tabletting, compression, extrusion, pelettisation.
Content: >= 0 % - <= 100 %

characterisation.
Effectiveness: 90 %
than 20%
2.
Worker - dermal
Page: 32/57

PROC21: Low energy manipulation of substances bound in
materials and/or articles PROC24: High (mechanical)
energy work-up of substances bound in materials and/or
articles
Content: >= 0 % - <= 100 %
Physical state Solid, high dustiness

Exposed skin area Both hands and main part of the arms (1980 cm²)
characterisation.
Effectiveness: 90 %
PROC21
2.
Worker - dermal
PROC24
Page: 33/57
2.
****************

Use as a Process chemical, Rubber production and processing
SU22; SU12, SU19; ERC8c, ERC8f; PROC10, PROC11, PROC13; PC32

ERC8c: Wide dispersive indoor use resulting in inclusion
into or onto a matrix

ERC8f: Wide dispersive outdoor use resulting in inclusion

PROC10: Roller application or brushing PROC13:
Treatment of articles by dipping and pouring.
Use domain: professional
Content: >= 0 % - <= 100 %

Relevant for PROC 10


Page: 34/57
characterisation.
Effectiveness: 80 %
than 5%
2.
Worker - dermal

PROC11: Non industrial spraying
Use descriptors covered Use domain: professional
Content: >= 0 % - <= 100 %

Room size 100 m3
Page: 35/57
characterisation.
Worker - dermal

Content: >= 0 % - <= 100 %

Room size 100 m3
characterisation.
Ensure doors and windows are
Effectiveness: 97 %
opened (general ventilation).
Ensure mechanical ventilation is in
place. Ensure that the worker is in a
Page: 36/57
2.
Worker - dermal
****************

Use in coatings
SU3; ERC5; PROC7, PROC8a, PROC8b, PROC10, PROC13; PC9

ERC5: Industrial use resulting in inclusion into or onto a
matrix

Content: >= 0 % - <= 100 %

Room size 1,000 m3
Page: 37/57
characterisation.
Worker - dermal

Content: >= 0 % - <= 100 %

Room size 1,000 m3
characterisation.
Effectiveness: 97 %
Page: 38/57
2.
Worker - dermal

Content: >= 0 % - <= 100 %

Room size 1,000 m3
characterisation.
Effectiveness: 97 %
Ensure that the worker is in a
2.
Worker - dermal
Page: 39/57

Content: >= 0 % - <= 100 %

manual phases
characterisation.
Effectiveness: 90 %
Worker - dermal

Use descriptors covered (charging/discharging) from/to vessels/large containers at
dedicated facilities
Page: 40/57
Content: >= 0 % - <= 100 %

characterisation.
Effectiveness: 97 %
less than 60 min
Worker - dermal

Page: 41/57
Content: >= 0 % - <= 100 %



characterisation.
Effectiveness: 90 %
than 20%
2.
Worker - dermal
****************

Use in coatings
SU22; ERC8c, ERC8f; PROC8a, PROC8b, PROC10, PROC11, PROC13; PC9
Page: 42/57


Content: >= 0 % - <= 100 %

characterisation.
Effectiveness: 80 %
Page: 43/57
Worker - dermal

Content: >= 0 % - <= 100 %

characterisation.
Effectiveness: 90 %
Worker - dermal
Page: 44/57

Content: >= 0 % - <= 100 %



characterisation.
Effectiveness: 80 %
than 5%
2.
Worker - dermal
Page: 45/57

Content: >= 0 % - <= 100 %

Room size 100 m3
characterisation.
Worker - dermal

Content: >= 0 % - <= 100 %

Page: 46/57
Room size 100 m3
characterisation.
Ensure doors and windows are
Effectiveness: 97 %
opened (general ventilation).
Ensure mechanical ventilation is in
place. Ensure that the worker is in a
2.
Worker - dermal
****************

Road and construction applications
SU22; ERC8f; PROC5, PROC8a, PROC10, PROC13, PROC19, PROC21, PROC24; PC0

Use descriptors covered As no environmental hazard was identified no
Page: 47/57

Content: >= 0 % - <= 100 %

characterisation.
Effectiveness: 80 %
Worker - dermal

Page: 48/57
Content: >= 0 % - <= 100 %



characterisation.
Effectiveness: 80 %
than 5%
2.
Worker - dermal

PROC5: Mixing or blending in batch processes for
Use descriptors covered formulation of preparations and articles (multistage and/or
significant contact). PROC19: Hand-mixing with intimate
Page: 49/57
contact and only PPE available.
Content: >= 0 % - <= 100 %

Relevant for PROC 5


characterisation.
Effectiveness: 80 %
Worker - dermal

PROC21: Low energy manipulation of substances bound in
materials and/or articles
Page: 50/57
Content: >= 0 % - <= 100 %

characterisation.
Effectiveness: 80 %
2.
Worker - dermal

PROC24: High (mechanical) energy work-up of substances
bound in materials and/or articles
Content: >= 0 % - <= 100 %

Duration and Frequency of activity 480 min 5 days per week
Page: 51/57
characterisation.
Effectiveness: 75 %
less than 60 min, Alternatively:,
80%
2.
Worker - dermal
****************

Use as Monomer
SU22; ERC8c, ERC8f; PROC14; PC9, PC32

Use descriptors covered As no environmental hazard was identified no
Page: 52/57


Content: >= 0 % - <= 100 %

characterisation.
Effectiveness: 80 %
than 80%
Page: 53/57
Worker - dermal
****************

Use as Monomer
SU3; ERC6c; PROC14; PC9, PC32

ERC6c: Industrial use of monomers for manufacture of
thermoplastics

Content: >= 0 % - <= 100 %

characterisation.
Effectiveness: 90 %
Page: 54/57
than 20%
2.
Worker - dermal
****************

Polymer processing
SU22; ERC8c, ERC8f; PROC2, PROC14, PROC15



PROC2: Use in closed, continuous process with occasional
controlled exposure.
Content: >= 0 % - <= 100 %

Page: 55/57
characterisation.
Effectiveness: 80 %
Worker - dermal

Content: >= 0 % - <= 100 %

Page: 56/57
characterisation.
Effectiveness: 80 %
than 80%
Worker - dermal

PROC15: Use a laboratory reagent.
Content: >= 0 % - <= 100 %

Page: 57/57
characterisation.
Effectiveness: 80 %
less than 60 min
Worker - dermal
****************

Dmapa MSDS

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Dmapa MSDS

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Safety data sheet

1. Identification of the substance/mixture and of the company/undertaking

REACH registration number: 01-2119486842-27-0000, 01-2119486842-27-0001,

Details of the supplier of the safety data sheet

Telephone: +49 621 60-42259

Emergency telephone number

International emergency number:

Globally Harmonized System, EU (GHS)

Precautionary Statements (Prevention):

Precautionary Statements (Response):

Precautionary Statements (Storage):

According to Regulation (EC) No 1272/2008 [CLP]

Hazard determining component(s) for labelling: 3-AMINOPROPYLDIMETHYLAMINE

According to Directive 67/548/EEC or 1999/45/EC

as in Annex VI REGULATION (EC) No 1272/2008 and Annex VI of Directive 67/548/EEC

Hazard determining component(s) for labelling: 3-AMINOPROPYLDIMETHYLAMINE

Classification of the substance or mixture

According to Regulation (EC) No 1272/2008 [CLP]

According to Directive 67/548/EEC or 1999/45/EC

According to Regulation (EC) No 1272/2008 [CLP]

Hazardous ingredients (GHS)

On contact with eyes:

Most important symptoms and effects, both acute and delayed

Indication of any immediate medical attention and special treatment needed

Special hazards arising from the substance or mixture

Advice for fire-fighters

6. Accidental Release Measures

Methods and material for containment and cleaning up

Reference to other sections

7. Handling and Storage

Protection against fire and explosion:

Suitable materials for containers: Stainless steel 1.4541

Specific end use(s)

8. Exposure Controls/Personal Protection

Components with workplace control parameters

109-55-7: 3-aminopropyldimethylamine; N,N-dimethyl-1,3-diaminopropane

marine water: 0.00535 mg/l

intermittent release: 0.535 mg/l

sediment (marine water): 0.0585 mg/kg

soil: 0.0854 mg/kg

STP: 69.5 mg/l

General safety and hygiene measures

Thermal decomposition: 680 kJ/kg (DSC (DIN 51007))

10. Stability and Reactivity

Formation of Remarks: Forms no flammable gases in the

Possibility of hazardous reactions

Hazardous decomposition products

Hazardous decomposition products:

11. Toxicological Information

Assessment of acute toxicity:

LD50 rabbit (dermal): 2,139 mg/kg (OECD Guideline 402)

Assessment of irritating effects:

Serious eye damage/irritation rabbit: irreversible damage (BASF-Test)

Germ cell mutagenicity

Study not necessary due to exposure considerations.

Assessment of reproduction toxicity:

The results were determined in a Screening test (OECD 421/422).

Specific target organ toxicity (single exposure)

Assessment of STOT single:

Assessment of repeated dose toxicity:

No aspiration hazard expected.

12. Ecological Information

Assessment of aquatic toxicity: