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 Most Asked Topics on 27 and 29
● Practical Organic chemistry ● Physical Theoretical
● Amino Acids (Aromatic and Alcohol containing) ● Hydrolysis
● Biomolecules (Linkages) ● Buffer Solution
● Lone Pair in molecules/Central Atom ● Delta G
● Hybridisation ● Second Law
● Bond Order ● %w/w
● Dipole moment ● Nernst equation
● Electronegativity ● Electrolysis
● Electron Gain Enthalpy ● Bohr’s Model
● Oxidation Number ● Chemical kinetics formula based
● Magnetic Moment ● Solution Formula Based
● Amphoteric Oxides ● GOC
● Oxoacids ● Isomerism
● Inorganic Reactions p block ● Organic Reagents
For elements B, C, N, Li, Be O and F, the correct order of
first ionization enthalpy is

A Li < Be < B < C < O < N < F

B Li < B < Be < C < O < N < F

C Li < Be < B < C < N < O < F

D B > Li > Be > C > N > O > F

The first ionization energy (in kJ/mol) of Na, Mg, Al and Si
respectively. are:

A 496, 577, 737, 786

B 786, 737, 577, 496

C 496, 577, 786, 737

D 496, 737, 577, 786

Which of the following statements is incorrect?

A Helium has the highest first ionisation enthalpy in the periodic table

B Chlorine has less negative electron gain enthalpy than fluorine

C Mercury and bromine are liquids at room temperature

D In any period, atomic radius of alkali metal is the highest

Which of the following ions has the maximum
magnetic moment ?

+2
A Mn

2+
B Fe

C +2
Ti

D Cr +2
Ceric ammonium nitrate and CHCl3/alc. KOH are used
for the identification of functional groups present in
___ and __ respectively

A Alcohol, phenol

B Amine, phenol

C Amine, alcohol

D Alcohol, amine
The formula of the purple colour formed in Lassaigne's test for
sulphur using sodium nitroprusside is

A NaFe[Fe(CN)6]

B Na[Cr(NH3)2(NCS)4]

C Na2[Fe(CN)5(NO)]

D Na4[Fe(CN5)(NOS)]
Which of the following is amphoteric oxide?
Mn2O7 , CrO3 , Cr2O3 , CrO, V2O5 , V2O4

A V2O5 , Cr2O3

B Mn2O7 , CrO3

C CrO, V2O5

D
V2O5 , V2O4
The correct order of following 3d metal oxides, according to their
oxidation number is
(a) CrO3 (b) Fe2O3
(c) MnO2 (d) V2O5
(e) Cu2O

A (a) > (d) > (c) > (b) > (e)

B (d) > (a) > (b) > (c) > (e)

C (a) > (c) > (d) > (b) > (e)

D (c) > (a) > (d) > (e) > (b)

 –1 –1
Standard entropy of X2, Y2 and XY3 are 60, 40 and 50 JK mol ,
respectively.
For the reaction, 𝚫H = –30 kJ.

To be at equilibrium the temperature will be :

A 500 K

B 750 K

C 1000 K

D 1250 K
When two mole of an ideal gas heated from 300 K to
600 K at constant pressure, the change in entropy of gas (∆S) is:

C 5R In 2

D None of these
From the following ∆H° and ∆S° values, predict which of
O
reactions I, II, and III would be spontaneous at 25 C
O
∆H (kJ) ∆S° (J/K)
I. + 10.5 +30
II. + 1.8 -113
III. - 126 +84

A III

B I

C II and III

D I and II
 -
Consider, PF5, BrF5, PCl3, SF6, [ICI4] , CIF3 and IF5. Amongst the above
3 2
molecule(s)/ ion(s), the number of molecules(s)/ion(s) having sp d
hybridisation is
The number of species below that have two lone pairs of electrons in
their central atom is____.
(Round off to the Nearest Integer).
-
SF4, BF4 , CIF3, AsF3, PCl5, XeF4 , SF6
 - +
The hybridisations of the atomic orbitals of nitrogen in NO2 , NO2
+
and NH4 respectively are :

3 2
A sp , sp and sp

2 3
B sp, sp and sp

2 3
C sp , sp and sp

2 2
D sp , sp and sp
Among the following molecules/ions,
2- 2- 2-
C2 , N2 , O2 , O2
Which one is diamagnetic and has the shortest bond length?

A O2

2-
B O2

C N22-

2-
D C2
The dipole moments of CCl4, CHCl3 and CH4 are in the order:

A CHCl3 < CH4 = CCl4

B CCl4 < CH4 < CHCl3

C CH4 < CCl4 < CHCl3

D CH4 = CCl4 < CHCl3

Identify compound A:

A B

C D
In the following sequence of reactions :

the product C is :

A C6H5COOH

B C6H5CH3

C C6H5CH2OH

D C6H5CHO
Identify the product formed (A and E)

A B

C D
 6
How many minutes are required to deliver 3.21 x 10 coulombs
using a current of 500 A used in the commercial production of
chlorine?

A 8.3

4
B 5.3 x 10

C 6420

D 107