MODEL PAPER SECOND YRAR B.Sc., DEGREE EXAMINATION SEMESTER-OL CHEMISTRY COURSE-III: ORGANIC CHEMISTRY & SPECTROSCOPY ‘Time: 3 hours Maximum Marks:75 PART- A ‘Answer any FIVE of the following questions. Bach carries FIVE marks 5 X'$=25 Marks 1. Discuss any two methods for the: preparation of aryl halides. DOS HBS odd Sobre Toi IST Boe SSeboendd SHyocAw. 2, Explain the mechanism for Pinacol-Pinacolone rearrangement. S555 DSESS HIGHS 55 WY STYDTSOS DSO’. 3, Discuss the mechanism for Baeyer-viliger oxidation reaction, BoB-DONG 58 y85e0 SOs Sosy SOYDPSOS DSGorS. 4, Explain the effect of substituents on acidic strength of mono-carboxylic acids. BAT SO )E OE SATO Vp DOOD HSFASO WarSowH ASGoddSy 5, Explain the mechanism for Claisen Condensetion reaction. Somys HOMSS Uso SOYDGHSIk DSSorsa0. 6. Write the selection rules in rotational spectroscopy. Bsa SHHdTVOS'A DoDs Nabaroad Benyen. 7, Explain Spin ~ Spin coupling and Coupling Constant, 275-075 SHON SSakw SYoH Yorosas NAGoeSw. 8, Explain the types of electronic transitions in UV spectrosco PY. UV. Sos QOSA DDS dso DATS HASGSoakd DHSoro. PART-B “Answer ALL the questions. Bach carries TEN marks 5X 10= 50 Marks 9(a) Explain the mechanism & stereochemistry of SN’ & SN* reactions of alkyl halides with suitable examples. By SBS o SN! SvOciw SN’ SGseor Doky HoyOqrasoay svOat wae SOLS TTD] ACMETSED SS sSor DSHODSY, (x) (b) Explain the following reactions with mechanisms. (i) Reimer-Tiemann reaction (i) Fries rearrangement (800 Bee DoydqrSoa DSGoes0 () 66-85 55s (i) |HH DSSHOS 10(a) Discuss the mechanism for the following reactions: (Perkin reaction. (ii) Camnizaro resction Page 1of 2Bod Boje oyderdodd GOzoevSo © DOS SEs (il) BE SSO (on) (®). Write the preparation and any three synthetic applications of diethy! malonate. Bass DIS Sotrb Od, sare Sofia eHstrm® aso, 1i(@)). Explain acid and base hydrolysis reactions of esters with mechanisms. AYE © wy HOw HS BODIo dso STO DSoordsn. (2) (). Explain the mechanisms of Curtits rearrangement & Arndt —Eistert reaction, RQawH HISHOK SS; HEakw aos5.cHS Spo Soy Nerdy 2SSordaw 12(a). Define Bathochromic shift. Explain the effect of conjugation in U.Y. spectroscopy. ePSISWS HarTDy OO jNocoSw, W SPHHoD Sookotyer erSos DSCodSn. (or) ©), Discuss the principle of NMR spectroscopy. NMR SGaOT Zo Sky ATED) Sojordaw. 13(a) Write Woodward-Fieser rules for calculating Za, value for conjugsted dienes and ‘B-unsatureted carbory! compounds by taking one example for each 28 doninGes oo Socknt) Bar 608 af-e5%0: Owgd NGO $45G- B85 LabdSrens Seay, @) SOyBS SBT (b) ). () What is the Fingerprint region? Explain its significance with an example. Gi) Write 1R spectral data for any ono aldchyds and ketone () 9086 Go Godse wArAb? sata ayo od Wrwonssd DS80eSn0. (i) DBa 2s Op Hodw {S'S oh Sowka Afso deorod jrcosn. we" (All the Best) *** Dr. A. V. Ramesh Qt (Member) (Dr. A. Ram Gopal) ‘BoS Chairmen UG_Chemistry Andhra University Poge2of 2MODEL PAPER SECOND YEAR B.Se., DEGREE EXAMINATION SEMESTER-LV CHEMISTRY COURSE -IV: INORGANIC, ORGANIC & PHYSICAL CHEMISTRY ‘Time: 3 hours Maximum Marks: 75 PART-A Answer any FIVE of the following questions. Each carries FIVE marks 5X5=25 Marks 1. Describe the 18 electron rule for mononuclear and polynuclear metal carbonyls with suitable ‘examples. DSLOBS SOD HSV LO\GS Sy SEITE © Ohodd 18 DIGS DadSTa Nd aersdaOs DSocdSu, 2, What are epimers and anomers? Give examples. DDS SHGaswo See warrTa7 acrrdeaDsoy 3. Discuss isoelectric point and zwitterion. HD DegS PS HOoww fH eoair§ hr SOpoedSw. 4, Discuss the Paul-Kaorr synthesis of heterocyclic compounds. derdd Sock Saytaro TH. Sofia & SOjocbin. 5. Explain Tautomerism shown by nitro alkanes. BUS eps SOj0 erSto0a0d DSOocvdn. 6. Discuss the basic nature of amines. dtag 86S erTDy Oo, 7. Write the differences between thermal and photochemical reactions. a} Ocho S08 Sarabs Wyo SdSs Boros Senso. 8, Define hat capacities and derive Cp~Cv 8 GOBABT}OS 055000, Cp- Cv=R Haw yoidsy, FART-B Answer ALL the questions. Each carries TEN marks 5X10=50 ‘Marks 9 (@). What are organometallic compounds? Write their classification on the basis of type of bonds with examples, 86,5 Se Sven wr Taw? 20d S8o aero OB SMa aerirde Srsor s (or) (b). Discuss the general methods of preparations of mono & bi-nuclear carbonyls of 3d-series. 3d-[BE3 Bink, d8 Cov O Solis SHS Sater Marto dairb HHdo& DS6oeSu. 10 (a). Discuss the ring structure and ring size of glucose. Draw the Haworth structure of glucose. iPS er Sock SO ywo HOcky Soc Sosrerdy WOyoddaw? KpSer Bins SSE, Page 1 of 2Aoyerd; fondo. (or) ().@ Explain Ruff's degradation. OD Gs SHavdy MSCorbsw. (ii) Explain Kiliani- Fischer synthesis, SOc. HAE Sokdass HSCocds, 11(@). What are amino acids? Write any three general methods of preparation of amino acids. dds adres wir Hie? MDs edro STi dar SHdos NEw Hardola Feogsw. (or) Discuss the aromatic character of Furan, Thiophene and. Pyrrole. SES, PICS MEd SBrHS o eISrelS S serard) 6S ordaw. 12(a). Write the mechanism for the following: @Nef reaction (i) Mannich reaction G08 sre88 Sj Dorwisy Bes rsw: OBO SSS Gi) SPOS GO eo (b) (i) Explain Hinsberg separation of amines, Srp a6 Doro S NAS ok Stderooa 2S00cds0. (Gi) Discuss any three synthetic applications of diazonium salts, Bae dL OSero Ts; NBT Sd Loss eMsderos S8zocsSn. 13(a). What is quentum yield? Explain the photochemical combinations of Hydrogen- Chlorine and Hydrogen - Bromine, S0b0 48S warns SSankod SSEorvSn. WEASLES How wGFasSBST soB Sos (or) (®). Define entropy. Describe entropy changes in the reversible and irreversible processes. DOGHA ASsQoHsw? Sew Hoch warssoeicd Bspad" Qos" Sedyos SSdosSm. +45 (All the Best) *** ‘Smt. D. Prasanna s (Blanbe m We (Dr. A. Ram Gopal) BoS Chairman Page 2 of 2MODEL PAPER SECOND YEAR B,Sc., DEREE EXAMINATION SEMESTER-IV CHEMISTRY COURSE V: INORGANIC & PHYSICAL CHEMISTRY Time: 3 hours Maximum Marks: 75 PART- A Answer any FIVE of the following questions. Bach carries FIVE marks 5X 5=25Marks L ‘Write a short note on Jahn-Teller theorem, BS-BQ HGOSO B odo args arctan. Explain Labile and inert complexes. WalrFo Octo aFo Soro DSGoeda0. Explain Job's method for the determination of composition of complexes. Bd AGSOS SOR" HoMoWD AGowoeoerk DSBordzi. '. Explain Gibb’s phase rule. AS) BSH AahSrD) AS6oeSa, Explain any two conductometric titrations. IIrde sosssrsrod IST FoG08d ASSoch0. 5. Write a short aote on Fuel Cells with examples and applications. SOIrOe HPS Sor Hoy SSW Sersorr goss ser Dosw ays wdwan. 1. What is enzyme catalysis? Specify any three factors affecting enzyme catalysis, lysis? 43 61850 OAS? AS d1Sy6ns ardSo Td Larch eoros Beng. PART: B Answer ALL the questions. Each carries TEN marks 5X10=50 Marks . (@). Explain Valence Bond Theory (VBT) in terms of Inner and Outer orbital complexes. Write the limitations of VBT. 0865 HOakd ang HOBO Storr J5Hy Dod HOw) (VBT) DSGordS., VBTSEMAHOA’ wrososw, (@) () Define CFSE. Explain the factors affecting the magnitude of erystal feld splitting energy. CFSE & DS sQortdso9, HBS Als Bas #§ SOSrard ardso Td woreds DS60uS0, . (a). Explain Trans effect. Explain the theories of trans effect. Write any two applications of trans effect. Page 1 of 2Ss 2. Erp SeroDy DSSodAw. EPS) erSo Tas, Hr owWos DACordSw, UrS) HerSo Gs, NBT Tom ELAGWow Sorgsw. (es) (0). @ Write the biological functions of Haemogiobi: and Myoglobin. (ii), Write 2 note on the use of chelating agents in medicines. OLSrFDS Oo Har FS o fs Adoow roto. (BSR Qos FHxOF Soc) STO DVIMOW 2s Ody Typ; aoa. . @). Explain phase diagram of Pb-Ag system, PSP StrQ} GHDIFIoD Pb-Ag SpSgeo MSHSorioao. (or) (b). Explain phase diagram for NaCl-water system. DSP SD} SSANHOD Nacho S{SHso DSSocvsv. |. (a). Define Transport number. Explain the experimental method for the determination of transport umber by Hittor? method. SDSS HoMIJaH DE {DOD HTH HUSor wASoa Somsds QMYoroe grab) MOTO) DSEorvan. (or) (b), State and explain Koblrauseh's law, Write about its applications. 5 oO DoHSND} BOH, DSSocwSn, A OAnasdaren APS} wrainsn. (a), Explain any two methods for the determination of order of a reaction. Dory SPOS) MGowor’s ABar Foch SGcwowk ASEocvaw. @ (b). Derive Michaelis- Meaten equation. ROD. oHS HAIardz SE yBordsw. HOO-Mond Hroso dsp, SSnasSw DSSocS0. +++ {ll the Best) *** toh (Dr. A. Ram Gopal) BoS Chairman UG_Chemistry Andra University Page 2 of 2