1 Jeem 2023 Jan 24 First Shift Paper 21 40

JEE-MAIN-2023 (24th January-First Shift)-PCM-21
FIITJEE
Solutions to JEE (Main)-2023
PART – A (PHYSICS)
SECTION – A
-1
Sol1. Momentum = mv= [ MLT ]
Work function     E  kE  
 ML2 T 2 
218 2 214  214 Y 214  210  210

Sol2. A   A  A   A   A  A
84 82 83 83 81 80
u2 sin2  u2
Sol3.  for main h   136
2g 2g
u2 u2
sin 2  for mane R   136  2  272m
g g
Sol4. Statement 1 : True

When a = 0,
 uniform speed
F
Statement 2 : False
Elevator goes down with increasing
speed  downward one.
 Weight > force a
GM
Sol5. g
R2
GM GM 4GM 4 GM
g'  2
 2
 2

R  3200   R  3R  9 R2
R  
 2 2
4
  182  8N
9
Sol6.   U  
10
   W  3  105  1600  106  480  W
100
   4800
 4800
 U
 480
4320
 U  4320 J
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Sol7. Statement 1 is false Reflected


 B will be Hu < u.
2
Statement 2 is true. 90
Reflected
Am 1
Sol8.  
Ac 2
a
3 T a
Sol9. 40  T  4a
2
41k 1kg
 T5 a
4g sin60 g sin30
20 3  5  5a
a  4 3 1
 T  a5
 4 34
4  3 1 N 
d 0.5 10  10
Sol10. e   a  104
dt 0.5 a
 102 v  10mv
Bcentre 0 I 0I 
Sol11.   3/ 2
Br 2 2 2  2  
3/2
 I 2  2
 0 
2
 
2a 0 1
1
 2 2
2
 2 2 :1
F 
Sol12. Y
A 
250 
 10 4  1010 
6.25 100
250
 106  108  
625
10
 10 2  
25
4  103 m  
1 1 5
 
5 20 20
Re q  1  2  4  2  3  12
Sol13. v 4  v 5  I 4  20  IS  5 2 I4 20 
2 2
 4 I4  I5
I4  I5  2 2 I5 5 
5I4  2  I4  2 / 5
I5  8 / 5 3
24v
12
24
Itotal = 2A
Sol14. FP  F1  I    B
10A 10A
0 I
 I  
2
'   / 2
I'  2I 5cm
  2I  2
F2  2I    0
2   P Q
 8F1
Sol15. F 
1 k q1 q2 d
K q2
q1 q2
1 q1 q2 q1 q 2
 2
k d2 d
2 2
 d  kd
 d'  k d
Sol16. Photoelectric effect commit be aquaplaned using wave throaty

kE  E    kE doesn’t depend on intensity so opt B is only correct.
3RT
Sol17. v 
M
Ti  200k
T f  800k
T f  4Ti
 v gets doubled
PV  KET

Sol18. E  electric field

k  direction EM wave
 
Magnitude field  k  E
Sol19. Photodiodes used in remise bias current in forward bias is more. Than current in reuese bias.
Sol20. y  x,t   0.05 sin  8x  4t  
SECTION - B
1.6  1027
Sol1. Nuclear density 
4
a  1.5  1.5  1.5  1045 A
3
Sol2. T  2a
m k k
k eq 2kg
2 1
T  2a  2a
2k k
1
 2a
20
 x 5
dp
Sol3. F
dt
1
 2  v 2  104
2
v  100m / s
  100m / s
P  200
t5
200
F   40
5
1  1 1   0.75
Sol4.  1.75  1   
fconcerve   30  30
fconserve   40cm
1 1 1
   v 1   40 cm
v1  40
40cm
1 1 1 1 1
     v  80
v 80 40 v 80
 distance from conserve dens 80  40  120cm

Sol5. R
A
2.4  108  3.14
 n  103 
2  3.14   4  2   10 3  3.14 
2.4  108  3.14
n  10 3 
 16  4   10 6
24
 10 3
12
n2
Sol6. 2a  3b  4  0
2a  3b   4  6a  9b  12
3a  2b  7 6a  4b  14
 13b  26
a 1
a x 1
    x 1
b 2 2
Sol7. d  103  1.6  105  150  100

1.6  15  104
d
103
16  15

100
240 120
 5   12
100 10
Sol8. F  Fq
qE
a  2  1011  1.8  103
m
 36  1013
10  102 1
Time =   108
3  107 3
1
 y  a t2
2
1 1
  36  1013   1016
2 9
 2  103 m
 2mm
2 2
Sol9. I about  PQ  MR2  M  10  10   25M  100M
5 5
 110M
2
MR  110M
 R  110
x  110
WL R
Sol10.   , Bandwidth  W 
R L
1 L

R C
 L 3 3
 2   10
  R C 100  3 3  10 3 
PART – B (CHEMISTRY)
SECTION – A
Sol1. n  Z (according to graph)
According to moseley theory
  a  z  b  where a & b are constants
  1/2  Z
1
n 
2
Sol2. Hydrolysis of R-Cl is slow reaction but hydrolysis increases due to better nucleophiliciy of I
Sol3. Vapour pressure of solvent is greater than vapour pressure of solution, only solvent freezes at
this condition.
NH3 (aq)
Sol4. Ni2  DMG   Ni DMG 2 
(Brilliant Re d ppt)
Sol5.
O O
P P
H4P 2O 5 H O H
OH OH
O O
P P
H4P 2O 7 HO O OH
OH OH
O O
H4P 2O 6 HO P P OH
OH OH
H2P2O5 has P-H bond so it can reduce AgNO3 to Ag.
Sol6.
CH3
CH3 CH3 H
CH3Br
CH3 Br
C CH2 H Br C CH2 Rearrangement
CH3 CH3 CH3
H
Sol7. According to Fajjans rule

1
Polarisation   sizeof anion  Covalent charater
Size of cation
(a) KF > KI & LiF > KF (Incorrect)
(b) KI > KF & LiF > KF (Correct)
(c) SnCl4 > SnCl2 & CuCl > NaCl (Correct)
(d) LiF > KF & CuCl < NaCl (Incorrect)
(e) KI > KF & CuCl > NaCl(Correct)
Sol8. Primary valency = Oxidation number of central metal = 3

In Co  NH3 5 Cl Cl2 O. No of Co = +3
Secondary valency = co-ordination No = 6
Sol9. Statement-I For colloidal particles, the values of colligative properties are of small order as
compared to values shown by true solution at same concentration (True)
Statement-II Zeta potential or electrokinetic potential
Zeta potential – The potential difference between the fixed layer and the diffused layer is called
electrokinetic potential or zeta potential
Sol10. (a) Chlorophyll  Mg+2 complex.

(b) Soda ash  Na2CO3
(c) Density & ornamental work  CaSO4
(d) Used in white washing  Ca(OH)2
Sol11. Extent of hydrogen bonding

Ice > liquid H2O > Impure water
Extent of H-bonding decreases in impure water due to impurity present in it.
Sol12.
H O CH3 O
CH3 OH
CH C O H C H CH3 C C H
CH3 ALDOL
CH2
OH O CH3 OH
CH3 H3O OH
C CH C OH CH3 C CH KCN(alc)
CH3  CN
CH2 OH H2C
OH
OH
CH3 CH C O
C
CH3 (Lactone)
CH2 O
Sol13. C < A < B < D

In (D) octet of each atom is complete (D) is more stable than (C)
Any answer is not correct (BONUS)
Sol14. Reverberatory furnace  Used for roasting Cu- ore

Electrolytic cell  Used for reactive metal (Al)
Blast furnace  Used for haematite (Fe2O3) ore to pig iron formation
Zone-Refining furnace  Used for semiconductors or ultra pure element like Si.
Sol15. BeO  2NH3  4HF  NH4 2 BeF4  H2O


NH4 2 BeF4   BeF2  2NH4F
Sol16. Noradrenaline also known as norepinephrine. It is both neurotransmitter and a hormone.

Its role as fight or flight in body.
Sol17. V 2   Ar  4so 3d3 , n3    3  3  2   15  3.87 B.M
Cr 2   Ar  4so 3d4 ,  n  4   4  4  2   24  4.89 B.M
Mn2   Ar  4so 3d5 ,  n  5   5  5  2   35  5.91B.M

Ti2   Ar  4so 3d2 ,  n  2   2  2  2   8  2.82 B.M
Sol18.
O OH
C CH3 C CN
NaCN
CH3
Cl Cl AcOH
OH
C COOH
CH3
Cl
(P)
OH OH
C COOH C C OC2H5
C2H5OH
CH3 CH3 O
H
Cl Cl
(P) (Q)
OH OH
OH
C C Me
C C OC2H5 (1) 2MeMgBr
CH3 Me
CH3 O (2) H3O
Cl
Cl (R)
(Q)
Sol19. Freons is chlorofluorocarbon compounds

CFCl3 , CF2Cl2, CF3Cl
Sol20.
OH OH
HBr + H2O

CH2OH CH2Br
OH OH
HBr + CH3Br

OCH3 OH
SECTION – B
Sol1. Molecular formula of Uracil
O
H
NH
C4N2H4O 2
C O
H N
H
Molecular mass  12  4  14  2  1 4  16  2
 48  28  4  32
 112
28
 % of N in uracil   100  25%
112
5 1000 5
Sol2. M of NaOH solution    M
40 450 18
M1V1  M2 V2
5
 V  500  0.1
18
500  0.1 18
V   180 ml.
5
Sol3.
Cl
Cl
Cl
AgNO3
H 2AgCl + Prdduct
Cl
o
3 and benzylic carbocations are more stable, thus only circled chlorine removed as AgCl.
Sol4. pH  PKa  log

Salt 
 Acid
 5 
 
5   log x  10 5  log  
 0.5 
 5 
5  5  log x  log  
 0.5 
log x  log 10 
x  10
2
Sol5. CoCl4   W.F.L complex
Co 2   Ar  4so d7
-
Number of unpaaired e =3
t2
4 3 m n
e t2 = e t2
 m + no. of unpaired e-
= 4+3 = 7
Sol6. (a) K  A.eEa/RT When Ea increases K decreases

K  T 10
(b) Temperature co-efficient 
KT
Ea

(c) K only depends on Temperature  k  A.e RT
1
(d) lnk Vs  
T
Ea
lnk  ln A 
RT
 Ea 
Slope   
 R 
lnk
1
T
Sol7. For Paschen series

 1  1 1  1 1   7 
For 1st line    RHZ 2  2  2   RHZ 2     RHZ 2  

 1 3 4   9 16   9  16 
 1   1 1  1 1   16 
For 2nd line    RHZ 2  2  2   RH Z2     RH Z2  
 2  3 5   9 25   9  25 
   7 / 9  16
 2  
 1  16 / 9  25
7  9  25

16  9  16
7  25

16  16
7  25 7  25  90
2   720 
16  25 16  2
7  25  45
  492.18nm
16
 492nm
 2/0.93  ( 3)
O2
Sol8. (a) Fe0.93 O   Fe2 O3

2
O.S of Fe in Fe0.93 O   O.S of Fe in Fe2O3  3
0.93
 2 
 n factor   3    0.93
 0.93 
  3  2.15   0.93  0.79
 molar wt. 
 Eq. wt. of Fe0.93 O   
 0.79 
(b) 2x   0.93  x   3  2
  x  0.79 
 Fe 2  0.79 Fe 3  0.93  0.79  0.21
(c) Fe0.93 O is metal deficient lattice
0.79
(d) % of Fe2   100  85%
0.93
% of Fe 3  100  85   15%
Sol9. 6e   14H  Cr2O72  2Cr 3  7H2O

2
Cr 3 
o 0.059  
E E  log 14
n Cr2 O72  H 
  
2
 1.33 
0.059
log
101  
6 14

102 103  
0.059 42
 1.33  log 10 
6
0.059
 1.33   42
6
 1.33  0.413
 0.917
E  0.917
x  103  917  103
 x  917
Sol10. G  H  TS
(a) For process A
G  25  1000  80  2580 J  Spontaneous process
(b) For process B
G  22  1000  40  2200  40  Spontaneous process
(c) For process C
G  25  1000  50  2500  50
 2450J
 Non spontaneous process
(d) For process D
G  22  1000  20
 2200  20  2220J  Non spontaneous process
PART – C (MATHEMATICS)
SECTION – A
   
a2  a1 b1 b2
Sol1. Shortest distance =  
b1  b2
i j k
b1  b2  3 3 2
3 2 3
 5iˆ  3 ˆj  3kˆ
5  3  3 11
Shortest distance 
25  9  9 43
 1 3  84 3
tan1   sec 1
 3  3  63 3
 
 1  1 3  
 tan1      sec
1
4 2 3  
 3 1 3 
   3 2 3  
 1  1  2 
 tan1    sec  
 3  3
  
  
6 6 3
Sol2. As t  0
sin2 t  0
1

sin2 t
sin2 t
1 1 1
 
  1  sin2 t  2  sin2 t  3  sin2 t
lim n        .....  1  n 0  0  0  .....  1  n
t 0  n  n n 
 
Sol3. y 2  24x
Equation of tangent to the parabola of slope ‘m’
a
y  mx 
m
y 2  24x
y 2  4.6x a=6
6
Equation of tangent y  mx 
m
my  m2 x  6
m2 x  my  6  0 ………..(i)
Let mid point of AB is (h, k)
Equation of chord given mid point
T  S1
xk  yh
 hk
2
kx  hy  2hk  0 ………….(ii)
Now comparing (i) & (ii)
m2 m 3
 
k h k
 3 3
m2  ,m 
h k
3q 3

k2 h
k 2  3h  y 2  3x
 3 
y2  4  x
 4 
22
22 23
Sol4. 
r 0
Cr Cr
22 23
Coefficient of x 23 in the expansion of 1  x  1  x 
22
  22 Cr  23 C23 r
r 0
45
 C23
Sol5. A 2  B  A 2B
A 2  B  A 2B  I  I
A 2 I  B   B  I  I
 B  I  A 2  I  I
Inverse of each other
B  I  A 2  I   A 2  I B  I
BA 2  A 2B
Sol6. D0
1 1 1
N 1 10
3 N3 1
  N  1 N  4   0
N  1,4
N can be 2, 3, 5, 6
4
Required probability = k 4
6
Sum =  2  3  5  6   4  20
    R
2q  r 2r q
Sol7. A  ,B  ,C   A
3 3 3 r
1 B
1    Q
Area of PQR  q  r c q
2 OP
1  
Area of ABC  AB  AC
2
 r  2q   
r  q
AB  , AC 
3 3
1  
Area of ABC  q  r
6
Area of PQR
 3
Area of ABC
 ˆ v  2iˆ  ˆj  kˆ
Sol8. u  ˆi  ˆj  2k,
     
v  w  2, v  w  u  v
   
Now v  w  u  v
      
 
w  v  w  u  w  v  w
 
 0  u  w  2
Now
   
v  w  u  v
      
 
v  v  w  u  v  v  v
 0   2  1  2   6
1

2
 
 u  w  2  1
Sol9. 0
2  1
1 1 1 0
a b c
 2 c  b    c  a   b  a   0
2 2 2
 a  c   b  a    c  b 
b  a  c  b   a  c  c  b   a  c  b  a 
3 3 3

 a  b   b  c    c  a 
 a  b b  c  c  a 
3  c  b  b  c  c  a 
 3
 a  b b  c  c  a 
200
Sol10. 1  3i  2199  p  iq 
200
  
2200  cos  isin   2199  p  iq 
 3 3 
 1 3
2   i   p  iq
 2 2 

p  1, q   3
  p  q  q2  2  3
  p  q  q2  2  3
   4
   1
 x 2  4x  1  0
Sol11. Equation of plane

x  2 y  3 z 1
3 4 3  0
4 5 4
x  z 1 0
7  4 1
Distance of point  7, 3, 4   5 2
2
Sol12. x 3 dy   xy  1 dx
dy
x 3  dy    xy  1  dx  py  
px
dy   xy  1

dx x3
dy  1  1
  2 y  3
dx  x  x
1 1
 x2 dx
I.F. = e ex
1 1
1 
y  e x   3  e x dx
x
1
Put t
x
1
y  e x    et  t  dt
1
1
y  1 c  e x
x
1
Put x 
2
3  e  2  1  ce2
1
c
e
y 1  1
Sol13. Logical based
Sol14. Reflexive  a, a   gcd of  a, a   1

not true for a  z
symmetric
a = 2 b = 1  gcd  2,1  1
Sol15. pq2  logx k, qr  logy k, p2r  logz k

1 1 1
logk x  , logk y  , log2 k  2
pq2 q2 pr
qr pq2 p 2r
logy x  , logz x  , logz y 
pq2 p 2r qr
 Now 3,3logy x, 3logz y, 7logx z  AP (As per question)
3r 3p2 7q2
3, , , in AP
pq q pr
3r 1
 3   common difference given
pq 2
7
r  pq
6
r  pq  1  given
 pq  6
r7
3p2
4
q
on solving p = 2, q = 3
Sol16. Equation of line

x  1 y  9 z  16
  
3 4 12

 3  1,  4  q, 12  16 
point of intersection of line and plane
2  3  1  3  4  9   12  16   5
2
Point  5,1, 8 
Distance from  1, 9,  16   36  64  576  26
Sol17. Required area y

2 y  2x  2
 4  y2 y  2  y
  4  2  dy
4 
 0, 2  2
y  4x  4
2
 y3 y 2  1, 0 
 2y    x
 12 4  4
 8   16 
 4   1   8   4
 12   3 
 2 16  3,  4 
  3    12 
 3 3
 9 sq. unit
Sol18. x 2  4x   x   3  x  x 
x 2  4x  3  x  x    x 
x 2  4x  3   x   x  1
 x  1 x  3    x   x  1
x  1 or  x  3    x 
x   x   3
x  3 Not possible
x  1 is only one solution.
Sol19. 
 p  Q    p   Q    p   Q 
 
A B
P Q ~P ~Q  P  Q   P   Q A B A B
T T F F F F F F T
T F F T T F T F F
F T T F T T T F F
F F T T T F T T T
 2 1,
 x sin   x  0
Sol20. f  x    x
 x0
 0 ,
  1  1 ,
2x  sin    cos   x  0
f ' x   x x
 x0
 0 ,
 1
 f '  x  is not continuous due to high oscillation of cos   at x = 0.
x
SECTION – B
13 + +
Sol1. 12 x2  3x  2 dx
0 1 2
f  x   x 2  2x  x  2
 x  x  2   1 x  2 
  x  1 x  2 
1 2 3
 
   
 12   x 2  3x  2 dx    x 2  3x  2 dx   x 2  3x  2   
 0 1 2 
1 2 3
  x 3 x2   x3 3x 2   x 3 3x 2  
 12    3  2x      2x      2x  
  3 2 0  3 2 1  3 2  2 
 11 
 12    22
 16 
2023
2 2023
Sol2. r
r 0
Cr
2023
2023 2022 2021
   r r  1  r  
r 0 r

r  1
 Cr  2
 2023  2024  2 2021  2023  1012  22022

  1012
2023
8
/ 2
 cos x 
Sol3. I 0  sin x 2023  cos x 2023  dx ………..(i)

a a
As  f  x    f a  x 
0 0
2023
8
/ 2
 sin x 
I 0 cos x 2023   sin x 2023 dx ………..(ii)

Adding (i) & (ii)

82
2I   dx
0
8  /2
2I   x
  0
8 
2I    
 2
I=2
Sol4. 9x 2  16y2  144

x2 y2
 1
16 9
a = 4, b = 3
Point on ellipse  4cos , 3 sin  
Equation of tangent to the ellipse
x cos  y sin 
 1
4 3
Point of intersection with axes
A  4 sec , 0 , B  0, 3 cosec  
AB  25  16 tan2   9cot 2 
Minimum value is 7
2
Sol5. x 2 x  3  0
2
x  2 x   3 1 1
2
 x  1  3 1
2
 x  1  1   3
Maximum value x    5 (for integral solution)
1
Sol6. Common ratio =
m
T4  500
ar 3  500
a
 500
m3
Sn  Sn1  ar n 1
1
S 6  S5  1 & S 7  S 6  [given]
2
a 1
S 6  S5  1 
m6 2
ar 5  1
500 a 1
1 
m2 3
m m 3
2
500 1
m2  500 
m3 2
1000  m3
m  10
m = 11, 12, 13….22
Number of m is 12
Sol7. Shortest distance

4 2 14
3 2 2
3 2 0

i 3 k
3 2 2
3 2 0
16  12  168 196
   14
ˆ ˆ ˆ
4i  6 j  12k 14
5
Sol8. C0  7 C5  5 C1  7 C4  5 C2  7 C3  546
  
No One two
language language language
Sol9. Even place occupied by even digit

4! 5!
  60
2! 2! 2!3!
Sol10. Equation of normal Y

3 sec x  2cos ecy  10
Passing through (2, 0) P  6cos , 4 sin  
3 4 X
cos   , sin    2,0
5 5
 18 16 
Point P   , 
 5 5 
2 2
 18   16 
Radius of circle   2    0
 5   5 
320

5
2 64
Equation of circle  x  2   y 2 
5
Passing through 1,  
59
2 
5
10 2  118

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JEE-MAIN-2023 (24th January-First Shift)-PCM-21

218 2 214  214 Y 214  210  210

Sol4. Statement 1 : True

Sol7. Statement 1 is false Reflected

Sol16. Photoelectric effect commit be aquaplaned using wave throaty

Sol20. y  x,t   0.05 sin  8x  4t  

Sol7. d  103  1.6  105  150  100

Sol7. According to Fajjans rule

Sol8. Primary valency = Oxidation number of central metal = 3

Sol10. (a) Chlorophyll  Mg+2 complex.

Sol11. Extent of hydrogen bonding

Sol13. C < A < B < D

Sol14. Reverberatory furnace  Used for roasting Cu- ore

Sol15. BeO  2NH3  4HF  NH4 2 BeF4  H2O

Sol16. Noradrenaline also known as norepinephrine. It is both neurotransmitter and a hormone.

Sol17. V 2   Ar  4so 3d3 , n3    3  3  2   15  3.87 B.M

Cr 2   Ar  4so 3d4 ,  n  4   4  4  2   24  4.89 B.M

Mn2   Ar  4so 3d5 ,  n  5   5  5  2   35  5.91B.M

Sol19. Freons is chlorofluorocarbon compounds

Sol4. pH  PKa  log

Sol6. (a) K  A.eEa/RT When Ea increases K decreases

Sol7. For Paschen series

Sol9. 6e   14H  Cr2O72  2Cr 3  7H2O

Sol11. Equation of plane

Sol13. Logical based

Sol14. Reflexive  a, a   gcd of  a, a   1

Sol15. pq2  logx k, qr  logy k, p2r  logz k

Sol16. Equation of line

Sol17. Required area y

 2023  2024  2 2021  2023  1012  22022

Sol4. 9x 2  16y2  144

Sol7. Shortest distance

Sol9. Even place occupied by even digit

Sol10. Equation of normal Y

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