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SAFE HANDLING OF CHEMICALS (SHOC)

CARDS

SHOC NO: 001

HARPIC

COMPOSITION: Hydrochloric acid 5-10% APPEARANCE AND ODOUR: Blue colour liquid with a pungent
odour
Cationic surfactant >5%

Anionic surfactant 80%

USAGE: Cleansing agent/germicide. INCOMPATIBILITIES: Oxidizing materials.

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING


EXPOSURE AGENTS / FIRST AID

SAFETY:

FIRE: Flammable. No open flames, no smoking, Carbon dioxide, water, foam, dry
no sparks. chemical powder.

STABILITY: Stable.

HEALTH

INHALATION Prolonged inhalation may cause Breathing protector. Fresh air, obtain medical attention.
(BREATHING): dizziness.

SKIN: Redness, may be absorbed by the PVC gloves. Wash with soap and water, obtain
skin. medical attention.

EYES: May cause vision impairment. Mono-goggles. Flush with plenty of water, obtain
medical attention.

INGESTION Toxic. DO NOT INDUCE VOMITING,


(SWALLOWING): obtain medical attention.

ENVIRONMENT Toxic to aquatic life. Avoid gross contamination of


soil and water.

SPILLAGE MITIGATION: PACKAGING Plastic drums.


MATERIAL:

Absorb/prevent spreading with sand/earth or any other STORAGE: Keep in a cool and well ventilated area away
absorbent, collect into waste containers, do not flush away from heat.
remainder.

DISPOSAL OPTION: FLASH POINT:

Dilute with plenty of water. Dispose of at sea. AUTO IGNITION TEMPERATURE:

VERSION: 01 DATE OF ISSUE: Oct, 2014

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SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

SHOC NO: 002

LIQUID NITROGEN

COMPOSITION: Liquefied Nitrogen APPEARANCE AND ODOUR: Colourless, odourless liquid.

USAGE: Start-up of wells INCOMPATIBILITIES: None.

TYPES OF HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING


HAZARD/ AGENTS / FIRST AID
EXPOSURE

SAFETY:

FIRE: Non - flammable None Use extinguishing agent


appropriate to the surrounding
fire conditions.

STABILITY: Stable None

HEALTH

INHALATION Suffocation Face shield. Fresh air, artificial respiration of


(BREATHING): necessary.

SKIN: Frostbite, pain, blister, skin burns PVC gloves, coverall. Do not remove clothes; rinse
with plenty of water, obtain
medical attention.

EYES: Frostbite, pain, blurred vision. Face shield. Rinse with plenty of water,
obtain medical attention.

INGESTION/
SWALLOWING:

ENVIRONMENT Non toxic

SPILLAGE MITIGATION: PACKAGING Special insulated cylinder.


MATERIAL:

Ventilate wear self contained breathing apparatus. STORAGE: Store in a well ventilated area, away from heat.

DISPOSAL OPTION: FLASH POINT:

Allow to evaporate in a well ventilated area. AUTO IGNITION TEMPERATURE:

VERSION: 01 DATE OF ISSUE: Oct, 2014

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SHOC NO: 003


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

RAID
COMPOSITION: Pyrethrroids 0.415% Solvents, APPEARANCE AND ODOUR: Colourless spray with pungent odour
fragrance, propellant 99.585%

USAGE: Insecticides INCOMPATIBILITIES: Heat, Sparks and strong oxidants.

TYPES OFHAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING


EXPOSURE AGENTS / FIRST AID

SAFETY:

FIRE: Inflammable Avoid heat and spark Carbon dioxide, dry chemical powder,
foam.

STABILITY: Stable

HEALTH

INHALATION Sneezing Respirator Remove to fresh air


(BREATHING):

SKIN: Redness, pain Hand gloves and coverall. Wash with water and soap, obtain
medical attention.

EYES: Redness, blurred vision. Mono-goggles. Flush with water and obtain medical
attention.

INGESTION/ N/A N/A


SWALLOWING:

ENVIRONMENT No data.

SPILLAGE MITIGATION: PACKAGING Steel can.


MATERIAL:

N/A STORAGE: Store in cool and well ventilated area.

DISPOSAL OPTION: FLASH POINT:

Bleed off gradually AUTO IGNITION TEMPERATURE:

VERSION: 01 DATE OF ISSUE: Oct, 2014

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SHOC NO: 004

SHELL ROTELLA X OIL 40


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

COMPOSITION: Blend of highly refined mineral APPEARANCE AND ODOUR: Amber liquid at ambient temperature,
oils and additives. May contain odour characteristic of mineral oil
< 1% Calcium sulphonate

USAGE: High - speed diesel and gasoline INCOMPATIBILITIES: Strong oxidising agents, extremes of
engine oil temperature sunlight

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID:

SAFETY:

FIRE: Not classified as flammable, but No open flames, no sparks, Foam and dry chemical powder. Carbon
will burn. no smoking dioxide, sand or earth

STABILITY: Stable

HEALTH

INHALATION May form vapours /mists Breathing apparatus. Remove to fresh air. Obtain medical
(BREATHING): /fumes/dusts. May not be inhaled. attention if necessary

SKIN: Mild, short-lasting irritation. Impermeable gloves , boots, Wash with soap and water until
overalls adequately cleaned.

EYES: Mild, short-lasting irritation Chemical slash goggles Flush eyes with copious amounts of
water. Obtain medical attention

INGESTION/ Harmful/fatal in large doses. Do not eat while handling Do not induce vomiting. Wash out mouth
SWALLOWING: with water. Obtain medical attention

ENVIRONMENT May cause physical fouling. Avoid contamination of soil Not readily biodegradable
and water.

SPILLAGE MITIGATION: PACKAGING Steel drums


MATERIAL:

Contain with absorbent material, e.g. clay, soil. Shovel STORAGE: Store in a cool, dry, well ventilated area, away
reclaimed liquid & absorbent into clearly marked recovery from strong oxidants and.
drums for disposal.

DISPOSAL OPTION: FLASH POINT: > 240o C None

Recycle or landfill. AUTO IGNITION TEMPERATURE: N/A

VERSION: 01 DATE OF ISSUE: Oct, 2014

SHOC NO: 005

METHYLATED SPIRIT
SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

COMPOSITION: Ethyl alcohol - 80-90% APPEARANCE AND ODOUR: Light blue liquid with
methanol - 3%; characteristic odour.
aldehyde/ketones/esters - 2-7%.

USAGE: Clinical use. INCOMPATIBILITIES: Oxidants.

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS


EXPOSURE / FIRST AID

SAFETY:

FIRE: Highly flammable. No open flames, no sparks, Dry chemical powder, alcohol
no smoking. resistant foam, carbon dioxide.

STABILITY: Stable.

HEALTH

INHALATION Coughing, headache, dizziness, Organic vapour respirator Fresh air.


(BREATHING): dullness. (NPF-20).

SKIN: Redness. PVC gloves, coverall. Wash with soap and water.

EYES: Redness. Mono-goggles. Flush with water; obtain medical


attention, if irritation persists.

INGESTION/ Coughing, headache, dullness, DO NOT DELAY; obtain medical


SWALLOWING: abdominal spasm, diarrhoea. attention immediately. DO NOT
INDUCE VOMITING.

ENVIRONMENT Insignificantly toxic to aquatic life, Avoid gross contamination of


indirect hazard from oxygen soil and water.
depletion.

SPILLAGE MITIGATION: PACKAGING Metal container, glass bottle to be put in


MATERIAL: unbreakable container, keep closed.

Absorb/prevent spreading by using sand/earth; collect and STORAGE: Fire proof; separate from oxidants.
wash away remainder with plenty of water; if spilled into
surface water; dilute or re-aerate.

DISPOSAL OPTION: FLASH POINT: 12oC

Incinerate. AUTO IGNITION TEMPERATURE: 425oC

DENSITY: 0.8

VERSION: 01 DATE OF ISSUE: Oct, 2014

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SHOC NO: 006


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

ARGON
COMPOSITION: Argon. APPEARANCE AND ODOUR: Colourless, odourless compressed gas.

USAGE: Welding. INCOMPATIBILITIES:

TYPES OFHAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Non- combustible. Use extinguishing agent appropriate to


the surrounding fire conditions.

STABILITY: Stable.

HEALTH

INHALATION Headache, dizziness, shortness of Respirator Fresh air. Obtain medical attention
(BREATHING): breath and laboured breathing immediately

SKIN: At most minor discomfort. No specific measures.

EYES: At most minor discomfort. No specific measures.

INGESTION/ At most minor discomfort. No specific measures.


SWALLOWING:

ENVIRONMENT No data. Prevent contamination of


soil and water.

SPILLAGE MITIGATION: PACKAGING Plastic or plastic lined metal drums.


MATERIAL:
(Wear self contained breathing apparatus).

Ventilate. STORAGE: Cool place, ventilate.

DISPOSAL OPTION: FLASH POINT:

Bleed off cylinder in a well ventilated place. AUTO IGNITION TEMPERATURE:

VERSION: 01 DATE OF ISSUE: Oct, 2014

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SHOC NO: 007

CARBON DIOXIDE (COMPRESSED)


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

COMPOSITION: Carbon dioxide gas. APPEARANCE AND ODOUR: Colourless odourless gas.

USAGE: Laboratory use. Fire fighting. INCOMPATIBILITIES:

TYPES OFHAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Non-combustible. Use extinguishing agent appropriate to


the surrounding fire conditions.

STABILITY:

HEALTH

INHALATION Headache, dizziness, laboured Respirator. Fresh air, artificial respiration if


(BREATHING): breathing, unconsciousness. necessary, obtain medical attention.

SKIN: Redness, pain, blisters. Cold insulating gloves. Do not remove clothes, wash with plenty
of water, obtain medical attention.

EYES: Redness. Face shield. Flush with plenty of water and obtain
medical attention.

INGESTION At most minor discomfort. No specific measures.


(SWALLOWING):

ENVIRONMENT Non-toxic. Minimise contamination of


soil and water.

SPILLAGE MITIGATION: PACKAGING Cold insulating container.


MATERIAL:

Ventilate. STORAGE: Well ventilated area.

DISPOSAL OPTION: FLASH POINT:

Bleed off cylinder in a well ventilated area. AUTO IGNITION TEMPERATURE:

RE. VAPOUR DENSITY:

VERSION: 01 DATE OF ISSUE: Oct, 2014

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SHOC NO: 008


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

SODIUM CHLORIDE (SALT)


COMPOSITION: Sodium chloride (Nacl) APPEARANCE AND ODOUR: White free flowing crystals.

USAGE: Increase salinity of INCOMPATIBILITIES:


Drilling/workover fluids.

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Not combustible. Use extinguishing agent appropriate to


the surrounding fire condition.

STABILITY: Stable.

HEALTH

INHALATION Dust causes sneezing. Respirator for inert dust. Fresh air.
(BREATHING):

SKIN: At most minor discomfort. PVC gloves. No specific measures.

EYES: Redness, pain. Mono-goggles. Flush with water.

INGESTION/ Non-toxic, at most slight Observe personal hygiene. If ill health occurs, obtain medical
SWALLOWING: discomfort. attention.

ENVIRONMENT No data. Prevent contamination of


soil and water.

SPILLAGE MITIGATION: PACKAGING Polythene sacks


MATERIAL:

Scoop up and collect into container, do not wash away STORAGE: Keep dry.
remainder.

DISPOSAL OPTION: FLASH POINT:

Dissolve in plenty of water acid flush away with running AUTO IGNITION TEMPERATURE:
water.

VERSION: 01 DATE OF ISSUE: Oct, 2014

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SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

SHOC NO: 009

OMO DETERGENT
COMPOSITION: Detergent (Properitary) APPEARANCE AND ODOUR: Blue/ Powder

USAGE: Cleansing INCOMPATIBILITIES:

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Not combustible Use extinquishing agent appropriate to


the environment

STABILITY: Stable.

HEALTH

INHALATION NA No specific measure


(BREATHING):

SKIN: Peeling Wash with water.

EYES: Redness Handle carefully Wash with plenty of water.

INGESTION/ Discomfort Do not handle while eating Rinse mouth with plenty of water.
SWALLOWING:

ENVIRONMENT No data.

SPILLAGE MITIGATION: PACKAGING Cartons or sachets


MATERIAL:

Flush into the drain STORAGE: Store in cool, dry place .

DISPOSAL OPTION: FLASH POINT:

Flush into the drain AUTO IGNITION TEMPERATURE:

VERSION: 01 DATE OF ISSUE: Oct, 2014

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SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

SHOC NO: 010

PROPANE
COMPOSITION: Hydrocarbon. APPEARANCE AND ODOUR: Colourless Compressed Liquefied gas.

USAGE: Fuel, INCOMPATIBILITIES:

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Highly Combustible. No open flame, no sparks, Shut-off supply, extinguish using carbon
no smoking. dioxide, chemical powder.

STABILITY: Stable.

HEALTH

INHALATION Headache, dullness, shortness of Ventilation, Local exhaust Remove to fresh air and obtain medical
(BREATHING): breath, unconsciousness. or breathing protection. attention.

SKIN: In case of frostbite: redness, Cold-insulating gloves. In case of frostbite: DO NOT remove
pain, blister. clothes rinse skin with water and obtain
medical attention.

EYES: Redness, pain, blurred. Face shield Rinse with plenty of water, obtain
medical attention if necessary.

INGESTION/ Ensure personal hygiene Drink plenty of water. Obtain medical


SWALLOWING: while in use. attention immediately

ENVIRONMENT Greenhouse gas

SPILLAGE MITIGATION: PACKAGING Steel cylinder.


MATERIAL:

Never wet with water. Evacuation requires breathing STORAGE: Fireproof, cool, dry, well ventilated place.
apparatus.

DISPOSAL OPTION: FLASH POINT:

As in spillage mitigation above. AUTO IGNITION TEMPERATURE: 465oC

Rel. Vapour density: 1.6

VERSION: 01 DATE OF ISSUE: Oct, 2014

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SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

SHOC NO: 011

KEROSENE
COMPOSITION: Mixture of hydro-carbons. APPEARANCE AND ODOUR: Colourless liquid with characteristic
odour.

USAGE: Production chemical. INCOMPATIBILITIES: None.

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Flammable. No fires, no sparks, no Carbon dioxide, dry chemical powder,


smoking. foam

STABILITY: Stable.

HEALTH

INHALATION Headache. Ventilation or breathing Fresh air, rest, obtain medical attention.
(BREATHING): protection.

SKIN: Redness. Protective gloves, rubber Wash with plenty of water, obtain
boots. medical attention.

EYES: Redness, pain. Mono - goggles. Flush with plenty of water, obtain
medical attention.

INGESTION/ Abdominal pain, diarrhoea, Personal hygiene advised Drink plenty of water, do not induce
SWALLOWING: laboured breathing. vomiting, obtain medical attention.

ENVIRONMENT No data. Prevent contamination of


soil and water.

SPILLAGE MITIGATION: PACKAGING Steel drums/tanks


MATERIAL:

Absorb/ prevent spreading by using sand/ earth, collect STORAGE: Keep cool, fire proof.
and do not wash away remainder.

DISPOSAL OPTION: FLASH POINT: >39 ºC

Dispose in crude delivery facilities. AUTO IGNITION TEMPERATURE: 220-300 ºC

Incinerate. DENSITY: 0.8 -0.9

VERSION: 01 DATE OF ISSUE: Oct, 2014

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SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

SHOC NO: 012

NITROGEN (COMPRESSED)
COMPOSITION: Nitrogen gas. APPEARANCE AND ODOUR: Colourless, odourless gas.

USAGE: Well lifting, Dry blanketing. INCOMPATIBILITIES:

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Non flammable. Use extinguishing agent appropriate to


the surrounding fire condition.

STABILITY: Stable.

HEALTH

INHALATION Can lead to suffocation. Ventilation, breathing Fresh air, artificial respiration if
(BREATHING): protection. necessary.

SKIN: In case of frostbite; redness, Cold-insulating gloves, In case of frostbite; Do not remove
pain, blisters, skin burns. coveralls. clothes, rinse skin with plenty of water or
shower and obtain medical attention.

EYES: In case of frost bite; redness, Face shield, mono-goggles. Flush with plenty of water, obtain
pain, blurred vision. medical attention.

INGESTION/
SWALLOWING:

ENVIRONMENT Non-toxic. No specific measures.

SPILLAGE MITIGATION: PACKAGING


MATERIAL:

Ventilate. STORAGE: Store in a well ventilated area, away from heat.

DISPOSAL OPTION: FLASH POINT:

Bleed off cylinder in a well ventilated area. AUTO IGNITION TEMPERATURE: 0.97

DENSITY:

VERSION: 01 DATE OF ISSUE: Oct, 2014

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SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

SHOC NO: 013

DIESEL OIL
COMPOSITION: Mixture of hydrocarbons. APPEARANCE AND ODOUR: Colourless liquid with characteristic
odour.

USAGE: Fuel; drilling fluid additive. INCOMPATIBILITIES:

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING


EXPOSURE AGENTS / FIRST AID

SAFETY:

FIRE: Combustible. No open flames, no sparks Carbon dioxide, powder, foam.


and smoking.

STABILITY: Stable.

HEALTH

INHALATION Headache. Respirator, good ventilation. Fresh air.


(BREATHING):

SKIN: Degreases the skin. Protective gloves, rubber Wash with plenty of water and soap.
boots and coverall.

EYES: Pain. Mono-goggles. Flush with water, obtain medical


attention.

INGESTION/ Abdominal pain, nausea. Drink plenty of water, DO NOT


SWALLOWING: INDUCE VOMITING seek medical
attention immediately.

ENVIRONMENT Moderately toxic to aquatic life. Avoid gross contamination of


soil and water.

SPILLAGE MITIGATION: PACKAGING Bulk steel drums


MATERIAL:

Absorb/prevent spreading with sand/earth, collect and wash STORAGE: Keep cool, fire proof.
away remainder with plenty of water.

DISPOSAL OPTION: FLASH POINT: > 62 ºC

Incinerate AUTO IGNITION TEMPERATURE: 220-300 ºC

Dispose of in crude delivery facilities. DENSITY:

VERSION: 01 DATE OF ISSUE: Oct, 2014

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SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

SHOC NO: 014

DRY CHEMICAL POWDER


COMPOSITION: Sodium bicarbonate and APPEARANCE AND ODOUR: White powder and odourless
potassium bicarbonate

USAGE: Class A/B fire. INCOMPATIBILITIES: Strong acids.

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Non Flammable Use extinguishing media appropriate to


the surrounding fire conditions.

STABILITY: Stable.

HEALTH

INHALATION Irritation to upper respiratory NIOSH approved respirator. Remove to fresh air
(BREATHING): tract

SKIN: May cause irritation General purpose work Wash with soap and water.
gloves, apron.

EYES: Moderate irritation Goggles, face shield Flush eyes with plenty of water and
obtain medical attention if irritation
persists..

INGESTION/ Stomach upset Obtain medical attention.


SWALLOWING:

ENVIRONMENT No data. Avoid contamination of soil


and water.

SPILLAGE MITIGATION: PACKAGING


MATERIAL:

Scoop up and collect in container with broom or shovel, STORAGE: Store in sheltered area, or cover for moisture
do not disperse remainder. protection.

DISPOSAL OPTION: FLASH POINT:

Dispose in controlled landfill AUTO IGNITION TEMPERATURE:

VERSION: 01 DATE OF ISSUE: Oct, 2014

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SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

SHOC NO: 015

COMPRESSED OXYGEN
COMPOSITION: Oxygen. APPEARANCE AND ODOUR: Colourless, odourless gas.

USAGE: INCOMPATIBILITIES:

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING


EXPOSURE AGENTS / FIRST AID

SAFETY:

FIRE: Non-combustible. Use extinguishing agent appropriate


to the surrounding fire condition.

STABILITY: Stable.

HEALTH

INHALATION At most minor discomfort. No specific measures.


(BREATHING):

SKIN: At most minor discomfort. No specific measures.

EYES: At most minor discomfort. No specific measures.

INGESTION At most minor discomfort. No specific measures.


(SWALLOWING):

ENVIRONMENT Non - toxic

SPILLAGE MITIGATION: PACKAGING Cylinder with special fittings.


MATERIAL:

Ventilation. STORAGE: Ventilate.

DISPOSAL OPTION: FLASH POINT:

Bleed of cylinder in a well ventilated area. AUTO IGNITION TEMPERATURE:

VERSION: 01 DATE OF ISSUE: Oct, 2014

Page 15

SHOC NO: 016


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

CHLORINE
COMPOSITION: Chlorine. APPEARANCE AND ODOUR: Liquid (if compressed) or greenish
yellow gas with pungent/irritating
odour.

USAGE: Biocide (in water injection INCOMPATIBILITIES: Reducing agents, metals, rubber.
systems).

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Non-combustible. Use extinguishing agent appropriate to


the surrounding fire conditions.

STABILITY: Stable under normal Avoid mixtures with


conditions. hydrogen, acetylene,
ammonia.

HEALTH

INHALATION Pungent, coughing, laboured Self contained breathing Fresh air, obtain medical attention
(BREATHING): breathing. apparatus. immediately.

SKIN: Corrosive. PVC gloves DO NOT DELAY; wash with water


while removing clothing and obtain
medical attention immediately.

EYES: Corrosive. Mono-goggles DO NOT DELAY; Flush with water and


obtain medical attention immediately.

INGESTION/ At most minor discomfort. No specific measures.


SWALLOWING:

ENVIRONMENT Highly toxic to aquatic life. Prevent contamination of


soil and water.

SPILLAGE MITIGATION: PACKAGING Cylinders with special fittings.


MATERIAL:

For liquid: Absorb/prevent spill with sand/earth, collect STORAGE: Keep cool, ventilate along the floor.
and do not wash away remainder.

DISPOSAL OPTION: FLASH POINT:

Take to a safe open area and evaporate. AUTO IGNITION TEMPERATURE: 1.4
REL. DENSITY:

VERSION: 01 DATE OF ISSUE: Oct, 2016

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SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

SHOC NO: 017

SILICONE FLUID
COMPOSITION: Polymeric silicon oxides. APPEARANCE AND ODOUR: Colourless substance with vinegar-like
odour.

USAGE: Defoamer. INCOMPATIBILITIES:

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Non-combustible. Use extinguishing agents appropriate to


the surrounding fire condition.

STABILITY: Stable under normal


condition.

HEALTH

INHALATION Pungent sore throat, coughing. Fresh air, obtain medical attention.
(BREATHING):

SKIN: Redness, pain, skin burns. PVC gloves, apron and Remove contaminated clothes, rinse with
boots. plenty of water, obtain medical attention.

EYES: Redness, pain, blurred vision. Mono-goggles. Flush with plenty of water and obtain
medical attention.

INGESTION/ Abdominal pains, diarrhoea, Rinse mouth, give plenty of water to


SWALLOWING: nausea. drink, obtain medical attention.

ENVIRONMENT No data. Prevent contamination of


soil and water.

SPILLAGE MITIGATION: PACKAGING


MATERIAL:

Neutralise with moist sodium bicarbonate carbonate then STORAGE: Cool dry ventilation.
wash away with plenty of water.

DISPOSAL OPTION: FLASH POINT: 320 ºC

Incinerate. AUTO IGNITION TEMPERATURE:

Dispose of in a controlled landfill site.

VERSION: 01 DATE OF ISSUE: Oct, 2014

Page 17
SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

SHOC NO: 018

SULPHURIC ACID
COMPOSITION: 98% H2SO4 pure. APPEARANCE AND ODOUR: Colourless viscous liquid.

USAGE: Battery acid, Laboratory use. INCOMPATIBILITIES: Most metals alkalis, many organic
compounds.

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Non-combustible. Use extinguishing agent appropriate to


the surrounding fire conditions.

STABILITY: Stable.

HEALTH

INHALATION Pungent coughing, laboured Respirator/ ventilation. Fresh air, obtain medical attention.
(BREATHING): breathing, sore throat.

SKIN: Redness, pain. PVC gloves. DO NOT DELAY ; remove


contaminated clothes wash with plenty of
water and obtain medical attention.

EYES: Redness, pain. Mono-goggles. DO NOT DELAY; flush with plenty of


water and obtain medical attention
immediately.

INGESTION/ Abdominal pain, sore throat. DO NOT DELAY; rinse mouth, give
SWALLOWING: plenty of water to drink and obtain
medical attention immediately DO NOT
INDUCE VOMITING.

ENVIRONMENT Slightly toxic to aquatic life. Minimise contamination of


soil and water.

SPILLAGE MITIGATION: PACKAGING Unbreakable material.


MATERIAL:

Absorb/prevent spreading by using sand/earth, collect and STORAGE: Separate from all substances, keep dry.
wash away remainder with plenty of water.

DISPOSAL OPTION: FLASH POINT:

Small quantities may be washed down drain. Dispose of at AUTO IGNITION TEMPERATURE:
sea at controlled dosage.

VERSION: 01 DATE OF ISSUE: Oct, 2014

Page 18
SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

SHOC NO: 019

WITESOL (DEGREASER)
COMPOSITION: Amidophenolic Adduct APPEARANCE AND ODOUR: Lemon yellow with faint amine smell.

USAGE: Degreaser/Cleaner INCOMPATIBILITIES: Strong oxidizing agents

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Mildly flammable. Avoid sparks, open flames Dry chemical powder, foam, carbon
and smoking. dioxide and water mist.

STABILITY: Stable. Do not expose to heat.

HEALTH

INHALATION Excessive vapour Not normally required. Fresh air and rest. Give artificial
concentration can cause respiration or oxygen if there is difficulty
gastro-intestinal distress. in brea- thing, obtain medical attention.
(BREATHING):

SKIN: Irritation. Rubber hand gloves and Wash with plenty of water and soap.
protective clothing.

EYES: Severe eye irritation. Chemical splash goggles. Flush with water for at least 15mins.
Obtain medical attention.

INGESTION Sore throat, abdominal pain. Give two glasses of water and induce
(SWALLOWING): vomiting if conscious.

ENVIRONMENT

Biodegradable, non-toxic, No data. No data


non abrasive and non-ionic.

SPILLAGE MITIGATION: PACKAGING Steel drums.


MATERIAL:

Absorb/prevent spreading with sand/earth, contain spill STORAGE: Under ambient temperatures and well ventilated
and place waste material in suitable containers for area.
disposal.

DISPOSAL OPTION: FLASH POINT: > 200

Incinerate. Chemical landfill. AUTO IGNITION TEMPERATURE:

VERSION: 01 DATE OF ISSUE: Oct, 2014

Page 19
SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

SHOC NO: 020

JIK
COMPOSITION: Sodium hypochlorite APPEARANCE AND ODOUR: Colourless

USAGE: Bleaching agent INCOMPATIBILITIES: Strong oxidizers.

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Flammable. No open flames, sparks or Water, alcohol foam, carbon dioxide, dry
heat. chemical.

STABILITY: Stable.

HEALTH

INHALATION Mild irritation from prolonged Expose to fresh air and seek medical
(BREATHING): / repeated exposure. attention.

SKIN: Mild irritation from prolonged Gloves Wash with soap and water.
/ repeated exposure.

EYES: Pain, redness and discomfort. Chemical goggles. Flush with water and obtain medical
attention.

INGESTION/ Illness if swallowed in large Avoid eating while handling Induce vomiting after which milk should
SWALLOWING: quantities. be given and obtain medical attention.

ENVIRONMENT Toxic to aquatic life Prevent contamination of


soil and water.

SPILLAGE MITIGATION: PACKAGING Plastic container


MATERIAL:

Wash off splash immediately with water STORAGE: Store away from light

DISPOSAL OPTION: FLASH POINT:

Dispose off at controlled landfill. AUTO IGNITION TEMPERATURE:

DENSITY

VERSION: 01 DATE OF ISSUE: Oct, 2014

Page 20
SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

SHOC NO: 021

GREASE
COMPOSITION: Highly refined prtroleum oils- APPEARANCE AND ODOUR: Yellow – brown stiff paste
80%
Lithium 12 –Hydroxysterate in
compounds and additives

USAGE: Lubricant. INCOMPATIBILITIES: Strong oxidising agents

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING


EXPOSURE AGENTS / FIRST AID

SAFETY:

FIRE: Toxic fumes may be evolved on No open flames, sparks or ignition Carbon-dioxide, dry chemical
combustion. sources. powder, foam and water fog

STABILITY: Stable. None.

HEALTH

INHALATION At very high temperatures Not ordinarily required. Fresh air.


(BREATHING): vapours irritating to nose, throat
and upper reparatory tract.

SKIN: Prolonged exposure results in Rubber gloves. Wash with soap and water.
irritation and dermatitis

EYES: Redness and blurred vision. Safety mono-goggles. Flush with water, obtain medical
attention.

INGESTION/ Abdominal pain. Drink water, induce vomiting,


SWALLOWING: and obtain medical attention.

ENVIRONMENT Slightly toxic to mammals. Avoid gross contamination of soil


Biodegradable. and water.

SPILLAGE MITIGATION PACKAGING Plastic cups/steel drums


MATERIAL:

Scoop up and place in a container for spillage on water STORAGE: Cool, dry ventilated area.
remove by skimming/suitable absorbents.

DISPOSAL OPTION FLASH POINT: 221ºC

Dispose of at controlled landfill. AUTO IGNITION TEMPERATURE:


DENSITY:

VERSION: 01 DATE OF ISSUE: Oct, 2014

SHOC No: 022


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

HYDRAULIC OIL
COMPOSITION: Ether of ethyl, butyl,and propyl APPEARANCE AND Pale yellow liquid ether- like odour
ethelene glycol ODOUR:

USAGE: Mechanical transmission fluid INCOMPATIBILITIES: Oxidizing agent, fuming Nitric acid
strong bases, metallic powders,
carbides, hydrogen sulfide, carpentive
and combustible organics.
TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /
EXPOSURE FIRST AID
SAFETY:
FIRE: Flammable Avoid combustible organic Use extinguishing media suitable for
(charcoal, organic refuse) and surrounding fire
other sources of iginition

STABILITY: Stable under normal condition. Avoid Heat, light moisture -


and incompatible.

HEALTH
INHALATION At high temperature, inhalation Use NIOSH approved Remove to fresh air, Get medical
(BREATHING): of vapours causes mild burning respirator. attention.
sensation in the nose throat and
lungs
SKIN: Minor redness, pain, temporary Coveralls, gloves boot. Flush with water for at least 15 minutes,
burning sensation remove contaminated clothing Get
medical attention.

EYES: Irritation, pain, redness and Chemical safety goggles Flush Immediately, for at least 30
blurred vision minutes, get medical attention.

INGESTION Vomiting, Aspiration and Do not induce vomiting, keep Drink plenty or milk Get medical
(SWALLOWING): possibly death head below hip if vomiting attention.
occurs

ENVIRONMENT No information Avoid contamination of -


soil/water
SPILLAGE MITIGATION: Shut off source of leak if safe PACKAGING
to do so. Dike and contain spill. Soak up small spills with an MATERIAL: Metallic Drums
adsorbent such as clay sand

STORAGE: Keep out of heat , open flames and strong


oxidizing agents

DISPOSAL OPTION: User at the point of disposal FLASH POINT: 171 oC


determines if it fits into hazardous area classification or not.

VERSION: 01 DATE OF ISSUE: Oct, 2014

Page 22

SHOC NO: 023


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

LUBE OIL
COMPOSITION: Blend of fatty acids APPEARANCE AND Dense viscous Liquid and Oudourless
ODOUR:

USAGE: Lubricant INCOMPATIBILITIES: Not mixable with water

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID
SAFETY:
FIRE: flammable Keep away from all igniting Use extinguishing media suitable for
sources surrounding fire

STABILITY: Stable under normal condition. Avoid Heat, light moisture -


and incompatible.

HEALTH
INHALATION .
(BREATHING):

SKIN: Clogs skin pores Coveralls, gloves boot. Wash off with toilet soaps, remove
contaminated clothing Get medical
attention.

EYES: Poor vision Chemical safety goggles Immediately, for at least 15 minutes, get
medical attention.

INGESTION Stomach upset/ gastrointestinal Drink plenty milk Get medical attention
(SWALLOWING): tract contamination.

ENVIRONMENT Reduction of oxygen diffusion Avoid contamination of Clean –up and Biodegradation -
soil/water
SPILLAGE MITIGATION: Collect in a container for PACKAGING
disposal/ use, use of booms and adsorbents. MATERIAL:
Tightly closed – cool dry and well-ventilated
STORAGE: area. Keep out of direct sunlight

DISPOSAL OPTION: Recycle FLASH POINT:

VERSION: 01 DATE OF ISSUE: Oct, 2014

Page 23

SHOC NO: 024


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

Page 24

SHOC NO: 025

POLYGARD CELLULOSE THINNERS


COMPOSITION: Aromatic hydrocarbons, Esters APPEARANCE AND ODOUR: Colourless liquid with characteristic
and ketones and alcohol (toluene odour.
and xylene)

USAGE: Laboratory use, general INCOMPATIBILITIES: Can react with oxidi


cleaning.

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Highly Flammable. No open flames, no sparks, Carbon dioxide, dry chemical powder,
no smoking. foam.

STABILITY: Stable.

HEALTH

INHALATION Headache, dizziness, nausea Respirator for organic Fresh air.


(BREATHING): vapour.

SKIN: Itching, pain, degreases the PVC gloves and coverall. Wash with soap and water.
skin.

EYES: Itching, redness, pain and Mono-goggles. Flush with plenty of water for at least 15
blurred vision. minutes and obtain medical attention.

INGESTION Abdominal pain and nausea. Give plenty of water to drink, DO NOT
(SWALLOWING): INDUCE VOMITING, and obtain
medical attention.

ENVIRONMENT No data. Prevent contamination of


soil and water.

SPILLAGE MITIGATION: (Wear rubber boots). PACKAGING


MATERIAL:

Volatilisation / absorption in sediments STORAGE: Keep cool, fire proof. Flame proof electrical
materials in store

DISPOSAL OPTION: FLASH POINT: < 19 ºC


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

Disposal method to conform with national regulation in AUTO IGNITION TEMPERATURE: 250 ºC
force. Incinerate.

VERSION: 01 DATE OF ISSUE: Oct, 2014

Page 25

SHOC NO: 026

RED OXIDE
COMPOSITION: Titanium Oxide, trimethyl APPEARANCE AND ODOUR: Red
benzene butanool

USAGE: Corrosion control primer INCOMPATIBILITIES:

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Flammable. No open flames, no Carbon dioxide, dry chemical powder,


smoking, no sparks. alcohol resistant foam, sand/earth.

STABILITY: Stable.

HEALTH

INHALATION Shortness of breath, dizziness, Respirator. Fresh air, obtain medical attention.
(BREATHING): fainting.

SKIN: Bluish skin. Nitrile gloves, Coverall. Use recognised skin cleanser wash with
plenty of water, do not use solvents and
thinners

EYES: Redness, pain. Mono-goggles/ Visors. Flush with plenty of water. Obtain
medical attention.

INGESTION Sore throat, abdominal pain. Do not induce vomiting.


(SWALLOWING):

ENVIRONMENT

Slightly toxic to aquatic life. Avoid gross contamination


of soil and water.

SPILLAGE MITIGATION: PACKAGING Steel drums with plastic lining.


MATERIAL:

Prevent/absorb spreading by using sand/earth, collect and STORAGE: Keep dry in well ventilated area.
wash away remainder plenty of water.

DISPOSAL OPTION: FLASH POINT: 31 ºC


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

Re-cycle. Incinerate. Comply with national legislations. AUTO IGNITION TEMPERATURE: Nil ºC

VERSION: 01 DATE OF ISSUE: Oct, 2014

Page 26

SHOC NO: 027

WHITE PAINT
COMPOSITION: Light aromatic xylene, trimethyl APPEARANCE AND ODOUR: White
benzene

USAGE: Corrosion control finishing INCOMPATIBILITIES:

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Flammable. No open flames, no Carbon dioxide, dry chemical powder,


smoking, no sparks. alcohol resistant foam, sand/earth.

STABILITY: Stable.

HEALTH

INHALATION Shortness of breath, dizziness, Respirator. Fresh air, obtain medical attention.
(BREATHING): fainting.

SKIN: Bluish skin. Nitrile gloves, Coverall. Use recognised skin cleanser wash with
plenty of water, do not use solvents and
thinners

EYES: Redness, pain. Mono-goggles/ Visors. Flush with plenty of water. Obtain
medical attention.

INGESTION Sore throat, abdominal pain. Do not induce vomiting.


(SWALLOWING):

ENVIRONMENT

Slightly toxic to aquatic life. Avoid gross contamination


of soil and water.

SPILLAGE MITIGATION: PACKAGING Steel drums with plastic lining.


MATERIAL:

Prevent/absorb spreading by using sand/earth, collect and STORAGE: Keep dry in well ventilated area.
wash away remainder plenty of water.

DISPOSAL OPTION: FLASH POINT: 30 ºC


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

Re-cycle. Incinerate. Comply with national legislations. AUTO IGNITION TEMPERATURE: Nil ºC

VERSION: 01 DATE OF ISSUE: Oct, 2014

Page 27

SHOC No: 028

PAINT (MAYRE/BERGER)
COMPOSITION: Butyl acetate, Epichlorohydrin, APPEARANCE AND Liquid with strong solvent odour
methyl ethyl ketone, calcium ODOUR:
chromate, titanium dioxide, talc
powder, iron oxide
USAGE: Industrial use - painting INCOMPATIBILITIES: Strong Oxidiser, Heat.

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID
SAFETY:
FIRE: Extremely flammable No open flames no sparks, no Carbon dioxide, dry chemical powders
smoking. or sprays.

STABILITY: Stable under normal condition. Avoid extreme heat, sparks -


flame or ignition

HEALTH
INHALATION Throat irritation, CNS effects, Use NIOSH approved Remove to fresh air, artificial
(BREATHING): reversible liver damage at high respirator. respiration, get medical attention.
dosage

SKIN: May cause irritation Chemical - resistant gloves Remove contaminated clothing. Wash
and protective clothing skin with soap / water. Get medical
attention

EYES: Irritation and redness Chemical safety goggles Flush Immediately, for at least 15
minutes, get medical attention.

INGESTION Vomiting, nausea, and dizziness Do not eat drink or smoke Get medical attention immediately.
(SWALLOWING): during work. Wash before
eating.

ENVIRONMENT Very toxic to aquatic and Avoid contamination of


terrestrial life soil/water
SPILLAGE MITIGATION: do not allow materials to enter PACKAGING Metallic Drums and cans
drains, sewers or watercourses. Absorb in sand or inert MATERIAL:
material.

STORAGE: Store well away from any alkaline material such


as caustic soda. Avoid contact with skin.

DISPOSAL OPTION: Incinerate with scrubber FLASH POINT:

VERSION: 01 DATE OF ISSUE: Oct, 2014


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

Page 28

SHOC No: 029

BERGER LUXOL EPOXY A AND B


COMPOSITION: Butyl acetate, Epichlorohydrin, APPEARANCE AND Liquid with strong solvent odour
methyl ethyl ketone, calcium ODOUR:
chromate, titanium dioxide, talc
powder, iron oxide
USAGE: Laboratory chemical INCOMPATIBILITIES: Strong Oxidants

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID
SAFETY:
FIRE: Extremely flammable No open flames no sparks, no Carbon dioxide, dry chemical powders
smoking. or sprays.

STABILITY: Stable under normal condition. Avoid extreme heat, sparks -


flame or ignition

HEALTH
INHALATION Throat irritation, CNS effects, Use NIOSH approved Remove to fresh air, artificial
(BREATHING): reversible liver damage at high respirator. respiration, get medical attention.
dosage

SKIN: May cause irritation Chemical - resistant gloves Remove contaminated clothing. Wash
and protective clothing skin with soap / water. Get medical
attention

EYES: Irritation and redness Chemical safety goggles/ Flush Immediately, for at least 15
full-face shield minutes, get medical attention.

INGESTION Vomiting, nausea, and dizziness Do not eat drink or smoke Get medical attention immediately.
(SWALLOWING): during work. Wash before
eating.

ENVIRONMENT Very harmful to aquatic and Avoid contamination of


terrestrial life soil/water
SPILLAGE MITIGATION: do not allow materials to enter PACKAGING
drains, sewers or watercourses. Absorb in sand or inert MATERIAL: Metallic cans and drums
material.

STORAGE: Store well away from any alkaline material such


as caustic soda. Avoid contact with skin.

DISPOSAL OPTION: Incinerate with scrubber FLASH POINT:

VERSION: 01 DATE OF ISSUE: Oct, 2014


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

Page 29

SHOC NO: 30

ALVANIAGREASE (EP2 /R2 / R3)


COMPOSITION: Mineral oil, heavy paraffinic APPEARANCE AND ODOUR: Smooth, dark brown, shiny semi –
petroleum distillates additives solids with pleasant fatty odour

USAGE: For single buoy mooringns INCOMPATIBILITIES: None


(SBM), shackles

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING


EXPOSURE AGENTS / FIRST AID

SAFETY:

FIRE: Combustible No smoking open flames, sparks Carbon-dioxide, dry chemical


or ignition sources. powder, foam and water fog

STABILITY: Stable. None.

HEALTH

INHALATION At most minor discomfort Adequate ventilation Fresh air.


(BREATHING):

SKIN: Prolonged exposure results in Rubber gloves. Wash with soap and water.
irritation and dermatitis

EYES: Redness and pain Safety mono-goggles. Flush with water, obtain
medical attention.

INGESTION/ Abdominal spasm / nausea Do not eat, drink or smoke Drink water, induce vomiting,
SWALLOWING: during work and obtain medical attention.

ENVIRONMENT Harmful to the environment Avoid gross contamination of soil


and water.

SPILLAGE MITIGATION PACKAGING Plastic cups/steel drums


MATERIAL:

Scoop up and place in a container for spillage on water STORAGE: Cool, dry ventilated area.
remove by skimming/suitable absorbents.

DISPOSAL OPTION FLASH POINT: 221ºC

Dispose of at controlled landfill. AUTO IGNITION TEMPERATURE:


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

DENSITY:

VERSION: 01 DATE OF ISSUE: Oct, 2014

Page 30
SHOC No: 031

PAINT (MAYER/BERGER)
COMPOSITION: Butyl acetate, Epichlorohydrin, APPEARANCE AND Liquid with strong solvent odour
methyl ethyl ketone, calcium ODOUR:
chromate, titanium dioxide, talc
powder, iron oxide
USAGE: Industrial use - painting INCOMPATIBILITIES: Strong Oxidiser, Heat.

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID
SAFETY:
FIRE: Extremely flammable No open flames no sparks, no Carbon dioxide, dry chemical powders
smoking. or sprays.

STABILITY: Stable under normal condition. Avoid extreme heat, sparks -


flame or ignition

HEALTH
INHALATION Throat irritation, CNS effects, Use NIOSH approved Remove to fresh air, artificial
(BREATHING): reversible liver damage at high respirator. respiration, get medical attention.
dosage

SKIN: May cause irritation Chemical - resistant gloves Remove contaminated clothing. Wash
and protective clothing skin with soap / water. Get medical
attention

EYES: Irritation and redness Chemical safety goggles Flush Immediately, for at least 15
minutes, get medical attention.

INGESTION Vomiting, nausea, and dizziness Do not eat drink or smoke Get medical attention immediately.
(SWALLOWING): during work. Wash before
eating.

ENVIRONMENT Very toxic to aquatic and Avoid contamination of


terrestrial life soil/water
SPILLAGE MITIGATION: do not allow materials to enter PACKAGING Metallic Drums and cans
drains, sewers or watercourses. Absorb in sand or inert MATERIAL:
material.

STORAGE: Store well away from any alkaline material such


as caustic soda. Avoid contact with skin.

DISPOSAL OPTION: Incinerate with scrubber FLASH POINT:

VERSION: 01 DATE OF ISSUE: Oct, 2014


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

Page 31

SHOC No: 032

LINCOLN ELECTRIC
COMPOSITION: Titanium dioxide, Natural APPEARANCE AND Whitish powdery solid.
cellulose, silicate binders ODOUR:
magnesia, fibre etc

USAGE: Industrial use - painting INCOMPATIBILITIES: Organic materials and combustibles

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID
SAFETY:
FIRE: Non-flammable. Welding arc and No open flames no sparks, no Carbon dioxide, dry chemical powders
sparks can ignite combustibles smoking. or sprays.
and flammables

STABILITY: Stable. Avoid incompatibles -

HEALTH
INHALATION Dizziness, nausea, dryness, Restorable fume respirator. Remove to fresh air, artificial
(BREATHING): irritation of nose/throat/eyes. Ventilation respiration, get medical attention.
Pulmonary function effects

SKIN: Burns Dark substantial clothing Remove contaminated clothing. Wash


skin with soap / water. Get medical
attention

EYES: Irritation , redness and damage to Face shields with appropriate Flush Immediately, for at least 15
eyes filter lens minutes, get medical attention.

INGESTION Could be fatal Do not eat drink or smoke Get medical attention immediately.
(SWALLOWING): during work. Wash before
eating.

ENVIRONMENT Very toxic to aquatic and Avoid contamination of


terrestrial life soil/water
SPILLAGE MITIGATION: Absorbs spill with inert PACKAGING Metallic Drums and cans
materials, use PPE. Place into a chemical waste container. MATERIAL:

STORAGE: Train welder not to touch live live electrical


parts

DISPOSAL OPTION: dispose in a controlled landfill or FLASH POINT:


incinerate

VERSION: 01 DATE OF ISSUE: Oct, 2014

Page 32
SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

SHOC NO: 033

PORTLAND CEMENT
COMPOSITION: Silicates, aluminates and APPEARANCE AND ODOUR: Gray or white powder. No distinct
sulphates of calcium odour.

USAGE: Biocide. INCOMPATIBILITIES: Keep away from acids , ammonium


salts & aluminium metal

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Non-combustible. Use extinguishing agent appropriate to the


surrounding fire conditions.

STABILITY: Stable. Unintentional contact with


water

HEALTH

INHALATION Irritation to moist mucous Respirator. Fresh air & medical attention.
(BREATHING): membrane of ENT

SKIN: Irritation, drying, and PVC gloves. Wash with cool water and pH-neutral
fissuring of skin soaps. Get medical attention for prolong
contact.

EYES: Irritation and inflammation Use safety glasses Flush with plenty of water, obtain medical
attention.

INGESTION Not to be eaten under any Do not eat, drink or smoke DO NOT INDUCE VOMITING. Get
(SWALLOWING): circumstance during work. medical attention

ENVIRONMENT No noticeable toxic reaction Prevent contamination of soil


to plant or animals and water.

SPILLAGE MITIGATION: PACKAGING Paper and nylon bags


MATERIAL:

Scoop dry and scrape wet material and collect in STORAGE: Keep dry, separate from moist weather
container, do not disperse as.

DISPOSAL OPTION: FLASH POINT:

Dispose of waste materials/bags according to national AUTO IGNITION TEMPERATURE N/A


legislations.
REL. DENSITY:
SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

3.15

VERSION: 01 DATE OF ISSUE: Oct, 2014

Page 34

SHOC NO: 034

MAYER ALUMINUM COATING


COMPOSITION: Epoxy/epoxy esters, APPEARANCE AND ODOUR: Bright Aluminum
chlorinated rubber,
polyurethane, vinyl modified
alkyds

USAGE: Corrosion control finishing INCOMPATIBILITIES: Water

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Flammable. No open flames, no Carbon dioxide, dry chemical powder,


smoking, no sparks. alcohol resistant foam, sand/earth.

STABILITY: Stable.

HEALTH

INHALATION Shortness of breath, dizziness, Respirator. Fresh air, obtain medical attention.
(BREATHING): fainting.

SKIN: Bluish skin. Nitrile gloves, Coverall. Use recognised skin cleanser wash with
plenty of water, do not use solvents and
thinners

EYES: Redness, pain. Mono-goggles/ Visors. Flush with plenty of water. Obtain
medical attention.

INGESTION Sore throat, abdominal pain. Do not induce vomiting.


(SWALLOWING):

ENVIRONMENT

Slightly toxic to aquatic life. Avoid gross contamination


of soil and water.

SPILLAGE MITIGATION: PACKAGING Steel drums with plastic lining.


MATERIAL:

Prevent/absorb spreading by using sand/earth, collect and STORAGE: Keep dry in well ventilated area.
wash away remainder plenty of water.

DISPOSAL OPTION: FLASH POINT: 30 ºC


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

Re-cycle. Incinerate. Comply with national legislations. AUTO IGNITION TEMPERATURE: Nil ºC

VERSION: 01 DATE OF ISSUE: Oct, 2014

SHOC NO: 035

ABRO SRAY PAINTS


COMPOSITION: Monochlorodifluoromathane APPEARANCE AND ODOUR: Typical

USAGE: Air conditioning units INCOMPATIBILITIES: Alkalis

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING


EXPOSURE AGENTS / FIRST AID

SAFETY:

FIRE: Flammable No open flames, smoking Carbon dioxide, water, foam, dry
and sparks chemical powder.

STABILITY: Stable.

HEALTH

INHALATION Intentional misuse can be fatal Breathing protector Fresh air, obtain medical attention
(BREATHING):

SKIN: Slight Irritation Lined butyl gloves Wash with soapy water

EYES: May cause irritation Mono – goggles Flush with plenty of water, obtain
medical attention

INGESTION N/A N/A No specific measures.


(SWALLOWING):

ENVIRONMENT Depletion of ozone layer Minimise usage towards


elimination

SPILLAGE MITIGATION: PACKAGING Cylinder with special fittings.


MATERIAL:

Ventilation areas especially low areas where vapours may STORAGE: Keep in a cool dry place
collect. Use SCBA for large spills or releases.

DISPOSAL OPTION: FLASH POINT: None

Treat as hazardous waste AUTO IGNITION TEMPERATURE: >1382oF

VERSION: 02 DATE OF ISSUE: Oct, 2014


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

Page 35

Page 36

SHOC NO: 36

NITRO – CELLULOSE THINNER


COMPOSITION: Mixture of medium boiling APPEARANCE AND ODOUR: Colourless liquid with characteristic odour.
point aliphatic solvents.

USAGE: Laboratory use, general INCOMPATIBILITIES:


cleaning.

TYPES OF HAZARD/ HAZARDS/SYMPTOMS: PRECAUTIONS: FIRE EXTINGUISHING AGENTS /


EXPOSURE FIRST AID

SAFETY:

FIRE: Flammable. No open flames, no sparks, no Carbon dioxide, dry chemical powder, foam.
smoking.

STABILITY: Stable.

HEALTH

INHALATION Headache, dizziness. Respirator for organic vapour. Fresh air.


(BREATHING):

SKIN: Itching, pain, degreases the PVC gloves and coverall. Wash with soap and water.
skin.

EYES: Itching, redness, pain and Mono-goggles. Flush with plenty of water for at least 15
blurred vision. minutes and obtain medical attention.

INGESTION Abdominal pain and nausea. Give plenty of water to drink, DO NOT
(SWALLOWING): INDUCE VOMITING, obtain medical
attention.

ENVIRONMENT No data. Prevent contamination of soil


and water.

SPILLAGE MITIGATION: (Wear rubber boots). PACKAGING


MATERIAL:

Absorb/prevent spreading with sand/earth, collect and do not STORAGE: Keep cool, fire proof.
wash away remainder with water

DISPOSAL OPTION: FLASH POINT: < 21 ºC

Dispose of in crude delivery facility. Incinerate. AUTO IGNITION TEMPERATURE: 250 ºC

VERSION: 01 DATE OF ISSUE: Oct, 2014


SAFE HANDLING OF CHEMICALS (SHOC)
CARDS

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