Chemistry

BSEH Practice Paper (March 2024)
CLASS: 12th (Sr. Secondary) Code: A
Roll No.
रसायन व ान
CHEMISTRY
[Hindi and English Medium]
ACADEMIC / OPEN
[Time allowed: 3 hours] [Maximum Marks: 70]
________________________________________________________
 कृपया सु नि चत कर क इस न प म मु त पृ ठ सं या म 21 ह
और इसम 35 न ह।
Please make sure that the printed pages in this question
paper are 21 in number and it contains 35 questions.
 न प के दा ओर दए गए कोड न बर को छा वारा उ र-पुि तका
के पहले पृ ठ पर लखा जाना चा हए।
The Code No. on the right side of the question paper should
be written by the candidate on the front page of the answer-
book.
 कसी न का उ र दे ना शु करने से पहले उसका मांक लखना होगा।
Before beginning to answer a question, its Serial Number
must be written.
1
BSEH Practice Paper Class: XII March-2024
 अपनी उ र पुि तका म खाल प ना/प ने न छोड़।

Don’t leave blank page/pages in your answer-book.
 उ र-पुि तका के अ त र त कोई अ य शीट नह ं द जाएगी। अतः
आव यकतानुसार ह लख व लखे उ र को न काट।
Except answer-book, no extra sheet will be given. Write to
the point and do not strike the written answer.
 पर ाथ अपना रोल नंबर न प पर अव य लख।
Candidates must write their Roll Number on the question
paper.
 कृपया न का उ र दे ने से पूव यह सु नि चत कर ल क नप पूण
व सह है, पर ा के उपरांत इस संबंध म कोई भी दावा वीकार नह ं कया
जाएगा।
Before answering the questions, ensure that you have been
supplied the correct and complete question paper, no claim
in this regard, will be entertained after examination.
________________________________________________________
सामा य नदश:
(i) सभी न अ नवाय ह।
(ii) व तु न ठ न के सह वक प लख।
(iii) येक न के अंक उसके सामने दशाए गए ह।
General Instructions:
(i) All questions are compulsory.
(ii) Write the correct option in objective type questions.

2
Chemistry Code: A
(iii) Marks of each question are indicated against it.
________________________________________________________
1. Which of the following is an example of solid solution? 1

a) Copper dissolved in Gold.
b) Glucose in water
c) Camphor in nitrogen gas
d) None of these
न न ल खत म से कौन सा ठोस वलयन का एक उदाहरण है?
a) तांबे का सोने म वलयन
b) पानी म लूकोज
c) नाइ ोजन गैस म कपरू
d) इनम से कोई नह ं
2. Value of KH for a gas is: 1
a) Constant at all temperatures
b) Increases with increase in temperature.
c) Decreases with increase in temperature.
d) Increases with decrease in temperature.
एक गैस के लए KH का मान:
a) सभी तापमान पर ि थर
b) तापमान म व ृ ध के साथ बढ़ता है
c) तापमान म व ृ ध के साथ घटता है
d) तापमान म कमी के साथ बढ़ता है
3. What is SI unit of conductivity?
a) S cm
b) S cm-1
3
Chemistry Code: A
c) S m
d) S m-1
चालकता क SI इकाई या है?
a) S cm
b) S cm-1
c) S m
d) S m-1
4. Which of the following is an example of corrosion? 1
a) Tarnishing of silver
b) Rusting of iron
c) Green coating on copper
d) All of these
न न ल खत म से कौन सा सं ारण का एक उदाहरण है ?
a) चांद का बदरं ग होना
b) लोहे म जंग लगना
c) तांबे पर हरे रंग का लेप होना
d) ये सभी
5. Which of the following cannot be molecularity of a chemical
reaction? 1
a) 0
b) 1
c) 2
d) 3
न न ल खत म से या रासाय नक अ भ या क आि वकता नह ं हो
सकती है ?
4
Chemistry Code: A
a) 0
b) 1
c) 2
d) 3
6. What is represented by A in Arrhenius equation? 1
a) Temperature
b) Frequency factor
c) Activation energy
d) Collision frequency
आर नअस समीकरण म A वारा या दशाया गया है?
a) तापमान
b) आव ृ त गुणक
c) स यण ऊजा
d) संघ ट आव ृ त
7. Which of the following does not exhibit variable oxidation
state? 1
a) Sc
b) Cu
c) Ti
d) Fe
न न ल खत म से कौन प रवतनीय ऑ सीकरण अव था द शत नह ं

करता है?
a) Sc
b) Cu
5
Chemistry Code: A
c) Ti
d) Fe
8. Which of the following is a coordination compound of cobalt?
1
a) Vitamin B12
b) Chlorophyll
c) Haemoglobin
d) All of the above
न न ल खत म से कौनसा कोबा ट का एक उपसहसंयोजन यौ गक है ?
a) वटा मन B12
b) लोरो फल
c) ह मो लो बन
d) उपयु त सभी
9. Which reagent is used in Finkelstein reaction? 1
a) NaCl
b) NaBr
c) NaI
d) All of the above
फं केल टाइन क त या म कस अ भकमक का उपयोग कया जाता

है ?
a) NaCl
b) NaBr
c) NaI
6
Chemistry Code: A
10. Which of the following has the lowest boiling point? 1

a) Pentan-1-ol
b) n-Butane
c) Pentanal
d) Ethoxyethane
न न ल खत म से कसका वथनांक यन
ू तम है ?
a) पे टे न-1-ऑल
b) n- यूटेन
c) पटे नैल
d) एथॉ सीएथेन
11. What is IUPAC name of cinnamaldehyde? 1
a) 2-Hydroxybenzaldehyde
b) 3-Phenylprop-2-en-1-al
c) 3-Hydroxybenzaldehyde
d) 3-Phenylbut-2-en-1-al
सनेमैि डहाइड का आईयप

ू ीएसी नाम या है?
a) 2-हाइ ॉ सीबे जैि डहाइड

b) 3-फ़े नल ोप-2-इन-1-अल
c) 3-हाइ ॉ सीबे जैि डहाइड
d) 3-फ़े नल यट
ू -2-इन-1-अल
12. What is the type of isomerism between Propan-1-amine and
Propan-2-amine? 1
a) Chain isomerism
b) Functional group isomerism
7
Chemistry Code: A
c) Position isomerism
d) Optical isomerism
ोपेन-1-ऐमीन और ोपेन-2-ऐमीन के बीच समावयवता का कार या है ?
a) ं ृ ला समावयवता
ख
b) या मक समूह समावयवता
c) ि थ त समावयवता
d) काशीय समावयवता
13. Which of the following is not a disaccharide? 1
a) Sucrose
b) Ribose
c) Maltose
d) Lactose
न न ल खत म से कौनसा डाइसैकेराइड नह ं है?
a) सू ोस
b) राइबोस
c) मा टोस
d) लै टोस
14. Which of the following is involved in blood clotting? 1
a) Vitamin A
b) Vitamin C
c) Vitamin E
d) Vitamin K
न न ल खत म से कौन र त के थ के म शा मल है ?
a) वटा मन A
8
Chemistry Code: A
b) वटा मन C
c) वटा मन E
d) वटा मन K
15. The question below consists of two statements: Assertion (A)
and Reason (R), answer the question by selecting the
appropriate option given below. 1
Assertion (A): Study of actinoids is difficult than the study of

lanthanoids.
Reason (R): Actinoids are radioactive elements.
a) Both A and R are true, and R is the correct explanation

of A.
b) Both A and R are true, and R is not the correct explanation
of A.
c) A is true but R is false.
d) A is false but R is true.
न न ल खत न म दो कथन है: अ भकथन (A) और कारण (R), न

के नीचे दये गए उपयु त वक प का चयन करते हुए उ र द िजए।
अ भकथन (A): ऐि टनॉयड का अ ययन लथेनॉयड के अ ययन से मुि कल

है ।
कारण (R): ऐि टनॉयड रे डयोधम त व ह।
a) A व R दोन स य ह तथा R, A क सह याखया है ।

b) A व R दोन स य ह तथा R, A क सह याखया नह ं है।
c) A स य है परं तु R अस य है ।
9
Chemistry Code: A
d) A अस य है परं तु R स य है ।
Assertion (A): Thiocyanate ligand can cause linkage

isomerism.
Reason (R): Ambidentate ligands results in linkage isomerism

in coordination compounds.

of A.
of A.

अ भकथन (A): थायोसायनेट लग ड बंधनी समावयवता का कारण बन

सकता है।
कारण (R): उभयदं ती सलं नी यु त उपसहसंयोजन यौ गक म बंधनी

समावयवता पाई जाती ह।

10
Chemistry Code: A
Assertion (A): Alcohols are readily soluble in water.
Reason (R): Alcohols form hydrogen bonding with water.

of A.
of A.

अ भकथन (A): ऐ कोहॉल जल म आसानी से घल

ु नशील होते ह।
कारण (R): ऐ कोहॉल पानी के साथ हाइ ोजन संबंध बनाते ह।

11
Chemistry Code: A
Assertion (A): When nucleotide is linked to phosphoric acid,

we get a nucleoside.
Reason (R): Nucleotides are joined together by phosphodiester

linkage.

of A.
of A.

अ भकथन (A): जब यूि लओटाइड फ़ॉ फ़ो रक अ ल से जुड़ता है , तो हम

यूि लओसाइड मलता है।
कारण (R): यिू लओटाइड फ़ॉस ्फ़ोडाइए टर आबंध वारा एक दस

ू रे के
साथ जड़
ु ते ह।

19. Differentiate between ideal and non-ideal solutions. 2
आदश और अनादश वलयन के बीच अंतर कर।
Or
अथवा
12
Chemistry Code: A
Calculate the amount of benzoic acid (C6H5COOH) required

for preparing 250 mL of 0.15 M solution in methanol. 2
बे ज़ोइक अ ल का मेथन
े ॉल म 0.15 M वलयन बनाने के लए
आव यक मा क गणना क िजए।
20. State Faraday’s law of electrolysis. 2
फैराडे के वै युत अपघटन के नयम ल खए।
21. What is pseudo first order reaction? Give an example. 2
छ म थम को ट अ भ या या है? एक उदाहरण द िजए।
22. What are interstitial compounds? Why are such compounds
well known for transition metals? 2
अंतराकाशी यौ गक या ह? इस कार के यौ गक सं मण धातओ
ु ं के
लए भल कार से ात य है?
23. Write a note on Wurtz reaction. 2
वु ज़ अ भ या पर एक नोट लख।
Or
अथवा
What are ambident nucleophiles? Give an example. 2
उभदं ती न भकरागी या होते ह? एक उदाहरण द िजए।
24. Write two uses of carboxylic acids. 2
काब ि स लक अ ल के दो योग ल खए।
25. Accomplish the following conversions: 2
न न प रवतन न पा दत क िजए:
i) Ethanoic acid to Propanoic acid
एथेनॉइक अ ल को ोपेनॉइक अ ल म
ii) Nitromethane to Dimethylamine
13
Chemistry Code: A
नाइ ोमेथेन को डाइमे थलऐ मन म

26. An aqueous solution of 2% non-volatile solute exerts a
pressure of 1.004 bar at the normal boiling point of the
solvent. What is the molar mass of the solute? 3
वलायक के सामा य वथनांक पर एक अवा पशील वलेय के 2% जल य
वलयन का 1.004 bar वा प दाब है। वलेय का मोलर यमान या है ?
27. The rate of the chemical reaction doubles for an increase of
10K in absolute temperature from 298K. Calculate Ea. 3
परमताप, 298K म 10K क व ृ ध होने पर रासाय नक अ भ या का वेग
दग
ु ुना हो जाता है। इस अ भ या के लए Ea क गणना क िजए।
28. What is meant by ‘disproportionation’? Give two examples of
disproportionation reaction in aqueous solution. 3
असमानुपातन से आप या समझते ह? जल य वलयन म असमानुपातन
अभ याओं के दो उदाहरण द िजए।
Or
अथवा
Indicate the steps in preparation of K2Cr2O7 from chromite
ore. 3
ोमाइट अय क से K2Cr2O7 बनाने के व भ न पद का उ लेख क िजए।
29. Explain why haloarenes are extremely less reactive towards
nucleophilic substitution reactions. 3
समझाएं क ना भकरागी त थापन अ भ याओं के त है लोएर न बेहद
कम त याशील य ह।
14
Chemistry Code: A
30. Describe a method for the identification of primary, secondary

and tertiary amines. Also write chemical equations of the
reactions involved. 3
ाथ मक, वतीयक एवं तत
ृ ीयक ऐमीन क पहचान क व ध का वणन
क िजए। इन अ भ याओं के रासाय नक समीकरण भी ल खए।
Or
अथवा
Give plausible explanation for each of the following: 3
न न ल खत म येक का संभा वत कारण बताइए:
i) Why are amines less acidic than alcohols of comparable
molecular masses?
समतु य अणु यमान वाले ऐमीन क अ लता ऐ कोहॉल से कम
होती ह।
ii) Why do primary amines have higher boiling point than
tertiary amines?
ाथ मक ऐमीन का वथनांक तत
ृ ीयक ऐमीन से अ धक होता है ।
iii) Why are aliphatic amines stronger bases than aromatic
amines?
ऐरोमै टक ऐमीन क तुलना म ऐल फै टक ऐमीन बल ारक होते
ह।
31. Read the passage given below and answer the following
questions:
नीचे दए गए ग यांश को पढ़ और न न ल खत न के उ र द:
An organic compound (A) having molecular formula C6H6O
gives a characteristic colour with aqueous FeCl3 solution. (A)
15
Chemistry Code: A
on treatment with CO2 and NaOH at 400 K under pressure

gives (B), which on acidification gives a compound (C). The
compound (C) reacts with acetyl chloride to give (D) which is
a popular analgesic.
आण वक सू C6H6O वाला एक काब नक यौ गक (A) जल य FeCl3 घोल
के साथ एक व श ट रं ग दे ता है । (A) दबाव म 400 K पर CO2 और
NaOH के साथ उपचार करने पर (B) दे ता है, जो अ ल करण पर एक
यौ गक (C) दे ता है। यौ गक (C) ऐसी टल लोराइड के साथ त या
करके यौ गक (D) दे ता है जो एक लोक य पीड़ाहार है।
i) What is compound (A)? 1
यौ गक (A) या है ?
ii) What is the number of carbon atoms in compound (D)?
1
यौ गक (D) म काबन परमाणओ
ु ं क सं या या है?
Or
अथवा
Write the name of compound (C). 1
यौ गक (C) का नाम ल खए।
iii) What is the name of the conversion reaction of
compound (A) to (C)? 1
यौ गक (A) को (C) म प रव तत करने क अ भ या का नाम या
है ?
iv) Write one use of compound (D). 1
यौ गक (D) का एक योग लख।
16
Chemistry Code: A
questions:
Proteins are the most abundant biomolecules of the living
system. The chief sources of proteins are milk, cheese, pulses,
fish, meat, peanuts, etc. They are found in every part of the
body and form a fundamental basis of the structure and
functions of life. These are also required for the growth and
maintenance of the body. The word protein is derived from
the Greek word, ‘proteios’ meaning ‘primary’ or of ‘prime
importance’. Chemically, proteins are the polymers in which
the monomeric units are the α-amino acids. Amino acids
contain an amino (-NH2) and carboxylic (-COOH) functional
groups. Amino acids which are synthesised by the body are
called non-essential amino acids. On the other hand, those
amino acids which cannot be synthesized in the human body
and are supplied in the form of diet (because they are required
for proper health and growth) are called essential amino acids.
ोट न जीव जगत म सवा धक पाए जाने वाले जैव अणु ह। ोट न के
मु य ोत दध
ू , पनीर, दाल, मछल , मांस, मंग
ू फल आ द ह। ये शर र के
हर ह से म पाए जाते ह और जीवन क संरचना और काय का एक
मौ लक आधार बनाते ह। ये शर र क व ृ ध और अनुर ण के लए भी
आव यक ह। ोट न श द क यु प त ीक श द, ' ो टयोस' से हुई है ,
िजसका अथ है ' ाथ मक' या 'अ तमह वपण
ू '। रासाय नक प से, ोट न
बहुलक ह िजनम एकलक इकाइयां α-ऐमीनो अ ल ह। ऐमीनो अ ल म
17
Chemistry Code: A
ऐमीनो (-NH2) और काब ि स लक (-COOH) काया मक समूह होते ह।

ऐमीनो अ ल जो शर र वारा सं ले षत होते ह, उ ह गैर-आव यक ऐमीनो
अ ल कहा जाता है । दस
ू र ओर, वे ऐमीनो अ ल िज ह मानव शर र म
सं ले षत नह ं कया जा सकता है और आहार के प म उनक आपू त क
जाती है ( य क वे उ चत वा य और वकास के लए आव यक ह)
आव यक ऐमीनो अ ल कहलाते ह।
i) Why amino acids show amphoteric behaviour? 1
ऐमीनो अ ल उभयधम यवहार य दखाते ह?
ii) What is the name of the linkage joining two amino acids?
1
दो ऐमीनो अ ल को जोड़ने वाले आब ध का नाम या है?
iii) What are polypeptides? 1
पॉ लपे टाइड या ह?
iv) Give an example of non-essential amino acid. 1
एक गैर-आव यक ऐमीनो अ ल का उदाहरण द।
Or
अथवा
How many types of amino acids are found in proteins?
1
ोट न म कतने कार के ऐमीन अ ल पाए जाते ह?
33. Write the Nernst equation and calculate emf and ΔrGo of the
cell Mg(s)|Mg2+(0.001M)||Cu2+(0.0001 M)|Cu(s) at 298 K if 𝐸
is 2.70 V. 5
18
Chemistry Code: A
नेन ट समीकरण ल खए और 298 K पर सेल;

Mg(s)|Mg2+(0.001M)||Cu2+(0.0001 M)|Cu(s), के emf और ΔrGo क
गणना क िजए य द 𝐸 2.70 V है ।
Or
अथवा
Conductivity of 0.00241 M acetic acid is 7.896×10–5 S cm–1.
Calculate its molar conductivity. If  for acetic acid is 390.5
S cm2 mol–1, what is its dissociation constant? 5
0.00241 M ऐ स टक अ ल क चालकता 7.896×10–5 S cm–1 है । इसक
मोलर चालकता क गणना कर। य द ऐ स टक अ ल के लए  का मान
390.5 S cm2 mol–1 है , तो इसका वयोजन ि थरांक या है ?
34. Specify the oxidation numbers of the metals in the following
coordination entities: 5
न न ल खत उपसहसंयोजन स ा म धातुओं के ऑ सीकरण अंक का
उ लेख कर:
i) [Co(H2O)(CN)(en)2]2+
ii) [CoBr2(en)2]+
iii) [PtCl4]2–
iv) K3[Fe(CN)6]
v) [Cr(NH3)3Cl3]
Or
अथवा
Explain on the basis of valence bond theory that [Ni(CN)4]2–

ion with square planar structure is diamagnetic and the
[NiCl4]2– ion with tetrahedral geometry is paramagnetic. 5
19
Chemistry Code: A
संयोजकता आब ध स धांत के आधार पर समझाइए क वग समतल य

सरं चना वाला [Ni(CN)4]2– आयन तचब
ुं क य है तथा चतु फलक य
या म त वाला [NiCl4]2– आयन अनच
ु ंब
ु क य है ।
35. Write structural formulas and names of four possible aldol

condensation products from propanal and butanal. In any one
case of cross aldol condensation, indicate which aldehyde acts
as nucleophile and which as electrophile.
5
ोपेनल
ै और यूटेनल
ै के ए डोल संघनन से बनने वाले से चार संभा वत
उ पाद के संरचना सू और नाम लख। कसी एक ॉस ए डोल संघनन
म बताएं क कौन सा ऐि डहाइड ना भकरागी होगा और कौन सा
इले ॉनरागी होगा?
Or
अथवा
Draw the structures of following compounds: 5
न न ल खत यौ गक क सरं चना बनाइये:
i) p-Nitropropiophenone
p-नाइ ो ो पओफ नोन
ii) 4-Methylpent-3-en-2-one
4-मे थलपे ट-3-ईन-2-ओन
iii) 3-Bromo-4-phenylpentanoic acid
3- ोमो-4-फे नलपे टे नॉइक अ ल
iv) p-Methylbenzaldehyde
p-मे थलबे ज़ैि डहाइड
20
Chemistry Code: A
v) 3-Methylbutanal
3-मे थल यूटेनैल
21
Chemistry Code: A
CLASS: 12th (Sr. Secondary) Code: B
Roll No.
CHEMISTRY
ACADEMIC / OPEN
________________________________________________________
book.
must be written.
1

paper.
जाएगा।
________________________________________________________

2
Chemistry Code: B
________________________________________________________
1. Which of the following is often used to express the

concentration of pollutants in water or air? 1
a) mg/mL
b) ppb
c) μg/mL
d) mol L-1
न न ल खत म से कसका उपयोग अ सर पानी या वायु म दष
ू क क
सां ता को य त करने के लए कया जाता है ?
a) mg/mL
b) ppb
c) μg/mL
d) mol L-1
2. The osmotic pressure of fluid inside human blood cell is
equivalent to that of: 1
a) 9.0% (mass/volume) NaCl
b) 0.9% (mass/volume) NaCl
c) 1.9% (mass/volume) NaCl
d) None of these
मानव र त को शका के अंदर व का परासरण दाब कसके तु यांक होता
है ?
a) 9.0% ( यमान/आयतन) NaCl
b) 0.9% ( यमान/आयतन) NaCl
c) 1.9% ( यमान/आयतन) NaCl
3
Chemistry Code: B
d) इनमे से कोई नह ं
3. In a Galvanic cell, the half-cell in which oxidation takes place
is called: 1
a) Cathode
b) Anode
c) Electrolyte
d) Salt bridge
गै वैनी सेल का अध सेल िजसम ऑ सीकरण होता है उसे कहा जाता है:
a) कैथोड
b) ऐनोड
c) वै यत
ु अपघ य
d) लवण सेतु
4. Which of the following is a unit of rate of reaction? 1
a) mol L-1
b) mol L s-1
c) mol L-1s-1
d) s-1
न न ल खत म से या अ भ या वेग क एक इकाई है?
a) mol L-1
b) mol L s-1
c) mol L-1s-1
d) s-1
5. Which of the following is not a transition element? 1
a) Au
b) Ag
4
Chemistry Code: B
c) Zn
d) Cu
न न ल खत म से कौन सा सं मण त व नह ं है ?
a) Au
b) Ag
c) Zn
d) Cu
6. What is obtained from pyrolusite ore? 1
a) KMnO4
b) K2Cr2O7
c) KNO3
d) Na2Cr2O7
पाइरोलुसाइट अय क से या ा त होता है?
a) KMnO4
b) K2Cr2O7
c) KNO3
d) Na2Cr2O7
7. What is secondary valency of CoCl3.4NH3 if its one mole
reacts with excess AgNO3 to give one mole of AgCl? 1
a) 3
b) 4
c) 5
d) 6
5
Chemistry Code: B
CoCl3.4NH3 क वतीयक संयोजकता या है य द इसका एक मोल

आ ध य AgNO3 के साथ त या करके AgCl का एक मोल दे ता है ?
a) 3
b) 4
c) 5
d) 6
8. Which of the following is effective in inhibiting growth of
tumours? 1
a) Dimethylglyoxime
b) cis-platin
c) α–nitroso––naphthol
d) cupron
न न ल खत म से कौन यूमर क व ृ ध को रोकने म भावी है ?
a) डाइमे थल लाईऑ सीम

b) समप - ले टन
c) α–नाइ ोसो––ने थॉल
d) यप
ू फेरॉन
9. Which of the following is allylic halide? 1
a) Bromomethane
b) Bromoethene
c) 3-Chloropropene
d) None of the above
न न ल खत म से कौन सा ऐ ल लक हैलाइड है?
a) ोमोमेथेन
6
Chemistry Code: B
b) ोमोएथीन
c) 3- लोरो ोपेन
d) उपयु त म से कोई नह ं
10. What is carbolic acid? 1
a) Acetic acid
b) Acetone
c) Phenol
d) Acetaldehyde
काब लक अ ल या है?
a) ऐसी टक अ ल
b) ऐसीटोन
c) फ़ नॉल
d) ऐसीटै ि डहाइड
11. Which of the following is major product for nitration anisole?
1
a) 2-Nitroanisole
b) 3-Nitroanisole
c) 4-Nitroanisole
न न ल खत म से ऐ नसोल के नाइ ोकरण का कौन सा मख

ु उ पाद है ?
a) 2-नाइ ोऐ नसोल
b) 3-नाइ ोऐ नसोल
c) 4-नाइ ोऐ नसोल
d) ऊपयु त म से कोई नह ं
7
Chemistry Code: B
12. What is the monomer of cellulose? 1

a) α-D-Glucose
b) β-D-Glucose
c) α-D-Fructose
d) β-D-Fructose
सेलल
ु ोस क इकाई या है?
a) α-D- लक
ू ोस
b) β-D- लक
ू ोस
c) α-D- टोज़
d) β-D- टोज़
13. How many amino acids are present in insulin? 1
a) 51
b) 52
c) 53
d) 54
इंसु लन म कतने ऐमीनो अ ल मौजद

ू होते ह?
a) 51
b) 52
c) 53
d) 54
14. Which of the following is not fat soluble? 1
a) Vitamin A
b) Vitamin C
c) Vitamin E
8
Chemistry Code: B
d) Vitamin K
न न ल खत म से कौन वसा म घुलनशील नह ं है ?
a) वटा मन A
b) वटा मन C
c) वटा मन E
d) वटा मन K
Assertion (A): Mercury cell is a primary cell.
Reason (R): In primary battery reaction occurs only once and

cannot be reused again.

of A.
of A.

अ भकथन (A): म यरू सेल एक ाथ मक सेल है ।
कारण (R): ाथ मक बैटर म त या केवल एक बार होती है और फर

से पुन: उपयोग नह ं क जा सकती है।
9
Chemistry Code: B

Assertion (A): Half-life of a first order reaction is variable.
Reason (R): For first order reaction, half-life is independent of

initial concentration of reactant.

of A.
of A.

अ भकथन (A): थम को ट क अ भ या क अधायु ि थरांक है ।
कारण (R): थम को ट क अ भ या क अधाय,ु अ भ यक क ारि भक

सां ता पर नभर नह ं करती है।

10
Chemistry Code: B
Assertion (A): Aldehydes are more reactive than ketones

towards nucleophilic addition reactions.
Reason (R): Aldehydes give positive Tollen’s test.

of A.
of A.

अ भकथन (A): ऐि डहाइड ना भकरागी योगज अ भ याओं म क टोन क

अपे ा अ धक अ भ याशील होते ह।
कारण (R): ऐि डहाइड सकारा मक टॉलेन-पर ण दे ते ह।

11
Chemistry Code: B

Assertion (A): Carbylamine reaction is shown by secondary

amines.
Reason (R): Carbylamines are foul smelling substances.

of A.
of A.

अ भकथन (A): का बलऐमीन अ भ या, वत यक ऐमीन वारा दशाई

जाती है।
कारण (R): का बलऐमीन दग

ु धयु त पदाथ ह।

19. Define colligative properties. Give two examples. 2
अणुसं य गुणधम को प रभा षत कर। दो उदाहरण द िजए।
12
Chemistry Code: B
20. The conductivity of 0.20 M solution of KCl at 298 K is 0.0248

S cm–1. Calculate its molar conductivity. 2
298 K पर 0.20 M KCl वलयन क चालकता 0.0248 S cm-1 है।
इसक मोलर चालकता का प रकलन क िजए।
Or
अथवा
How much electricity in term of Faraday is required to produce
40 g of Al from molten Al2O3? 2
ग लत Al2O3 से 40 ाम Al का उ पादन करने के लए कतने फैराडे
व युत क आव यकता होगी?
21. List the factors affecting the rate of reaction. 2
रासाय नक अ भ या के वेग को भा वत करने वाले कारक क सच
ू ी
बनाइए।
22. Which metal in the first series of transition metals exhibits
+1 oxidation state most frequently and why? 2
सं मण धातओ
ु ं क पहल ंख
ृ ला म कौन सी धातु बहुधा +1 ऑ सीकरण
अव था द शत करती है और य?
23. Write increasing order of reactivity four isomers of
bromobutane for SN2 reaction. 2
SN2 अ भ या के लए ोमो यट
ू े न के चार समावयव क अ भ याशीलता
का बढ़ता म ल खए।
24. What is decarboxylation? Give an example. 2
वकाब ि सलन या है? एक उदाहरण द िजए।
Or
अथवा
13
Chemistry Code: B
What is cyanohydrin? Give an example of reaction. 2

सायनोहाइ न या है? अ भ या का एक उदाहरण द िजए।
25. Arrange the following in increasing order of basic strength:
2
न न ल खत को ारक य ाब य के बढ़ते म म ल खए:
i) Aniline, p-nitroaniline and p-toluidine
ऐ नल न, पैरा-नाइ ोऐ नल न एवं पैरा-टॉलड
ू ीन
ii) C2H5NH2, (C2H5)2NH, (C2H5)3N and NH3 (in gas phase)
C2H5NH2, (C2H5)2NH, (C2H5)3N एवं NH3 (गैस अव था म)
26. Differentiate between two types of non-ideal solutions. 3
दो कार के अनादश वलयन के बीच अंतर कर।
27. For a first order reaction, show that time required for 99%
completion is twice the time required for the completion of
90% of reaction. 3
दशाइए क थम को ट क अ भ या म 99% पण
ू होने म लगा समय
90% अ भ या पण
ू होने वाले समय से दग
ु न
ु ा होता है।
Or
अथवा
Derive an integrated rate equation for a zero-order reaction.
3
शू य-को ट क एक अ भ या के लए एक समाक लत वेग समीकरण का
यु प न क िजए।
28. Explain with at least three reasons why transition metals act
as good catalyst. 3
14
Chemistry Code: B
कम से कम तीन कारण से समझाइए क सं मण धातुएँ अ छे उ ेरक

के प म य काय करती ह।
29. Give the uses of freon 12, carbon tetrachloride and iodoform.
3
े ओन-12, काबन टे ा लोराइड और आयोडोफाम के उपयोग बताइए।
30. Give the structures of A, B and C in the following reactions:
3
न न ल खत अ भ याओं म A, B और C क संरचना द िजए:
i) 𝐶𝐻 𝐶𝐻 𝐵𝑟 ⎯⎯⎯⎯⎯⎯⎯ 𝐴 ⎯⎯⎯⎯⎯⎯⎯⎯ 𝐵 ⎯⎯⎯⎯⎯⎯⎯⎯ 𝐶

℃
/ /
ii) 𝐶 𝐻 𝑁𝑂 ⎯⎯⎯⎯⎯⎯⎯⎯ 𝐴 ⎯⎯⎯⎯⎯⎯⎯⎯⎯ 𝐵 ⎯⎯⎯⎯⎯⎯⎯⎯ 𝐶
∆
Or
अथवा
Give plausible explanation for each of the following: 3
न न ल खत म येक का संभा वत कारण बताइए:
i) Ethylamine is soluble in water whereas aniline is not.
ऐ थलऐ मन जल म वलेय है जब क ऐ नल न नह ं।
ii) Aniline does not undergo Friedel-Crafts reaction.
ऐ नल न डेल ा स अभ या द शत नह ं करती है ।
iii) Gabriel phthalimide synthesis is preferred for
synthesising primary amines.
ाथ मक ऐमीन के सं लेषण म गै एल थै लमाइड सं लेषण को
ाथ मकता द जाती है।
questions:
15
Chemistry Code: B
A compound (A) containing C, H and O is unreactive towards

sodium. It also does not react with Schiff’s reagent. On
refluxing with an excess of hydroiodic acid, (A) yields only
one organic product (B). On hydrolysis, (B) yields a new
compound (C) which can be converted into (B) by reaction
with red phosphorous and iodine. The compound (C) on
oxidation with potassium permanganate gives a carboxylic acid
(D). The equivalent weight of this acid is 60.
C, H और O यु त यौ गक (A) सो डयम के त अ याशील है । यह

शफ के अ भकमक के साथ भी अ भ या नह ं करता है । हाइ ोआयो डक
अ ल क अ धकता के साथ र ल स पर, (A) केवल एक काब नक उ पाद
(B) पैदा करता है। जलअपघटन पर, (B) एक नया यौ गक (C) उ प न
करता है िजसे लाल फॉ फोरस और आयोडीन के साथ अ भ या वारा
(B) म प रव तत कया जा सकता है। पोटै शयम परमगनेट के साथ
ऑ सीकरण पर यौ गक (C) एक काब ि स लक अ ल (D) दे ता है । इस
अ ल का तु यांक यमान 60 है।
i) What is compound (A)? 1

यौ गक (A) या है ?
ii) What is the number of carbon atoms in compound (D)?
1
यौ गक (D) म काबन परमाणओ
ु ं क सं या या है?
Or
अथवा
Write the name of compound (D). 1
यौ गक (D) का नाम ल खए।
16
Chemistry Code: B
iii) What is compound (C)? 1

यौ गक (C) या है ?
iv) Draw structure of compound (B). 1
यौ गक (B) क सरं चना बनाइए।
questions:
Nucleic acids are the polymers of nucleotides which in turn
consist of a base, a pentose sugar and phosphate moiety.
Nucleic acids are responsible for the transfer of characters
from parents to offsprings. There are two types of nucleic
acids — DNA and RNA. DNA contains a five-carbon sugar
molecule called 2-deoxyribose whereas RNA contains ribose.
Both DNA and RNA contain adenine, guanine and cytosine.
The fourth base is thymine in DNA and uracil in RNA. The
structure of DNA is a double strand whereas RNA is a single
strand molecule. DNA is the chemical basis of heredity and
have the coded message for proteins to be synthesised in
the cell. There are three types of RNA — mRNA, rRNA and
tRNA which actually carry out the protein synthesis in the cell.
यू ल क अ ल, यूि लओटाइड के बहुलक ह जो एक ारक, एक पटोस
शकरा और एक फ़ा फ़ेट अधाश से मलकर बनता है। यू ल क अ ल
जनक से संत त म गण
ु के थानांतरण के लए िज मेदार होते ह।
यू ल क अ ल दो कार के होते ह- DNA तथा RNA। इनम से DNA
म पाँच काबन परमाणु वाला शकरा अणु होता है िजसे 2-डीऑ सीराइबोस
17
Chemistry Code: B
कहते ह, जब क RNA म राइबोस शकरा होती है । DNA तथा RNA

दोन म ऐडेनीन, वानीन तथा साइटोसीन ारक होते ह। चतुथ ारक
DNA म थायमीन तथा RNA म यरू े सल होता है । DNA क सरं चना
वर जुक वकंु डलनी है जब क RNA क सरं चना एक र जक
ु कंु डलनी
होती है। DNA आनव
ु ां शकता का रासाय नक आधार होता है तथा इनम
कसी को शका म ोट न सं लेषण का को डत संदेश होता है। RNA तीन
कार के होते ह- mRNA, r-RNA तथा t-RNA, जो क वा तव म एक
को शका म ोट न सं लेषण करते है ।
i) Write full form of DNA. 1
DNA का परू ा नाम ल खए।
ii) What is the name of the linkage joining two nucleotides?
1
दो यिू लओटाइड को जोड़ने वाले आब ध का नाम या है ?
iii) What is ‘r’ in r-RNA? 1
r-RNA म 'r' या है?
iv) How many hydrogen bonds are formed by cytosine with
guanine in DNA? 1
DNA म वानीन के साथ साइटो सन वारा कतने हाइ ोजन आब ध
बनते ह?
Or
अथवा
How many oxygen atoms are present in 2-deoxyribose
sugar? 1
2-डीऑ सीराइबोस शकरा म कतने ऑ सीजन परमाणु मौजद
ू होते
ह?
18
Chemistry Code: B
33. Three electrolytic cells A, B, C containing solutions of ZnSO4,

AgNO3 and CuSO4, respectively are connected in series. A
steady current of 1.5 amperes was passed through them until
1.45 g of silver deposited at the cathode of cell B. How long
did the current flow? What mass of copper and zinc were
deposited? 5
ZnSO4, AgNO3 एवं CuSO4 वलयन वाले तीन वै यत
ु अपघटनी सेल A,
B, C को ेणीब ध कया गया एवं 1.5 ऐि पयर क व युतधारा, सेल B
के कैथोड पर 1.45 g स वर न े पत होने तक लगातार वा हत क
गई। व युतधारा कतने समय तक वा हत हुई? न े पत कॉपर एवं िजंक
का यमान या होगा?
Or
अथवा
The electrical resistance of a column of 0.05 mol L–1 NaOH
solution of diameter 1 cm and length 50 cm is 5.55 × 103
ohm. Calculate its resistivity, conductivity and molar
conductivity. 5
0.05 mol L–1 NaOH वलयन के कॉलम का व युत तरोध 5.55 ×
103 ohm है । इसका यास 1 cm एवं लंबाई 50 cm है। इसक
तरोधकता, चालकता एवं मोलर चालकता का प रकलन क िजए।
34. List various types of isomerism possible for coordination
compounds, giving an example of each. 5
उपसहसंयोजन यौ गक के लए संभा वत व भ न कार क समावयवताओं
को सच
ू ीब ध क िजए तथा येक का एक उदाहरण द िजए।
Or
19
Chemistry Code: B
अथवा
Write down the IUPAC name, indicate the oxidation state,

electronic configuration, coordination number and magnetic
moment of the complex K4[Mn(CN)6]. 5
संकुल K4[Mn(CN)6] का IUPAC नाम ल खए एवं इसके ऑ सीकारण

अव था, इले ॉ नक व यास, उपसहसंयोजन सं या तथा चुंबक य आघण
ू
को दशाइए।
35. An organic compound (A) (molecular formula C8H16O2) was

hydrolysed with dilute sulphuric acid to give a carboxylic acid
(B) and an alcohol (C). Oxidation of (C) with chromic acid
produced (B). (C) on dehydration gives but-1-ene. Write
equations for the reactions involved. 5
एक काब नक यौ गक (A) (आण वक सू , C8H16O2) को तनु स फयू रक
अ ल के साथ जलअपघ टत करने के उपरांत एक काब ि स लक अ ल
(B) एवं एक ऐ कोहॉल (C) क ाि त हुई। (C) को ो मक अ ल के साथ
ऑ सीकृत करने पर (B) उ प न होता है। (C) नजल करण पर यट
ू -1-
ईन दे ता है । अ भ याओं म यु त होने वाल सभी रासाय नक समीकरण
को ल खए।
Or
अथवा
Predict the products formed when cyclohexanecarbaldehyde

reacts with following reagents: 5
साइ लोहे सेनकाबि डहाइड क न न ल खत अ भकमक के साथ

अभ या से बनने वाले उ पाद को पहचा नए:
20
Chemistry Code: B
i) PhMgBr and then H3O+

PhMgBr एवं त प चात ् H3O+
ii) Tollens’ reagent
टॉलेन अ भकमक
iii) Semicarbazide and weak acid
सेमीकाबज़ाइड एवं दब
ु ल अ ल
iv) Excess ethanol and acid
एथेनॉल का आ ध य तथा अ ल
v) Zinc amalgam and dilute hydrochloric acid
िज़ंक अमलगम एवं तनु हाइ ो लो रक अ ल
21
Chemistry Code: B
CLASS: 12th (Sr. Secondary) Code: C
Roll No.
CHEMISTRY
ACADEMIC / OPEN
________________________________________________________
book.
must be written.
1

paper.
जाएगा।
________________________________________________________

2
Chemistry Code: C
________________________________________________________
1. What is unit of cryoscopic constant? 1

a) kg K-1mol-1
b) K kg mol-1
c) K kg-1 mol-1
d) K kg mol
ायो को पक ि थरांक क इकाई या है?
a) kg K-1mol-1
b) K kg mol-1
c) K kg-1 mol-1
d) K kg mol
2. What happens to conductivity upon dilution of solution of a
strong electrolyte? 1
a) decreases
b) increases
c) remains same
d) may increase or decrease.
एक बल वै युतअपघ य के वलयन के तनुकरण का चालकता पर या
भाव होता है?
a) घट जाती है
b) बढ़ जाती है
c) वह रहती है
d) बढ़ या घट सकती है
3. Which of the following is a secondary cell? 1
3
Chemistry Code: C
a) Leclanche cell
b) Mercury cell
c) Fuel cell
d) Nickel-Cadmium cell
न न ल खत म से कौनसा एक संचायक सेल है?
a) लै लांशे सेल
b) म यरू सेल
c) धन सेल
d) नकैल-कैड मयम सेल
4. Which of the following is not a lanthanoid? 1
a) Thorium
b) Lutetium
c) Terbium
d) Europium
न न ल खत म से कौन एक लै थेनॉयड नह ं है ?
a) थोर यम
b) यट
ू शयम
c) ट बयम
d) यूरो पयम
5. How many nitrogen atoms can make a coordination bond in
EDTA ion? 1
a) 0
b) 2
c) 3
d) 4
4
Chemistry Code: C
ईडीट ए (EDTA) आयन म कतने नाइ ोजन परमाणु उपसहसंयोजन

आबंध बना सकते ह?
a) 0
b) 2
c) 3
d) 4
6. Which of the following is dihydroxy derivative of benzene?
1
a) Catechol
b) Resorcinol
c) Quinol
d) All of the above
न न ल खत म से कौन सा बे जीन का डाइहाइ ॉ सी यु प न है ?
a) कैटे कोल
b) रसॉ सनॉल
c) ि वनॉल
7. What is the name of the reaction in which toluene is treated
with chromyl chloride to produce benzaldehyde? 1
a) Etard reaction
b) Stephen reaction
c) Cannizzaro reaction
d) Gatterman reaction
5
Chemistry Code: C
उस अ भ या का नाम या है िजसम टॉलूईन को ो मल लोराइड के

साथ उपचा रत करके बे जैि डहाइड का उ पादन कया जाता है?
a) ईटाड अ भ या
b) ट फैन अ भ या
c) कै नज़ारो अ भ या
d) गाटरमान अ भ या
8. What is Fehling solution B? 1
a) Ammonical silver nitrate
b) Alkaline sodium potassium tartarate
c) Aqueous copper sulphate
d) Acidified potassium permanganate
फे लंग वलयन B या है?
a) अमो नयामय स वर नाइ े ट

b) ार य सो डयम पोटै शयम टा ट
c) जल य कॉपर स फेट
d) अ ल कृत पोटै शयम परमगनेट
9. Which of the following is most soluble in water? 1
a) Dimethylamine
b) Trimethylamine
c) Methylamine
d) Aniline
न न ल खत म से कौन सा जल म सबसे अ धक वलेय है?
a) डाइमे थलऐमीन
b) ाईमे थलऐमीन
6
Chemistry Code: C
c) मे थलऐमीन
d) ऐ नल न
10. What is Hinsberg’s reagent? 1
a) C6H5SO2Cl
b) CH3SO2Cl
c) C6H5CH2SO2Cl
ह सबग अ भकमक या है ?
a) C6H5SO2Cl
b) CH3SO2Cl
c) C6H5CH2SO2Cl
11. Which of the following is an essential amino acid? 1
a) Glycine
b) Lysine
c) Alanine
d) Proline
न न ल खत म से कौनसा एक आव यक ऐमीनो अ ल है ?
a) लाइसीन
b) लाइसीन
c) ऐला नन
d) ोल न
12. Deficiency of which vitamin causes cheilosis? 1
a) Vitamin B1
7
Chemistry Code: C
b) Vitamin B2
c) Vitamin B6
d) Vitamin B12
कस वटा मन क कमी से क लो सस होता है?
a) वटा मन B1
b) वटा मन B2
c) वटा मन B6
d) वटा मन B12
13. Thyroxine is an iodinated derivative of which amino acid?
1
a) Tryptophan
b) Tyrosine
c) Histidine
d) Lysine
थायरॉि सन कस ऐमीनो अ ल का एक आयोडीन यु त वयु प न है ?
a) टोफेन
b) टायरो सन
c) हि टडीन
d) लाइसीन
14. Double strand helix structure of DNA is its ____ structure.
1
a) Primary
b) Secondary
c) Tertiary
8
Chemistry Code: C
d) Quaternary
DNA क वकंु डलनी संरचना इस क ___________ संरचना है ।
a) ाथ मक
b) वतीयक
c) तत
ृ ीयक
d) चतु क
Assertion (A): Testosterone is the major sex hormone

produced in males.
Reason (R): Testosterone participates in the control of

menstrual cycle.

of A.
of A.

अ भकथन (A): टे टो ट रॉन पु ष म उ पा दत मख

ु यौन हॉम न है।
कारण (R): टे टो ट रॉन रजोधम के नय ंण म भागीदार होता है।
9
Chemistry Code: C

Assertion (A): Reaction of propene with HCl yields

Chloropropane as major product.
Reason (R): Addition of HCl to propene follows Markonikov’s

rule.

of A.
of A.

अ भकथन (A): HCl के साथ ोपीन क अ भ या लोरो ोपेन को मख

ु
उ पाद के प म उ प न करती है ।
कारण (R): ोपीन म HCl का संयोजन माक नीकॉफ के नयम का पालन

करता है।
10
Chemistry Code: C

Assertion (A): Unit of rate constant for a radioactive decay is

time-1.
Reason (R): Radioactive decay is a pseudo first order reaction.

of A.
of A.

अ भकथन (A): एक ना भक य य के लए वेग ि थरांक क इकाई
-1
समय है ।
कारण (R): ना भक य य एक छ म थम को ट अ भ या है।

11
Chemistry Code: C
Assertion (A): Air is an ideal solution.
Reason (R): The solutions which obey Raoult’s law over the
entire range of concentration are known as ideal solutions.

of A.
of A.

अ भकथन (A): वायु एक आदश वलयन है।
कारण (R): वे वलयन जो सभी सां ताओं पर राउ ट के नयम का पालन

करते ह, उ ह आदश वलयन के प म जाना जाता है ।
A व R दोन स य ह तथा R, A क सह याखया है।
a) A व R दोन स य ह तथा R, A क सह याखया नह ं है।

b) A स य है परं तु R अस य है ।
c) A अस य है परं तु R स य है ।
12
Chemistry Code: C
19. Actinoid contraction is greater from element to element than

lanthanoid contraction. Why? 2
लै थेनॉयड आकंु चन क तल
ु ना म एक त व से दस
ू रे त व क बीच
एि टनॉयड आकंु चन अ धक होता है । य?
20. What are alloys? Name an important alloy which contains
some of the lanthanoid metals. 2
म ातुएं या ह? एक मह वपण
ू म ातु का नाम बताइए िजसम कुछ
ल थेनॉयड धातुएं शा मल ह।
Or
अथवा
Calculate the ‘spin only’ magnetic moment of M2+ (aq) ion (Z
= 27). 2
M2+(aq) आयन (Z = 27) के लए ‘ च ण-मा ’ चुंबक य आघूण क
गणना क िजए।
21. Which of the 3d series of the transition metals exhibits the
largest number of oxidation states and why? 2
सं मण त व क 3d ेणी का कौन सा त व बड़ी सं या म ऑ सीकरण
अव थाएं दशाता है और य?
22. Draw the structures of optical isomers of [Co(en)3]3+. 2
[Co(en)3]3+ के का शत समावयव क सरं चना बनाइए।
23. Write IUPAC name of the following compounds: 2
न न ल खत यौ गक के IUPAC नाम ल खए:
i) (CH3)3N
ii) C6H5NHCH3
13
Chemistry Code: C
24. Write chemical reaction of aniline with benzoyl chloride and

write the name of the product obtained. 2
ऐ नल न क बे जॉयल लोराइड के साथ रासाय नक अ भ या लख एवं
उ प न उ पाद के नाम ल खए।
25. What type of bonding help in stabilising the α-helix structure
of proteins? 2
ोट न क α-है ल स सरं चना के थायीकरण म कौन से आब ध सहायक
होते है ?
Or
अथवा
Differentiate between globular and fibrous proteins. 2
रे शेदार और गो लकाकार ोट न को वभे दत क िजए।
26. A solution of Ni(NO3)2 is electrolysed between platinum
electrodes using a current of 5 amperes for 20 minutes. What
mass of Ni is deposited at the cathode? 3
Ni(NO3)2 के एक वलयन का लै टनम इलै ोड के बीच 5 ऐ पीयर क
धारा वा हत करते हुए 20 मनट तक व युत अपघटन कया गया। Ni
क कतनी मा कैथोड पर न े पत होगी?
27. Derive an integrated rate equation for a first-order reaction.
3
थम-को ट क एक अ भ या के लए एक समाक लत वेग समीकरण का
यु प न क िजए।
28. A first order reaction takes 40 min for 30% decomposition.
Calculate t1/2. 3
14
Chemistry Code: C
एक थम-को ट क अ भ या के 30% वयोजन होने म 40 मनट लगते

ह। t1/2 क गणना क िजए।
Or
अथवा
The rate of a reaction quadruples when the temperature
changes from 293 K to 313 K. Calculate the energy of
activation of the reaction assuming that it does not change
with temperature. 3
ताप म 293 K से 313 K तक व ृ ध करने पर कसी अ भ या का वेग
4 गुना हो जाता है। इस अ भ या के लए स यण ऊजा क गणना यह
मानते हुए क िजए क इसका मान ताप के साथ प रव तत नह ं होता है ।
29. Arrange the following compounds in increasing order of their
property as indicated: 3
न न ल खत यौ गक को उनसे संबं धत दए गए गुणधम के बढ़ते म
म यवि थत क िजए:
i) Acetaldehyde, Acetone, Di-tert-butyl ketone, Methyl tert-
butyl ketone (reactivity towards HCN)
ऐ सटै ि डहाइड, ऐसीटोन, डाइ-तत
ृ ीयक- यू टलक टोन, मे थल-
तत
ृ ीयक- यू टलक टोन (HCN के त अभ याशीलता)
ii) CH3CH2CH(Br)COOH, CH3CH(Br)CH2COOH,
(CH3)2CHCOOH, CH3CH2CH2COOH (acid strength)
CH3CH2CH(Br)COOH, CH3CH(Br)CH2COOH,
(CH3)2CHCOOH, CH3CH2CH2COOH (अ लता के साम य के
म म)
15
Chemistry Code: C
iii) Benzoic acid, 4-Nitrobenzoic acid, 3,4-Dinitrobenzoic

acid, 4-Methoxybenzoic acid (acid strength)
बे ज़ोइक अ ल, 4-नाइ ोबे ज़ोइक अ ल, 3,4-डाइनाइ ोबे ज़ोइक
अ ल, 4-मेथॉ सीबे ज़ोइक अ ल (अ लता के साम य के म म)
30. Describe aldol condensation. 3
ऐ डोल संघनन का वणन क िजए।
Or
अथवा
Give simple chemical tests to distinguish between the following
pairs of compounds:
न न ल खत यौ गक यग
ु ल म वभेद करने के लए सरल रासाय नक
पर ण को द िजए:
i) Propanal and Propanone
ोपेनैल एवं ोपेनोन
ii) Benzoic acid and Ethyl benzoate
बे ज़ोइक अ ल एवं ए थलबे ज़ोएट
iii) Benzaldehyde and Acetophenone
बे ज़ैि डहाइड एवं एसीटोफ़ नोन
questions:
Products of electrolysis depend on the nature of material being

electrolysed and the type of electrodes being used. If the
electrode is inert (e.g., platinum or gold), it does not participate
in the chemical reaction and acts only as source or sink for
16
Chemistry Code: C
electrons. On the other hand, if the electrode is reactive, it

participates in the electrode reaction. Thus, the products of
electrolysis may be different for reactive and inert electrodes.
The products of electrolysis depend on the different oxidising
and reducing species present in the electrolytic cell and their
standard electrode potentials.
वै यत
ु अपघटन के उ पाद अपघ टत होने वाले पदाथ क अव था तथा
यु त इलै ोड के कार पर नभर करते ह। य द इलै ोड अ य हो
(उदाहरण के लए Pt अथवा Au) तो यह अ भ या म ह सा नह ं लेता
एवं यह केवल इलै ॉन के ोत अथवा संक का काय करता है। दस
ू र
ओर य द इलै ोड अ भ याशील हो तो यह इलै ोड अ भ या म ह सा
लेता है । इस कार अ भ याशील एवं अ य इलै ोड के लए
वै युतअपघटन के उ पाद अलग-अलग हो सकते ह। वै यत
ु अपघटन के
उ पाद वै यत
ु अपघटनी सेल म उपि थत व भ न ऑ सीकारक एवं
अपचायक पीशीज़ एवं उनके मानक इलै ोड वभव पर नभर करते ह।
i) What is electrolysis? 1
वै युतअपघटन या है ?
ii) What is an electrochemical cell? 1
वै युत रासाय नक सेल या है ?
Or
अथवा
How can you convert an electrochemical cell to an
electrolytic cell? 1
आप एक वै यत
ु रासाय नक सेल को वै यत
ु अपघटनी सेल म कैसे
बदल सकते ह?
17
Chemistry Code: C
iii) Write the products of electrolysis of molten NaCl. 1

ग लत NaCl के वै युतअपघटन के उ पाद ल खए।
iv) Write one use of electrolysis. 1
वै युतअपघटन का एक उपयोग लख।
questions:
To explain bonding in coordination compounds various
theories were proposed. One of the important theories was
valence bond theory. According to that, the central metal ion
in the complex makes available a number of empty orbitals
for the formation of coordination bonds with suitable ligands.
The appropriate atomic orbitals of the metal hybridise to give
a set of equivalent orbitals of definite geometry. The d-orbitals
involved in the hybridisation may be either inner d-orbitals i.e.,
(n-1)d or outer d-orbitals i.e., nd. For example, CO3+ forms
both inner orbital and outer orbital complexes, with ammonia
it forms [Co(NH3)6]3+ and with fluorine it forms
[CoF6]3- complex ion.
उपसहसंयोजन यौ गक म आबंधन क कृ त को समझने के लए अनेक
ताव दए गए थे। एक मह वपूण ताव संयोजकता आब ध स धांत
था। इसके अनुसार संकुल म के य परमाणु/आयन उ चत ल नड से
उपसहसंयोजन आब ध बनाने के लए अनेक र त क क उपल ध करता
है । इसके अनस
ु ार संकुल म के य परमाण/ु आयन अपने क क को
संक रत करके नि चत या म त के समक क क का समु चय दान
18
Chemistry Code: C
करते है । संकरण म शा मल d-क क या तो आंत रक d-क क अथात (n-

1)d क क या बा य d-क क अथात nd क क हो सकते ह। उदाहरण के
लए, CO3+ दोन आंत रक क क एवं बा य क क संकुल बनाता है,
अमो नया के साथ यह [Co(NH3)6]3+ तथा लओ
ु रन के साथ
[CoF6]3- संकुल आयन बनाता है ।
i) Which of the above-mentioned complexes is inner orbital
complex? 1
उपयु त संकुल म से आंत रक क क संकुल कौन सा है?
ii) Which type of hybridisation is found in [Co(NH3)6]3+ ?
1
[Co(NH3)6]3+ म कस कार का संकरण पाया जाता है ?
iii) What is magnetic nature of [CoF6]3- ? 1
[CoF6]3- का चुंबक य यवहार या है?
iv) What is geometry of [CoF6]3- ? 1
[CoF6]3- क या म त या है?
Or
अथवा
How many unpaired electrons are present in central atom
of [Co(NH3)6]3+ ? 1
[Co(NH3)6]3+ के के य परमाणु म कतने अयग
ु लत इले ॉन ह?
33. Write five examples of electrophilic substitution of haloarenes.
5
है लोऐर न क इले ॉनरागी त थापन अ भ या के पाँच उदाहरण
ल खए।
Or
19
Chemistry Code: C
अथवा
Accomplish the following conversions: 5
न न प रवतन न पा दत क िजए:
i) Ethanol to ethyl fluoride
एथेनॉल से ए थल लुओरोइड
ii) Bromomethane to propanone
ोमोमेथेन से ोपेनोन
iii) But-1-ene to but-2-ene
यूट-1-ईन से यूट-2-ईन
iv) Aniline to chlorobenzene
ऐ नल न से लोरोबे जीन
v) Chloroethane to butane
लोरोएथेन से यूटेन
34. Name the reagents used in the following reactions: 5
न न ल खत अ भ याओं म यु त अ भकमक के नाम बताइए:
i) Oxidation of a primary alcohol to carboxylic acid
ाथ मक ऐ कोहॉल का काब ि स लक अ ल म ऑ सीकरण
ii) Oxidation of a primary alcohol to aldehyde
ाथ मक ऐ कोहॉल का ऐि डहाइड म ऑ सीकरण
iii) Bromination of phenol to 2,4,6-tribromophenol
फ़ नॉल का 2,4,6- ाइ ोमोफ़ नॉल म ोमीनन
iv) Benzyl alcohol to benzoic acid
बेि जल ऐ कोहॉल से बे ज़ोइक अ ल
v) Dehydration of propan-2-ol to propene
ोपेन-2-ऑल का ोपीन म नजलन
20
Chemistry Code: C
Or
अथवा
Explain with example: 5
उदाहरण स हत या या कर:
i) Kolbe’s reaction
को बे अ भ या
ii) Reimer-Tiemann reaction
राइमर-ट मन अ भ या
35. What is a colligative property? Which colligative property is
considered the best to determine the molar mass of solute?
Give at least three reasons to support your answer. 5
अणस
ु ं य गण
ु धम या है ? वलेय के मोलर यमान को नधा रत करने
के लए कौन सा अणुसं य गुणधम सबसे अ छा माना जाता है ? अपने
उ र के समथन म कम से कम तीन कारण लख।
Or
अथवा
What are azeotropes? Explain its types with example. 5
ि थर वाथी या ह? उदाहरण के साथ इसके कार को प ट क िजए।
21
Chemistry Code: C
CLASS: 12th (Sr. Secondary) Code: D
Roll No.
CHEMISTRY
ACADEMIC / OPEN
________________________________________________________
book.
must be written.
1

paper.
जाएगा।
________________________________________________________

2
Chemistry Code: D
1. Which of the following is an example of ideal solution? 1

a) Bromobenzene and Bromoethane
b) Chloroethane and Chlorobenzene
c) Benzene and Ethanol
d) Benzene and Toluene
न न ल खत म से कौन सा आदश वलयन का एक उदाहरण है?
a) ोमोबे ज़ीन एवं ोमोएथेन
b) लोरोएथेन एवं लोरोबे ज़ीन
c) बे ज़ीन एवं एथेनॉल
d) बे ज़ीन एवं टॉलूईन
2. Which of the following is not affected by catalyst? 1
a) Enthalpy
b) Gibbs energy
c) Speed of reaction
न न ल खत म से कौन उ ेरक से भा वत नह ं होता है ?
a) ए थै पी (ऊजा)
b) ग ज़ ऊजा
c) अ भ या का वेग
d) ऊपयु त म से कोई नह ं
3. What is order of thermal decomposition of HI on gold surface?
1
a) 1
3
Chemistry Code: D
b) 1.5
c) 0
d) 0.5
वण सतह पर HI के ऊ मीय वयोजन क को ट या है ?
a) 1
b) 1.5
c) 0
d) 0.5
4. Which of the following ion has highest oxidation state of Mn.
1
a) Mn2+
b) MnO42-
c) MnO4-
d) All of the above
न न ल खत म से कस आयन म Mn क अ धक म ऑ सीकरण अव था
है ?
a) Mn2+
b) MnO42-
c) MnO4-
5. Which of the following has the highest magnetic moment?
1
a) V2+
b) Ti2+
c) Cr2+
4
Chemistry Code: D
d) Co2+
न न ल खत म से कसका चुंबक य आघण

ू सबसे अ धक है?
a) V2+
b) Ti2+
c) Cr2+
d) Co2+
6. What is oxidation number of Ni in [Ni(CO)4]? 1
a) 0
b) 1
c) 2
d) 4
[Ni(CO)4] म Ni क ऑ सीकरण सं या या है?
a) 0
b) 1
c) 2
d) 4
7. Which of the following has the highest boiling point? 1
a) Bromomethane
b) Bromoform
c) Chloromethane
d) Dibromomethane
न न ल खत म से कसका वथनांक सबसे अ धक है ?
a) ोमोमेथेन
b) ोमोफॉम
5
Chemistry Code: D
c) लोरोमेथेन
d) डाइ ोमोमेथेन
8. Which of the following is fastest to react by SN1 mechanism?
1
a) tert-Butyl bromide
b) sec-Butyl bromide
c) Isobutyl bromide
d) n-Butyl bromide
न न ल खत म से कौन सा SN1 या व ध वारा अ भ या करने के

लए सबसे ती है?
a) tert- यू टल ोमाइड
b) sec- यू टल ोमाइड
c) आईसो यू टल ोमाइड
d) n- यू टल ोमाइड
9. Which of the following is obtained from isopropyl benzene?
1
a) Phenol
b) Acetone
c) Both of the above
न न ल खत म से या आइसो ो पल बे जीन से ा त कया जाता है ?
a) फ़ नॉल
c) उपयु त दोन
6
Chemistry Code: D
10. Which reagent is used to yield picric acid from phenol? 1
a) Conc. H3PO4
b) Conc. HNO3
c) Dilute H2SO4
d) Dilute HNO3
फ़ नॉल से प क अ ल ा त करने के लए कस अ भकमक का उपयोग

कया जाता है?
a) सां H3PO4
b) सां HNO3
c) तनु H2SO4
d) तनु HNO3
11. Which of the following does not give iodoform test? 1
a) Ethanal
b) Acetone
c) Benzaldehyde
d) Acetophenone
न न ल खत म से कौन सा आयोडोफॉम पर ण नह ं दे ता है?
a) ऐथेनैल
c) बे जैि डहाइड
d) ऐसीटोफ़ नॉन
12. What is the major product formed by Friedel-Crafts
methylation of benzoic acid? 1
7
Chemistry Code: D
a) o-methylbenzoic acid
b) m-methylbenzoic acid
c) p-methylbenzoic acid
बे ज़ोइक अ ल के डेल- ा स मे थलन वारा ग ठत मुख उ पाद या

है ?
a) o-मे थलबे ज़ोइक अ ल

b) m-मे थलबे ज़ोइक अ ल
c) p-मे थलबे ज़ोइक अ ल
13. Which of the following regulate glucose level in blood? 1
a) Insulin and Thyroxine
b) Epinephrine and Norepinephrine
c) Insulin and Glucagon
d) Glucagon and Estradiol
न न म से कौन र त म लक
ू ोस के तर को नयं त करता है ?
a) इ सु लन और थायरॉि सन
b) ए पनेफ रन और नॉरए पनेफ रन
c) इ सु लन और लूकागॉन
d) लक
ू ागॉन और ए ाडाइऑल
14. How many hydrogen bonds are formed between adenine and
guanine in a DNA? 1
a) 0
b) 1
8
Chemistry Code: D
c) 2
d) 3
DNA म एडे नन और वा नन के म य कतने हाइ ोजन आबंध बनते ह?
a) 0
b) 1
c) 2
d) 3
Assertion (A): Aniline does not undergo Friedel-Crafts reaction.
Reason (R): Aniline being basic forms salt with aluminium

chloride.

of A.
of A.

अ भकथन (A): ऐ न लन डेल- ा स अभ या नह ं करता है ।
9
Chemistry Code: D
कारण (R): ऐ न लन ार य होने के कारण ऐलम

ु ी नयम लोराइड के साथ
लवण बनाता है।

Assertion (A): o-Nitrophenol is more acidic than m-Nitrophenol.
Reason (R): Nitro group is an electron releasing group.

of A.
of A.

अ भकथन (A): o-नाइ ोफ़ नॉल, m-नाइ ोफ़ नॉल क तुलना म अ धक

अ ल य है।
कारण (R): नाइ ो समूह एक इले ॉन वमोचक समूह है।
10
Chemistry Code: D

Assertion (A): Tetrahedral complexes show Geometric

isomerism.
Reason (R): Geometric isomerism arises due to different

possible geometric arrangements of the ligands.

of A.
of A.

अ भकथन (A): चतु फलक य संकुल या मतीय समावयवता दशाते ह।
कारण (R): या मतीय समावयवता लग ड क व भ न संभा वत

या मतीय यव था के कारण उ प न होती है ।

11
Chemistry Code: D
Assertion (A): The conductance of electricity by ions present

in the solutions is called ionic conductance.
Reason (R): Ionic conductance decreases with increase in

temperature.

of A.
of A.

अ भकथन (A): वलयन म उपि थत आयन वारा व युत के चालक व

को आय नक चालक व कहा जाता है।
कारण (R): आय नक चालक व तापमान म व ृ ध के साथ कम हो जाती

है ।
12
Chemistry Code: D
19. State Henry’s law. Write its two applications. 2
हे नर का नयम बताइए। इसके दो अनु योग ल खए।
Or
अथवा
1.00 g of a non-electrolyte solute dissolved in 50 g of benzene

lowered the freezing point of benzene by 0.40 K. The freezing
point depression constant of benzene is 5.12 K kg mol–1. Find
the molar mass of the solute. 2
एक वै यत
ु अपघ य के 1.00 g को 50 g बे ज़ीन म घोलने पर इसके
हमांक म 0.40 K क कमी हो जाती है। बे ज़ीन का हमांक अवनमन
ि थरांक 5.12 K kg mol-1 है । वलेय का मोलर यमान ात क िजए।
20. State Kohlrausch law of independent migration of ions. Write

its two applications. 2
आयन के वतं अ भगमन का कोलराउश नयम बताइए। इसके दो
अनु योग लख।
21. Draw structures of geometrical isomers of [Fe(NH3)2(CN)4]-.
[Fe(NH3)2(CN)4]- के या मतीय समावयव क सरं चना दशाइए।

22. Draw structures of following derivatives: 2
न न ल खत यत
ु प न क सरं चना बनाइए:
i) Cyclopropanone oxime
13
Chemistry Code: D
साइ लो ोपेनोन ऑि सम
ii) Methyl hemiacetal of formaldehyde
फॉमि डहाइड का मे थल हेमीऐसीटे ल
23. Give plausible explanation for each of the following: 2
न न ल खत के संभा वत कारण द िजए:
i) Cyclohexanone forms cyanohydrin in good yield but
2,2,6-trimethylcyclohexanone does not.
साइ लोहे सेनोन अ छ लि ध म सायनोहाइ न बनाता है परं तु

2,2,6- ाइमे थलसाइ लोहे सेनोन ऐसा नह ं करता है ।
ii) There are two –NH2 groups in semicarbazide. However,

only one is involved in the formation of semicarbazones.
सेमीकाब ज़ाइड म दो -NH2 समूह होते ह, परं तु केवल एक -NH2
समूह ह सेमीकाब ज़ोन वरचन म यु त होता है।
24. What is aldol? Give an example of a reaction. 2
ऐ डोल या है ? एक अ भ या का उदाहरण द िजए।
Or
अथवा
Give simple chemical tests to distinguish between the following
pairs of compounds: 2
न न ल खत यौ गक यग
ु ल म वभेद करने के लए सरल रासाय नक
पर ण द िजए:
i) Ethanal and Propanone
एथेनैल एवं ोपेनोन
ii) Propanal and Benzaldehyde
14
Chemistry Code: D
ोपेनैल एवं बे ज़ैि डहाइड

25. What is quaternary structure of proteins? Give an example.
2
ोट न क चतु क सरं चना या है ? एक उदाहरण द िजए।
26. Define molar conductivity for the solution of an electrolyte.
How does it vary with concentration for a weak electrolyte?
3
कसी वै यत
ु अपघ य के वलयन क मोलर चालकता क प रभाषा द िजए।
यह एक दब
ु ल वै युतअपघ य के लए सां ता के साथ कैसे प रव तत होता
है ?
Or
अथवा
Draw a labelled diagram of standard hydrogen electrode. 3
मानक हाइ ोजन इलै ड का नामां कत आरे ख बनाय।
27. The cell in which the following reaction occurs:
2Fe3+(aq) + 2I-(aq)  2Fe2+(aq) + I2(s) has E0cell = 0.236 V at
298 K. Calculate the standard Gibbs energy and the
equilibrium constant of the cell reaction. 3
एक सेल िजसमे न न ल खत अ भ या होती है:
2Fe3+(aq) + 2I-(aq)  2Fe2+(aq) + I2(s) का 298 K ताप पर E0सेल
= 0.236 V है । सेल अ भ या क मानक ग ज़ ऊजा एवं सा य ि थरांक
का प रकलन क िजए।
28. Write IUPAC names of following coordination compounds:
3
न न ल खत उपसहसंयोजन यौ गक के IUPAC नाम ल खए:
15
Chemistry Code: D
i) [Pt(NH3)2Cl(NO2)]
ii) K3[Cr(C2O4)3]
iii) [Co(NH3)5(CO3)]Cl
29. Write the mechanism of acid dehydration of ethanol to yield
ethene. 3
एथेनॉल के अ ल य नजलन से एथीन ा त करने क या व ध ल खए।
Or
अथवा
Explain how you will distinguish between primary, secondary
and tertiary alcohols. 3
समझाएं क आप ाथ मक, वतीयक और तत
ृ ीयक ऐ कोहॉल के म य
अंतर कैसे करगे।
30. What happens when D-glucose is treated with the following
reagents? 3
या होता है जब D- लक
ू ोस क अ भ या न न ल खत अ भकमक से
करते ह?
(i) HI
(ii) Bromine water
ोमीन जल
(iii) HNO3
questions:
The spontaneous flow of solvent through a semipermeable

membrane from a pure solvent to solution or from a dilute
16
Chemistry Code: D
solution to a concentrated solution is called osmosis. The

phenomenon of osmosis can be demonstrated by taking two
eggs of the same size. In an egg, the membrane below the
shell and around the egg material is semi-permeable. The
outer hard shell can be removed by putting the egg in dilute
hydrochloric acid. After removing the hard shell, one egg is
placed in distilled water and the other in a saturated salt
solution. After some time, the egg placed in distilled water
swells-up while the egg placed in salt solution shrinks. The
external pressure applied to stop the osmosis is termed as
osmotic pressure which is a colligative property.
एक अधपारग य झ ल के मा यम से शु ध वलायक से वलयन तक

या एक तनु वलयन से एक सां वलयन तक वलायक के सहज वाह
को परासरण कहा जाता है । एक ह आकार के दो अंडे लेकर परासरण क
घटना का दशन कया जा सकता है। एक अंडे म, कवच के नीचे और
अंडे क साम ी के चार ओर झ ल अध-पारग य होती है । अंडे को तनु
हाइ ो लो रक अ ल म डालकर बाहर कठोर कवच को हटाया जा सकता
है । कठोर कवच को हटाने के बाद, एक अंडे को आसुत जल म और दस
ू रे
को संत ृ त नमक के वलयन म रखा जाता है। कुछ समय बाद, आसुत
जल म रखा अंडा फूल जाता है जब क नमक के वलयन म रखा अंडा
सकुड़ जाता है। परासरण को रोकने के लए लागू बाहर दबाव को परासरण
दाब कहा जाता है जो एक अणुसं य गुणधम है।
i) What is reverse osmosis? 1

तलोम परासरण या है ?
17
Chemistry Code: D
ii) What would happen if red blood corpuscles were placed

in 0.5% NaCl solution? 1
या होगा य द लाल र त क णकाओं को 0.5% NaCl वलयन म
रखा जाए?
Or
अथवा
What are isotonic solutions? 1
समपरासार वलयन या ह?
iii) Write one application of osmosis in food preservation.
1
खा य प रर ण म परासरण का एक अनु योग ल खए।
iv) Out of 1 M KCl and 1 M urea, which will have higher
osmotic pressure? 1
1 M KCl और 1 M यू रया म से कसका उ च परासरण दाब
होगा?
questions:
Primary alkyl halide C4H9Br (A) reacted with alcoholic KOH to
give compound (B). Compound (B) is reacted with HBr to give
(C) which is an isomer of (A). When (A) is reacted with
sodium metal it gives compound (D), C8H18 which is different
from the compound formed when n-butyl bromide is reacted
with sodium.
18
Chemistry Code: D
ाथ मक ऐि कल है लाइड C4H9Br (A), ऐ कोहॉ लक KOH म अ भ या

वारा यौ गक (B) दे ता है। यौ गक (B) HBr के साथ अ भ या से यौ गक
(C) दे ता है जो क यौ गक (A) का समावयवी है । जब यौ गक (A) क
अभ या सो डयम धातु से होती है तो यौ गक (D) C8H18 बनता है , जो
क यू टल ोमाइड क सो डयम से अ भ या वारा बने उ पाद से भ न
है ।
i) Which type of isomerism is present between compounds
(A) and (C)? 1
यौ गक (A) एवं (C) के म य कस कार क समावयवता है ?
ii) Write IUPAC name of compound (D). 1
यौ गक (D) का IUPAC नाम ल खए।
iii) Draw structure of compound (B). 1
यौ गक (B) क सरं चना बनाइए।
iv) How will you convert compound (B) to (A)? 1
आप यौ गक (B) को (A) म कैसे प रव तत करगे।
Or
अथवा
What is the name of the reaction in which compound
(A) is converted to compound (D). 1
उस अ भ या का नाम या है िजसम यौ गक (A) को यौ गक (D)
म प रव तत कया जाता है।
90
33. During nuclear explosion, one of the products is Sr with
90
half-life of 28.1 years. If 1μg of Sr was absorbed in the
bones of a newly born baby instead of calcium, how much of
19
Chemistry Code: D
it will remain after 10 years and 60 years if it is not lost

metabolically. 5
90
ना भक य व फोट का 28.1 वष अधायु वाला एक उ पाद Sr होता है।
90
य द कैि सयम के थान पर 1μg, Sr नवजात शशु क अि थय म
अवशो षत हो जाए उपापचयन से ास न हो तो इसक 10 वष एवं 60
वष प चात ् कतनी मा ा रह जाएगी?
Or
अथवा
The time required for 10% completion of a first order reaction
at 298K is equal to that required for its 25% completion at
308K. If the value of A is 4 × 1010s–1. Calculate k at 318K
and Ea. 5
298 K ताप पर थम को ट क अ भ या के 10% पूण होने का समय
308 K ताप पर 25% अ भ या पूण होने मे लगे समय के बराबर है।
य द A का मान 4 × 1010s–1 हो तो 318 K ताप पर k तथा Ea क
गणना क िजए।
34. What are lanthanoids? Write their general electronic
configuration. What is lanthanoid contraction? What are the
consequences of lanthanoid contraction? 5
लै थेनॉयड या ह? इनका सामा य इले ॉ नक व यास लख। लै थेनॉयड
आकंु चन या है ? लै थेनॉयड आकंु चन के प रणाम या है ?
Or
अथवा
Describe the preparation of potassium permanganate. How

does the acidified permanganate solution react with (a) iron
20
Chemistry Code: D
(II) ions (b) SO2 and (c) oxalic acid? Write the ionic equations
for the reactions. 5
पोटै शयम परमगनेट को बनाने क व ध का वणन क िजए। अ ल य

पोटै शयम परमगनेट कस कार (a) आयरन (II) आयन (b) SO2 तथा
(c) ऑ सै लक अ ल से अ भ या करता है? अ भ याओं के लए
रासाय नक समीकरण ल खए।
35. An aromatic compound ‘A’ on treatment with aqueous

ammonia and heating forms compound ‘B’ which on heating
with Br2 and KOH forms a compound ‘C’ of molecular formula
C6H7N. Write the structures and IUPAC names of compounds
A, B and C. 5
एक ऐरोमै टक यौ गक ‘A’ जल य अमो नया के साथ गरम करने पर यौ गक
‘B’ बनाता है जो Br2 एवं KOH के साथ गरम करने पर अणु सू C6H7N
वाला यौ गक ‘C’ बनाता है । A, B एवं C, यौ गक क सरं चना एवं इनके
IUPAC नाम ल खए।
Or
अथवा
Complete the following reactions: 5
न न ल खत अ भ याओं को पूण क िजए:
i) C6H5N2Cl + H3PO2 + H2O 
ii) C6H5NH2 + (CH3CO)2O 
iii) C6H5SO2Cl + CH3NH2 
iv) C6H5NH2 + CHCl3 + alc. KOH 
v) C6H5NH2 + H2SO4 (conc.) 
21
Chemistry Code: D
BSEH MARKING SCHEME
CLASS- XII Chemistry (March-2024) Code: A
 The answer points given in the marking scheme are not

final. These are suggestive and indicative. If the examinee
has given different, but appropriate answers, then he should
be given appropriate marks.
Q. Answers Marks
No.
1. a) Copper dissolved in Gold. 1
2. b) Increases with increase in temperature 1
3. d) S m-1 1
4. d) All of these 1
5. a) 0 1
6. b) Frequency factor 1
7. a) Sc 1
8. a) Vitamin B12 1
9. c) NaI 1
10. b) n-Butane 1
11. b) 3-Phenylprop-2-en-1-al 1
12. c) Position isomerism 1
13. b) Ribose 1
14. d) Vitamin K 1
15. a) Both A and R are true, and R is the correct 1
explanation of A.
1
BSEH Marking Scheme Class: XII March-2024

explanation of A.
explanation of A.
18. d) A is false but R is true 1
19. Ideal Solutions Non-ideal solutions 2
1. Those liquid-liquid 1. Those liquid-liquid
solutions which obey solutions which do not
Raoults’ law at each obey Raoults’ law at
concentration. each concentration.
2. The molecular 2. The molecular
interactions of solution interactions of solution
is same as that of is not same as that of
solute and solvent. solute and solvent.
3. ∆𝑉 =0 3. ∆𝑉 ≠0
4. ∆𝐻 =0 4. ∆𝐻 ≠0
(any two differences, 1 mark each)
Or
Given molarity (M) = 0.15 M
Volume (V) = 250 mL
Molar mass of solute (M2) = 122 g/mol
Mass of solute (w2) =?
×
⸪ 𝑀 =
×
(1 2 𝑚𝑎𝑟𝑘)
× ×
⸫ 𝑤 =
2
Chemistry Code: A
× × .
⇒ 𝑤 = 𝑔
(1 2 𝑚𝑎𝑟𝑘)
⇒ 𝑤 = 4.575 𝑔
(1 2 𝑚𝑎𝑟𝑘 𝑓𝑜𝑟 𝑐𝑜𝑟𝑟𝑒𝑐𝑡 𝑎𝑛𝑠𝑤𝑒𝑟, 1 2 𝑚𝑎𝑟𝑘 𝑓𝑜𝑟 𝑢𝑛𝑖𝑡)
20. First Law: The amount of chemical reaction which 2

occurs at any electrode during electrolysis by a
current is proportional to the quantity of electricity
passed through the electrolyte.
(1 mark)
Second Law: The amounts of different substances

liberated by the same quantity of electricity passing
through the electrolytic solution are proportional to
their chemical equivalent weights.
(1 mark)
21. The reaction which is not of first order but behaves
like first order is called pseudo first order reaction.
(1 mark) 2
Example: acid hydrolysis of ethyl acetate or inversion
of cane sugar
3
Chemistry Code: A
(Any one, 1 mark)

22. Interstitial compounds are those which are formed
when small atoms like H, C or N are trapped inside
the crystal lattices of metals.
(1 mark)
Interstitial compounds are well known for transition
2
compounds due to their closed crystalline structure
with voids in them. The atomic size of transition
metals is very large hence have large voids to occupy
these small atoms.
(1 mark)
23. Alkyl halides react with sodium in dry ether to give
hydrocarbons containing double the number of carbon
atoms present in the halide. This reaction is known
as Wurtz reaction.
(1 mark)
2CH3Br + 2Na ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ CH3CH3 + 2NaBr

Methyl bromide Ethane
2
(1 mark)
Or
Groups which possess two different nucleophilic
centres and are called ambident nucleophiles.
(1 mark)
nitrite ion represents an ambident nucleophile with
two different points of linkage. The linkage through
4
Chemistry Code: A
oxygen results in alkyl nitrites while through nitrogen

atom, it leads to nitroalkanes.
(1 mark)
24. i) Methanoic acid is used in rubber, textile, dyeing,
leather and electroplating industries.
ii) Ethanoic acid is used as solvent and as vinegar
in food industry.
iii) Hexanedioic acid is used in the manufacture of
nylon-6, 6. 2
iv) Esters of benzoic acid are used in perfumery.
v) Sodium benzoate is used as a food preservative.
vi) Higher fatty acids are used for the manufacture
of soaps and detergents.
(Any two, 1 mark each)
25. i)
(1 mark) 2
ii)
(1 mark)
5
Chemistry Code: A
26. Here
Vapour Pressure of solution at normal boiling point
(p1) = 1.004 bar
Vapour Pressure of pure water at normal boiling
point
(po1) = 1.013 bar
(½ mark)
Let mass of solution (W) = 100 g
(½ mark)
Mass of solute (w2) = 2 g 3

Mass of solvent (w1) = 98 g
Molar mass of solvent (water) (M1) = 18 g/mol
According to Raoult’s law:
𝑤
𝑝 −𝑝 𝑀
= 𝑤 𝑤
𝑝 +
𝑀 𝑀
(½ mark)
. .
⇒ =
.
(½ mark)
⇒ 𝑀 = 40.98 𝑔/𝑚𝑜𝑙
(½ mark for answer, ½ mark for unit)
27. T1=298K
3
After the increase in temperature by 10K
6
Chemistry Code: A
T2=(T1+10)K
T2=298+10=308K
(½ mark)
Let us take the value of K1=K
Now, K2=2K
Also, R=8.314JK−1mol−1
Now, substituting these values in the Arrhenius

equation:
𝑘 𝐸 𝑇 − 𝑇
𝑙𝑜𝑔( )=
𝑘 2.303𝑅 𝑇 𝑇
(1 mark)
We get:
2𝑘 𝐸 308 − 298
𝑙𝑜𝑔( )=
𝑘 2.303 × 8.314 308 × 298
(½ mark)
∴Ea =52897.78Jmol−1
=52.9kJmol−1
7
Chemistry Code: A
28. When a particular oxidation state becomes less

stable relative to other oxidation states, one lower,
one higher, it is said to undergo disproportionation.
(1 mark)
For example,
manganese (VI) becomes unstable relative to
manganese (VII) and manganese (IV) in acidic
solution.
3MnO42– + 4H+  MnO4– + MnO2 + 2H2O
(1 mark)
copper (I) compounds are unstable in aqueous
solution and undergo disproportionation.
2Cu+  Cu2+ + Cu 3
(1 mark)
Or
Chromates are obtained by the fusion of chromite

ore (FeCr2O4) with sodium or potassium carbonate in
free access of air. The reaction with sodium
carbonate occurs as follows:
4FeCr2O4 + 8Na2CO3 + 7O2  8Na2CrO4 + 2Fe2O3

+ 8CO2
(1 mark)
The yellow solution of sodium chromate is filtered

and acidified with sulphuric acid to give a solution
8
Chemistry Code: A
from which orange sodium dichromate can be

crystallised.
2Na2CrO4 + 2H+  Na2Cr2O7 + 2Na+ + H2O
(1 mark)
Sodium dichromate is more soluble than potassium
dichromate. The latter is therefore, prepared by
treating the solution of sodium dichromate with
potassium chloride and orange crystals of potassium
dichromate crystallise out.
Na2Cr2O7 + 2KCl  K2Cr2O7 + 2NaCl
(1 mark)
29. Aryl halides are extremely less reactive towards

nucleophilic substitution reactions due to the
following reasons:
(i) Resonance effect:
In haloarenes, the electron pairs on
halogen atom are in conjugation with p-
3
electrons of the ring and the resonating
structures are possible. C—Cl bond
acquires a partial double bond character
due to resonance. As a result, the bond
cleavage in haloarene is difficult than
haloalkane and therefore, they are less
9
Chemistry Code: A
reactive towards nucleophilic

substitution reaction.
(ii) Difference in hybridisation of carbon
atom in C—X bond:
The sp 2 hybridised carbon with a
greater s-character is more
electronegative and can hold the
electron pair of C—X bond more tightly
than sp 3 -hybridised carbon in haloalkane
with less s-character. Thus, C—Cl bond
length is shorter in haloarene. Since it
is difficult to break a shorter bond than
a longer bond, therefore, haloarenes are
less reactive towards nucleophilic
substitution reaction.
(iii) Instability of phenyl cation:
In case of haloarenes, the phenyl cation
formed as a result of self-ionisation will
not be stabilised by resonance and
therefore, S N 1 mechanism is ruled out.
(iv) Because of the possible repulsion, it is
less likely for the electron rich
nucleophile to approach electron rich
arenes.
(any three, 1 mark each)
10
Chemistry Code: A
30. The Hinsberg test is used for the identification of

primary, secondary and tertiary amines.
(½ mark)
Benzenesulphonyl chloride (C6H5SO2Cl), which is also

known as Hinsberg’s reagent, reacts with primary and
secondary amines to form sulphonamides.
(1 mark)
Tertiary amines do not react with Hinsberg’s reagent.
(½ mark)
(½ mark)
(Insoluble in alkali)
(½ mark)
Or
i) Amines undergo protonation to give amide

ion. Similarly, alcohol loses a proton to give
alkoxide ion.
11
Chemistry Code: A
In an amide ion, the negative charge is on

the N-atom whereas in alkoxide ion, the
negative charge is on the O-atom. Since O
is more electronegative than N, O can
accommodate the negative charge more
easily than N. As a result, the amide ion is
less stable than the alkoxide ion. Hence,
amines are less acidic than alcohols of
comparable molecular masses.
(1 mark)
ii) Intermolecular hydrogen bonding is present

in primary amines but not in tertiary
amines (H-atom absent in amino group) so
primary amines have higher boiling point than
tertiary amines.
(1 mark)
iii) In aromatic amines, the −NH2 group is

attached to a −C6H5 group, which is an
electron withdrawing group. So, the
availability of a lone pair of electrons on N
is decreased. Therefore, aliphatic amines are
more basic than aromatic amines.
12
Chemistry Code: A
(1 mark)
31. i) Phenol
(1mark)
ii) 8
(1 mark)
Or
Salicylic Acid
4
(1 mark)
iii) Reimer-Tiemann reaction
(1 mark)
iv) Aspirin possesses analgesic, anti-inflammatory
and antipyretic properties.
(any one, 1 mark)
32. i) Amino acids have amino (−NH2) group, basic in
nature and accepts a proton and COOH group loses
a proton forming a dipolar ion, called the Zwitter ion.
In this form, amino acids behave both as acids and
bases, so they are amphoteric in nature.
(1 mark)
ii) Peptide bond
(1 mark)
iii) If more than ten α-amino acids are joined together
by peptide bond the structure thus formed is called
Polypeptides.
(1 mark)
13
Chemistry Code: A
iv) Glycine/ Alanine/ Glutamic acid/ Aspartic acid/

Glutamine/ Asparagine/ Serine/ Cysteine/ Tyrosine/
Proline
(Any one, 1 mark)
Or
20
(1 mark)
33. Nernst equation:
0.0591 𝑀𝑔
𝐸 = 𝐸 − 𝑙𝑜𝑔
𝑛 𝐶𝑢
(1 mark)
Calculation of 𝐸 :
0.0591 0.001
𝐸 = 2.70 − 𝑙𝑜𝑔
2 0.0001
(½ mark)
0.0591
𝐸 = 2.70 − 𝑙𝑜𝑔10
2
(½ mark)
𝐸 = 2.67 𝑉 5

Calculation of ΔrGo :
∆ 𝐺 ° = −𝑛𝐹𝐸 °
(½ mark)
∆ 𝐺 ° = −2 × 96500 × 2.70
(½ mark)
∆ 𝐺 ° = −521100 𝐽𝑚𝑜𝑙 = −521.1 𝑘𝐽𝑚𝑜𝑙
Or
14
Chemistry Code: A
Given
κ = 7.896×10–5 S cm–1
c = 0.00241 M
 = 390.5 S cm2 mol–1
Molar conductivity 
×
=
(½ mark)
7.896 × 10 × 1000
 =
0.00241
(½ mark)
 = 32.76 S 𝑐𝑚 𝑚𝑜𝑙

Degree of dissociation; 𝛼 =
°
(½ mark)
= 0.084
.
𝛼=
.
(½ mark)
Dissociation constant; 𝐾 =
(½ mark)
0.00241 × (0.084)
𝐾 =
1 − 0.084
(½ mark)
𝐾 = 1.86 × 10
(1 mark)
34. i) 3
(1 mark)
5
ii) 3
(1 mark)
15
Chemistry Code: A
iii) 2
(1 mark)
iv) 3
(1 mark)
v) 3
(1 mark)
Or
Ni is in the +2 oxidation state i.e., in d8 configuration.
(½ mark)
There are 4 CN− or Cl− ions. Thus, it can either have
a tetrahedral geometry or square planar geometry.
(1 mark)
Since CN− ion is a strong field ligand, it causes the
pairing of unpaired 3d electrons.
(½ mark)
(½ mark)
It now undergoes dsp2 hybridization.
(½ mark)
16
Chemistry Code: A
Since all electrons are paired, it is diamagnetic.

(½ mark)
In case of [NiCl4]2−, Cl− ion is a weak field ligand.
Therefore, it does not lead to the pairing of unpaired
3d electrons.
(½ mark)
Therefore, it undergoes sp3 hybridization.
(½ mark)
Since there are 2 unpaired electrons in this case, it
is paramagnetic in nature.
(½ mark)
35. Case I
Propanal + Propanal + dil. NaOH 
CH3CH2CH=C(CH3)CHO (2-Methylpent-2-en-1-al)
(½ mark + ½ mark)
Case II
Butanal + Butanal + dil. NaOH  5
CH3CH2CH2CH=C(C2H5)CHO (2-Ethylhex-2-en-1-al)
(½ mark + ½ mark)
Case III
Butanal + Propanal + dil. NaOH 
CH3CH2CH2CH=C(CH3)CHO (2-Methylhex-2-en-1-al)
17
Chemistry Code: A
(½ mark + ½ mark)
Case IV
Propanal + Butanal + dil. NaOH 
CH3CH2CH=C(C2H5)CHO (2-Ethylpent-2-en-1-al)
(½ mark + ½ mark)
In case III butanal act as electrophile and propanal
act as nucleophile
Or
In case IV propanal act as electrophile and butanal
act as nucleophile
(any one, ½ mark + ½ mark)
Or
i)
(1 mark)
ii)
(1 mark)
iii)
(1 mark)
iv)
18
Chemistry Code: A
(1 mark)
v)
(1 mark)
19
Chemistry Code: A
BSEH MARKING SCHEME
CLASS- XII Chemistry (March-2024) Code: B

Q. Answers Marks
No.
1. c) µg/mL 1
2. b) 0.9% (mass/volume) NaCl 1
3. b) Anode 1
4. c) mol L-1s-1 1
5. c) Zn 1
6. a) KMnO4 1
7. d) 6 1
8. b) cis-platin 1
9. c) 3-Chloropropene 1
10. c) Phenol 1
11. c) 4-Nitroanisole 1
12. b) β-D-Glucose 1
13. a) 51 1
14. b) Vitamin C 1
explanation of A.
1
16. d) A is false but R is true. 1

17. b) Both A and R are true, and R is not the correct 1
explanation of A
19. The properties which depend on the number of solute 2
particles irrespective of their nature relative to the
total number of particles present in the solution are
called colligative properties.
(1 mark)
Examples: (1) relative lowering of vapour pressure
of the solvent
(2) depression of freezing point of the solvent
(3) elevation of boiling point of the solvent
(4) osmotic pressure
(Any two, ½ mark each)
20. Given: 2
c = 0.20 M
κ = 0.0248 S cm–1
molar conductivity
𝜅 × 1000
 =
𝑐
(½ mark)
0.0248 × 1000
 =
0.20
2
Chemistry Code: B
(½ mark)
 = 124 S 𝑐𝑚 𝑚𝑜𝑙
Or
Given
Production of Al from Al2O3 has a reaction as
following:
Al3+ + 3e-  Al
(½ mark)
i.e. production of 1 mole of Al (27 g) from Al2O3
requires electricity = 3 F
or production of 1 g of Al from Al2O3 requires
electricity = 3/27 F
(½ mark)
So, production of 40 g of Al from Al2O3 requires
electricity = 40/9 F
= 4.44 F
21. concentration of reactants & pressure in case of
gases, temperature, and catalyst. 2
(½ mark each)
22. In the first transition series, Cu exhibits +1 oxidation
state very frequently. 2
(1 mark)
3
Chemistry Code: B
It is because Cu (+1) has an electronic configuration

of [Ar] 3d10. The completely filled d-orbital makes it
highly stable.
(1 mark)
23. tert-butyl bromide < sec-butyl bromide < isobutyl
2
bromide < n-butyl bromide
24. Carboxylic acids lose carbon dioxide to form
hydrocarbons when their sodium salts are heated with
sodalime (NaOH and CaO in the ratio of 3:1). The
reaction is known as decarboxylation.
(1 mark)
& , ∆
𝐶𝐻 𝐶𝑂𝑂𝑁𝑎 ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ 𝐶𝐻 + 𝑁𝑎 𝐶𝑂
(1 mark)
Or
2
Addition products formed by the reaction of aldehydes
and ketones with hydrogen cyanide (HCN) are known
as cyanohydrins.
(1 mark)
(1 mark)
25. i) p-nitroaniline, Aniline, p-toluidine
(1 mark) 2
ii) NH3, C2H5NH2, (C2H5)2NH, (C2H5)3N
4
Chemistry Code: B
(1 mark)
26. Positive Deviation Non- Negative Deviation Non-
Ideal Solutions ideal solutions
1. Those liquid-liquid 1. Those liquid-liquid
solutions which has solutions which has
vapour pressure more vapour pressure less
than expectations from than expectations from
Raoults’ law. Raoults’ law.
2. The molecular 2. The molecular
3
interactions of solution interactions of solution
is weaker than that of is stronger than that of
solute and solvent. solute and solvent.
3. ∆𝑉 >0 3. ∆𝑉 <0
4. ∆𝐻 >0 4. ∆𝐻 <0
5. They form minimum 5. They form maximum
boiling azeotrops. boiling azeotrops.
(Any three, 1 mark each)
27. For a first order reaction:
2.303 [𝑅]
𝑡 = 𝑙𝑜𝑔
𝑘 [𝑅]
(½ mark) 3
Using this we get:
2.303 100
𝑡 = 𝑙𝑜𝑔
𝑘 1
5
Chemistry Code: B
(½ mark)
2.303 × 2
𝑡 =
𝑘
(½ mark)
Also
2.303 100
𝑡 = 𝑙𝑜𝑔
𝑘 10
(½ mark)
2.303
𝑡 =
𝑘
(½ mark)
. ×
Now .
𝑡
=2
𝑡
(½ mark)
Or
Consider the reaction, R  P is zero order reaction.
𝑑[𝑅]
𝑅𝑎𝑡𝑒 = − = 𝑘[𝑅]
𝑑𝑡
(½ mark)
𝑑[𝑅]
⇒ 𝑅𝑎𝑡𝑒 = − =𝑘
𝑑𝑡
⇒ 𝑑[𝑅] = −𝑘𝑑𝑡
Integrating both sides
6
Chemistry Code: B
[𝑅] = −𝑘𝑡 + 𝐼 ………Eq. 1

Where I is the constant of integration
(½ mark)
At t = 0, the concentration of the reactant R = [R]0 ,
where [R]0 is initial concentration of the reactant.
(½ mark)
Substituting in above equation 1
[𝑅] = −𝑘 × 0 + 𝐼
[𝑅] = 𝐼
(½ mark)
Substituting the value of I in the equation 1
[𝑅] = −𝑘𝑡 + [𝑅]
(½ mark)
[𝑅] − [𝑅]
⇒ 𝑘=
𝑡
This is the integrated rate equation for a zero-order
reaction.
(½ mark)
28. i) ability to adopt multiple oxidation states
ii) ability to form complexes.
iii) transition metals utilise outer d and s electrons for
bonding. This has the effect of increasing the
3
concentration of the reactants at the catalyst surface
and also weakening of the bonds in the reacting
molecules.
(1 mark each)
7
Chemistry Code: B
29. i) Freon-12 is used for aerosol propellants,

refrigeration and air conditioning purposes.
ii) Carbon tetrachloride is used in the synthesis
of chlorofluorocarbons and other chemicals,
3
pharmaceutical manufacturing, and general
solvent use.
iii) Iodoform can be used as antiseptic.
(1 mark each)
30. i)
A: CH3CH2CN
B: CH3CH2CH2NH2
C: CH3CH2CH2OH
(½ mark each)
ii)
A: C6H5NH2
B: C6H5N+2Cl-
3
C: C6H5OH
(½ mark each)
Or
i) Ethylamine is capable of forming hydrogen bonds
with water as it is soluble but in aniline the bulk
carbon prevents the formation of effective hydrogen
bonding and is not soluble.
(1 mark)
8
Chemistry Code: B
ii) A Friedel-Crafts reaction is carried out in the

presence of AlCl3. But AlCl3 is acidic in nature, while
aniline is a strong base. Thus, aniline reacts with
AlCl3 to form a salt and benzene ring is deactivated.
Hence, aniline does not undergo the Friedel-Crafts
reaction.
(1 mark)
iii) Gabriel phthalimide reaction gives pure primary
amines without any contamination of secondary and
tertiary amines. Therefore, it is preferred for
synthesising primary amines.
(1mark)
31. i) ether or C2H5OC2H5
(1 mark)
ii) 2
(1 mark)
or
Ethanoic acid 4
(1 mark)
iii) C2H5OH
(1 mark)
iv) CH3CH2I
(1 mark)
32. i) Deoxyribonucleic acid
(1 mark)
9
Chemistry Code: B
ii) Phosphodiester bond

(1 mark)
iii) ribosomal
(1 mark)
iv) 3
(1 mark)
or
4
(1 mark)
33. The reactions occurring in cells A, B and C
respectively are as following:
Zn2+ + 2e- Zn
Ag+ + e-  Ag
Cu2+ + 2e-  Cu
(½ mark)
In cell B:
108 g of Ag deposition requires charge = 96500 C
5
1 g of Ag deposition requires charge = 96500/108 C
1.45 g of Ag deposition requires charge =
𝐶 = 1296 C
× .
(½ mark)
⸪ Q= It
⸫ 1296 = 1.5t
⇒ t = 863 s
10
Chemistry Code: B
In cell A:
2 x 96500 C charge deposits Zn = 65 g
1 C charge deposits Zn = 𝑔
×
1296 C charge deposits Zn =

×
𝑔
×
(½ mark)
= 0.438 g
In cell C:
2 x 96500 C charge deposits Cu = 63.5 g
1 C charge deposits Cu =
.
𝑔
×
1296 C charge deposits Cu =

. ×
𝑔
×
(½ mark)
= 0.426 g
Or
Given
Length of cell (l) = 50 cm
Diameter of cell = 1 cm
Resistance (R) = 5.55 x 103 ohm
Concentration (c) = 0.05 mol L-1
So area of cell (A) = πr2 = 3.14 x 0.5 x 0.5 cm2

= 0.785 cm2
(½ mark)
11
Chemistry Code: B
Resistivity (ρ) =
. × × .
=
(½ mark)
= 87.135 ohm cm
Conductivity (κ) = = 𝑆 𝑐𝑚
.
(½ mark)
= 0.001148 𝑆 𝑐𝑚
Molar conductivity(Λm) =
× . ×
= .
𝑆 𝑐𝑚 𝑚𝑜𝑙
(½ mark)
= 229.6 𝑆 𝑐𝑚 𝑚𝑜𝑙
34. (a) Geometric isomerism:
This type of isomerism is common in heteroleptic

complexes. It arises due to the different possible
geometric arrangements of the ligands. For example:
(b) Optical isomerism:
This type of isomerism arises in chiral molecules.

Isomers are mirror images of each other and are non-
superimposable.
12
Chemistry Code: B
(c) Linkage isomerism: This type of isomerism is

found in complexes that contain ambidentate ligands.
For example:
[Co(NH3)5 (NO2)]Cl2 and [Co(NH3)5 (ONO)Cl2
Yellow form Red form
(d) Coordination isomerism:
This type of isomerism arises when the ligands are

interchanged between cationic and anionic entities of
different metal ions present in the complex.
[Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6]
(e) Ionization isomerism:
This type of isomerism arises when a counter ion

replaces a ligand within the coordination sphere. Thus,
complexes that have the same composition, but
furnish different ions when dissolved in water are
13
Chemistry Code: B
called ionization isomers. For e.g., Co(NH3)5SO4)Br

and Co(NH3)5Br]SO4.
(f) Solvate isomerism:
Solvate isomers differ by whether or not the solvent

molecule is directly bonded to the metal ion or
merely present as a free solvent molecule in the
crystal lattice.
[Cr[H2O)6]Cl3 (Violet) ,[Cr(H2O)5Cl]Cl2⋅H2O (Blue-

green) [Cr(H2O)5Cl2]Cl⋅2H2O (Dark green)
(Any five, 1 mark each)

Or
Name: Potassium hexacyanomanganate (II)
(1 mark)
oxidation state: +2
(1 mark)
electronic configuration: [Ar]3d5
(1 mark)
coordination number: 6
(1 mark)
magnetic moment of the complex:
𝜇= 𝑛(𝑛 + 2)
= 1(1 + 2)
= √3
= 1.73 BM
14
Chemistry Code: B

35. Organic compound A is an ester as on acid hydrolysis
it gives a mixture of an acid and an alcohol.
(½ mark)
Oxidation of alcohol (C) gives acid (B). Hence, the
number of carbon atoms in (B) and (C) are the same.
(½ mark)
Ester (compound A) has eight C atoms. Hence, both

carboxylic acid (B) and alcohol (C) must contain 4 C
atoms each.
(½ mark)
Dehydration of alcohol C gives but-1-ene. Hence, C
5
must be a straight chain alcohol, i.e butan-1-ol.
(½ mark)
Reactions:
𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝐻 +
.
⎯⎯⎯⎯⎯⎯⎯⎯⎯ 𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 + 𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝐻 𝑂𝐻
(1 mark)
𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝐻 𝑂𝐻 ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ 𝐶𝐻 𝐶𝐻 𝐶𝐻 = 𝐶𝐻
(1 mark)
/
𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝐻 𝑂𝐻 ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ 𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻
(1 mark)
Or
15
Chemistry Code: B
i)
(1 mark)
ii)
(1 mark)
iii)
(1 mark)
16
Chemistry Code: B
iv)
(1 mark)
v)
(1 mark)
17
Chemistry Code: B
BSEH MARKING SCHEME
CLASS- XII Chemistry (March-2024) Code: C

Q. Answers Marks
No.
1. b) K kg mol-1 1
2. b) increases 1
3. d) Nickel-Cadmium cell 1
4. a) Thorium 1
5. b) 2 1
6. d) All of the above 1
7. a) Etard reaction 1
8. b) Alkaline sodium potassium tartarate 1
9. c) Methylamine 1
10. a) C6H5SO2Cl 1
11. b) Lysine 1
12. b) Vitamin B2 1
13. b) Tyrosine 1
14. b) Secondary 1
15. c) A is true but R is false. 1
16. d) A is false but R is true. 1
1

19. The shielding effect of 5f orbitals is poorer than the 2
shielding effect of 4f orbitals.
(1 mark)
Due to this, the valence shell electrons of actinide
experience greater effective nuclear charge than that
experienced by lanthanides. Hence, actinoid
contraction is greater than lanthanoid contraction.
(1 mark)
20. An alloy is a homogeneous mixture of a metal with 2

other metal or non - metals.
(1 mark)
An important alloy containing some of the lanthanoid

metal is mischmetal.
(1 mark)
Or
Number of unpaired electrons in M2+ = 3
(½ mark)
𝜇= 𝑛(𝑛 + 2)
(½ mark)
= 3(3 + 2)
2
Chemistry Code: C
= √15
= 3.87 BM
21. Manganese (Z=25) shows maximum number of
oxidation states.
(1 mark)
This is because its electronic configuration is 3d54s2.
2
As 3d and 4s are close in energy, it has maximum
number of electrons to lose or share (as all the 3d
electrons are unpaired).
(1 mark)
22.
23. i) N,N-Dimethylmethanamine
(1 mark)
2
ii) N-Methylaniline
(1 mark)
24. 𝐶 𝐻 𝑁𝐻 + 𝐶 𝐻 𝐶𝑂𝐶𝑙 ⎯⎯⎯⎯⎯⎯⎯ 𝐶 𝐻 𝑁𝐻𝐶𝑂𝐶 𝐻 + 𝐻𝐶𝑙
(1 mark)
2
N Methylbenzamide
(1 mark)
3
Chemistry Code: C
25. hydrogen bonds, disulphide linkages, van der Waals

and electrostatic forces of attraction.
(½ mark each)
Or
Globular proteins Fibrous Proteins
1. In this chains of 1. In this polypeptide
2
polypeptides coil around chains run parallel and
to give a spherical fibre– like structure is
shape. formed.
2. These are usually 2. These are usually
soluble in water. insoluble in water.
(1 mark each)
26. The reactions occurring in cell is as following:
Ni2+ + 2e- Ni
(½ mark)
Given:
I = 5 A
T = 20 minutes = 1200 s
Q =It = 1200 x 5 C = 6000 C 3
(½ mark)
2 x 96500 C charge deposits Ni = 59 g
(½ mark)
1 C charge deposits Ni = 𝑔
×
6000 C charge deposits Ni =

×
𝑔
×
(½ mark)
4
Chemistry Code: C
= 1.83 g
27. Consider the reaction, R  P is first order reaction.
𝑑[𝑅]
𝑅𝑎𝑡𝑒 = − = 𝑘[𝑅]
𝑑𝑡
(½ mark)
𝑑[𝑅]
⇒ = −𝑘𝑑𝑡
[𝑅]
Integrating both sides
𝑙𝑛[𝑅] = −𝑘𝑡 + 𝐼 ………Eq. 1
Where I is the constant of integration
(½ mark)
At t = 0, the concentration of the reactant R = [R]0 ,
where [R]0 is the initial concentration of the reactant.
(½ mark)
3
Substituting in above equation 1
𝑙𝑛[𝑅] = −𝑘 × 0 + 𝐼
𝑙𝑛[𝑅] = 𝐼
(½ mark)
Substituting the value of 𝐼 in the equation 1
𝑙𝑛[𝑅] = −𝑘𝑡 + 𝑙𝑛[𝑅]
(½ mark)
1 [𝑅] 2.303 [𝑅]
⇒ 𝑘 = 𝑙𝑛 = 𝑙𝑜𝑔
𝑡 [𝑅] 𝑡 [𝑅]
This is the integrated rate equation for a zero-order

reaction.
(½ mark)
5
Chemistry Code: C
28. Given:
Order of reaction = 1
Time = 40 minutes
Let [R]o = 100
Then after 30% decomposition [R] = 70
(½ mark)
2.303 [𝑅]
⸪𝑘 = 𝑙𝑜𝑔
𝑡 [𝑅]
(½ mark)
2.303 100
⇒ 𝑘= 𝑙𝑜𝑔
40 70
⇒ 𝑘 = 0.0089 𝑚𝑖𝑛
(½ mark)
0.693 3
⸪𝑡 =
𝑘
(½ mark)
0.693
⇒ 𝑡 = 𝑚𝑖𝑛
0.0089
⇒ 𝑡 = 77.8 𝑚𝑖𝑛
Or
Given:
T1=293 K
T2=313 K
Let us take the value of K1=K
6
Chemistry Code: C
Now, K2=4K
Also, R=8.314JK−1mol−1
(½ mark)
Now, substituting these values in the Arrhenius

equation:
𝑙𝑜𝑔( )=
𝑘 2.303𝑅 𝑇 𝑇
(1 mark)
We get:
4𝑘 𝐸 313 − 293
𝑙𝑜𝑔( )=
𝑘 2.303 × 8.314 313 × 293
(½ mark)
∴Ea = 52863.3 J mol−1
=52.8 kJ mol−1
29. i) Di- tert -butyl ketone < Methyl tert -butyl ketone
< Acetone < Acetaldehyde
ii) (CH 3 ) 2 CHCOOH < CH 3 CH 2 CH 2 COOH <
CH 3 CH(Br)CH 2 COOH < CH 3 CH 2 CH(Br)COOH 3
iii) 4-Methoxybenzoic acid < Benzoic acid < 4-
Nitrobenzoic acid < 3,4-Dinitrobenzoic acid
(1 mark each)
7
Chemistry Code: C
30. Aldol condensation: Aldehydes and ketones having at

least one α-hydrogen undergo a reaction in the
presence of dilute alkali as catalyst to form β-hydroxy
aldehydes (aldol) or -hydroxy ketones (ketol),
respectively. This is known as Aldol reaction.
(1 mark)
The aldol and ketol readily lose water to give α,-
unsaturated carbonyl compounds which are aldol
condensation products, and the reaction is called Aldol
condensation.
(1 mark)
Example:
3
(1 mark)
Or
i) Tollen’s test / Fehling’s test;
(½ mark)
Propanal gives the test while propanone does not.
(½ mark)
Or
Iodoform test
(½ mark)
8
Chemistry Code: C
Propanal does not give the test while propanone

gives the test.
(½ mark)
ii) Sodium bicarbonate test;
(½ mark)
Benzoic acid gives the test while Ethyl benzoate does
not.
(½ mark)
iii) Tollen’s test;
(½ mark)
Benzaldehyde gives the test while acetophenone does
not
(½ mark)
Or
Iodoform test
(½ mark)
Acetophenone gives the test while Benzaldehyde does

not
(½ mark)
31. i) The process in which external source of voltage is
used to bring about a chemical reaction. 4
(1 mark)
9
Chemistry Code: C
ii) An electrochemical cell converts the chemical

energy of a spontaneous redox reaction into electrical
energy.
(1 mark)
or
By applying external voltage more than emf of
electrochemical cell.
(1 mark)
iii) Sodium metal and Cl2 gas.
(½ mark+ ½ mark)
iv) electrorefining of metals/ electroplating of metals/
extraction of metals like Na, Mg, Al
(Any one,1 mark)
32. i) [Co(NH3)6]3+
(1 mark)
ii) d2sp3
(1 mark)
iii) paramagnetic
(1 mark)
iv) Octahedral
(1 mark)
or
zero
(1 mark)
10
Chemistry Code: C
33.
(v)
(1 mark each)
Or
i) 𝐶𝐻 𝐶𝐻 𝑂𝐻 + 𝐻𝐶𝑙 ⎯⎯ 𝐶𝐻 𝐶𝐻 𝐶𝑙 ⎯⎯⎯⎯⎯⎯ 𝐶𝐻 𝐶𝐻 𝐹
(1 mark)
11
Chemistry Code: C
ii) 𝐶𝐻 𝐵𝑟 ⎯⎯ 𝐶𝐻 𝐶𝑁 ⎯⎯⎯⎯⎯⎯⎯ (𝐶𝐻 ) 𝐶 = 𝑁𝑀𝑔𝐵𝑟 ⎯⎯ 𝐶𝐻 𝐶𝑂𝐶𝐻
(1 mark)
iii)
.
𝐶𝐻 𝐶𝐻 𝐶𝐻 = 𝐶𝐻 ⎯⎯ 𝐶𝐻 𝐶𝐻 𝐶𝐻(𝐵𝑟)𝐶𝐻 ⎯⎯⎯⎯ 𝐶𝐻 𝐶𝐻 = 𝐶𝐻𝐶𝐻
(1 mark)
iv)
(1 mark)
v) 2𝐶𝐻 𝐶𝐻 𝐶𝑙 + 𝑁𝑎 ⎯⎯⎯⎯⎯⎯ 𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝐻
(1 mark)
34. i) Acidified K2Cr2O7 or acidified KMnO4
(1 mark)
ii) Pyridinium chlorochromate (PCC) or CrO3
(1 mark)
iii) bromine water
(1 mark) 5
iv) Acidified K2Cr2O7 or acidified KMnO4
(1 mark)
v) 85% phosphoric acid (H3PO4)
(1 mark)
Or
i) Kolbe’s reaction:
12
Chemistry Code: C
Phenoxide ion generated by treating phenol with

sodium hydroxide is even more reactive than phenol
towards electrophilic aromatic substitution.
(½ mark)
Hence, it undergoes electrophilic substitution with
carbon dioxide, a weak electrophile.
(½ mark)
Ortho hydroxybenzoic acid is formed as the main
reaction product.
(½ mark)
(1 mark)
ii) Reimer-Tiemann reaction:

On treating phenol with chloroform in the presence of
sodium hydroxide, a –CHO group is introduced at
ortho position of benzene ring.
(1 mark)
The intermediate substituted benzal chloride is
hydrolysed in the presence of alkali to produce
salicylaldehyde.
(½ mark)
13
Chemistry Code: C
(1 mark)
35. The properties which depend on the number of solute
particles irrespective of their nature relative to the
total number of particles present in the solution are
called colligative properties.
(1 mark)
Osmotic pressure is considered the best to determine
the molar mass of solute.
(1 mark)
i) The osmotic pressure method has the advantage
over other methods as pressure measurement is
around the room temperature and the molarity of the 5
solution is used instead of molality.
ii) As compared to other colligative properties, its
magnitude is large even for very dilute solutions.
iii) The technique of osmotic pressure for
determination of molar mass of solutes is particularly
useful for biomolecules as they are generally not
stable at higher temperatures and polymers have poor
solubility.
(1 mark each)
Or
14
Chemistry Code: C
Azeotropes are binary mixtures having the same

composition in liquid and vapour phase and boil at a
constant temperature.
(1 mark)
In such cases, it is not possible to separate the
components by fractional distillation.
(½ mark)
There are two types of azeotropes called minimum
boiling azeotrope and maximum boiling azeotrope.
(½ mark)
The solutions which show a large positive deviation
from Raoult’s law form minimum boiling azeotrope at
a specific composition.
(½ mark)
For example, ethanol-water mixture (obtained by
fermentation of sugars) on fractional distillation gives
a solution containing approximately 95% by volume
of ethanol.
(½ mark)
Once this composition, known as azeotrope
composition, has been achieved, the liquid and vapour
have the same composition, and no further separation
occurs.
(½ mark)
15
Chemistry Code: C
The solutions that show large negative deviation from

Raoult’s law form maximum boiling azeotrope at a
specific composition.
(½ mark)
Nitric acid and water is an example of this class of
azeotrope.
(½ mark)
This azeotrope has the approximate composition, 68%
nitric acid and 32% water by mass, with a boiling
point of 393.5 K.
(½ mark)
16
Chemistry Code: C
BSEH MARKING SCHEME
CLASS- XII Chemistry (March-2024) Code: D

Q. Answers Marks
No.
1. d) Benzene and Toluene 1
2. b) Gibbs energy 1
3. c) 0 1
4. c) MnO4- 1
5. c) Cr2+ 1
6. a) 0 1
7. b) Bromoform 1
8. a) tert-Butyl bromide 1
9. c) Both of the above 1
10. b) Conc. HNO3 1
11. c) Benzaldehyde 1
12. d) None of the above 1
13. c) Insulin and Glucagon 1
14. a) 0 1
explanation of A.
1

19. The partial pressure of the gas in vapour phase (p) 2
is proportional to the mole fraction of the gas (x) in
the solution.
(1 mark)
i) To increase the solubility of CO2 in soft drinks and
soda water, the bottle is sealed under high pressure.
ii) To avoid bends the tanks used by scuba divers
are filled with air diluted with helium.
iii) At high altitudes the partial pressure of oxygen is
less than that at the ground level. This leads to low
concentrations of oxygen in the blood and tissues of
people living at high altitudes or climbers.
Or
Given:
Mass of solute (w1) = 1 g
Mass of solvent (w2) = 50 g
Kf = 5.12 K kg mol-1
ΔTf = 0.40
×
⸪ ∆𝑇 = 𝐾 ×
×
(½ mark)
So 𝑀 = 𝐾 ×
×
∆ ×
2
Chemistry Code: D
1 × 1000
= 5.12 × 𝑔 𝑚𝑜𝑙
0.40 × 50
(½ mark)
= 256 𝑔 𝑚𝑜𝑙
20. The law states that limiting molar conductivity of an 2
electrolyte can be represented as the sum of the
individual contributions of the anion and cation of the
electrolyte.
(1 mark)
i) to calculate limiting molar conductivity of any

electrolyte.
ii) to calculate the degree of dissociation of weak

electrolyte.
iii) to calculate dissociation constant of weak

electrolyte.

21.
3
Chemistry Code: D
22. i)
2
(1 mark)
ii)
(1 mark)
23. i) In 2,2,6 trimethyl cyclohexanone, three methyl
groups are presents at α −position with respect to the
ketonic (>C=O) group. Therefore, these groups cause
steric hindrance during the nucleophilic attack of CN−
ion so cyanohydrin is not formed. Due to the absence
of methyl groups in cyclohexanone, there is no steric
hindrance and cyanohydrin is formed. 2
(1 mark)
ii) Semicarbazide has two amino (NH2) groups, out of
which one is involved in resonance. Electron-density
on this (NH2) decreases and it does not act as a
nucleophile. But the other (NH2) group (attached o
NH) has a lone pair of electrons which are not
4
Chemistry Code: D
involved in resonance. So, this pair is available for

the nucleophilic attack on the carbonyl group (>C=O)
of aldehydes and/or ketones.
(1 mark)
24. Aldehydes and having at least one α-hydrogen
undergo a reaction in the presence of dilute alkali as
catalyst to form β-hydroxy aldehydes, this is known
as Aldol.
(1 mark)
(1 mark)
2
Or
i) Tollen’s test / Fehling’s test;
(½ mark)
Ethanal gives the test while propanone does not.
(½ mark)
ii) Fehling’s test;
(½ mark)
Propanal gives the test while benzaldehyde does not.
(½ mark)
25. Quaternary structure of proteins: Some of the proteins
are composed of two or more polypeptide chains 2
referred to as sub-units. The spatial arrangement of
5
Chemistry Code: D
these subunits with respect to each other is known

as quaternary structure.
(1 mark)
Example: Haemoglobin
(½ mark)
which has four polypeptide chains around a haeme
group.
(½ mark)
26. Molar conductivity of a solution at a given
concentration is the conductance of volume V of a
solution containing one mole of electrolyte kept
between two electrodes with an area of cross-
section A and distance of unit length.
(1 mark)
Molar conductivity increases with a decrease in
concentration. This is because the total volume V of 3
the solution containing mole of the electrolyte
increases on dilution.
(½ mark)
For weak electrolytes, molar conductivity increases
steeply on dilution, especially near lower
concentrations as shown in graph.
(½ mark)
6
Chemistry Code: D
(1 mark)
Or
7
Chemistry Code: D
(1½ mark for proper diagram, ½ mark for each of 3

labeling)
27. Given:
𝐸° = 0.236 𝑉
Number of electrons involved in cell reaction (n) = 2
(½ mark)
∆𝐺 ° = −𝑛𝐹𝐸 °
(½ mark)
∆𝐺 ° = −2 × 96500 × 0.236
3
∆𝐺 ° = −45548 𝐽 𝑚𝑜𝑙
𝑛 × 𝐸°
𝑙𝑜𝑔 𝐾 =
0.059
(½ mark)
𝐾 = 10
(½ mark)
28. i) Diamminechloridonitrito-N-platinum (II)
ii) Potassium trioxalatochromate (III)
3
iii) Pentaamminecarbonatocobalt (III) chloride
(1 mark each)
29.
(1 mark)
8
Chemistry Code: D
(1 mark)
(1 mark)
Or
Lucas test can be used to distinguish between
primary, secondary and tertiary alcohols.
(½ mark)
For this Lucas reagent (conc. HCl and ZnCl2) is used.
(½ mark)
Alcohols are soluble in Lucas reagent while their
halides are immiscible and produce turbidity in
solution.
(½ mark)
In case of tertiary alcohols, turbidity is produced
immediately as they form the halides easily.
(½ mark)
Secondary alcohols produce turbidity after some time.
(½ mark)
Primary alcohols do not produce turbidity at room
temperature.
(½ mark)
9
Chemistry Code: D
30. i)
(1 mark)
ii)
(1 mark)
iii)
(1 mark)
31. i) if a pressure larger than the osmotic pressure is
applied to the solution side, the pure solvent flows
out of the solution through the semi permeable
membrane. This phenomenon is called reverse
osmosis. 4
(1 mark)
ii) Red blood corpuscles will swell up
(1 mark)
or
10
Chemistry Code: D
Two solutions having the same osmotic pressure at

a given temperature are called isotonic solutions.
(1 mark)
iii) The preservation of meat by salting or the
preservation of fruits by adding sugar
(any one, 1 mark)
iv) 1 M KCl
(1 mark)
32. i) Position isomerism
(1 mark)
ii) 2,5-Dimethylhexane
(1 mark)
iii) (CH3)2C=CH2
(1 mark)
iv) (CH3)2C=CH2 + HBr ⎯⎯⎯⎯⎯ (CH3)2CHCH2Br

(1 mark)
or
Wurtz reaction
(1 mark)
33. Given:
𝑡 ⁄ = 28.1 𝑦𝑒𝑎𝑟𝑠
[𝑅] = 1 𝜇𝑔
5
0.693
∵𝑘=
𝑡⁄
(½ mark)
11
Chemistry Code: D
0.693
⟹ 𝑘= = 0.0247 𝑦𝑒𝑎𝑟𝑠−1
28.1
(½ mark)
For Case I
t = 10 years
[R] = ?
2.303 [𝑅]
𝑘= 𝑙𝑜𝑔
𝑡 [𝑅]
[𝑅] 𝑘𝑡
⟹ 𝑙𝑜𝑔 =
[𝑅] 2.303
(½ mark)
1 0.0247 × 10
⟹ 𝑙𝑜𝑔 =
[𝑅] 2.303
1 0.0247 × 10
⟹ = 𝐴𝑛𝑡𝑖𝑙𝑜𝑔
[𝑅] 2.303
(½ mark)
⟹ [𝑅] = 0.78 𝜇𝑔
(1 mark each)
For Case II
t = 60 years
[R] = ?
2.303 [𝑅]
𝑘= 𝑙𝑜𝑔
𝑡 [𝑅]
12
Chemistry Code: D
[𝑅] 𝑘𝑡
⟹ 𝑙𝑜𝑔 =
[𝑅] 2.303
(½ mark)
1 0.0247 × 60
⟹ 𝑙𝑜𝑔 =
[𝑅] 2.303
1 0.0247 × 60
⟹ = 𝐴𝑛𝑡𝑖𝑙𝑜𝑔
[𝑅] 2.303
(½ mark)
⟹ [𝑅] = 0.227 𝜇𝑔
Or
Given for same time period:
T1 = 298 K, reaction completed is 10 %
T2 = 308 K, reaction completed is 25 %
A = 4 × 1010s–1
For a first order reaction:
2.303 100
𝑘 = 𝑙𝑜𝑔
𝑡 90
0.1055
⇒𝑘 =
𝑡
(½ mark)
And
2.303 100
𝑘 = 𝑙𝑜𝑔
𝑡 75
13
Chemistry Code: D
0.2879
⇒𝑘 =
𝑡
(½ mark)
According to Arrhenius equation:
𝑙𝑜𝑔 =
𝑘 2.303 × 𝑅 𝑇 × 𝑇
(½ mark)
0.2879
𝑡 𝐸 308 − 298
⇒ 𝑙𝑜𝑔 =
0.1055 2.303 × 8.314 298 × 308
𝑡
(½ mark)
⇒ 𝐸 = 76622.7 𝐽 𝑚𝑜𝑙
For k at 318 K:
According to Arrhenius equation
𝐸
log 𝑘 = log 𝐴 −
2.303 × 𝑅𝑇
(½ mark)
76622.7
⇒ log 𝑘 = log(4 × 10 ) −
2.303 × 8.314 × 318
⇒ 𝑘 = antilog (− 1.9822)
(½ mark)
⇒ 𝑘 = 1.042 × 10 𝑠
14
Chemistry Code: D
34. The elements of the first series of the inner transition

metals; 4f (Ce to Lu) are known as lanthanoids.
(1 mark)
General electronic configuration for lanthanoids is:

(n−2)f1−14(n−1)d0−1ns2 where n = 6.
(1 mark)
The steady decrease in the atomic and ionic radii of
lanthanide elements with increasing atomic number
is called Lanthanide contraction.
(1 mark)
Consequences:
i) The size of the atom of the third transition series 5
is closely the same as that of the atom of the second
transition series.
(1 mark)
ii) As there is only a minute change in the ionic radii
of lanthanides, their chemical properties are the same.
This makes the separation very difficult.
(1 mark)
Or
Potassium permanganate is prepared by fusion of
MnO2 with an alkali metal hydroxide and an oxidising
agent like KNO3.
(½ mark)
15
Chemistry Code: D
2MnO2 + 4KOH + O2  2K2MnO4 + 2H2O

(½ mark)
This produces the dark green K2MnO4 which
disproportionate in a neutral or acidic solution to give
permanganate.
(½ mark)
3MnO42- + 4H+ 2MnO4- + MnO2 + 2H2O
(½ mark)
a)
(1 mark)
b)
(1 mark)
c)
(1 mark)
35. It is given that compound ‘C’ having the molecular
formula, C6H7N is formed by heating compound ‘B’
with Br2 and KOH. This is a Hoffmann bromamide
degradation reaction. Therefore, compound ‘B’ is an 5
amide and compound ‘C’ is an amine.
(½ mark)
16
Chemistry Code: D
Compound A is Benzoic acid.

(½ mark)
(1 mark)
Compound B is Benzamide.
(½ mark)
(1 mark)
Compound C is Aniline.
(½ mark)
(1 mark)
Or
i) C6H6
(1 mark)
17
Chemistry Code: D
ii) C6H5NHCOCH3
(1 mark)
iii) C6H5SO2NHCH3
(1 mark)
iv) C6H5NC
(1 mark)
v) C6H5N+H3HSO-4
(1 mark)
18
Chemistry Code: D

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BSEH Practice Paper (March 2024)

CLASS: 12th (Sr. Secondary) Code: A

[Hindi and English Medium]

[Time allowed: 3 hours] [Maximum Marks: 70]

 अपनी उ र पुि तका म खाल प ना/प ने न छोड़।

(i) सभी न अ नवाय ह।

(iii) येक न के अंक उसके सामने दशाए गए ह।

(i) All questions are compulsory.

(ii) Write the correct option in objective type questions.

(iii) Marks of each question are indicated against it.

1. Which of the following is an example of solid solution? 1

आर नअस समीकरण म A वारा या दशाया गया है?

न न ल खत म से कौन प रवतनीय ऑ सीकरण अव था द शत नह ं

न न ल खत म से कौनसा कोबा ट का एक उपसहसंयोजन यौ गक है ?

फं केल टाइन क त या म कस अ भकमक का उपयोग कया जाता

10. Which of the following has the lowest boiling point? 1

सनेमैि डहाइड का आईयप

a) 2-हाइ ॉ सीबे जैि डहाइड

ोपेन-1-ऐमीन और ोपेन-2-ऐमीन के बीच समावयवता का कार या है ?

न न ल खत म से कौनसा डाइसैकेराइड नह ं है?

Assertion (A): Study of actinoids is difficult than the study of

Reason (R): Actinoids are radioactive elements.

a) Both A and R are true, and R is the correct explanation

न न ल खत न म दो कथन है: अ भकथन (A) और कारण (R), न

अ भकथन (A): ऐि टनॉयड का अ ययन लथेनॉयड के अ ययन से मुि कल

कारण (R): ऐि टनॉयड रे डयोधम त व ह।

a) A व R दोन स य ह तथा R, A क सह याखया है ।

Assertion (A): Thiocyanate ligand can cause linkage

Reason (R): Ambidentate ligands results in linkage isomerism

a) Both A and R are true, and R is the correct explanation

न न ल खत न म दो कथन है: अ भकथन (A) और कारण (R), न

अ भकथन (A): थायोसायनेट लग ड बंधनी समावयवता का कारण बन

कारण (R): उभयदं ती सलं नी यु त उपसहसंयोजन यौ गक म बंधनी

a) A व R दोन स य ह तथा R, A क सह याखया है ।

Assertion (A): Alcohols are readily soluble in water.

Reason (R): Alcohols form hydrogen bonding with water.

a) Both A and R are true, and R is the correct explanation

न न ल खत न म दो कथन है: अ भकथन (A) और कारण (R), न

अ भकथन (A): ऐ कोहॉल जल म आसानी से घल

कारण (R): ऐ कोहॉल पानी के साथ हाइ ोजन संबंध बनाते ह।

a) A व R दोन स य ह तथा R, A क सह याखया है ।

Assertion (A): When nucleotide is linked to phosphoric acid,

Reason (R): Nucleotides are joined together by phosphodiester

a) Both A and R are true, and R is the correct explanation

न न ल खत न म दो कथन है: अ भकथन (A) और कारण (R), न

अ भकथन (A): जब यूि लओटाइड फ़ॉ फ़ो रक अ ल से जुड़ता है , तो हम

कारण (R): यिू लओटाइड फ़ॉस ्फ़ोडाइए टर आबंध वारा एक दस

a) A व R दोन स य ह तथा R, A क सह याखया है ।

Calculate the amount of benzoic acid (C6H5COOH) required

नाइ ोमेथेन को डाइमे थलऐ मन म

30. Describe a method for the identification of primary, secondary

on treatment with CO2 and NaOH at 400 K under pressure

ऐमीनो (-NH2) और काब ि स लक (-COOH) काया मक समूह होते ह।

नेन ट समीकरण ल खए और 298 K पर सेल;

Explain on the basis of valence bond theory that [Ni(CN)4]2–

संयोजकता आब ध स धांत के आधार पर समझाइए क वग समतल य

35. Write structural formulas and names of four possible aldol

Draw the structures of following compounds: 5

न न ल खत यौ गक क सरं चना बनाइये:

CLASS: 12th (Sr. Secondary) Code: B

[Hindi and English Medium]

[Time allowed: 3 hours] [Maximum Marks: 70]

 अपनी उ र पुि तका म खाल प ना/प ने न छोड़।

(i) सभी न अ नवाय ह।