= 2024! COMPLETE ORGANIC Seve ALL TESTS®: 7s ~ Av Ue hs Cc .All India Mock Test (AIMT) 2024 Series fe Compete with 20k+ live aspirants. f Know your Rank before the actual JEE Main exams f Attempted by JEE 2023 AIR 11, 12 & 13 eT OR RM ca aD Bet ee eee cyUnlock the power of learning Get 20% off* & upto 6 months extension On IIT JEE Subscriptions Arcs) Seer) Peron) pa eee eee) Scena acnr (oT) ee ee) Crees rein ee ee Cee esol Ral elu ola ats) ee a ~ Mind 1 U1 9 For more details, contact: 85 85 85 85 85 ee Cesee 0) EAN dis xa Oe eye eee Coe ya oney Detection of carbon and Nitrogen Tae C+ 2Cu0 —4> CO, + 2Cu 2H + Cu0 —4> Cu + H,0 CO, + Ca(OH), —> CaCO,) + H,0 CuSO, + 5H,0 ——> CuSO,-5H;0 (white) (e531TT} This method is known as coppet\oxide test.Na cS NTreN! FeSO, + 2NaCN ——> Fe(CN), + Na,SO, TCO Ea NO Een MeO) Ro UM Lats SEMIS (CNA eae e nee Mac ON) A REPO RS e roar Ce as um eco ot) ee N on oo a ea an - we asara ETT Laas ae ” nNTest For Sulphur Sodium nitroprusside test: Sy a uu ee en ee eer De eS CC Ce Sct acd Ce Cees ati Na,S + Na, [Fe(CN), NO] —> Na,[Fe(CN),NO-S] if ROTM Re rast Somme crtetr) cr SO aa ee par SA es) aa a Smee g aa a aa ais f k 2 ) (res an pitta‘est For Halogens Sodium will combine with the halogen (from the organic compound) to form sodium halide 0 ii) Na +X — > NaX(X = Cl, Br, A white precipitate soluble in ammonium hydroxide solution indicates the presence of chlorine in the organic TE NaCl + AgNO; — AgCl + NaNO, ra A dull yellow precipitate partially soluble in ammonium hydroxide solution indicates the presence of bromine in Cores NaBr + AgNO, ——> AgCl + NaNO, Price naa? A bright yellow precipitate, completely insoluble in ammonium hydroxide solution, indicates the presence of iodine eerste ett ee TNO Poe eeWhich of the following compound is added to the sodium Cee Cae em bad Peerurd Sart) een ed w ex Pee OW CD CoWhich of the following compound is added to the sodium Cee Cae em bad Peerurd Sart) Deena Be ead Oa Dera)‘The sodium fusion extract is acidified with nitric acid and then treated with silver nitrate.PO ee ae a ony Dee ea OP Cue ea eae ce kd X A) Sodamide OTC) a PePO ee ue a Ry nitrogen of an organic compound is converted to X A) Sodamide cPC Oe tea Ene) POE a no X eco) PO a) SCC ound Meo cor)PC Oe tea Ene) POE a no X eco) Peer) 2) Co eC reset Meo cor)ey Test For Phosphorus Na,PO, + 3HNO, ——> HPO, + 3NaNO; HPO, + 12(NH,); MoO, + 21HNO, aac Pony (NTA ROnsPAV COs POs + 21NH,NO, + 12H,0 CONT (Nia), PAM; RUThe formula of the purple colour formed in Lassaigne's test for sulphur using sodium nitroprusside is Bsa UPd Cen ws 7 — NO (Bp) Nafer(nn,),(Nes),] Md em CA GCAO) fe AP)Ra eat tg sulphur using sodium nitroprusside is Retry) an NaFefFo(en),)~ CCAR A] CAG RO) se Na,[Fe(cN,)(Nos)]s* + [Fe(CN),NO}* — [Fe(CN),(Nos)]* rdecu eal Tee eco kero) eee) (a) Lassaigne's Test (i) carbon (b) cu(t) oxide (ii) Sulphur (c) Silver nitrate CCD DA el) OMe ae ee ers Orc eg precipitate with acetic acid and lead acetate Necsus N A (aC), (0)-(), (€)-Civ), (@)-(i) _ FEE @In 2021 Om ORO MOR Om (EC MD) © ) (a)-(iti), (b)-(), (¢)-(i), (@)-(iv) 08 (DO 0)ecu eal Tee eco kero) eee) (a) Lassaigne's Test (i) carbon (b) cu(t) oxide (ii) Sulphur (c) Silver nitrate CCD DA el) OMe ae ee ers Orc eg Pee ee atest Pat ect cid LS eliinasidenatiled WA ; @ o Om ORO MOR Om (EC MD) ), (b)-(i), (c)-(iv), (a)-(ii) Slay © ) (a)-(iti), (b)-(), (¢)-(i), (@)-(iv) D ) (a)-(i), (6)-Gi), (€)-(iv), (a)-(iii)Pee eC Rae uC oaks Suen (nen) OT a hm anes (b) > (i) SCR Rm cre cae ‘organic compounds (Carius Method) (On) ‘Sodium fusion extract when treated with acetic acid and lead acetate gives black precipitate if sulphur es S* +Pb* > PbS cy) [ORO® Test For Unsaturation TR LCs Oe UR Cua Ray SO eu kl ee) Re ecu ean eerie UU Cue os) ae | H,C = CH, + Br, ~ H—C—CH ] saese (colourless)Cea C=C— CEC® Test For Unsaturation larg RO ee ECR Cc aha Ra and vicinal glycols are formed (Bayer’s test). OH I 3CH, = CH, + 4H,O + 2MnO; > 3CH,—CH, + 20H + 2MnO, thst) iiGive a simple test to differentiate cyclohexane and a L ail eae eet CR ay D> Both (a) and (b)Give a simple test to differentiate cyclohexane and cyclohexene 8 eae) Weve B Bayer’s reagent a anal Coat ere on Both (a) and (b)® Test For (-OH) Alcoholic group rere Cad Pere ree eRe cd Pee ote un iC aaa es (NH,), [Ce(NO,),] + 3ROH —> [Ce(NO,),(ROH),] + 2NH,NO, Correos ita} Reon retey Test For (-OH) Alcoholic group reas Soi raealL | aa nae ~pi ks Tertiary alcohols react almost instantaneously, secondary Cte een aera Nee OL aa Cl cee ee ZnCl, RCH, OH+HC1——~—2-5 No reaction/Slow reaction cr oa beta ZnCl, R,CHOH+HC1——2 R, CHCI+H,O ZnCl, R,COH+HCI———2-4R,CCI+H,OAledds | Phot eee cee cee q a PC i he Bhan’ forme Fed, Lhoyws) peed. ae ee Tor es a PCR eee a® Test For Phenols Ferric Chloride Test DOCU Re ee at RSs 6C,H,OH + FeCl, —> [Fe(C,H,0),]* + 3HCl + 3H" Violet complex® Test For Phenols ate pC Rtg Ge Coe ae ee a Pe ee OU Rend erica) which gives a dark pink colour Pelee ee Phe + phic iirc coe ih oaey Test For Phenols ST Neco cnea meeen a is hol pone OL os ye ine coe renee) cc)® Test For Phenols PCr Ca) While phenol is reacted with NaNO, and concentrated eS Cee eo Secuencia Cue Car) OCIS ea aD Cea Ce aeey Test For Phenols ere Ca) RON eg ee Ona oe oe HO Nv O ae Cee Core) ee Oe ear eee co) Pee ro)® Test For Phenols CR as Oe ea eRe Td Cee EE eer et eae eee oy MU es cae OH a a: ig Se a aT eonsOe uo rT aie Ce eee Ure ieee Cm) ro remo Con Caer Crd— Pkeelo PCa bir ad EU Te) ote aM peas ees Pal OM ‘ 1H ee Pan “$6 Once xi EA Ca A en Caer ® ry Whe mR ee ee Tufhons pedot pee TToo yt BS a rd (white ppt.) ie OH one COIs sts) FeCl, is test for enol and phenol is enol.® Test For carbonyl group PPS ag On reaction with 2,4-dinitrophenylhydrazine (2,4-DNP), they DO ce ee To ney Non Oona AEN TI ome NO, NO, Pe EO eg Nee PA ee TONG ENC aE Nae oritROU Ni-Mh Os _ . pie eae Ay y A 3 Ey a Ca ies elas ais la / Ke form eres) eT / Wem Bynes , (sy Stas iraav let oe® Test For carbonyl group rary a Sg Q Oe iad Q C_ + NaHSo, ———> —C-oH i —_ Aon @ CtHh—c a A Tresee ences PNT Bree Ei coe _ sa ie a This test is not given by aromatic ketones like acetophenone Ce eee a Cane aes | eee ay VNey Test For Aldehydes Only Cay ws fo) eS Il i oO PLN eon + H,O +3NH, a I a ih Pree oy slat of the erste Both aliphatic and aromatic aldehydes give this test but ketones do not respond to this test because like aldehydes they IS eee eRePDO ens aoe Ae eB ws a Once) OFRSamt a © sect OY”SCloec anaes So 7 @) eee pae mr oO) sical oe a ae (ON eas eae ayia y (Qual onyica an oC five Con Cente 1 oo i Ke AS fool tal : . eat Pane Naa mGeab .ey Test For Aldehydes Only Fehling’s Test RCHO + 2Cu” (complexed) + 50H —> RCOO™ + Cu,O + 3H,O bel lreree mre) tte Ce ey ANC OU a ee ae Ce ee Cun edey Test For Aldehydes Only ECU encod Benedict modified the original Fehling’s test by using a single Be Seo ae eSe e Sec Rua eee encanto] CO MCE Cea aaa Rare ed copper sulphate and sodium citrate (2Na,C,H,0,,11H,0). rn R 40 ae 4 cH A c | Po | + Cu,0(s) c u~ No rome CONOR e NC mm LDTS) exter oe mod Rees)(Sy, aa a acre ae ) ree a2 peer ue e acre ror) rae ae ae on nes “en Reta uae Ke eeL ity evry) Ether PredPa CEC X Rae ay ok EVO cy c Ether CadAcetaldehyde and benzaldehyde can be Oe e \ eee if a ete H rr ~ ete Mh cy reg iB e fre} ee ee nt a i POL 1C))DCU ae kd CT read \ a cd Prd MR a on both (a) and (b)o CHI, +HCO3 OS S +ve iodoform CH,—CHO R cs tes > +ve test RRO aoe Ph—CHO cp en SassBou cea ca ae Cr res (i) Fehling’s Test: Positive (ii) Na fusion extract upon treatment with sodium nitroprusside Ree etek ade es NOE i a7 anc Oe —— a ¥ ° © [| ov IAoi i Chicka ean Oe ruri ne (i) Fehling’s Test: Positive (ii) Na fusion e: tssct upon treatment with sodium nitroprusside 5 Derr arn le y iy N Ore @& iv ‘CHO my ny IN \ preaDee OL Oe cc ee amd Pere Ce ro ee een ne ee OL) Cea Le@- Which of following compounds give positive Tollen’s test? a ss Sy om@- Which of following compounds give positive Tollen’s test? OCH; Zor 5 sey° eon ee, OO ares (positive Tollen’s test) (Scans Peter)ey Test For COOH group ' ” P ew ST er Sy RCOOH + NaHCO, — RCOONa + H,0 +O, = RNC_ + 3KCl + 3H,O (Sako niece) (omni N en)ey Test For Amines pT SC Bg Primary Aliphatic Amines It reacts with nitrous acid to give bubbles of gas. RNH, + HONO-> ROH + H,0 +N; ene SOS! RYT ee ee RU cel eee ROR OE Bee An core R,NH + HONO —> R,N-NO +H,0 Rent Nitrosoamine OTe 2 ee eR UB KOO ROB COs CB tite CRT CeBIT R,N +HONO —*R;NH* ONO™ Perera Bert ag Renata RT er® Test For Amines EP Cox. Azo dye test Cad De Ca Ca aC ke Nee DCCC Our C eee une htucic ci onal nua RE RU ner CR as eld tet hod od Peter Cron tae cet uae erick . re Ree OR Sani ee ean cs iw, (Gore Te in eames a ion kaa ) ema dasian aan Piezo sete © ia Serenaey Test For Amines ve a RENO + Ni eee ioe N=NcI bronco eon Re aa bse { : oer PEN OEE VmNs ee micel)PY resroramines ed ood SNe at Hinsberg’s Test Benzenesulphonyl chloride (C,H,S0,Cl), which is also POO et ee A Picea hare uence BZ waar Ror © iro mara rr Nu Ae k ¥ Lal ™ : a ord yD voy CEN ee aT ula Ayaan a IVSey Test For Ami Ss Hinsberg’s Test (Primary Amines) i if een Sa Oe amo sel fe} ast OH ett ng erent Sen (soluble in alkali)® Test For Amines Hinsberg’s Test (Secondary Amines) Q ° Osa + H-N-C,H, —> Os aa + HCl I | fe) CH, ° CH, N,N-Diethylbenzenesulphonamide Tro Rlyaoe ae see Ni teealaed Cy al Are dye4err t : u Sr Oe ee eaeCeric ammonium nitrate and CHCI,/alc. KOH are used for the identification of functional groups present in CO cg NM TO baal Po OR PuCeric ammonium nitrate and CHCI,/alc. KOH are used for the identification of functional groups present in CO cg iN TO baal Po OR ic) TdCee CL Ra ka retort Put Cs D | both (a) and (b)CU eR CL Ra ka retort Put © hg D | both (a) and (b)ee eta) een eee)Biuret Test Alkaline copper sulphate reacts with compounds ee ons aero Cee UCC ce te suceestal eal Ce eee teste RUS eer ad compound, biuret, which gives this test. The reaction is Dre ee ad compounds containing two carbonyl groups linked through nitrogen or carbon atoms give a positive result.ey if rami (5 ea Pa nD ee ee a ele Nectam ys Kon caprotc ahd 4 n Vi teainal a C-N ie stad kes ed ee ess (Rhee , met) ) me tes [eet ieBiuret Test and [Cu (NHCONHCONH),]|”Cee eee ae Er ue RU Ce ead Pee ae uC Ce Serer a Peete) Pe ee eee ee See ea er ee hie ee Lanta Creates eee en tee en eed Caen ee eee uC cag Sener ee ete eet eae eae eaou nie cr a ere) non zo I aired S aie nh HO \-Naphthol Product of nei ers NSH Oh om - i Perel A rd cee Roca ees LOH es 101 —/ ‘oH won HO Or buon k Recut Perak creer fa cme) rr aay ees em ire format) can Peco ee etd mon Perey Perot eect) itesPT ssinonttstest Ketoses dehydrate very rapidly under acidic conditions to give furfural, which reacts with resorcinol (1,3-dihydroxy DUO RT OL ct cra * Ketohexoses give red colour and eed blue-green colour. Aldoses take longer time to produce colour because under the same conditions, aldoses form DN eA Sd eect eet ee eee eed De Ou Ge ae CCL} TT ‘+ Seliwanoff's reagent: Add 0.05% resorcinol (m-hydroxybenzene) in3 NHCI. Dissolve 50 mg resorcinol in 33 ml concentrated HCI Ces eiSeliwanoff’s test cay a et mee ea ra a ee SNF cotourea ie ile a? cary ee eee Ee ncaa nN furfural " a ye on Pood te ee Pere core " arena Ce Say cee TaNrrees Kore erom Fructose and glucose can be distinguished by: aaa JEE Main 2019 Neotel oe B | Sellwanoffstest zs arneee ap c | Barfoed’stest Pg t A) Fehling'stest. — 7Fructose and glucose can be distinguished by: Rear Ma os co ECan c | Barfoed’stest PendFee RCL SE ee Ls® Barfoed test gent is cupric acetate in acetic acid solution. It is weal Pere et dura ance a) CM ee ees coe nhc Coats rd Ode TU CT Malle ee aa URLs eu ed Pe eee ee cece ed Oks Ce eee acd Oe eet eee oe Cae cr unas Cee Ces aci RCHO + 2Cu*—+ RCOOH + Cu,O Monosaccharide sey uCoeonuel RO er keke eee OC eS: eae ae ee a Ra 7Fens oe eon Seiad aa mb pe Bg ie ia ig be ‘ ae rica wae i Rac iccaeaees we oe Fone ae teWhich of the following tests cannot be used for identifying amino acids? nn Veet eared ary Menor sors 4 eaten Pea a) aaa Pocus ooPU Coe nue ce Rd Rae) @ Dee Try [esc a Cu ecard Py unrBarfoed test is used for carbohydrate to check reducing nature of sugar.Ninhydrin test Ninhydrin is a powerful oxidizing agent and reacts with proteins jolet compound called Rhumann’s purple. Oy nee (oreo) Re Ce eC CE ac ce aia) SnXanthoproteic test Aromatic groups of either the free amino acid or protein, undergo nitration on heating with concentrated nitric acid. The Dee Cae etn Cue 9° fo one +105 “Oo 0 W m Ley y re Tyrosine Ce cu icCerca DOC Co RCC Tag A Positive De DCS Co Dey Crd Peery Ley RC ng ee Ce CeO Ree CLIT Rear) Te Cree Eo cee ry ee aout Bac Ree Ly Pe Coot eer Ty and C are three biomolecules. The results of the tests performed on them ~7 iy A, Band C are three biomolecules. The results of the tests performed on them. Cerca DOC RCC Tag A Positive DCS Negative Peery Te tc ery SUE) Pe Cee Eo cee ry Soe Eee ay oy A= Lactose, B = Glucose, ¢ = AlbuminSee OD Loot aoe See CE ec ened See et cc a cute ccaWhich one of the following tests used for the identification of functional groups in organic compounds does not use copper eters unto Parte) Pees 4 Cec a PCa)Which one of the following tests used for the identification of functional groups in organic compounds does not use copper eters ic Peery Rare aN og eg ava Pd oeCeCe eee con Leo ee ae as‘Q- Match the following: CTT OC TTT a ke) Orrin Onternt OT ORC ented (c) Benedict's test Olteead (d)lodoformtest _ (s) Green colour > (a) - (9), (&) - (P), () - (9), (A) - (@) B ) (a)- (9). (b)- (p). ()- ). )- (9) © ) (a)- (Pp), (b) - (s). (¢)- (9). (4) - (a) Ol Oba) bel Od ad‘Q- Match the following: CTT OC TTT a ke) Orrin Onternt (p)Leibermann’stest _(q) Yellow colour (c) Benedict's test OL ron (d) lodoform test (s) Green colour @ ©-0.0-0.0-0.-@ __ 8) @-@.0)-@.0)-0.)-@ c ) (a)-(p). (6) - (s), (e) - (7), (a) - (@) Ol Oba) bel Od adPee ee aa ae Lu Ce Free Nab ooo Bro mae oa hccad ea ae) pot na ee ee hall tea’ Te pac sat Nira ral Ae seas Ve a (exe Pa Yr eee aa Don Feet Cage ea isa Pram enue NSuied [oon - ae Cera eo Ol i ras . Betas ee © at reat arom, (oe Micah acm an Tqer laPOAC a Quantitative analysis® Estimation of carbon and Hydrogen Ce nL 44 Mass of organic compound Paty) Peet pie Remedi MeL cc i vetomecant) anes NUey Estimation of nitrogen DIEM niratirered Okt AO) eee Nee 2. % of N = = — x ———___—_____ POLIO UMMM Ee merece Ti Comes tinea Cel Ny wales =) pene pam kvt)® Estimation of nitrogen Kjeldahl’s method: This method cannot be used for OR RR Oe Ce a CMe mcs (mere Rccn Stance ae ee eNO ETT CORON Ee CT Enea eal rei N = Normality of acid. Nee CC RTE Om cua NITee SER Romo U com) aaa Pemal arm ed inca Sane” a E Es Fun( In Dumas method for the estimation of N,. the sample is heated with copper oxide and the gas evolved is Aaa Rea ILP Lee} mL amr rs od( In Dumas method for the estimation of N,. the sample is heated with copper oxide and the gas evolved is Aaa mL oduc Remeron Cue Ree cel eR UROr OR eRe kA} re ori oar cuo —> xco, +¥H,0+2N, oer f v2 2 va DER ce CR ae ee ae oc eY eratDe ee Lae See ery Reagent (i) Lucas Test (a)c,H,S0,cl/aq. KOH (ii) Dumas method (b) HNo,/ AgNo, PCD Curr (c) cuo/co, (iv) Hinsberg test CORR L aan (e)H,s0, A) (-() (a), (iii) - (e), (iv) - (a) Rar) B } (i)- (4), (ii) - (c), (iti) - (e), (iv) - (a) ; CA Ok OD ad) Bad OO Bad] D ) (i) (4), Gi)- (©), (ii) - (b), (iv) - (e)Dee See ery (i) Lucas Test (ii) Dumas method PCD Curr (iv) Hinsberg test a) ()-(b), Cerra (a)c,H,S0,Cl/aq. KOH (b) HNO,/ AgNO, (c) cuo/co, (4) conc. Hel and zncl, (OT -(e).(iv)- (a) Rte) (i) (4), Gil) - (©), (ill) - (e), (iv) - (a) ()- (©), (il) - (a), (ill) - (€), (iv) - (d) (i) - (A), Gi) - (©), (ii) - (b), (iv) - (e)lucasTest -Conc.HCI/Zncl, Dumas method -cuo/co, Kjeldaht’s method - H,50, DN Ro aA RR (oC ColdFRSC Sa Rae a se ed AON, COLA (oe ud _—_——_—_—FRSC Rae a se ed oe udIn a Dumas experiment, 0.5 g of an organic compound on heating with copper oxide liberated 112 mL of N, at STP. The percentage of nitrogen (by weight) in the compound is: Ne yy) ee) rd cs aeDT ee Re ae ea) Dt Re oe og RL percentage of nitrogen (by weight) in the compoundis: ee) rd cses) vol. of N,(ml) LUO morris verre ayia a Paes. aN x 100ey Estimation of Halogens fore atte PopSrammN CSSD Cennard ' re Mass of AgCl Ce ee ee se CR Ce TT Se 7 Pa Neo ela tal en nrenTeeT rTTs Nee ioe Cn een eee ani x 100 a CO ee co- a Cray ponc 7 fo wo ome ederih clin OC temden of Aey Estimation of Sulphur Peale ea Raat Mass of BaSO, =a nnn aSeEEEraed (la!) PERM CSRey mere CURSO MOUsey Estimation of Phosphorus Peale PA ga A LN 2 Li SL ya) Mass of organic compound 100}GPT EL ar eet to AgBr in Carius method for estimation of bromine % of bromine in the compound (x) is, \ (Given: Molar mass AgBr = 188 g mol StU L yx) -3 OX Gin LT ae vi mea v Sih r |e por = POR ae a ee RTT Lo AgBr in Carius method for estimation of bromine % of bromine in the compound (x) is__. \ (Given: Molar mass AgBr = 188 g mo! ce Bisa UP xd re Le)Moles of Br = Moles of AgBr mr rT) EL Mass of Br= 8 tee *°09 ee OA LET A v1 amrs RU cue us PCR cet ert a omit) aS Pee en uate Star 2% _ (Nearest integer) (Given: \ TEES 1") Rta Pied . vis _ Ws saad f oO 4 an al nisl 04 tr on iy mate(In sulphur estimation, 0.471 of an organic Pee Cee CeCe etn cmd Pee ne ue cE Te OG RR ee eRe roar Ans: 42 Ray)el wt. of BaSO, sof § = 32, _WL Of BASO, _ 499 LEME neil ELE en PCM EZ 32, alan 39 ra) LEE) ETN) vr)All India Mock Test (AIMT) 2024 Series fe Compete with 20k+ live aspirants. f Know your Rank before the actual JEE Main exams f Attempted by JEE 2023 AIR 11, 12 & 13 eT OR RM ca aD Be eee cyUnlock the power of learning Get 20% off* & upto 6 months extension On IIT JEE Subscriptions Arcs) Scent sree tot) Peron) Scena acnr (oT) : ee ee) Crete eel Cee esol Ral elu ola ats) ee a ~ Mind 1 U1 9 For more details, contact: 85 85 85 85 85 ee Cesa Cre ae (ae Se een laa AC al ee