Chemettel - Products - Penetrant Remover

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Ardrox 9PR5, Aerosol 10x400ml

Version: 3.0 Revision Date 09.04.2014 Print Date 12.01.2015
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier

Trade name : Ardrox 9PR5, Aerosol 10x400ml
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub- : Cleaning agent
stance/Mixture
Recommended restrictions : None known.
on use
1.3 Details of the supplier of the safety data sheet

Company : Chemetall GmbH
Trakehner Strasse 3
60487 Frankfurt a.M.
Lead Organisation : Surface Treatment
Telephone : +49(0)69 7165-0
Telefax : +49(0)69 7165-3018
Contact person product safety

Telephone : +49(0)6971652832
E-mail address : msds.de@chemetall.com
In South Africa:
1.4 Emergency telephone number Chemetall,
Emergency telephone : +49(0)5326 51-0P.O. Box 232,
number Boksburg 1460
Telephone: 011-914-2500 Fax: 011-914-4792
Emergencies: 082 800 9294 or 082 551 5444
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)
Aerosols, Category 1 H222: Extremely flammable aerosol.
H229: Pressurized container: May burst if heated.
Skin irritation, Category 2 H315: Causes skin irritation.
Specific target organ toxicity - single ex- H336: May cause drowsiness or dizziness.
posure, Category 3, Central nervous
system
Chronic aquatic toxicity, Category 2 H411: Toxic to aquatic life with long lasting effects.
Classification (67/548/EEC, 1999/45/EC)
Extremely flammable R12: Extremely flammable.
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SAFETY DATA SHEET

Irritant R38: Irritating to skin.

Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environ-
ment.
R67: Vapours may cause drowsiness and dizzi-
ness.
2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms :
Signal word : Danger
Hazard statements : H222 Extremely flammable aerosol.

H229 Pressurized container: May burst if heated.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements : Prevention:

P210 Keep away from heat, hot surfaces, sparks,
open flames and other ignition sources. No
smoking.
P211 Do not spray on an open flame or other
ignition source.
P243 Take precautionary measures against static
discharge.
P251 Do not pierce or burn, even after use.
P260 Do not breathe dust/ fume/ gas/ mist/ va-
pours/ spray.
P262 Do not get in eyes, on skin, or on clothing.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/
eye protection/ face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Take off imme-
diately all contaminated clothing. Rinse skin
with water/shower.
P304 + P341 IF INHALED: If breathing is difficult, remove
victim to fresh air and keep at rest in a posi-
tion comfortable for breathing.
P308 + P313 IF exposed or concerned: Get medical ad-
vice/ attention.
Storage:
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SAFETY DATA SHEET

P410 + P412 Protect from sunlight. Do not expose to

temperatures exceeding 50 °C/ 122 °F.
Disposal:
P501 Dispose of contents/ container to an ap-
proved waste disposal plant.
Hazardous components which must be listed on the label:

• Hydrocarbons, C7, n-alkanes, isoalkanes, cyclics
Labelling according to EC Directives (1999/45/EC)

Hazard pictograms :
Extremely Irritant Dangerous

flammable for the envi-
ronment
R-phrase(s) : R12 Extremely flammable.

R38 Irritating to skin.
R51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic
environment.
R67 Vapours may cause drowsiness and dizzi-
ness.
S-phrase(s) : S16 Keep away from sources of ignition - No

smoking.
S23 Do not breathe gas/fumes/vapour/spray.
S24/25 Avoid contact with skin and eyes.
S36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S51 Use only in well-ventilated areas.
S61 Avoid release to the environment. Refer to
special instructions/ Safety data sheets.
Special labelling of certain : Pressurized container. Protect from sunlight and do not ex-
mixtures pose to temperatures exceeding 50 °C.
Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material.
Keep away from sources of ignition - No smoking.
Keep out of the reach of children.
Detergents Regulation EC : Aliphatic hydrocarbons 30 % and more

907/2006
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SAFETY DATA SHEET

2.3 Other hazards

The information required is contained in this Material Safety Data Sheet.
SECTION 3: Composition/information on ingredients

3.1 Substances
not applicable
3.2 Mixtures
Chemical nature : Mixture of organic solvents.
Hazardous components
Chemical Name CAS-No. Classification Classification Concentration
EC-No. (67/548/EEC) (REGULATION [%]
Registration num- (EC) No
ber 1272/2008)
Hydrocarbons, C7, n- F; R11 Flam. Liq. 2; >= 50 - < 65
alkanes, isoalkanes, 927-510-4 H225
cyclics 01-2119475515-33 Xn; R65
Skin Irrit. 2;
Xi; R38 H315
R67 STOT SE 3;
H336
N; R51/53
Asp. Tox. 1;
H304
Aquatic Chronic
2; H411
Propane 74-98-6 F+; R12 Flam. Gas 1; >= 10 - < 25

200-827-9 H220
01-2119486944-21
Press. Gas
Cyclohexane 110-82-7 F; R11 Flam. Liq. 2; >= 1 - < 2.5

203-806-2 H225
01-2119463273-41 Xn; R65
Asp. Tox. 1;
Xi; R38 H304
R67 Skin Irrit. 2;

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SAFETY DATA SHEET

H315
N; R50-R53
STOT SE 3;
H336
Aquatic Acute
1; H400
Aquatic Chronic
1; H410
WEL substance :
Butane 106-97-8 F+; R12 Flam. Gas 1; >= 10 - < 25
203-448-7 H220
Nota C Press. Gas
For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.
For the full text of the Notas mentioned in this Section, see Section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures

General advice : First-aid crew: Ensure self-protection.
Move out of dangerous area.
Take off contaminated clothing and shoes immediately.
If inhaled : Move to fresh air.

If symptoms persist, call a physician.
In case of skin contact : Wash off with soap and plenty of water.
If symptoms persist, call a physician.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.
Consult a physician.
If swallowed : Rinse mouth with water.

Do NOT induce vomiting.
Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : No information available.
5 / 17
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SAFETY DATA SHEET

Risks : Causes skin irritation.

May cause drowsiness or dizziness.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.
For specialist advice physicians should contact the Poisons
Information Service.
SECTION 5: Firefighting measures
5.1 Extinguishing media

Suitable extinguishing media : Carbon dioxide (CO2)
Dry powder
Alcohol-resistant foam
Water spray
Unsuitable extinguishing : High volume water jet

media
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire- : May form toxic gases on heating or in case of fire.
fighting Carbon monoxide
Carbon dioxide (CO2)
5.3 Advice for firefighters

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters
Further information : Use water spray to cool unopened containers.
Risk of bursting.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Wear personal protective equipment.
6.2 Environmental precautions

Environmental precautions : Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration.
6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Ensure adequate ventilation.
Contain spillage, soak up with non-combustible absorbent
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SAFETY DATA SHEET

material, (e.g. sand, earth, diatomaceous earth, vermiculite)

and transfer to a container for disposal according to local /
national regulations (see section 13).
6.4 Reference to other sections

See chapter 8 and 13
SECTION 7: Handling and storage
7.1 Precautions for safe handling

Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms.
Floor level ventilation required.
Have eye wash bottle or eye rinse ready at the work place.
To avoid risks to man and the environment, comply with the
instructions for use.
Advice on protection against : Keep away from sources of ignition - No smoking.

fire and explosion Take precautionary measures against static discharges.
Vapours may form explosive mixtures with air.
Normal measures for preventive fire protection.
7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Keep containers tightly closed in a dry, cool and well-
areas and containers ventilated place.
Store in a place accessible by authorized persons only.
To maintain product quality, do not store in heat or direct sun-
light.
Storage temperature : < 40 °C
7.3 Specific end use(s)

Specific use(s) : Cleaning agent
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Control para-
Components CAS-No. Value Update Basis
meters
Butane 106-97-8 TWA 600 ppm 2007-08-01 GB EH40
1,450 mg/m3
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SAFETY DATA SHEET

Further informa- : Carc: Capable of causing cancer and/or heritable genetic damage. The identified substances
tion include those which: - are assigned the risk phrases 'R45: May cause cancer'; 'R46: may
cause heritable genetic damage'; 'R49: May cause cancer by inhalation' or - a substance or
process listed in Schedule 1 of COSHH.
Carcinogenic only applies if butane contains more than 0.1% of buta-1,3-diene
106-97-8 STEL 750 ppm 2007-08-01 GB EH40

1,810 mg/m3
Further informa- : Carc: Capable of causing cancer and/or heritable genetic damage. The identified substances
tion include those which: - are assigned the risk phrases 'R45: May cause cancer'; 'R46: may
cause heritable genetic damage'; 'R49: May cause cancer by inhalation' or - a substance or
process listed in Schedule 1 of COSHH.
Carcinogenic only applies if butane contains more than 0.1% of buta-1,3-diene
Cyclohexane 110-82-7 TWA 200 ppm 2006-02-09 2006/15/EC

700 mg/m3
Further informa- : Indicative

tion
110-82-7 TWA 100 ppm 2005-04-06 GB EH40
350 mg/m3
110-82-7 STEL 300 ppm 2005-04-06 GB EH40

1,050 mg/m3
DNEL/DMEL
Hydrocarbons, C7, n- : End Use: DNEL, Workers
alkanes, isoalkanes, cyclics Exposure routes: Inhalation
Potential health effects: Long-term systemic effects
Value: 2085 mg/m3
End Use: DNEL, Workers

Exposure routes: Skin contact
Value: 300 mg/kg bw/d
Cyclohexane : End Use: DNEL, Industrial use, Workers

Exposure routes: Inhalation
Potential health effects: Short-term exposure, Systemic effects
Value: 700 mg/m3
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SAFETY DATA SHEET

End Use: DNEL, Industrial use, Workers

Potential health effects: Short-term exposure, Local effects
Value: 700 mg/m3

Value: 700 mg/m3

Potential health effects: Long-term local effects
Value: 700 mg/m3

Exposure routes: Skin contact
Value: 2016 mg/kg
PNEC
Cyclohexane : Water
Value: 0.207 mg/l
Sediment
Value: 3.627 mg/kg
Soil
Value: 2.99 mg/kg
Behaviour in waste water treatment plants

Value: 3.24 mg/l
8.2 Exposure controls

Engineering measures
Ensure adequate ventilation, especially in confined areas.
Electrical equipment should be protected to the appropriate standard.
Use only explosion-proof equipment.
Personal protective equipment

Respiratory protection : In case of insufficient ventilation wear suitable respiratory
equipment.
Recommended Filter type:
AX-P2
Hand protection : Nitrile rubber

Neoprene gloves
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SAFETY DATA SHEET

butyl-rubber
Protective gloves complying with EN 374.
Please observe the instructions regarding permeability and
breakthrough time which are provided by the supplier of the
gloves. Also take into consideration the specific local condi-
tions under which the product is used, such as the danger of
cuts, abrasion, and the contact time.
Eye protection : Eye protection (EN 166)

Tightly fitting safety goggles
Skin and body protection : Chemical resistant protective clothing according to DIN EN
13034 (Type 6)
Hygiene measures : Take off contaminated clothing and shoes immediately.

Keep away from food, drink and animal feedingstuffs.
Wash hands before breaks and immediately after handling the
product.
Avoid contact with skin and eyes.
Do not breathe vapour.
Do not breathe spray.
Environmental exposure controls

General advice : Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Appearance : aerosol
Colour : colourless
Odour : hydrocarbon-like
Flash point : -4 °C
Active substance
-60 °C
Butane/Propane
Ignition temperature : > 210 °C
Boiling point/boiling range : > 90 °C

Active substance
Density : 0.68 g/cm3

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SAFETY DATA SHEET

at 20 °C
Active substance
9.2 Other information

Explosivity : Vapours may form explosive mixture with air.
Directive 1999/13/EC on the : Value: 100 %

limitation of emissions of vo-
latile organic compounds
SECTION 10: Stability and reactivity
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : Vapours may form explosive mixture with air.
Pressurized container: May burst if heated.
10.4 Conditions to avoid

Conditions to avoid : Keep away from open flames, hot surfaces and sources of
ignition.
Strong sunlight for prolonged periods.
10.5 Incompatible materials

Materials to avoid : Alkali metals
Strong oxidizing agents
Acids
10.6 Hazardous decomposition products

Risk of decomposition. : No decomposition if stored and applied as directed.
SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
11 / 17
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SAFETY DATA SHEET

Acute oral toxicity

Hydrocarbons, C7, n- : LD50: > 5,840 mg/kg
alkanes, isoalkanes, cyclics Species: rat
Method: OECD Test Guideline 401
Cyclohexane : LD50: > 5,000 mg/kg

Species: rat
Acute inhalation toxicity

Hydrocarbons, C7, n- : LC50: > 23.3 mg/l
alkanes, isoalkanes, cyclics Exposure time: 4 h
Species: rat
Cyclohexane : LC50: 14 mg/l

Exposure time: 4 h
Species: rat
Acute dermal toxicity

Hydrocarbons, C7, n- : LD50: > 2,920 mg/kg
alkanes, isoalkanes, cyclics Species: rat
Cyclohexane : LD50: > 2,000 mg/kg

Species: rabbit
Skin corrosion/irritation
Skin irritation : Causes skin irritation.
Serious eye damage/eye irritation

Eye irritation : May cause eye irritation with susceptible persons.
Respiratory or skin sensitisation

Sensitisation : No data available
Germ cell mutagenicity

Cyclohexane : Ames test
In vitro tests did not show mutagenic effects
Aspiration hazard
12 / 17
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SAFETY DATA SHEET

Aspiration toxicity
Cyclohexane : The substance or mixture is known to cause human aspiration
toxicity hazards or has to be regarded as if it causes a human
aspiration toxicity hazard.
Neurological effects : May cause drowsiness or dizziness.
SECTION 12: Ecological information
12.1 Toxicity
Ecotoxicology studies for the product are not available.
Toxicity to fish
Hydrocarbons, C7, n- : > 13.4 mg/l
Species: Oncorhynchus mykiss (rainbow trout)
Cyclohexane : LC50: 4.53 mg/l

Exposure time: 48 h
Species: Fish
Toxicity to daphnia and other aquatic invertebrates

Hydrocarbons, C7, n- : 3 mg/l
Species: Daphnia magna (Water flea)
Cyclohexane : EC50: 0.9 mg/l

Exposure time: 48 h
Species: Daphnia magna (Water flea)
Toxicity to algae
Hydrocarbons, C7, n- : 10 - 30 mg/l
Species: Pseudokirchneriella subcapitata
Cyclohexane : IC50: > 4 mg/l

Exposure time: 72 h
Species: Selenastrum capricornutum (green algae)
Toxicity to bacteria
Cyclohexane : EC50: 29 mg/l
Exposure time: 24 h
Species: Photobacterium phosphoreum
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SAFETY DATA SHEET

12.2 Persistence and degradability
Biodegradability : No data available
12.3 Bioaccumulative potential
Bioaccumulation : Bioaccumulation is unlikely.
12.4 Mobility in soil
Distribution among environ- : No data available

mental compartments
12.5 Results of PBT and vPvB assessment
This mixture does not contain substances considered to be persistent, bioaccumulating and toxic
(PBT)., This mixture does not contain substances considered to be very persistent and very bioac-
cumulating (vPvB).
12.6 Other adverse effects
Additional ecological informa- : water endangering
tion Toxic to aquatic life with long lasting effects.
Do not flush into surface water or sanitary sewer system.
Do not allow material to contaminate ground water system.
Even leakage of small amounts in the subsoil can contaminate
drinking water.
SECTION 13: Disposal considerations
13.1 Waste treatment methods

Product : Dispose of in accordance with local regulations.
Contaminated packaging : Dispose of as unused product.
Waste Code : Waste codes should be assigned by the user, preferably in

discussion with the waste disposal authorities.
SECTION 14: Transport information
ADR
UN number : 1950
UN proper shipping name : AEROSOLS
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SAFETY DATA SHEET

Transport hazard class(es) : 2

Classification Code : 5F
Limited Quantity (LQ) Inner : 1.00 L
Packaging
Maximum quantity : 30.00 KG
Labels : 2.1
Tunnel restriction code : (D)
Environmentally hazardous : yes
IATA
UN number : 1950
Description of the goods : Aerosols, flammable
Class : 2.1
Labels : 2.1
IATA_C
Packing instruction (cargo : 203
aircraft)
Packing instruction (LQ) : Y203
Environmentally hazardous : no
IATA_P
Packing instruction (passen- : 203
ger aircraft)
Packing instruction (LQ) : Y203
Environmentally hazardous : no
IMDG
UN number : 1950
Description of the goods : AEROSOLS Heptane
Class : 2.1
Labels : 2.1
EmS Number 1 : F-D
EmS Number 2 : S-U
Marine pollutant : yes
Shaded from sources of heat.
"IMDG-Code segregation group not applicable".
Shaded from sources of heat.

"IMDG-Code segregation group not applicable".
RID
UN number : 1950
Description of the goods : AEROSOLS
Transport hazard class(es) : 2
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SAFETY DATA SHEET

Classification Code : 5F
Hazard Identification Number : 23
Labels : 2.1
Limited Quantity (LQ) Inner : 1.00 L
Packaging
Environmentally hazardous : yes
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
REACH - Candidate List of : This product does not contain substances of very high con-
Substances of Very High cern (Regulation (EC) No 1907/2006 (REACH), Article 57).
Concern for Authorisation
(Article 59).
Water contaminating class : WGK 2 water endangering

(Germany) VWVWS A4
Other regulations : The product is classified and labelled in accordance with EC

directives or respective national laws.
Regional or national implementations of GHS may not imple-
ment all hazard classes and categories.
: Classification / Labeling according to Directive 2008/47/EU.
15.2 Chemical Safety Assessment

For a mixture it is not mandatory to include an exposure scenario in the material safety data sheet.
The necessary safety - related information is stated in the first 16 sections.
SECTION 16: Other information

Full text of R-phrases referred to under sections 2 and 3
16 / 17
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SAFETY DATA SHEET

R11 Highly flammable.

R12 Extremely flammable.
R38 Irritating to skin.
R50 Very toxic to aquatic organisms.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R53 May cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.
Full text of H-Statements referred to under sections 2 and 3.

H220 Extremely flammable gas.
H222 Extremely flammable aerosol.
H225 Highly flammable liquid and vapour.
H229 Pressurized container: May burst if heated.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
Full text of Notas referred to under section 3
Nota C Some organic substances may be marketed either in a specific isomeric

form or as a mixture of several isomers. In Annex I, a general designa-
tion of the following type is sometimes used: "xylenol". In this case the
manufacturer or any other person who markets such a substance must
state on the label whether the substance is a specific isomer (a) or a
mixture of isomers (b). Example: (a) 2,4-dimethylphenol (b) xylenol
(mixture of isomers).
Further information
The information provided is based on our current knowledge and experience and apply to the product
as delivered. Regarding the product properties, these are not guaranteed. The delivery of this safety
datasheet does not free the recipient of the product from his own responsibility to follow the relevant
rules and regulations concerning this product.
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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Ardrox 9PR5, Aerosol 10x400ml

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

Contact person product safety

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Ardrox 9PR5, Aerosol 10x400ml

Irritant R38: Irritating to skin.

2.2 Label elements

Signal word : Danger

Hazard statements : H222 Extremely flammable aerosol.

Precautionary statements : Prevention:

Ardrox 9PR5, Aerosol 10x400ml

P410 + P412 Protect from sunlight. Do not expose to

Hazardous components which must be listed on the label:

Labelling according to EC Directives (1999/45/EC)

Extremely Irritant Dangerous

R-phrase(s) : R12 Extremely flammable.

S-phrase(s) : S16 Keep away from sources of ignition - No

Detergents Regulation EC : Aliphatic hydrocarbons 30 % and more

Ardrox 9PR5, Aerosol 10x400ml

2.3 Other hazards

SECTION 3: Composition/information on ingredients

Propane 74-98-6 F+; R12 Flam. Gas 1; >= 10 - < 25

Cyclohexane 110-82-7 F; R11 Flam. Liq. 2; >= 1 - < 2.5

R67 Skin Irrit. 2;

Ardrox 9PR5, Aerosol 10x400ml

Nota C Press. Gas

SECTION 4: First aid measures

4.1 Description of first aid measures

If inhaled : Move to fresh air.

If swallowed : Rinse mouth with water.

Ardrox 9PR5, Aerosol 10x400ml

Risks : Causes skin irritation.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Unsuitable extinguishing : High volume water jet

5.3 Advice for firefighters

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

6.3 Methods and materials for containment and cleaning up

Ardrox 9PR5, Aerosol 10x400ml

material, (e.g. sand, earth, diatomaceous earth, vermiculite)

6.4 Reference to other sections

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on protection against : Keep away from sources of ignition - No smoking.

7.2 Conditions for safe storage, including any incompatibilities

Storage temperature : < 40 °C

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Ardrox 9PR5, Aerosol 10x400ml

106-97-8 STEL 750 ppm 2007-08-01 GB EH40

Cyclohexane 110-82-7 TWA 200 ppm 2006-02-09 2006/15/EC

Further informa- : Indicative

110-82-7 STEL 300 ppm 2005-04-06 GB EH40

End Use: DNEL, Workers

Cyclohexane : End Use: DNEL, Industrial use, Workers