Chemistry may-19

1.
a) Discuss ion exchange process for softening of water with the
help of chemical reaction and diagram. (may-19, June-20, June-
22)
b) Write a note on scales and sludges. (may-19, June-20, June-
23)what are the bad effects?

2.
Explain various units of hardness of water giving their
relationship. (may-19, dec-20, jun-22)
Discuss method for determination of alkalinity in given water
sample. (may-19, June-22)

3.
What is lubricant? Discuss the following properties of lubricant
giving their significance. (June-20, may-19)
i) Viscosity index (dec-20, june-22)
ii) flash point (dec-20, June-22, june-23)
{ iii) Steam Emulsion Number(dec-20) }
{Write a note on lubricants with special reference to their (i)
classification (ii) mode of action with examples and uses. (nov-
22)}

4.
What are polymers? Give their classification with examples.
Give preparation, properties, and uses of
i) PVC (may-19, nov-19, june-20, dec-20, June-22)
ii) NYLON 66 (may19, dec-20, nov-22)
iii) Teflon (may-19)
** Discuss mechanism of polymerization. ** (may-19, nov-19,
June-20, June-22 as living polymer)
What Is polymerization?

5.
Explain electrochemical theory of corrosion with reference to
iron. Discuss process of galvanization to protect iron. (may-19,
June-20)

6.
 What is spectroscopy? Discuss IR spectroscopy giving principle,
instrumentation, and applications.

7. Write short notes on. (any two)

i) Vulcanization
ii) EDTA method
iii) Saponification number
iv) Polarizability

8.
Write brief notes on (Any two)
i) Phase diagram of single component systems
ii) Electronics spectroscopy
iii) Electron affinity
iv) Lime soda process

Chemistry nov-19
1. Differentiate between hard water and soft water. What is
meant by hardness of water? Write various units to express
hardness of water giving their relationship.

2. What do you understand by boiler troubles? Name the

methods used for softening water. Describe the lime soda
process.

3. What is lubrication? Give classification of lubricants. Discuss

mechanism of lubrication.

4. What are polymers? Give classification of polymers. Discuss

mechanism of polymerization.

5. What is spectroscopy? Describe IR spectroscopy giving

principle, instrumentation, and applications.

6. What is periodic Table? Write trends of following in a group

and in a period giving suitable reason:
i) electronic configuration
ii) atomic size
iii) Electron affinity

7. Write short notes on (any three)

i) PVC
ii) Fire point
iii) Scale
iv) Alkalinity
v) Phase Equilibrium

8 Write brief notes on (Any three)

a) Aniline point
b) Corrosion
c) Electronegativity
d) Vulcanization of rubber
e) EDTA method
 Chemistry june-20
1.
What is corrosion? Discuss various theories to explain
corrosion with suitable examples. How corrosion may be
prevented?

2.
Discuss principle, Instrumentation, and applications of
vibrational spectroscopy.

3.
Explain hardness of water. How is it expressed in various units?
Discuss harmful effects of hard water in boilers.

4.
a) Discuss ion exchange process for softening of water with the
help of chemical reaction and diagram.
b) Write a note on scales and sludges.
5.
What is lubricant? Discuss the following properties of lubricant
giving their significance.
i) Viscosity index
ii) Flash point

6.
Explain electrochemical theory of corrosion with reference to
iron. Discuss process of galvanization to protect iron.

7.
What are polymers? Give classification of polymers. Discuss
mechanism of polymerization.

8.
Write short notes on . (any three)
i) PVC
ii) Fire point
iii) Scale
iv) Alkalinity
v) Phase Equilibrium

Chemistry dec-20
1.
a) Define the Hardness of water. Mention and define various
units of Hardness. Write the relationship between these units.

b) Discuss principle of EDTA method for determination of

hardness of water.

2.
a) Discuss the following boilers troubles:
i) scale and sludge formation
ii) caustic embrittlement
b) 100 ml water sample required 20 ml of N/50 H₂SO₄ for
neutralization to Phenolphthalein end point. After Methyl
orange was added to this and further acid required was 2.5 ml.
Calculate the alkalinity type and extent in terms of CaCO3
equivalent.
3. Explain following properties of lubricants giving their
significance:
i) Viscosity Index
ii) Flash point
iii) Steam Emulsion Number

4.
What is Polymerization? Discuss mechanism of Polymerization.
Write Preparation, properties, and uses of following.
i) PVC
ii) Nylon 6:6
iii) Polyethylene

5.
a) Define Corrosion. Write types of corrosion. Explain theory of
mechanism of corrosion.
b) Explain Phase Rule, Discuss phase diagram of single
component system.
6. What is Spectroscopy? Why it is superior over other
methods? Discuss Principle, Instrumentation, and applications
of IR spectroscopy.

7. Explain following terms for elements giving factors affecting

and Periodic trends.
i) atomic size
ii) Electron affinity
iii) lionization Energy

8.
Write short note on:(any three)
i) Lime Soda Process
ii) Aniline Point
iii)Vulcanization of Rubber
iv) Colorimetry
v) Rusting of Iron
 Chemistry june-22
1.
a) Discuss the lime soda process for softening of hard water.
b) Describe the ion exchange process used for softening of
water with neat diagram.

2.
a) Explain various units of hardness of water giving their
relationship.
b) Discuss method for determination of alkalinity in given water
sample.

3.
a) What is triple point? Explain water system with the help of
neat phase diagram.
b) Write a short note on
i) Viscosity Index
ii) Flash Point
4.
a) What are living polymers? Give preparation, properties, and
uses of PVC.
b) What are Elastomers? Give the preparation and properties
and uses of BUNA's.

5.
a) What is oxidation corrosion? And how does it take place?
Describe the mechanism of oxidation corrosion.
b) Explain pitting corrosion and stress corrosion.

6.
What is electronic spectroscopy? Discuss electronic transitions
and applications of U. V. Spectroscopy.

7.
Write short note on:
i) Polarizability
ii) Thin film lubricants and fluid film lubricants.
8.
Write brief on:(Any two)
i) Degree of freedom
ii) Biodegradable polymers
iii) Electron affinity
iv) Vulcanization of rubber

Chemistry nov-22
1.
a) What is the principle of EDTA method? Explain the estimation
of total hardness of water by complexometric method.
b) Calculate the total hardness of a water sample which shows
following analysis:
Ca (HCO3)2=4.86 mg/L; Mg(HCO3)2= 5.84 mg/L; CaSO4 = 6.8
mg/L and MgSO4 = 8.4 mg/L.
2.
a) What is Caustic embrittlement? How do you prevent it?
b) How is portable water disinfected by ozonation?

3.
Write a note on lubricants with special reference to their (i)
classification (ii) mode of action with examples and uses.

4.
a) What is the difference between free radical and ionic
polymerization?
b) Write a note on preparation, properties, and uses of
i) Bakelite
ii) NYLON 6,6

5.
Differentiate the following with suitable examples.
a) Galvanic series and Electrochemical series.
b) Thermosetting polymers and Thermoplastic polymers.
6.
a) What is Spectroscopy? Describe the principle,
instrumentation process of vibrational and rotational
spectroscopy.
b) Explain about Lambert and beer's law.

7. Describe about the following:

i) Zeolite process
ii) ion-exchange process with neat diagram

8.
Write brief note on (Any two):
i) Phase diagram of single component systems
ii) electronic transitions
iii) Vibrational modes in IR spectroscopy
iv) Electro negativity
 Chemistry june-2023
1.
a) Explain the formation and composition of scales in boilers.
How are they different from sludge's? What are the bad
effects?

b) A water sample contains the following impurities per liter

CaCl222 mg; Mg (HCO3),=73 mg; CaSO = 6.8 mg, NaC1-58.5mg
Ca(NO₂),-1 Ca(NO₂),162 mg and MgSO, = 73 mg. The sample of
lime available is 74% pure and soda is 90% pure. 20% excess
chemicals must be added.
Calculate the amount lime and soda required for the treatment
of 10000 liters of water.

2.
a) Explain the hot lime-soda process. What are its advantages?
b) Write an note on the ion-exchange process.

3.
a) Describe the mechanism of lubrication that is applied to
delicate instruments.
b) Explain about an aniline point and Saponification Number.

4.
a) Write a short note on the following.
i) Functionality
ii) free radical chain polymerization
iii) ionic polymerization.

b) Write a note on preparation, properties and uses of the

following
i) Phenol-formaldehyde resin
ii) Buna-S

5.
Describe the following with suitable examples.
i) Chemical corrosion and Electro chemical corrosion
ii) Phase diagram of one-component water system.
6.
Discuss principle, instrumentation and applications of
vibrational and rotational spectroscopy.

7.
a) How do you explain electro negativity, tonic sizes and
electron affinity of s, p-block elements?
b) State and explain beer-Lambert's Law.

8. Write brief note on (Any two)

i) Eutectic point
ii) Flash point & Fire point
iii) Caustic Embrittlement
iv) Polarizability