TERM – I LEAST ATTEMPTED QUESTIONS

CHEMISTRY
9TH CO-IIT PAPER - A WORK SHEET-2
51. Which of the following compounds are ionic?
1) Li2CO3 2) Be2C 3) Li4C 4) MgO

52. Which of the following order are correct?

1) M.P order: NaCl  KCl  RbCl  CSCl  LiCl
2) M.P order: Diamond > Al2O3  SiC  B 4C

3) Solubility in water order: BeF2  MgF2  CaF2  SrF2  BaF2

4) Covalent character order: LiF  LiCl  LiBr  LiI

Question Stem for Question Nos. 53 and 54:
I.E value A,B are 322.84Kcal / mol ; 275Kcal / mol & E .A value A,B are
193.70Kcal / mol ;86Kcal / mol respectively
53. Based on above data

Electronegetivity of A   Electronegetivity of B  is—

54. Percentage of Ionic character of the compound formed by A and B.

Question Stem for Question Nos. 55 and 56:

The electronic configuration of four elements given below
A  1s 2 2s 2 2 p 6 3s 2 3 p 4
B  1s 2 2s 2 2 p 6 3s 2 3 p 5
C  1s 2 2s 2 2 p 6 3s1
D  1s 2 2s 2 2 p 6 3s 2
55. The Number of Ionic compounds formed by above four elements
56. Sum of Atomicity of all Ionic compounds formed by above elements
is / are equal to ________

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Question Stem for Question Nos. 57 and 58:
I .E1
Mg( g )   Mg (g ) : I .E1  740 KJ / mol
I .E2
Mg(g )   Mg (2g) : I .E 2  1540 KJ / mol

If 1gm of Mg( g ) absorbs 50KJ of energy

⊕
57. What % in final product ?
58. What % Mg 2 in final product?

Question Stem for Question Nos. 59 and 60:

A gas of identical H-like atom has some atoms in the lowest (ground)
energy level(A) and some atoms in a particular upper (excited) energy level
‘B’ and there are no atoms in any other energy level. The atoms of the gas
make transition to a higher energy level by absorbing monochromatic
light of photon energy 2.7 eV. Subsequently, the atoms emit radiation of
only six different photons energies. Some of the emitted photons have
energy. 2.7eV. Some have more and some have less than 2.7 eV.
59. The principal quantum number of initially excited level ‘B’ is
1) 1 2) 2 3) 3 4) 4
60. The ionization energy for gas atoms is
1) 3.4 eV 2) 12.8 eV 3) 14.4 eV 4) 13.6
eV

Question Stem for Question Nos. 61 and 62:

The rule governing the transition from ionic to covalent bonding are called
Fajan’s rules. They are based on the deformation of the interacting ions
⊝
in the bond A+ (polarization of ions).
61. Which of the following incorrect order of solubility in water?
1) LiF < NaF < KF < RbF < CsF
2) BeSO4 > MgSO4 > CaSO4 > SrSO4> BaSO4
3) CsF > CsCl > CsBr > CsI
4) BeS < MgS < CaS < SrS < BaS

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62. Select the correct statement:
1) Solubility of bicarbonates of Na  , K  , Rb  ,Cs  decreases down the
group
2) Thermal stability of nitrates of group IA cations increases down
the group
3) Solubility of chromates of group II A cation increases down the
group
4) Melting point of fluorides of Na  , K  , Rb  ,Cs  increases down the
group
63. Not considering the electronic spin, the degeneracy of the second
excited state (n=3) of H atom is 9, while the degeneracy of the
second excited state of H  is ____________.
64. The ionization enthalpy of Na  formation from Na( g ) is

495.8 KJ mol 1 , while the electron gain enthalpy of Br is

325.0 KJ mol 1 . Given the lattice enthalpy of NaBr is

728.4KJ mol 1 . The energy for formation of NaBr ionic solid is(-)

X  102 KJ mol 1 ,Then X is -------- (Needed other values as zero)

(Nearest integer).
65. The dipole moment of HBr is 7.95 D and interatomic separation is
1.94  1010 m. the % of ionic character is HBr is xy % (Nearest
integer), (e  1.6 1019 C, 1D  3.33  1030 C. m) Then what is x  y ?
66. How many molecules out of the following have non zero value of
dipole moments CH 2 Cl 2 , CH 4 , CCl 4 , H 2 O, CHCl 3 , Chlorobenzene,
CO, CO 2 ,SO 2 ,SCl 2 , BF3 , IBr, PCl 3 F2 , PCl 2 F3 ?

67. Amongst the following, the number of species having the linear shape
is ______.
XeF2 , I3 ,C3O2 ,I3 ,CO2 ,SO2 ,BeCl2 , BCl2 , N3 , N 2O

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68. Total type of different bond length data are observed in PCl 2 F3 .
69. IE 1 and IE 2 of Mg metal are 178 and 348 kcal / mol respectively. The

energy required for the given reaction is P 102 .

Mg  g   Mg 2  g   2e ,Then what is P ? (Nearest integer)
70. If electro negativity of X be 3.2 and that of Y be 2.0, the percentage
PQ
covalent character of XY is PQ . (Nearest integer) What is ?
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71. In which of the following bond angle is maximum?
A) NH 3 B) OCl 2 C) SCl 2 D)

NH4
72. The electro negativity difference between N and F is greater than N

and H , yet the dipole moment of NH3 1.5D is greater than that of

NF3  0.2D. This is because :

1) In NH 3 as well as NF3 , the atomic dipole and bond dipole are in

opposite direction
2) In NH 3 the atomic dipole and bond dipole are in opposite

direction, Where as in NF3 these are in same direction

3) In NH 3 as well as NF3 , the atomic dipole and bond dipole are

in same direction
4) In NH 3 the atomic dipole and bond dipole are in same

direction, Where as in NF3 these are in opposite direction

73. d -orbitals used by 'S' in S F6 molecule are :

A) d x 2  y2 B) dxy C) dyz D) dz2

74. Stability order of +3 and +1 states of boron family elements is

A) Ga 3  In3  Tl3 B) Ga   In   Tl

C) Ga   In   Tl D) Ga 3  In3  Tl3

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75. Select correct statements from the following
A) S-1:- I.E1 of Sr > Rb but I.E2 Rb > Sr

B) S-2:- The ionic radii of Li ,K ,Mg2 and A

3 0
in A are 0.76,

1.38, 0.720 and 0.535 respectively.

C) S-3:- The negative value of electron again enthalpy of C > F
because there is weak electron-electron repulsions in the bigger 3p-
subshell of C as compared to compact 2p-subshell of F.
D) S-4:- The second ionization energy of copper is less than
potassium.
76. Select correct statements from the following.
A) S-1:- Na 2 O  MgO  ZnO  P4 O 10 : Acidic property

B) S-2:- Na  Si  Mg  Al: First ionization potential

C) S-3 :- F  Cl  Br : Electron affinity.

D) S-4 :- Te2  I  Cs  Ba 2 : Ionic size

77. Inter molecular hydrogen bonding is not present in

A) O-fluoro phenol B) Salicylaldehyde
C) O-nitro phenol D) P-nitro phenol
78. The correct statement is/are :

A) BeCl2  s  exist in polymeric form with SP2 hybridized state of Be

atom

B) B 2 H 6 acts as Lewis acid which contains 3c  2e bond

C)  SiH 3 3 N planar and weak Lewis base, due to delocalization of

lone pair of N -atom into vacant d-orbitals of Si -atom through

back bonding
D) BI 3 acts as strong Lewis acid among the boron halides due to

strong back bonding

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79. Which of the following statement(s) is (are) correct for solid ICl 3
molecule (it is I2Cl6 in solid state) ?
A) All I  Cl bond lengths are not equal
B) All adjacent bond angles are equal
C) All atoms do lie in the same plane
D) There are two three centre four electron bonds i.e. 3c-4e bonds.
80. Which of the following option is/are correct regarding of SO 2 C l 2 ?

ˆ  OSCl
A) OSO ˆ  ClSCl
ˆ  Bond angle 

B) Hybridization of S is sp3
C) It has two p  d bonds
D) Number of p  p bonds is equal to number of p  d bonds
81. At 250C vapour pressure of water is 23 mm of Hg. If partial pressure
of water vapour in air at 250C is 18.4 mm of Hg, the percentage
X
relative humidity in air is X ,What is ?
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82. How many of the following compounds are polar?
CH 3Cl , NH 3 ,CO 2 , H 2O ,CH 4 , PCl5 ,C 2H 2

83. The total number of lone pairs of electrons on oxygen atoms of

ozone ( O3 )is _____

84. A vessel of 10 L capacity contains 4 g He gas. The vessel is heated

such that its absolute temperature becomes double. In order to
make the pressure of gas half of its initial pressure, the mass of
gas (in g) which should be removed from the vessel is: (Assume no
change in the capacity of vessel.)
85. A quantity of gas is collected in a graduated tube over the mercury.
The volume of gas at 180C is 50ml and the level of mercury in the
tube is 100 mm above the outside mercury level. The barometer
reads 750 torr. Hence volume of gas (in mL) at 1 atm and 00 C is
X
approximately is X then  _________
10

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86. A flask containing air at 1070 C and 722 mm of Hg is cooled to 100k
and 760 mm of Hg. If density in the initial condition 1 g/cm3, then
what is the final density (g/cm3)
87. The time taken for a certain volume of a certain gas to diffuse
through a small hole was 2 min. under similar conditions an equal
volume of oxygen took 5.65 min to pass. what is the molecular
mass of gas (in amu)?
88. Under the identical conditions of temperature, the density of a gas
X is two times to that of gas Y while molecular mass of gas Y is
three times that of x. Calculate the ratio of pressure of X and Y.
89. Select the incorrect statement(s):
A) the product of pressure and volume of fixed amount of a gas is
independent of temperature
B) The value of universal gas constant upon temperature, volume
and number
of gaseous molecules
C) The gas constant also known as Boltzmann’s constant
D) The average kinetic energy of molecules depends only on
temperature
90. What conclusion would you draw from the following graphs for an
ideal gas?

A) As the temperature is reduced, the volume as well as the

pressure increase
B) As the temperature is reduced, the volume becomes zero and the
pressure
reaches infinity

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 C) As the temperature is reduced, the pressure decrease
D) A point is reached where, theoretically, the volume become zero
91. Which pairs cannot explain Dalton’s law?
A) H 2 , O2 B) H 2 , F2 C) NH 3 , HCl D)

NO, O2
92. In the equation P V=R T , the value of R will not depend upon
A) The nature of the gas
B) The temperature of the gas
C) The pressure of the gas
D) Units of measurement
93. Which of the following is true for Charles law?
 t  V1 T1
A) Vt =V0 1+  B) =
 273  V2 T2

C) d1T1 =d 2T2 D)None

94. Which of the following statement is / are correct?

A) Helium escapes at a rate of 2 2 times as fast as O2 does.

B) Helium escapes at a rate of 4 times as fast as SO2 does.
C) Helium escapes at a rate of 2.65 times as fast as CO does
D) Helium escapes at a rate of 8.65 times as fast as CO does
95. 8g of NaOH is dissolved in 18g of H2O. Mole fraction of NaOH in
solution and molality (in Mol kg-1) of the solution respectively are
1)0.2,11.11 2)0.167,22.20 3)0.2,220.20
4)0.167,11.11
96. Which of the following statements is true about oxidation state of
S in Na 2S 4O 6 ?

1) All S-atoms are in +2.5 state.

2) All S-atoms are in +2 state.
3) Two S-atoms are in 0 state and other two is in +5 state.
4) Two S-atoms are in –1 state and other two is in +6 state.

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 97. The equivalent weight of glucose in the reaction
C6 H12O6  6O2  6CO2  6H2O is [ M = mol, wt]
1) M 2) M/2 3) M/24 4) 2M
98. A bivalent metal has equivalent weight 12. The molecular weight of
its oxide is
1)16 2)32 3)40 4)52
99. What volume of H2 at at NTP is required to convert 2.8g of N 2 into
NH3?
1) 2240ml 2) 22400ml 3) 6.72 lit 4)224 lit
100. 70g of a sample of magnesite on treatment with excess of HCl gave
11.2L of CO2 at STP. The percentage purity of the sample is
(Given reaction : MgCO3  2HCl  MgCl 2  H 2O  CO2 )

1) 80 2) 70 3) 60 4)50

CHEMISTRY Key
Q.No. 51 52 53 54 55 56 57 58 59 60
6.79-
ANS. 24.24 4 10 70.13 29.87 B C
BCD AD 6.80
Q.No. 61 62 63 64 65 66 67 68 69 70
Ans. D B 3 6 3 9 7 3 5 4
Q.No. 71 72 73 74 75 76 77 78 79 80
ANS. B D AD CD ABCD AD ABC BC ACD ABC
Q.No. 81 82 83 84 85 86 87 88 89 90
ANS. 8 3 6 3 4 4 4 6 ABC CD
Q.No. 91 92 93 94 95 96 97 98 99 100
ANS. BCD ABC ABC ABC 4 3 3 3 3 3