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5 DSE F5CHEMACU/E/13c
CHEMISTRY
CHEMISTRY
1. All questions are COMPULSORY. Write your answers in the spaces provided in this
Question / Answer Book.
If you use supplementary answer sheet(s) for these two sections, write your Candidate
Number on each sheet and fasten them with string to this Question-Answer Book.
2. Write your class and class number in the spaces provided on this cover.
3. A Periodic Table and some useful constants are printed on this Question/Answer Book.
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Section A
1. A compound formed from element X and element Y has the following electronic structure:
A. Group II
B. Group IV
C. Group VI
D. Group VII
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4. Which of the following substances can be obtained from fractional distillation of liquid air?
(1) O2
(2) Ar
(3) H2
5. Which of the following pairs of solution, when mixed, would produce a pale blue precipitate?
6. Which of the following statements concerning carbon dioxide gas are correct?
(1) proton.
(2) electron.
(3) neutron.
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8. Which of the following statements concerning 10
5 B and 11
5 B are correct?
9. Element Y and Z are in the same group of the periodic table. Which of the following
statements concerning Y and Z is / are correct?
A. (2) only
B. (3) only
C. (1) and (2) only
D. (1) and (3) only
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11. Which of the following pair of substances can react with each other to give a brown solution?
12. Which of the following statements concerning chlorine water is / are correct?
(1) It is a mixture.
(2) It turns moist red litmus blue and then bleaches it.
(3) It is a common reducing agent.
13. To which of the following molecules is/are the ‘octet rule’ NOT applicable?
(1) NH3
(2) PCl5
(3) SF6
H C2H5 H Cl H Cl
C C C C C C
Cl H C2H5 H C2H5 H
A. 1-chlorobut-2-ene.
B. 1-chloro-1-ethylethene.
C. 1-chlorobut-1-ene
D. 1-ethyl-1-chloroethene.
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15. In which of the following reactions does the underlined substance act as a reducing agent?
A. Mg + 2HCl MgCl2 + H2
B. H2SO4 + SO3 H2S2O7
C. SO2 + 2NaOH Na2SO3 + H2O
D. 2MnO2 + H2 Mn2O3 + H2O
16. In which of the following substances does sulphur has the smallest oxidation number?
A. SO2
B. SO3
C. ZnS
D. CaSO3
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Directions: Q.18 and Q.19 refer to the following chemical cell:
18. Which of the following statements concerning the above chemical cell is / are correct?
A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only
A. calcium
B. magnesium
C. silver
D. lead
A. CH3Cl
B. PH3
C. HF
D. BCl3
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21. Consider the following equilibrium:
(1) If the pressure is kept constant, increasing the temperature would increase the yield of
ammonia.
(2) When the pressure is increased, the total number of molecules in the system decreases.
(3) When more nitrogen is injected to the system, the yield of ammonia increases.
23. Which of the following substances can be used to distinguish between dilute sulphuric acid
and concentrated sulphuric acid?
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24. Which of the following statements concerning one mole of carbon dioxide gas is/are correct?
A. (1) only
B. (2) only
C. (1) and (3) only
D. (2) and (3) only
25. 200 cm3 of a gas Y2 react completely with 300 cm3 of oxygen to form 200 cm3 of a gaseous
oxide. If all measurements are made at room temperature and pressure, the formula of the
gaseous oxide is
A. YO2
B. Y2O
C. Y2O3
D. Y3O2
26. Solution W is 50 cm3 of 1.5 M HCl and Solution X is 100 cm3 of 0.75 M CH3COOH.
Which of the following statements concerning W and X is correct?
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27.
In the above graph, curve A was obtained by the reaction between 100 cm3 of 1.5 M HCl and
10.0 g limestone.
Which of the following changes would produce curve B?
28. During the electrolysis of concentrated copper(II) chloride solution by using copper
electrodes. Which of the following combination is correct?
Anode Cathode
A. oxygen liberated copper deposited
B. copper dissolved copper deposited
C. chlorine liberated hydrogen liberated
D. copper deposited hydrogen liberated
29. Which apparatus should be used to prepare 250 cm3 of 1.0 M citric acid from its solid?
(1) pipette
(2) volumetric flask
(3) wash bottle
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30. Which of the following reactions does not require the use of a catalyst?
A. Cracking of kerosene.
B. Electrolysis of brine solution.
C. Hydrogenation of ethene to ethane.
D. Condensation polymerization of urea-methanal.
(1) OH-
(2) NH4+
(3) NH3
32. Which of the following cases is a practicable way of preparing the salt underlined?
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Direction: Each question below (Question Nos. 33 to 36) consists of two separate statements.
Decide whether each of the two statements is true or false; if both are true, then
decide whether or not the second statement is a correct explanation of the first
statement. Then select one option from A to D according to the following table:
A. Both statements are true and the 2nd statement is a correct explanation of the 1st
statement.
B. Both statements are true but the 2nd statement is NOT a correct explanation of the
1st statement.
C. The 1st statement is false but the 2nd statement is true.
D. Both statements are false.
33. Methanoic acid is a dibasic acid. The molecule of one methanoic acid has
two hydrogen atoms.
34. Ionic compounds are formed by metal Potassium oxide is an ionic compound.
and non-metal only.
35. Magnesium can displace copper from Magnesium occupies a higher position
copper(II) sulphate solution. than copper in the metal reactivity series.
36. For endothermic reaction, increasing Increasing temperature can increase the
temperature can increase the Kc value. rate of reaction.
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Section B
(b) Explain whether the reaction in (a) is a redox reaction or not. (2 marks)
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2. The flow diagram below shows some reactions about metal A.
(ii) Write the chemical reaction between metal A and dilute hydrochloric acid. State whether
it is a redox reaction or not. Explain your answer in term of the change in oxidation
number. (3 marks)
(b) Solution B react with aqueous ammonia to form a precipitate iron(II) hydroxide.
(ii) Write the chemical reaction between solution B and aqueous ammonia. (2 marks)
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(c) If calcium is added to solution B, metal A and colourless gas bubbles formed.
(a) State the type of polymerization for the formation of this polymer. Explain your answer.
(2 marks)
(b) Draw the repeating unit and write the equation to show the formation of the polymer.
(2 marks)
(c) Calculate the number of repeating units in this polymer if it has a relative molecular mass of
196000. (2 marks)
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4. The diagram below shows an industrial plant of oil refinery.
(b) Why can the various petroleum fractions be obtained from crude oil by fractional distillation?
(1 mark)
(c) Different fractions are obtained from crude oil under high temperature and absence of air.
(i) Explain why the process must undergo in the absence of air?
(ii) Explain whether the product from B or F has a higher boiling point. (2 marks)
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(d) Liquefied petroleum gas (LPG) consists mainly of butane.
5. For each of the following experiments, state an expected observation and write a chemical
equation for the reaction involved.
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6. A student says:
“Both sodium chloride solution and ethanol are electrolyte because they can ionize in water
to give mobile ions.”
State whether the above statements is true or false. Explain your answer.
(3 marks)
7. State whether each of the following statements is true or false. Explain your answer.
(c) In anodization process, the aluminium object should be connected to the negative terminal of
the output power supply. (2 marks)
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*8. Briefly describe how you would conduct an experiment, using the materials and apparatus
listed below, to nickel-plate a clean metal spoon. (Diagrams are NOT required.) State the
expected observation of the experiment.
a clean metal spoon, a nickel strip, nickel(II) nitrate crystals, a large beaker of deionized water,
a direct current power supply and connecting wires
(6 marks)
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For question 9, candidates are required to give a paragraph-length answer. In this
question, 6 marks will be awarded for chemical knowledge and 3 marks for effective
communication.
*9. A student has six unlabelled bottles and each contains one of the following colourless
chemicals:
Suggest how he would carry out chemical tests to identify the contents of each bottle, using
the materials and apparatus listed below. Your answer should include the observation of each
test.
Acidified potassium dichromate solution, 1 M iron (III) nitrate solution, magnesium ribbon, 1
M calcium nitrate solution, test tubes and a Bunsen burner
(You are NOT required to write chemical equations. Answers in the form of flow diagrams will
NOT be marked)
(7 marks)
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Section C
10. Consider the set-up shown below:
A, B, C and D are four electrodes. A, B and D are made of copper while C is made of zinc.
(b) State the direction of electron flow between electrode A and electrode D. (1 mark)
(c) The salt bridge is a filter paper soaked with a saturated solution.
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(d) A student says: “Sodium can be used for electrode C instead of zinc to give a higher
voltage.” Explain whether his answer is true or false. (2 marks)
(e) When the circuit is closed for several minutes, the mass of electrode B increase.
(i) Write chemical equations for the reaction occur in electrode A and B.
(ii) State the colour change of the copper (II) sulphate solution. (3 marks)
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11. A student carried out the following experiment to determine the purity of citric acid (a tribasic
acid with a relative molecular mass of 192) in a sample of vitamin tablet. The experiment
consisted of the following procedures:
2.5 g of the vitamin tablet powder dissolved in distilled water and made up to 250 cm3. 25
cm3 of the diluted solution was withdrawn to a conical flask and titrated against 0.1 M sodium
hydroxide solution.
(a) Name the apparatus that should be used to transfer 25 cm3 of the diluted sample to the
conical flask. (1 mark)
(b) Suggest a suitable indicator for the titration and state the colour change at the end point.
(2 marks)
The student carried out four titrations altogether. The titration results are listed in the table
below:
Titration
1 2 3 4
Burette reading
Final reading / cm3 12.5 13.7 17.1 21.6
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(c) (i) Based on the titration results, calculate a reasonable average for the volume of the
sodium hydroxide solution used.
(6 marks)
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12. Consider the following equilibrium at 298 K:
A mixture of 10 mol of X2(g) and 10 mol of Y2(g) was placed in a vessel of volume 10 dm3.
When the system had reached equilibrium, it was found that 6 mol of Y2(g) left in the system.
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13. KIO3 reacts with hydrogen peroxide according to the following equation
(ii) What would be seen if the reagents were mixed in a conical flask? (2 marks)
(iii) Suggest ONE physical method to follow the progress of this reaction. (1 marks)
END OF PAPER
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Suggested solution
Section A
Section B
1.
(a) 2NH3 + H2O2 N2H4 + 2H2O 1
H
(c) 2NH3(g) + H2O2(l) N2H4(l) + 2H2O(l)
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2.
(a) (i) Iron 1
(ii) Fe + 2HCl FeCl2 + H2 1
It is a redox reaction. 1
Because the oxidation number of Fe changes from 0 to +2 1
OR, The oxidation number of H changes from +1 to 0 (1)
(b) (i) Dirty green 1
(ii) Fe2+ + 2OH- Fe(OH)2 1
(c) (i) Metal displacement reaction 1
(ii) Calcium reacts with water in solution B to form hydrogen gas. 1
3.
(a) Addition polymerization 1
Because the monomer is unsaturated hydrocarbon. 1
(b) Repeating unit:
H H
C C
H CH2CH3
1
Equation:
H H
H H
n C C C C
H CH2CH3
H CH2CH3 1
n
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4.
(a) Crude oil originates from dead marine organisms / animals / plants. 1
(b) Because different components in crude oil have different boiling points. 1
(c) (i) Combustion of crude oil occurs if air is presence under high temperature. 1
(ii) F because its relative molecular mass is higher than that of B 1
(d) (i) A 1
(ii) 2C4H10 + 13O2 8CO2 + 10H2O 1
5.
(a) CaO + 2HCl CaCl2 + H2O 1
CaO + 2H Ca+ 2+
+ H2O (1)
The (white) solid dissolves. 1
Or, Heat evolved. (1)
6.
False
Sodium chloride solution is an electrolyte because it is an ionic compound. 1
When it dissolves in water, it will dissociate to give mobile ions. 1
Ethanol is not an electrolyte because it will not ionize to give mobile ions. 1
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7.
(a) False
The standard state of carbon is graphite. 1
The standard enthalpy change of formation of diamond is not zero. 1
(b) Ture.
Propan-1-ol molecules can form intermolecular hydrogen bonds with water molecules. 1
It has small molecular mass. 1
(c) False.
The aluminium object should be connected to the positive terminal of the output power
supply. 1
It is because it undergoes oxidation and acts as the anode of the electrolytic cell. 1
Connect the clean metal spoon to the negative terminal and the nickel strip to the positive
terminal of the power supply. 1
Or, connect the clean metal spoon and the nickel strip to the power supply with the spoon as the
cathode and the nickel strip as the anode. (1)
Immerse / dip the spoon and the nickel strip in the nickel(II) nitrate solution. 1
Observation
a layer of nickel (silvery metal) is deposited onto the spoon. 1
Communication mark 1
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9. Chemical knowledge (6 marks)
(For this question, candidates may give answers in an order different from that illustrated below.
In such cases, award one mark for each test, which can identify / eliminate a substance in the
list.)
Add acidified potassium dichromate solution to each chemical and heat the mixture.
Only ethanol can turn the solution from orange to green. 1
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Section C
10.
(a) A and C 1 or 0
(b) From A to D 1
(c)
(i) A solution containing the maximum amount of a solute at a specified temperature.
(Accept any correct definition of saturated solution.) 1
(d) He is false.
Sodium can react with water in the zinc sulphate solution. 1
No electrons flow through the external circuit and the voltage of the chemical cell drops.
1
(ii) The colour intensity of the copper (II) sulphate solution remains unchanged. 1
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11.
(a) 25 cm3 pipette 1
(b) Phenolphthalein 1
It changes from colourless to red. 1
0.7296
(iii) Percentage purity of citric acid in the tablet 100 %
2.5
= 29.2% 1
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12.
(a) 2X2(g) + Y2(g) ⇋ 2YX2(g)
Initial: 10 10 0
Eqm.: 2 6 8
13.
(i) (I) 2IO3-(aq) + 12H+(aq) + 10e- I2(aq) + 6H2O(l) 1
(II) H2O2(aq) O2(g) + 2H+(aq) + 2e- 1
(iii) Colorimetry 1
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