Professional Documents
Culture Documents
door
•P
1 1
8 8
7 2 7 2
6 3 6 3
5 4 5 4
1 5 3 7
(a) (b) (c) (d)
16 64 32 64
8. Consider the following inequalities
(i) 3 p q 4 (ii) 3q p 12
Which one of the following expressions below satisfies the above two inequalities?
(a) p q 8 (b) p q 8 (c) 8 p q 16 (d) p q 16
9. Given below are three statements and four conclusions drawn based on the statements.
Statement 1: Some engineers are writers.
Statement 2: No writer is an actor.
Statement 3: All actors are engineers.
(a)
(b)
GATE-CY 2022 QUESTION PAPER 3
(c)
(d)
CHEMISTRY-CY
Q.11 – Q.35 : Carry ONE mark each.
11. The major product M formed in the following reaction is
N2H4 (1 equiv.)
CuSO4, O2
M
13. The major product in the given reaction is Q. The mass spectrum of Q shows {[M] = molecular ion
peak}
Me
H Ph3P, CBr4
Me (Q)
Et3N, CH2Cl2, 0ºC
O
(a) [M], [M+2] and [M+4] with relative intensity of 1:2:1
(b) [M] and [M+2] with relative intensity of 1:1
(c) [M], [M+2] and [M+4] with relative intensity of 1:3:1
(d) [M] and [M+2] with relative intensity of 2:1
GATE-CY 2022 QUESTION PAPER 4
14. A tripeptide on treatment with PhNCS (pH = 8.0) followed by heating with dilute HCl afforded a
cyclic compound M and a dipeptide. The dipeptide on treatment with PhNCS (pH = 8.0) followed
by heating with dilute HCl afforded a cyclic compound N and an acyclic compound O. The COR-
RECT sequence (from N- to C-terminus) of the tripeptide is
S S
Ph Ph
N NH N NH NH2
M= N= O = HO2C
Ph
O O
(a) glycine-phenylalanine-valine (b) valine-phenylalanine-glycine
(c) glycine-tyrosine-valine (d) glycine-phenylalanine-alanine
15. The major product M in the following reaction is
Ph Ar
hv M Ar = CN
Ph Ar
Ar
Ar Ar Ph
Br Br
Ph Ph
(a) (b)
N OMe N OMe
Br Br Br Br
OH HO
(c) N (d) N OMe
Ph Ph
20. 1s A and 1s B are the normalized eigenfunctions of two hydrogen atoms HA and HB, respectively. If
S 1sA |1sB , the option that is ALWAYS CORRECT is
(a) S = 1 (b) S = 0
(c) S = imaginary constant (d) 0 S 1
21. The pure vibrational spectrum of a hypothetical diatomic molecule shows three peaks with the following inten-
sity at three different temperatures.
23.
A point originally at (1, 3, 5) was subjected to a symmetry operation Ô1 that shifted the point to (–1, –
3, 5). Subsequently, the point at (–1, –3, 5) was subjected to another symmetry operation Ô2 that
shifted this point to (–1, –3, –5). The symmetry operators Oˆ1 and Oˆ 2 are, respectively,,
O
Me Me
Me Me Me Me
O
(a) H2O2, NaOH (b)
O
(c) DIBAL-H, then mCPBA (d) SO3 pyridine, Me2SO
27. The CORRECT statement(s) about the 1H NMR spectra of compounds P and Q is(are)
Me N Me Me N Me
Ha Ha
Hb Ph Hb Ph
(P) (Q)
(a) P-V, Q-III, R-I, S-II (b) P-IV, Q-II, R-I, S-III
(c) P-II, Q-IV, R-V, S-III (d) P-V, Q-III, R-II, S-IV
GATE-CY 2022 QUESTION PAPER 7
31. The CORRECT statement(s) about the following phase diagram for a hypothetical pure substance
X is(are)
liquid
solid
1 atm
gas
Temperature
(a) The molar volume of solid X is less than the molar volume of liquid X
(b) X does not have a normal boiling point
(c) The melting point of X decreases with increase in pressure
(d) On increasing the pressure of the gas isothermally, it is impossible to reach solid phase before reach-
ing liquid phase.
32. The parameter(s) fixed for each system in a canonical ensemble is(are)
(a) temperature (b) pressure
(c) volume (d) composition
33. The number of peaks exhibited by T in its broadband proton decoupled 13 C NMR spectrum re-
corded at 25 ºC in CDCl3 is
Me
Me (T)
34. The diffraction angle (in degree, rounded off to one decimal place) of (321) sets of plane of a metal with
atomic radius 0.125 nm, and adopting BCC structure is
(Given: the order of reflection is 1 and the wavelength of X-ray is 0.0771 nm)
Lˆ Lˆ Y
2
x
2
y 21 , n 2 Y21 , . The value of n is
CN
(a) (b) NH
Me Me Me
Me
NH
CN
(c) (d)
Me O
Me
OCOCF3
Me
(c) OH (d)
Me
Me
Me SiMe3
Me O
(a) (b) Me
CO2Me
MeO O
OTf
O O CO2Me
(c) (d)
OMe
O Me
GATE-CY 2022 QUESTION PAPER 9
39. The major product P in the reaction sequence is
(a) Me Me
Me N O P
(b) H2/Raney Ni,
HCl, MeOH-H2O
O OH O OH
(a) Me Me (b) Me Me
Me Me
O NH2 OH
(c) Me Me (d) Me Me
Me Me
40. The major product P and Q in the following reaction sequence are
O O
N
O LDA, –78ºC (a) Grubbs-II
P Q
(b) LiBH4
Br
OH
O O
N
(a) P = O Q=
OH
O O
N
P= O Q=
(b)
OH
O O
N
P= O Q=
(c)
GATE-CY 2022 QUESTION PAPER 10
OH
O O
N
P= O Q=
(d)
41. The major products M and N in the given reaction sequence are
O
CO2Me CH2OH
Et Et
CO2Me CH2OH
Et Et
CO2Me CH2OH
(c) M = N=
CO2Me CH2OH
Et Et
CO2Me CH2OH
(d) M = N=
Et Et
CO2Me CH2OH
42. Three different crystallographic planes of a unit cell of a metal are given below (solid circles represent
atom). The crystal system of the unit cell is
0.30 nm
0.20 nm
0.25 nm
(110) (101) (011)
(a) triclinic (b) monoclinic (c) tetragonal (d) orthorhombic
GATE-CY 2022 QUESTION PAPER 11
43. The number of equivalents of H2S gas released from the active site of rubredoxin, 2-iron ferredoxin, and
4-iron ferredoxin when treated with mineral acid, respectively, are
(a) 4, 6, 8 (b) 0, 2, 4 (c) 1, 2, 4 (d) 0, 2, 3
44. The number of S O stretching vibration band(s) observed in the IR spectrum of the high-spin [Mn(dmso)6]3+
complex (dmso: dimethylsulfoxide) is
(a) only one (b) two with intensity ratio 1 : 2
(c) two with intensity ratio 1 : 1 (d) six with intensity ratio 1 : 1:1:12:1
2 k11 3 3 2
45. Fe H 2 O 6 Fe * H 2 O 6 Fe H 2 O 6 Fe * H 2 O 6
2 k 22 3 3 2
Fe bpy 3 Fe * bpy 3 Fe bpy 3 Fe* bpy 3
bpy bipyridyl
2 k33 3 3 2
Co NH 3 6 Co * NH 3 6 Co NH 3 6 Co * NH 3 6
*indicates a radioactive isotope
The rate constants in the given self-exchange electron transfer reactions at a certain temperature follow
(a) k11 k 22 k 33 (b) k 22 k11 k 33
(c) k 33 k 22 k11 (d) k 22 k 33 k11
CO CO CO
13 13
OC CH3 OC CO H3C CO
Mn + Mn + Mn
OC CO H3C CO OC CO
(c)
CO CO CO
(25%) (25%) (50%)
CO CO CO
13 13
OC CH3 OC CO H3C CO
Mn + Mn + Mn
OC CO H3C CO OC CO
(d)
CO CO CO
(20%) (20%) (60%)
GATE-CY 2022 QUESTION PAPER 12
47. The addition of K4[Fe(CN)6] to a neutral aqueous solution of the cationic species of a metal produces
a brown precipitate that is insoluble in dilute acid. The cationic species is
(a) Fe3+ (b) UO22+ (c) Th4+ (d) Cu2+
48. The electronic spectrum of a Ni(II) octahedral complex shows four d-d bands, labelled as P, Q, R, and S.
Match the bands corresponding to the transitions.
(a) P-IV, Q-III, R-II, S-I (b) P-III, Q-IV, R-II, S-I
(c) P-II, Q-IV, R-I, S-III (d) P-I, Q-IV, R-II, S-III
49. In the following table, the left column represents the rigid-rotor type and the right column shows a set of
molecules.
O
O +
O
(I) (II) (III)
S S– S
+O
O O O+ O O
'+' and '–' indicate
out-of-plane motion
(a) (I) and (II) are infrared active while (III) is infrared inactive
(b) (I) is infrared inactive while (II) and (III) are infrared active
(c) (I) and (III) are infrared inactive while (II) is infrared active
(d) None of the modes are infrared active since SO3 has zero dipole moment
51. The reaction(s) that yield(s) 3-phenylcyclopentanone as the major product is(are)
O OH
O O
O
M
Br
OEt
(a) t-BuLi, THF, –65ºC
(a) (b) (a) Mg, Et2O
(b) Br
(b) O
OMe , H3O+
Me N
(c) H3O+
Me
Br
Br
(a)
(c) Li Me (d) (a) NaOMe,
(b) HgSO4 (cat), Me NO2
H2SO4, H2O (b) 10 N H2SO4, –10 ºC
Rh Rh Cl Cl
C C Mo Mo
(a) (b)
O Rh O Cl
Cl
GATE-CY 2022 QUESTION PAPER 14
1+
C Cl
Os
Fe Fe N
(c) (d) Cl
Cl C N
ˆ B, ˆ , A,
ˆ and C ˆ ˆ ˆ ˆ ˆ ˆ
56. For three operators A, B, C B, C, A
ˆ A,
(a) C, ˆ ˆ ˆ B,
(b) C, ˆ ˆ ˆ , Cˆ
(c) B̂, A ˆ B
(d) A, ˆ , Cˆ
B A
57. The difference between the number of Gauche-butane interactions present in P and Q is
Me Me
H H
(P) (Q)
58. The calculated magnetic moment (in BM, rounded off to two decimal places) of a Ce3+ complex is
59. The state of the electron in a He+ ion is described by the following normalized wavefunction.
3 7
r , , R21 r Y10 , i R10 r Y00 , xR32 r Y20 ,
8 16
Here, Rn and Ym represent the radial and angular components of the eigenfunctions of He+ ion, respec-
tively, and x is an unknown constant. If the energy of the ion is measured in the above state, the probabil-
2
ity (rounded off to two decimal places) of obtaining the energy of atomic unit is
9
60. A certain wavefunction for the hydrogen-like atom is given by
1
5/2
22 Z Zr Zr /3 a0
r , , 1 6 r e cos
a
2 0 a0
81
The number of node(s) in this wavefunction is
61. EMF of the following cell
Cu | CuSO4(aq, 1.0 mol/kg) | Hg2SO4(s) | Hg(l) | Pt
at 25ºC and 1 bar is 0.36 V. The value of the mean activity coefficient (rounded off to three decimal
places) of CuSO4 at 25ºC and 1 bar is
[Given: Standard electrode potential values at 25ºC for
2
Cu 2 2e Cu and Hg 2SO 4 2e 2Hg SO 4 are 0.34 V and 0.62 V, respectively..
Consider: RT/F at 25ºC = 0.0256 V]
GATE-CY 2022 QUESTION PAPER 15
62. The radius of gyration (in nm, rounded off to one decimal place), for three dimensional random coil linear
polyethylene of molecular weight 8,40,000 is
[Given: C–C bond length = 0.154 nm]
63. The activation energy of the elementary gas-phase reaction O3 NO NO 2 O 2 is 10.5 kJ mol-1. The
value of the standard enthalpy of activation (rounded off to two decimal places in kJ mol-1) at 25 ºC is
[Given: R is 8.314 J mol-1 K-1]
64. In a collection of molecules, each molecule has two non-degenerate energy levels that are separated by
5000 cm-1. On measuring the population at a particular temperature, it was found that the ground state
population is 10 times that of the upper state. The temperature (in K, rounded off to the nearest integer)
of measurement is
[Given: Value of the Boltzmann constant = 0.695 cm-1 K-1]
65. The change in entropy of the surroundings (in J K-1, rounded off to two decimal places) to convert 1 mol
of supercooled water at 263 K to ice at 263 K at 1 bar is
[Consider: fus H 0 at 273 K = 6.0 kJ mol-1, and the molar heat capacity of water is higher than that of ice
by 37.0 J K-1 mol-1 in the temperature range of 263 K to 273 K]
GATE 2022 | CHEMISTRY-CY
ANSWER KEY GATE 2022
SECTION : GENERAL APTITUDE SECTION : CY-CHEMISTRY
Q. NO. ANSWER Q. NO. ANSWER Q. NO. ANSWER
1. (c) 11. (b) 39. (a)
2. (d) 12. (b) 40. (b)
3. (c) 13. (a) 41. (b)
4. (c) 14. (a) 42. (d)
5. (c) 15. (a) 43. (b)
6. (b) 16. (a) 44. (b)
7. (d) 17. (a) 45. (b)
8. (a) 18. (a) 46. (c)
9. (c) 19. (a) 47. (d)
10. (c) 20. (d) 48. (b)
21. (c) 49. (b)
22. (b) 50. (b)
23. (b) 51. (a,b)
24. (c) 52. (a,b,d)
25. (b) 53. (a,c)
26. (a,b) 54. (b,d)
27. (a,d) 55. (a,d)
28. (a,b,d) 56. (b,d)
29. (a,b,c) 57. (1)
30. (a) 58. (2.54)
31. (b,c) 59. (0.19)
32. (a,c,d) 60. (2)
33. (8) 61. (0.044)
34. (60) 62. (4.4)
35. (5) 63. (5.54)
36. (a) 64. (3124)
37. (a) 65. (21.4)
38. (a)
Disclaimer: Career Endeavour is not responsible for any discrepancy (if arises) in the answer key, which has
been published.