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No.

MCAS02828

MBR / Membrane Separation System


Preliminary Design and Calculation Proposal for
PALESTINE BATEN EL HAWA STP (Q222 Rev1)
3
(2,000m /d)

Submitted to:

MENA WATER FZC

Mitsubishi Chemical Aqua Solutions Co., Ltd.


URL: https://www.m-chemical.so.jp/sterapore/en/index.html

This document is property of Mitsubishi Chemical Corporation. Nothing from this document may be
duplicated and/or published without written approval of the owner.

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Contents
1. Introduction
TM
1.1 Features and Benefits of STERAPORE MBR Membranes
1.2 Key Parameters of Design and Operation, Maintenance

2. Design Parameters
2.1 Application
2.2 Capacity
2.3 Water quality

3. Summary of MBR System / Membrane separation system


3.1 Process flow
3.2 Volume and dimension of tank
3.3 Selected membrane module specification
3.4 Major equipment and instrument list for MBR system
3.5 Chemical Consumptiontem

4. Design and calculation


4.1 Membrane separation system
4.2 Biological treatment system
4.3 Oxygen supply system
4.4 T-P removal

5. Standard P&ID

6. Product Data Sheet

7. Reference drawing of Membrane Module

Disclaimer
This document is for reference only. We do not guarantee the accuracy of the information loss
or damages arising from use of the information in this document.

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1. Introduction
TM
1.1 Features and Benefits of STERAPORE MBR Membranes
Mitsubishi Chemical is a leading company of MF/UF hollow fiber membrane products in
the world. We can offer a wide range of MF/UF membrane products for wastewater
treatment, drinking and processing water treatment and so on. Our main products,
TM
STERAPORE , is submerged MF/UF membrane for MBR application.

TM
STERAPORE has been installed in more than 5,000 MBR systems for sewage and
industrial wastewater treatment in worldwide since 1992 with the following key features.
As a global leader of MBR membrane supplier, we are now expanding our membrane
business in the world.

TM
Key features of STERAPORE
Easy Storage
No Need Backwash
No Need Drain Membrane Tank
Available integrated MBR System

TM TM
STERAPORE Membrane Element STERAPORE Membrane Module

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1.2 Key Parameters of Design and Operation, Maintenance
1) Inlet limitation to Membrane Separation Tank
Screen
Bar or drum screen less than 1 mm
Large debris has membrane damage potential
Oil & Grease
Not exceed 150mg/L as normal hexane extracts
Significant flux decline may be observed in case of higher inlet Oil & Grease (Pay
attention mechanical oil).
Antifoaming Agent
Use alcohol base antifoaming agent
Do not use silicon antifoaming agent
Significant flux decline may be observed using silicon antifoaming agent

2) Recommended MLSS Range of Membrane Separation Tank

Product Recommended MLSS Range Instant MLSS Range


TM
STERAPORE 5000 Series 5,000 to 12,000 mg/L 3,000 to 15,000 mg/L
TM
STERAPORE 5600 Series 5,000 to 10,000 mg/L 3,000 to 15,000 mg/L
TM
STERAPORE 5700 Series 5,000 to 15,000 mg/L 3,000 to 18,000 mg/L

3) Filtration and Relaxation Mode


Relaxation time, in which membrane surface cleaning is conducted, must be provided
between suction intervals for stable treatment using the MBR system. Nonduct
intermittent filtration at at the following interval.

Filtration time: 7 minutes or less


Relaxation time: 1 minutes or longer

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4) CIP Mode
There are three types of chemical cleaning using NaNlO and/or acid.

Type of Cleaning Injection Injection and


Concentration
CIP Frequency Amount Immersion time

Maintenance Every week 500 mg/L 2 Only injection


2 L/m
Cleaning (M.C.) (Flux > 16.7 LMH) of NaCIO 30 min.
Recovery Every 3 months and/or 3,000 mg/L 2 Injection 30 min.
2 L/m
Cleaning (R.C.) +15 kPa-TMP of NaCIO Immersion 90 min.
Acid Cleaning 1 wt% 2 Injection 30 min.
Every 1 year 2 L/m
(acid) of Citric acid Immersion 90 min.

5) Diffuser Cleaning Mode


The diffusers embedded in the module are constructed so that the holes in the diffuser
are open into the pipe. When the diffusers are used for long periods of time, they must
be cleaned regularly as dried sludge will block the holes.

The diffuser cleaning process is composed of two processes. The first is a process where
air supply from the permeate pump and blower to the diffuser is stopped, and the MV
automatic valve in the branch line installed in the pipe is opened, which allows water in
the tank to flow into the diffuser. The second is a process where the MV automatic valve
is closed, the air supply is restored and the tank water in the diffuser is discharged. Clean
diffusers once every 1 to 6 hours with the inflow time kept to around 1 minute.

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2. Design Parameters
2.1 Aplication
- Application Municipal - Sewage

- Treatment process MBR for BOD and N removal (Separated)


2.2 Capacity
Description Unit Value
3
Average daily flow m /d 2000
3
Max monthly flow m /d
3
Max weekly flow m /d
3
Max daily flow m /d
3
Max hourly flow m /h

2.3 Water quality


Item Unit Inlet Outlet Removal Rate (%)
BOD mg/L 750 8 98.9%
COD(Cr)* mg/L 1500 55 96.3%
TSS mg/L 600 6 99.0%
T-N** mg/L 110 22 80.0%
T-P mg/L 47 10 78.7%
Oil & Grease*** mg/L 150 -
Average Water Temp. deg.C 30
Max. Water Temp.**** deg.C 37
Min. Water Temp. deg.C 14
Note:
* COD removal rate may be changed depending on COD composition.
** If T-N removal rate is more than 80%, other T-N removal process may need to be designed OEM.
*** If O&G are exceeded(animal and vegetable oil : 150mg/L, mineral oil : not allowed),
pre-treatment prior to MBR should be done by OEM.
**** If aeration tank temperature exceed 40 deg. C, biological processing performance declines.

3. Summary of MBR system / Membrane separation system


3.1 Process flow

Raw water → Pretreatment


Fine
- Coarse screen Equalization tank
- DAF etc. screen

Anoxic tank aeration tank Membrane tank


3 3 3
Tank V 280.0 m Tank V 1040.0 m Tank V 70.4 m Treated water →
3
Q(m /d) HRT 6.7 h HRT 25.0 h HRT 1.7 h
2000 Q'ty 2 pcs Q'ty 2 pcs Q'ty 2 pcs
RAS=4Q
3
8000.0 m /d
Scope of proposal : Anoxic tank, aeration tank and Membrane
(Pretreatment processes are out of scope)

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3.2 Volume and dimension of tank
Water Total
Length Width tank V Q'tv
Tank depth 3 tank V
(m) (m) (m ) (pcs) 3
(m) (m )
Anoxic tank 10 7 4 280.0 2 560.0
aeration tank 20 13 4 1040.0 2 2080.0

Membrane tank 4.4 4 4 70.4 2 140.8

Note
If you need brief layout of this system, please let us know.

3.3 Selected membrane module specification


- Product code 56M1200FF
2
- Membrane surface area 1200 m
- Size
Depth 1524 mm
Width 1870 mm
Height 2798 mm
- Weight (dry) 800 kg
- Weight (lifting) 1100-2600 kg

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3.4 Major equipment and instrument list for MBR system
No. Equipment Duty Required specification
1 Anoxic tank mixer 2 -
3
2 aeration tank blower 2 23.4 Nm /min
3 aeration tank diffuser 2 -
4 Membrane module 4 56M1200FF
3
5 permeate pump 2 0.79 m /min
3
6 membrane tank blower 2 9.0 Nm /min
3
7 RAS pump 2 2.78 m /min
3
8 dilution water tank 1 14.4 m
9 dilution water pump 1 160.0 L/min
10 CIP pump (M.C.) 1 0.6 L/min
11 CIP pump (R.C.) 1 3.4 L/min
12 CIP pump (acid) 1 2.6 L/min
13 NaCIO tank 1 302.5 L
14 Acid tank 1 154.2 L

No. Instrument Duty Note


1 Flow meter for permeate 2 For each membrane tank
2 Flow meter for RAS 2 For each train
3 Flow meter for aeration air 2 For each tank
4 Flow meter for membrane air 4 For each module
5 Level sensor for anoxic tank 2 For each tank
6 Level sensor for aeration tank 2 For each tank
7 Level sensor for membrane tank 2 For each tank
8 Pressure gage for permeate 4 For each module
9 DO sensor 2 For each aeration tank
10 pH sensor 2 For each aeration tank
Note
Stand-by equipments and instruments are not included in this proposal.
Safty factor is not included for required specifications.
Please select equipments and instruments by OEM in reference to this proposal.
Please design appropriate pre-treatment process (e.g.screen, DAF, etc.) by OEM.

3.5 Chemical Consumptiontem


Chemical Consumption
NaCIO (12%) 605 L/3months 2420 L/year
Citric acid - kg/month 154 kg/year
PAC (10%) 30.69 m /month
3
737 m3/year

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4. Design and calculation
4.1 Membrane separation system
1) Membrane module
- Product code 56M1200FF
2
- Membrane surface area per module 1200 m
3
- Design average daily flow 2000 m /d
- Number of train 2 train
- Number of module per train 2 module/train
- Total number of module 4 module
2
- Membrane surface area per train 2400 m
2
- Total Membrane surface area 4800 m
- Design average daily flux 0.42 m/d
17.4 LMH
- Design peak flux Designed by Average daily flow 0.42 m/d
17.4 LMH
2) Membrane tank
- Number of membrane tank 2
- Number of module per tank 2
- Tank size and volume
Length (inside, per tank) 4.4 m
Width (inside, per tank) 4 m
effective water depth 4 m
3
Volume 70.4 m
3
- Total membrane tank volume 140.8 m

3) Major equipment for membrane


a. Permeate pump
3
- Required total flow rate for peak flux 83.3 m /hr
- Intermittent operation
Filtration 7 min
Relaxation 1 min
- Number of duty per train 1
- Total number of duty 2
3
- Required flow rate per each 0.79 m /min

b. Membrane blower
3
- Required total air flow rate 18.0 Nm /min
- Number of duty per train 1
- Total number of duty 2
3
- Required air flow rate per each 9.0 Nm /min
- Prequired pump discharge pressure per each 50 kPa

4) Chemical cleaning system


a. Required chemical cleaning
CIP(M.C., Maintenance cleaning)
- NaCIO concentration 500 mg/L
- Required chemical solution volume per membrane module (2L/m ) 2400 L
- Total Number of cleand membrane module per each time (each train) 2
- Required chemical solution volume per each time 4800 L
- Chemical solution injection time 30 min

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CIP(R.C., Recovery cleaning)
- NaCIO concentration 3000 mg/L
- Required chemical solution volume per membrane module 2400 L
- Total Number of cleand membrane module per each time (each train) 2
- Required chemical solution volume per each time 4800 L
- Chemical solution injection time / leave time 30/90 min

CIP(acid, Recovery cleaning by citric acid)


- Citric acid concentration 1 wt%
- Required chemical solution volume per membrane module 2400 L
- Total Number of cleand membrane module per each time (each train) 2
- Required chemical solution volume per each time 4800 L
- Chemical solution injection time / leave time 30/90 min

b. Major equipment for chemical cleaning


Dilution water pump
3
- Required dilution water tank volume 14.4 m
(M.C. x 3 times)
- Required flow rate 160.0 L/min

CIP(M.C.) pump
- Required NaCIO(12%) volume per each time 16.8 L
- Number of duty 1
- Required flow rate 0.6 L/min

CIP(R.C.) pump
- Required NaCIO(12%) volume per each time 100.8 L
- Number of duty 1
- Required flow rate 3.4 L/min

CIP(acid) pump
- Required ctric acid(50wt%) volume per each time 77.1 L
- Number of duty 1
- Required flow rate 2.6 L/min

NaCIO tank
- Required NaCIO(12%) volume for 3 months 302.5 L
(M.C. x 12 times & R.C. x 1 time)
- Number of duty 1

Citric acid tank


- Required citric acid(50wt%) volume for 2 times of CIP(acid) 154.2 L
- Number of duty 1

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4.2 Biological treatment system
1) Load
3
- Design average daily flow 2000 m /d
- Inlet BOD concentration 750 mg/L
- Inlet BOD load 1500.0 kg-BOD/d
- Inlet T-N concentration 110 mg/L
- Inlet T-N load 220.0 kg-BOD/N
- Mass of produced excess sludge(assume excess sludge yield rate: 50%) 742.0 kg/d
3
- Volume of produced excess sludge(assume MLSS: 10,000mg/L) 74.2 m /d

2) Condition for process calculation


o
- Design liquid temperature (min. temp.) 14 C
- BOD removal rate in aeration tank 0.115 kg-BOD/kg-SS/d
o
- Nitrification rate (assume 0.08 kg-N/kg-VSS/d at 20 C) 0.053 kg-N/kg-VSS/d
o
- Denitrification rate (assume 0.10 kg-N/kg-VSS/d at 20 C) 0.067 kg-N/kg-VSS/d
- BOD consumption of dentrification 2.0 kg-BOD/kg-N
- MLVSS/MLSS 80 %

3) Membrane tank
3
- Required total volume of tank 29.0 m
3
- Design volume of each tank 70.4 m
3
- Design total volume of tank 140.8 m
- Hydraulic retention time (HRT) 1.7 h
- Design MLSS concentration 8000 mg/L
3
- BOD removal rate per unit volume 0.74 kg-BOD/m /d
- BOD removal capacity in membrane tank 103.6 kg-BOD/d
3
- Nitrification rate per unit volume 0.34 kg-N/m /d
- Nitrification capacity in membrane tank 48.0 kg-N/d

4) Anoxic tank
3
- Required total volume of tank 515.9 m
- Number of train per each anoxic tank 1
- Total number of anoxic tank 2
- Tank size and volume
Length (inside, per tank) 10 m
Width (inside, per tank) 7 m
effective water depth 4 m
3
Design volume 280.0 m
3
- Total design anoxic tank volume 560.0 m
- Design MLSS concentration 6400 mg/L
3
- Denitrification rate per unit volume 0.34 kg-N/m /d
- Denitrification capacity in anoxic tank 191.1 kg-N/d
3
- BOD removal rate per unit volume 382.11 kg-BOD/m /d
- BOD removal capacity in anoxic tank 213980.1 kg-BOD/d

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5) aeration tank
3
- Required total volume of tank 1898.1 m
- Number of train per each aeration tank 1
- Total number of anoxic tank 2
- Tank size and volume
Length (inside, per tank) 20 m
Width (inside, per tank) 13 m
effective water depth 4 m
3
Design volume 1040.0 m
3
- Total design aeration tank volume 2080.0 m
- Design MLSS concentration 6400 mg/L
3
- BOD removal rate per unit volume 0.74 kg-BOD/m /d
- BOD removal capacity in aeration tank 1530.2 kg-BOD/d
3
- Nitrification rate per unit volume 0.27 kg-N/m /d
- Nitrification capacity in aeration tank 567.7 kg-N/d

6) RAS pump
- Required recirculation activated sludge flow 4.0 Q
- Design recirculation activated sludge flow 4.0 Q
- Number of duty per train 1
- Total number of duty 2
3
- Required flow rate per each 2.8 m /min

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4.3 Oxygen supply system
1) Required oxygen
a. BOD removal
- BOD removal in aeration tank and membrane tank 1500.0 kg-BOD/d
- Oxygen consumption rate of BOD removal 0.60 kg-O 2 /kg-BOD
- Required oxygen for BOD removal 739.7 kg-O 2 /d

b. Nitrification
- Nitrification in aeration tank and membrane tank 220.0 kg-N/d
- Oxygen consumption rate of nitrification 4.57 kg-O 2 /kg-N
- Required oxygen for nitrification 574.0 kg-O 2 /d

c. Endogenous respiration
- Amount of MLSS in aeration tank 6400 mg/L
- Amount of MLSS in membrane tank 8000 mg/L
- MLVSS/MLSS 0.8
- Oxygen consumption rate of endogenous respiration 0.06 kg-O 2 /kg-MLSS/d
- Required oxygen for endogenous respiration 693.0 kg-O 2 /d

d. Maintain DO
3
- Design average daily flow 2000 m /d
3
- Recirculation flow rate (RAS) 8000.0 m /d
- Minimum residual DO 2 mg/L
- Required oxygen for maintain DO 20.0 kg-O 2 /d

e. Total oxygen for biological treatment 2026.7 kg-O 2 /d

2) Oxygen supplied by membrane module


3
- Required air flow rate per each 4.5 Nm /min
- Number of module 4
3
- Required total air flow rate 18.0 Nm /min
3
- Oxygen content of air 0.28 kg-O 2 /m -air
- Oxygen transfer efficiency 6.0 %
- Oxygen supplied by membrane module 430.8 kg-O 2 /d

3) Reqired air flow of aeration tank


- Reqired oxygen supply by aeration tank diffuser 1868.6 kg-O 2 /d
- Oxygen transfer efficiency 10.0 %
3
- Reqired air flow for aeration tank diffuser 46.8 Nm /min

4) aeration tank blower


3
- Reqired total air flow rate 46.8 Nm /min
- Total number of duty 2
3
- Reqired total air flow rate for each aeration tank blower 23.4 Nm /min

4.4 T-P removal


- Coagulant PAC
- Dosing condition Dosing Al 1mol per P 1mol
- Specific gravity of PAC (10% solution) 1.19
- Required volume of PAC (10% solution) 1023.0 L/d

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Membrane Department, Membrane Division
10F, Gate City Ohsaki East Tower
11-2, Osaki 1-chome, Shinagawa-ku,Tokyo 141-0032, Japan
Phone: +81-3-6748-7467 | Fax: +81-3-5487-6810
E-mail: membrane@m-chemical.co.jp
Document No. AQM-S-14-028E(D)

STERAPORETM Product Data Sheet

1) Product name STERAPORETM 5600 Series Membrane Module

2) Model No. 56M1200FF

3) Materials
A) Membrane Element
a) Membrane PVDF (Polyvinylidene fluoride) porous hollow fiber membrane
Nominal pore size: 0.05 micro meter
b) Element permeate header ABS resin, Polyurethane resin
c) Support pipe SUS316L
B) Cage SUS304
C) Permeate adapter ABS resin, O-ring (EPDM)

4) Dimensions 1,524 X 1,870 X 2,798 mm (D X W X H)

5) Dry weight 800 kg

6) Nominal membrane surface area 1200 m2

7) Connection
A) Effluent connection 65A flange(JIS10K) 2 port(s)
B) Diffuser connection 80A flange(JIS10K) 1 port(s)

8) Normal trans membrane pressure (Initial + 15) kPa

9) Operating temperature 1 - 40 °C

10) Drawing number ESA14A1008 rev.4


N-1b
N-2
N-1a
N-2 N-1a N-1b N-1a N-2 N-1b
Membrane part
Diffuser part

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