NZ) ea | Chapter 2 Structure of Atom SECTION -A : : 2 vo Intensity of light a cis he Threshold frequency IKE of electron increases after crossing threshold frequency] 2. Answer (2) All the wavelength are in visible region ie., between 400 nm to 760 nm. Therefore, maximum wavelength line will be 656 nm, 3. Answer (1) KE Ero Total energy =-3.4 eV (Gen) 2 KE = 3.4 eV) = 43.4 eV 4. Answer (4) As 1* excited state means n, = 2 For 5" excited state means n, Electrons wil transit between 6" level to 2° level No transition will be upto 1st level. Because no line will appear in Lyman series /., UV region. Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-4762345666 Structure of Atom Solutions of Assignment (Levelt) 5. Answer (1) Tline in the Balmer series means n, = 2,n,= 3 6. Answer (2) (Egous =xeV (given) Ena In=3 ecouse (2 excted stat) be] ee For He®, Z = = 1096784 om 4 oae7axd ~ aae77g =22x10 om [22x10 m| 8. Answer (2) Third line means third excited state ion =2 Balmer series (visible region) n= Third line Third line will appear when electron comes from 5! energy level to 2% level 9. Answer (1) In H atom g, = 21312 = 21312 g, = 21912 g, = 21312 e, = 2322 12 4 9 25 36 (E, — E,) > (E, — E,) > (Ey — E,) [Alternatively as the distance from the nucleus increases the value of AE (energy difference between two shell) decreases] Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456Solutions of Assignment (Level) Structure of Atom 67 10. Answer (3) Largest amount of energy is required for the transition between 1 > =» 1 1 AE=he x7 he] | Lage the efarence betwee n, ann age wil be the valu of AE} 11, Answer (2) circumference _ 2nr_n® 16 Sroumference _ Zit _ 2 <1.5x10" seconds velocity v, Time period = Time period sn? 12, Answer (1) First time of Paschen series n, = 3, n, = 4 a ALR ye a, 144 IR Second line of Paschen series n, = 3, ny = 5 1_pft_4 tert ie 5 25! 16k 225 225 2 TER [> = 144 2304 _ 256] ie 7R 1675 175 2. as ny =n, are constants more the nuclear charge smaller will be the A. L?* have shorter wavelength 14, Answer (1) AP = 10° kgms~! axxap = 2 an 86x10 D5 210% m 1074x314 Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-4762345668 Structure of Atom Solutions of Assignment (Levelt) 15. Answer 2) bse ay (Gwen) a TF] ig DP ‘hp = 2hq x 10-%m hg 22x85 x 105 = 10% 10m 4 m= 100 om = 107 m= 10 om 16. Answer (@) In 3 means 4f| for | = 3, m = -3, -2, -1, 0, 1, 2, 3 = 7 orbital “Therefore, maximum 14 electons ae preset 17, Answer (1) 18. Answer (2) Energy of an electron depends upon (n + /) value. More the (n + value more wil bee energy no m s (or) ms 2 1 np 5 @4 2 4 np 6 Max (n +1). max. energy (3) 4 1 0 12 5 ws 0 0 “1p 5 19. Answer (3) Total number of electrons in X° [Number of electrons in X= 22+ 3= 25) Atomic number = 25 Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456Solutions of Assignment (Level) Structure of Atom 69) 20. Answer (3) ons having all the electron paired will be non-paramagnetic or diamagnetic Ne*? 8 18%, 282, 2p* aii [4 2 unpaired electrons 2p Be® 3 18%, 2s! 4 1 unpaired electron 25 Cr = 18 = 182, 25%, 2p8, 382, 3p? ss 0 unpaired electron 3p ‘As® 33 18%, 28, 2p°, 38%, 3p®, 4s%, 30, 4p? 411i 3 unpaired electrons 21. Answer (1) Isoelectronic species have same number of electrons (co=14e" NO®=14e"] CN = 146° Ci =14 6° | [Al have same numberof electrons) 22. Answer (2) (9. (9), and (9) are not posse (i) n=2 I not equal to n not possible @n=t s= 2 Not possible because m = ~1 where | = 0 w n=3 s= +12 Not possible because m = 3 is not for | = 2 23, Answer (3) ‘Any ofbital have maximum of two electrons with opposite spin 24. Answer (1) For | = 3, m= -3, -2, -1, 0, +1, +2, +3 ie., 7 ombitals are present 25. Answer (3) K = 19 = 18%, 282, 2p%, 35%, 3p%, 4s! last e~ Last electron 4st ened m=0 26. Answer (1) M shell means 3" orbit Mn ='25 = 18’, 25°, 2p', 9s’, 3p", 4s’, 3c total 13 e in 3 orbit 8 5 Co = 27 = 1s%, 25%, 2p%, 352, 3p8, 482, 347 total 15 e in 3 orbit Ni = 28 = 15?, 28%, 2p®, 35%, 3p%, 452, 3d® total 16 e in 3 orbit Fe = 26 = 1s%, 2s?, 2p8, 35%, 3p%, 482, 3d® total 14 e in 3 orbit Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-4762345670 Structure of Atom Solutions of Assignment (Levelt) 27. Answer (2) = 3 [Not possible because value of | can never be equals to n] 28, Answer (2) h Orbital angular momentum = i(I+4) For 4s electron, the value of |= 0 *, [orbital angular momentum = zero] 29. Answer (2) Radial nodes = (n - 1-1) for 3s, (3-0-1)=2; For 3p, (3- 30. Answer (3) Energy = (n +1) A=n=4 121 244125 B=n=4 |=0 =4+0=4 C=n=3) 1-2 =342=5 D=n=3) I=1 9 =341=4 ‘According to Pauli exclusion principle (1) Larger the (n + ); larger will be eneray (2) Same value of (n +1) ; smaller n ; more will be eneray 31. Answer (4) 32. Answer (2) Value of m = 0 for 3s, 2p, and 3d,» 33. Answer (3) Total number of electron in subshell = 2(21 + 1), | = angular quantum number 2241) _ Number of electrons having same spin = (a+) 2 [Because half e~ have clockwise and half ~ have anti clockwise spin] 34. Answer (4) For 2nd period electronic configuration = 2%, 2p If each orbital have 3e~ then electronic configuration = 2s°, 2p,°, 2p,2, 2p, Total 12 e° will present Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456Solutions of Assignment (Level) Structure of Atom 71 SECTION - B 4. Answer (2) + Inan atom, all the five 3d orbitals are equal in energy in free state i.e., degenerate, + The shape of d,z_2 Is different then shape of dz dey a, y x y x + The size of orbital depends on principal quantum number ‘n’ therefore all the five 3d orbitals are different in size when compared to the respective 4d orbitals, + Shape of orbitals depends on azimuthal quantum number ‘therefore shapes of 4d orbitals are similar to the respective 3d orbitals, 2. Answer (3) fy hae Z (Li) “a(He") LP") _@F 2 1058 3 “(@2F 3 = 105.85 (LP*) = 158.7 pm 3. Answer (1) 1 |_| | Subshell notation 2/0 25 2f4 2p 3 [0 35 3 [4 3p 3 [2 ad 4, Answer (1) he Energy of one photon = “= (a= 300m) he For one mole photons, = 5>xNy 6.626107 x3x10° x6,023x 102% 300x107 E = 3.99 x 10° J mol" E Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-4762345672 Structure of Atom Kinetic energy = 1.68 x 10° J mot~? W, = E- KE. 3,99 108 — 1.68 x 10° = 2.31 « 108 J mor* 5. Answer (2) Energy of electromagnetic radiation (E) _ 3x10 = 7368x10° 6, Answer (4) a =219.3m MEL Number of Protons = 71 = No. of Electrons jass no. ~ No. of Protons = 175-71 = 104 Number of Neutrons 7. Answer (2) © Number of radial nodes =n — Number of angular nodes For 3s orbital, = Number of radial nodes = 3 - 0 © Number of angular nodes = 0 8 Answer (4) Total number of nodes = (n - 1) 3=n-1 ne4 Number of angular nodes = /= 3 > Fsubshell Correct answer is 4f, 8, Answer (3) = ay? 1, = 52.9 * (2)? pm Solutions of Assignment (Levelt) Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456Solutions of Assignment (Level) Structure of Atom 73, 10. Answer (1) (n+l) values for, 4d=4+2=6 Sp=54+1=6 f= 5+3=8 6p=6+1=7 Correct order of energy would be 5f> 6p > Sp > 4d 11, Answer (2) In H-spectrum, Balmer series transitions fall in visible region. 12. Answer (4) According to Hund's Rule of maximum multiplicity, the correct electronic configuration of N-atom is ty (MILT t | t is’ 2s 2p n) MGW Option (4) violates Hunct's Rule. 13. Answer (4) Energy of 2s-orbital and 2p-orbital in case of hydrogen ike atoms is equal 14, Answer (1) ‘An orbital can accommodate maximum of 2 electrons with anti-parallel spins. 15. Answer (3) z y d, dap 16. Answer (1) Fact. 17. Answer (2) ‘Angular momentum = irae = TRS 18, Answer (1) Itrepresents 3p orbital Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-4762345674° Structure of Atom Solutions of Assignment (Levelt) 19. Answer (4) APE 8691 xO AOE 868 sgt yaa gory x 48x10" 15 20. Answer (2) 21. Answer (3) Value of m 22. Answer (2) E 4 represents one orbital. Therefore, maximum number of electrons will be two, 3.0%10"7 nms- 6x10" § h=S| v 4.10? nm 2 = 0.5% 10? nm = 50 nm 23. Answer (3) In (n= 1) 1% shell eis tightly held compared to 24, Answer (1) Rb = 37 = [Ar] 4s", 30, 4p* last 5s° e- (6" shell) n=65,1=0,m=0,s= a 2 25. Answer (3) n=4 represents 4f subshell having 7 orbitals ‘Total number of electrons = 14 26, Answer (1) Angular momentum = (1-4) 27. Answer (3) Number of orbitals = n*] n = number of orbit =4=16 28. Answer (3) Te] he y= Re) a, = BE - iE aE E,=50eV he ay = he 5 a fe 2 50 @) he B fe 50 f= Oy 29. Answer (2) Putting the value of n and calculating the (n + |) value Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456Solutions of Assignment (Level) Structure of Atom 75) 6s < 4 < Sd < 6p (6+0) (443) (5+2) (6+1) 6 7 7 7 (lower energy) > (high energy) 30. Answer (1) Because (E, ~E,) > (E, -E,) > (E,-E,) > (E,-E,)> (E,-£,) As the difference is of one energy levels, (E, -E,) have less energy (Alternatively value of AE [difference between two successive energy level decreases] as the distance from the ly ay nucleus increases.) 31. Answer (3) Lh _ 8.6x10kgm?s?-s mv 0.66 kgx100 mis 32. Answer (4) KE = Energy observed by molecule ~ Energy required to break one bond 0x10" my = 44x1079J-4.0 x 107% 2 KE 0.4x10-* \-19, Ke pratm =| 24250) foaxtos] 33. Answer (4) 34, Answer (2) n=3 Value of m (orbital) depends upon fi.e., it cannot be more than I’, Therefore is wrong. 35. Answer (3) 36, Answer (2) h Axx Ap = 3 37. Answer (2) 38. Answer (4) 39. Answer (1) laxscmav = | ay =—_h__ an| ’ Demxaxn . 66x10 J-s . OAT <9. 10 kg 4xa.14 = 5.788X10" mis 40. Answer (3) 41, Answer (4) Av 372| a | kd mol for hydrogen Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-4762345676 Structure of Atom 42, Answer (3) 44, 2 ho 66x10" ia SAmaV 4309,14x9, 1410 x APOE xt08 43. Answer) p= BSS 0.1764 naver Energy of electron when n= 1, y= 32 ‘aim Evo of aletonwhonn = 96, = 1 45, 46. 47. =2.0x10° 6631089148], a ‘Answer (4) Solutions of Assignment (Levelt) +1166 kJ/mol = 1166 x 10° J/mol = 1166 x 10" erg/mol 1936 * 10- erglatom Gd have exceptional configuration e* will enter in 5d because 4fhave 7 electrons and have haf filed stability [oa = Xe)™ 477 50°65" ‘Answer (1) Isoelectronic means same number of electrons CO = Number of electrons = 14 ON= 64741214 Ist excited state for H 0.53x(2)* eee =0.534=212A ‘Answer (4) roxn® I a lumber of orbit, Z = charge on nucleus Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456Solutions of Assignment (Level) 48. Answer (4) 49, 50. 51 52 53. 54, lax, AXeleceon = =——— ee AXetectron = AXHe = 1.0 nm h an Xie XAPhe a) aR, _ ho AAP cron 4RAP ig AXte [aPie = 8.0% 10% kg ms" ‘Answer (4) Fe = 26 = 1s, 2s”, 2p, 38%, 3p®, 4s, 3% Answer (2) Nv = 4 = 15%, 25? Fe® = 24 = 152, 252, 2p, 382, 3p8, 30% Zn® = 29 = 1°, 25°, 2p8, 35°, 3p8, 4s", 30 Cu® = 28 = 18%, 25%, 2p®, 3s, 3p%, 4s°, 30"? Answer (4) Number of elliptical orbit in shell = (n ~ 1) Answer (3) h Rasy m=tg=0.001kg, v= 100 mis _6.6x10*kg m*s? 0.001 Kgx100 mis bh =6.63x10- m| Answer (1) As the value of m= +2 ie., one value Therefore one orbital is represented. Answer (3) 2 ce 1| vo Seoxr| 5-4 x [ nm Zero unpaired Tt T1114 ‘One unpaired Zero unpaired Structure of Atom 7 Four unpaired Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-4762345678 Structure of Atom Solutions of Assignment (Levelt) 0 1 2 v=3.0x10 xr09079| 5 ahi y=3x—9 109678 em] 18 ]~3.09x10'8 40" 16 Alternatively E=E,-E, 218x107 =. -| E,=-2.18x10°* J 18x10" 2.1810" (ay 16 AE = E, -E,[-0.136—(-2.18)}«10-"* = 2.0410" E 0.13610" J he xe a) vee @) Put equation (1) in equation (2) v= 2xae SE he h y= 2.041077 66x10 55. Answer (1) = 0.309x10""8 = 3.0910 s* Electronic configuration [Ar] 3d° represents 24 electrons ie., [Co% =24 e] Ni = 28-3 = 256" Mn** Fe =26-3=23 6 56. Answer (4) Bohr's model explain the energy level ‘e., energy of electron in each orbital is quantized. 57. Answer (2) 58. Answer (3) e, aaa Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456