NZ) ea | Chapter 4 Chemical Bonding and Molecular Structure SECTION - A 4. Answer (4) ca Sor NHI NaNo, covalent NH. CF tone Na’ NO NH, —goi} Corda Te ee | o —HCovalent NS o ‘° on o~ Co-ordinate covalent A nave ionic, covalent and co-ordinate covalent bond 2. Answer (2) Full filed and haf filed have maximum covalent character -. ZnCl, have 3d" configuration have maximum polarising power. 3. Answer (1) Etec charge ° P to Noe 5 (07 | So = 32125 & 4. Answer (1) ionic = HOPS = ___1.8x10"Posurem __ 554, weal” 700%40-* x48. 10" Pesucom 5. Answer (1) cl dipole moment of 1, 3, 5 chlorine wil be cancelled due to symmetry dipole moment exist only due to cr C-2.i8.1.1D Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-4762345646 Chemical Bonding and Molecular Structure Solutions of Assignment (Level-|!), 6. Answer (3) Electronegativity 7. Answer (4) H,0, have open book structure Non-polar covalent bond because atoms of same electronegativly are present Polar covalent bond because different electronegativity atoms are present 8. Answer (4) H / ° o Ht 9, Answer (4) Xe0,F, PCI, Hybridisation = 3iv-+M—C+ Al H=divem—o+al H=1ie+2-0+01 H=4i5+5-o+01 2 7 2 7 10 3 10g taps spd 105 top 7 See-saw shape TTigonal bipyramidal 10. Answer (2) x x] x + x, X-M-X siz NS 14. Answer (3) ch, —c~ a, ib 109.28" wil bein cy Gy Lo: Total af \ otal e1— CO — Oy o wci—c— Cl wi—c— cy wich 4. Answer (2) sp sp" sp CH—=CH—CH, sp. Sp Ps sp sp | Total 8‘C’ are present and have sp’ hybridisation 16. Answer (1) Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-4762345648 Chemical Bonding and Molecular Structure Solutions of Assignment (Level) 47. Answer (1) Hybridisation NO, = sp” H.0"= sp © iss Structure Il TH Pyramidal AS H ° o Different hydridisation and different structural arrangement 48. Answer (4) ‘AB, molecule geometry also depends upon the no. of lone pair always AB, will not have square pyramid structure ‘AB, = trigonal bipyramid, or square pyramid 19, Answer (1) 20. Answer (2) oT tN | xem ‘8 21. Answer (2) No. of bonding ~ No. of antibonding 2 8-2 Bond order Bond order of N, =3 22, Answer (3) NO=15= ots, os, 02%, o°28°, 02p,, o2p,?= n2p,2, n2p,! NO*= 14 = ots? a"ts?, o2s%, o°2s%, o2p,2, a2p,2= n2p,2, n2p,2, x'2pe 6 = otst, o'te?, 028%, 02st, o2p2, n2p,2= n2p,2, x2p,° CO = 14 = ost, o°ts?, o2s%, n'2p,2 = x2p,2, 0292, o*2ps? 3.0 INO 28 No’ 3 co 3 23, Angwer (2) O,-=17= ots? oMts?, 028%, o°2s?, o2p2, 12p,2= n2p,2, 12p,2 = x°2p," Number of antibonding electron pairs aro 3. Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456Solutions of Assignment (Level: 24, Answer (1) 25, 26. . ¢ Each oxygen atom will form 4 bonds ie. Intermolecular H-bonding Intramolecular (stronger bonding) H-bonding wo as itis within two (weaker bonding) 1, molecules asitisinthesame — o- molecule. N 2 em ~o c-nitrophenol will easily evaporated compared to p-nitrophenol Answer (4) Hy = ats! = 018'..n2p) = n2p,', 2°2p, = n*2p,! { | ‘unpaired electron 1 unpaired electron in 2*2p, inots SECTION - B Answer (3) (NH, N () OF, or H "gona pyramidal ag Ve Pol: CI=P: (a) BF, © A ® a “Togonal pyramidal Savare pyramidal (ae(ii), (b)-Civ), (c(i), (ACH) Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 Chemical Bonding and Molecular Structure50 Chemical Bonding and Molecular Structure Solutions of Assignment (Level) 2. Answer (2) CO, => sp? hybridisation, bond angle = 180° NH; — 5p hybridisation, bond angle = 109° 28° NH, = sp® hybridisation with one lone pair on central atom, bond angle = 107° H,0 = sp? hybridisation with two lone pairs on central atom, bond angle = 104.5° 3. Anon) i ee sry ost tone par ORE i XeF, > sp'd+ Sone pair F—Xe—F ’ oO CIF, > sp'd+2 lone pair IF, > sp'd +t lone pair | SF FE XeF; having maximum fone pairs, so, ithas maximum ‘lone pair-ione pair electron repulsions. 4. Answer 2) nop? n*2p), atstottstoas’o*2stozp? || 2p; 2p, Dus to one unpaired electron in "2p molecular orbital, 0; is a paramagnetic ion. 5. Answer (4) F i BL F Hybridization of B is sp’. ‘Shape is trigonal planar, 6. Answer (2) Fe ¢ Number of electrons around boron atom is 6. a cl @ on ‘pd hybridised and trigonal bipyramidal in. shape [Na a Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456Solutions of Assignment (Level: Chemical Bonding and Molecular Structure 51 : ALF (b) / Sv sp*d hybridised and octahedral in shape [NF t NO (c) Br, sp*é? hybridised and square pyramidal in shape “IN F F @ Fa polarmolecule oO. . “POC -fKg) = polar molecule a ° “CHO: 4 -C\,, = polarmolecule, 8. Answer (3) 9. Answer (4) For He, molecule Electronic configuration is o1s%, o*1s? 1 0 bond order= “IN, —Nq] 1 = 5R-4 =0 Since, bond order is zero, so He, molecule does not exist. Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-4762345652 Chemical Bonding and Molecular Structure Solutions of Assignment (Level) 10. Answer (2) e NH. TTrigonal pyramidal 8 WN a oni + Po, “gona bipyramidal * SF, Ss! Octahedral © BeCl, cl Be—cl Linear 11. Answer (2) * Potential energy of two H atoms at infinite distance = a + Potential energy of two H atoms at distance equal to bond length = b BE = (b - a) 12. Answer (3) Hybridisation [ Geometry Coordination number. sp Tetrahedral 4 dsp ‘Square planar 4 spd Trigonal bipyramidal 5 cPsp* Octahedral 6 43. Answer (1) ©, has 8 + 8 = 16 electrons, So distribution of electrons in MO(molecular orbitals) follows the order as (ots)? (o* 1s)” ,(028)* (0 *2s)* (02p,), (22p,)° (#'20,) (20, )" (n'2p, ) So, in 0, molecule, there are two (2) unpaired electrons, so, itis a "paramagnetic substance in nature. 14, Answer (3) Dipole moment of a molecule is the vector sum of dipoles of bonds. So based on molecular geometry of following molecules, i et x < ow <« gXe < EX OWS = Distorted octahedral (@) Xe0F, = Square pyramidal @) X00, oi =0 = Pyramidal o ° ‘Answer (2) The structure of CIF, is The number of lone pair of electrons on central Clis 2 Answer (3) Element (X) electronic configuration 182 2s? ap* So, valency of X will be 3. Valeney of Mg is 2 Formula of compound formed by Mg and X will be Mg,X; Answer (2) NO : (ats), (o°1s)?, (o28),(o"2s)?,(o2p,)?, (n2p,)? = (n2p,)?.(°2p,)" = (x°2p,)? 10-5 po = Si*-25 CN-: (ots), (0°18), (o2s),(0°2s), (n2p,)* = (n2p,). (020, Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 Chemical Bonding and Molecular Structure54 Chemical Bonding and Molecular Structure Solutions of Assignment (Level) 10-4 = ete, B0= 5 CN : (ots), (0°18, (o2s)/ (6°25), (n2p,)* = (n2p,,(02p,)" CNT : (ots), (oS, (025P.(0'2s), (n2p,)2 = (np, 8-4 “2 Hence, option(2) should be the right answer. 21. Answer (3) IBr;, XeF, BO ‘Total number of valence electrons are equal in both the species and both the species are linear also. 22, ‘Answer (4) ot a a” “cr 23. mover) CN“ and CO have bond order 3 each. (24. Answer (3) 25, Answer (3) ts te (Q=N=0]"; sp 26. Answer (1, 4) Option (1) Both have 32 electrons with trigonal planar structure. Option (4) Q WN 2) Both have 42 electrons with pyramidal structure 27. Answer (1) oF, has octahedral geometry where hybridisation of Xe is sp' Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456Solutions of Assignment (Level: Chemical Bonding and Molecular Structure 28. 29, 30. 31 32 33, 36. 36. 37. 38. 39. 40. a4 42, 43, 44, Answer (3) Shape of SeF,, would be see saw whereas that of CH, would be tetrahedral Answer (2) Fact ‘Answer (3) Molecules Bond angle cH, —> 1095" NH, —> 1075° HO —> 10445° ‘Answer (3) Stability « bond-order 0} > 0p > OF > OF Bond order: 25 20 16 10 ‘Answer (2) rae AY wer rah ‘Square planar Tetrahedral Answer (4) NO® have linear geometry ‘Answer (2) Answer (3) Answer (1) Answer (1) Answer (3) Answer (3) ‘Answer (3) Answer (2) 2 N =c= o% ~o o=Cc=0 Answer (1) H,0 have only sigma bond Answer (1) Answer (1) Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 5556 Chemical Bonding and Molecular Structure Solutions of Assignment (Level) 45. Answer (3) OF = 18= ats? o'ts%, 02s, a°2s%, a2p2, n2p,2= n2p,2, n2p,e= B, = 10 ots? atts?, 028%, 028%, n2p,"= n2p,! 0,* and B, have same bond order 46. Answer (4) 47. Answer 2) BFS NH," He dia44-o84l H= ts+4-140 Fi3v4-04 Use4-14 84 gp? 84 5p = 8a 4nyy Snag 2 i 2 i TTetrahedral shape Tetvahedral shape be Wy r\ WX F 4 [Both are having tetrahedral shape and same hybridisation} 48. Answer (1) Quetee ote ote—san! aa oe ‘int’ orbital OF =18= ats, o'ts%.....#2p = 2'2p2 49. Answer (4) 50. Answer (2) 1 Bond length = Bond order Bond order Oo 2 25) by molecular 1.5] orbital theory [0,* have minimum bond length] 51. Answer (2) 52, Answer (2) 53, Answer (2) Molecule having covalent bond. Without resonance have maximum stability; minimum energy 54, Answer (1) Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456Solutions of Assignment (Level: Chemical Bonding and Molecular Structure 56. 56. 87. 58. 59. 60, 6 62, 63, 65, 66 67 68. 68 70. m1 72. 73. 74. 75. 76. 7. 78. 79. Answer (2) For Be,, BO- Answer (2) Answer (3) Answer (2) Answer (1) Answer (4) Answer (1) Answer (3) Answer (3) For same cation larger anion more will be covalent character MI > MBr > MCI> MF Answer (1) Answer (1) , have angular shape have two « bond and 1 bond Answer (3) ‘Answer(1) ‘Answer (1) Answer (3) ‘Answer(1) ‘Answer (3) ‘Answer (2) gt “IS EY Answer (4) Answer (3) ‘Answer (3) Answer (3) Answer (3) Answer (2) or, CL-#—-F [3 bond pairs and 2 lone pairs) Answer (3) 0, = 15 = ots%, a'ts?, 028%, 02s", a2p2, n2p,?= 12p,?, n°2p," Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 5758 Chemical Bonding and Molecular Structure Solutions of Assignment (Level) 80. Answer (4) Hye a oH Ethene =" ScEGC Total no, of @ bond = 5 He] “4 bond =1 Bop 81. Answer (3) ©,%, 0,2, CO have even number of electron will be diamagnetic, NO, have unpaired electron will be paramagnetic. 82. Answer (1) 2 1 lz gi+5-0+0]==6 sp°d* Geometry = octahedral 1 2 83. Answer (3) 2 ol 1 a 1 8 NH, H= 4{5+3-0+0]===s H,0 H= 1i6+2-0+0]=5=5 Is giS+3-0+0]=5= sp 13 gi6+2-0+0]=5= sp INH, and H,0 have same hybridisation but have different shape.) 84. Answer (3) cH, GLAS by Hybridisation = spt op 85. Answer (1) 2s 3 =O forcs, “S=C=S _lineargeometry

CHSCH= CH, sp’ sp’ sp’ sp" 87. Answer (2) C=C have two 1 bond and one 6 bond, therefore will be more stronger. 88, Answer (2) contain both sp = sp" 84 sp? 1 [si(cHs), ] ql4+4-040] = Tetrahedral and sp" 89. Answer (3) N,=14= ots? o'ts2, 028%, 025%, n2p, 8 8 8 INo, of bonding pair = 5] 90. Answer (2) Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456Solutions of Assignment (Level: Chemical Bonding and Molecular Structure 59 a 92 93, 94, 95. 96. 97. 98. 99, Answer © 3/ a y Rs Polymeric due to H-bond \e/ 5/7 H Answer (1) Cation and anion form ionie bond in crystal. Answer (4) 1 Xe, gib+0-040) Bigg? $= 4 sp tetrahedral structure Answer (4) 1 (PCI H= 316+6-0+11= 2-6 spa? = 180" ‘As the bond angle is asked wc is maximum in PCI,- i.e. 180° between linear pair. Answer (1) 4 3 =H—-1Y Electron density on X will increase and on H will déerease. Answer (1) molecular orbital ©, ~ P, (Pe=P,) PROP, ‘Answer (2) CH, CH, [sp 1 H.C 6 —CH=cH—CH—C=cH 54 4 24 B b Answer (4) ‘Answer (2) H—c=c—H sp sp aaa Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456