Base Whi-Z-Sds

Safety data sheet
according to Regulation (EC) No.1907/2006

and Regulation (EC) No.1272/2008
BASE WHI-Z
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier: BASE WHI-Z
Fatty acids, C16-18, reaction products with diethanolamine
CAS: 91032-08-5
EC: 293-014-3
Index:
REACH: 01-2119979532-28-XXXX
1.2 Relevant identified uses of the substance or mixture and uses advised against:
Base for softener, for natural and synthetic fibers. For professional use only.
1.3 Details of the supplier of the safety data sheet: OFFICINA +39 SRL
VIA MARCONI, 18
13900 BIELLA (BI) - ITALY
Tel. +39 015.8492913
A. Venier
info@officina39.com
1.4 Emergency telephone number: +39.015.8492913
(office hours)
SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture:
The product is not classified as hazardous pursuant to the provisions set forth in Regulation (EC) No.1272/2008 (CLP) (and
subsequent amendments and supplements) and Regulation (EC) No.1907/2006 (REACH regulation).
2.1.1 CLP Regulation (EC) No.1272/2008:
2.2 Label elements
CLP Regulation (EC) No.1272/2008:

Warning:
Wng: Warning
Pictograms:
Cautionary advice:
P201: Obtain instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P233: Keep container tightly closed.
P264: Wash hands and face thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P501: Dispose of contents / container in accordance with the current legislation on waste treatment.
Supplementary information:
EUH210: Safety data sheet available on request.
2.3 Other hazards
Substance PBT: None
Substance vPvB: None
Other hazards:
No other hazards.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
- CONTINUED ON NEXT PAGE -
Printing date: 30/06/2021 Revised: 06/03/2020 Version: 1 Page 1/10

Safety data sheet
BASE WHI-Z
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS (continue)

Chemical description
3.2 Mixtures:
Fatty acids, C16-18, reaction products with diethanolamine 70 - < 80 %

CAS: 91032-08-5
EC: 293-014-3
Index:
REACH: 01-2119979532-28-XXXX
Not
classified
Acetic acid 1-<5%

CAS: 64-19-7
EC: 200-580-7
Index: 607-002-00-6
REACH: 01-2119475328-30-XXXX
Flam. Liq. 3 Skin Corr.
1A
H226 H314
SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures:
By inhalation:
Carry away patient to outside, let him rest and keep warm.
By skin contact:
Wash immediately with plenty of water for at least 10 minutes.
By eye contact:
Wash immediately with plenty of water for at least 10 minutes.
By consumption:
Do not induce vomiting. SEEK MEDICAL ADVICE IMMEDIATELY, showing the safety data sheet.
4.2 Most important symptoms and effects, both acute and delayed:
None.
4.3 Indication of any immediate medical attention and special treatment needed:
Treatment: None.
SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media:
SUITABLE EXTINGUISHING EQUIPMENT
Water spray, carbon dioxide (CO2).
UNSUITABLE EXTINGUISHING EQUIPMENT

Jets of water.
5.2 Special hazards arising from the substance or mixture:

Safety data sheet
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SECTION 5: FIREFIGHTING MEASURES (continue)

In case of fire acroleins, carbon oxides, nitrogen oxides can be released. Do not breathe fumes.
5.3 Advice for firefighters:
Use appropriate respiratory apparatus.
Pick up separately contaminated water used to extinguish fire.
Do not discharge it in sewerages.
If possible, move from immediate danger area containers not damaged.
Additional provisions:
No information.
SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:
Wear personal protection equipment.
Remove persons to safety.
See protective measures under point 7 and 8.
6.2 Environmental precautions:
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
Suitable material for taking up: absorbing material, organic, sand.

6.3 Methods and material for containment cleaning up:
Wash with plenty of water.
6.4 Reference to other sections:
See sections 8 and 13.
SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling:
Avoid contact with skin and eyes, inhalation of vapours and mists.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
7.2 Conditions for safe storage, including any incompatibilities:
Incompatible materials:
None in particular. See also section 10.
Instructions as regards storage premises:

Adequately ventilated premises.
7.3 Specific end use(s):
None in particular.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:
Substances whose occupational exposure limits have to be monitored in the work environment.
Environmental limits:
* Acetic acid
TLV-TWA: 10 ppm 25 mg/m³

TLV-STEL: 20 ppm 50 mg/m³

Safety data sheet
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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continue)
DNEL (Workers):
* Fatty acids, C16-18, reaction products with diethanolamine
Short exposure - Systemic:

Oral: Non-applicable
Dermal: 167 mg/kg
Inhalation: 294 mg/m³
Short exposure - Local:

Dermal: Non-applicable
Inhalation: Non-applicable
Long exposure - Systemic:

Dermal: 13,9 mg/kg
Inhalation: 24,5 mg/m³
Long exposure - Local:

* Acetic acid




DNEL (Population):

Oral: 100 mg/kg
Dermal: 100 mg/kg


Safety data sheet
BASE WHI-Z
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continue)

Oral: 8,33 mg/kg
Dermal: 8,33 mg/kg
Inhalation: 14,7 mg/m³

PNEC:
* Acetic acid
STP: 85 mg/l
Soil: 0,47 mg/kg
Intermittent: 30,58 mg/l
Fresh water: 3,058 mg/l
Marine water: 0,3058 mg/l
Sediment (fresh water): 11,36 mg/kg
Sediment (marine water): 1,136 mg/kg
8.2 Exposure controls:
No PPE are required under normal use conditions, we recommend the use of them in emergency situations.
To avoid getting dirty, it is recommended to use basic Personal Protection Equipment listed below, with the corresponding "CE
marking" (Regulation (EU) 2016/425).
For more information on Personal Protection Equipment (storage, use, cleaning, maintenance, class of protection, etc...) consult the
information leaflet provided by the manufacturer.
Information contained in this point refer to pure product.
Protection measures for diluted product may vary according to its dilution degree, use, method of application, etc...
To determine the requirement of emergency showers installation and / or collyrium in warehouses will take into consideration the
rules of chemicals storage applied to each case. For more infomation see subsection 7.1 and 7.2.
* Additional emergency measures:

It is not necessary to take additional emergency measures.
Specific protection for the hands

Not needed for normal use. Anyway, operate according good working practices.
Ocular and facial protection

Not needed for normal use. Anyway, operate according good working practices.
Bodily protection
Work clothing.
Respiratory protection
Not necessary for normal use.
Environmental exposure controls:
None. Use this product according to good hygiene practices and workplace safety.
Volatil organic compounds:
Information not available.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Safety data sheet
BASE WHI-Z
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continue)

9.1 Information on basic physical and chemical properties:
Appearance Flakes
Colour Yellowish
Odour Characteristic
Odour threshold Non-applicable
pH Non-applicable
Melting or freezing point Non-applicable °C
Initial boiling point and boiling range Non-applicable °C
Flammability of solids and gases Non-applicable
Lower/upper flammability or explosion limit Non-applicable
Flash point Non-applicable °C
Evaporation rate Non-applicable
Vapour pressure Non-applicable
Vapour density Non-applicable
Relative density Non-applicable
Solubility in water Non-applicable
Solubility in oil Non-applicable
Partition coefficient n-octanol/water Non-applicable
Autoignition temperature Non-applicable °C
Decomposition temperature Non-applicable °C
Viscosity Non-applicable
Explosive properties None
Comburent properties None
9.2 Other information:
Miscibility Non-applicable
Liposolubility Non-applicable
Conductivity Non-applicable
Substance groups relevant properties Non-applicable
SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity:
Stable under normal conditions.
10.2 Chemical stability:
10.3 Possibility of hazardous reactions:
None.
10.4 Conditions to avoid:
10.5 Incompatible materials:
Avoid contact with strong oxidising agents.
10.6 Hazardous decomposition products:
In case of overheating and fire, irritating/toxic gases/vapoures can form.
SECTION 11: TOXICOLOGICAL INFORMATION

The experimental information related to the toxicological properties of the mixture itself is not available.
11.1 Information on toxicological effects:
Dangerous health implications:
In case of exposure that is repetitive, prolonged or at concentrations higher than the recommended occupational exposure limits,

Safety data sheet
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SECTION 11: TOXICOLOGICAL INFORMATION (continue)

adverse effects on health may result, depending on the means of exposure:
A - Ingestion:
- Acute toxicity: Based on available data, the classification criteria are not met.
- Corrosivity/Irritability: Based on available data, the classification criteria are not met.
B - Inhalation:
- Acute toxicity: Based on available data, the classification criteria are not met.
- Corrosivity/Irritability: Based on available data, the classification criteria are not met.
C - Contact with the skin and the eyes:

- Contact with the skin: Based on available data, the classification criteria are not met.
- Contact with the eyes: Based on available data, the classification criteria are not met.
D - CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):

- Carcinogenicity: Based on available data, the classification criteria are not met.
- Mutagenicity: Based on available data, the classification criteria are not met.
- Reproductive toxicity: Based on available data, the classification criteria are not met.
E - Sensitizing effects:
- Respiratory: Based on available data, the classification criteria are not met.
- Cutaneous: Based on available data, the classification criteria are not met.
F - Specific target organ toxicity (STOT) - single exposure:

Based on available data, the classification criteria are not met.
G - Specific target organ toxicity (STOT) - repeated exposure:

- Specific target organ toxicity (STOT) - repeated exposure: Based on available data, the classification criteria are not met.
- Skin: Based on available data, the classification criteria are not met.
H - Inhalation hazard:
Based on available data, the classification criteria are not met.
Specific toxicology information on the substances:

* Acetic acid
Acute toxicity:
LD50, oral, rat: 3310 mg/kg
Skin corrosion/irritation:
Corrosive to skin, rabbit: positive
Eye damage/irritation:
Corrosive to eyes, rabbit: positive
Skin sensitization:
Skin sensitisation: negative
Acute toxicity:
LD50, oral, rat: >2000 mg/kg (OECD 423)
LD50, dermal, rat: >2000 mg/kg (OECD 402)
Skin corrosion/irritation:
Skin irritant, rabbit: negative
Eye damage/irritation:
Eye irritant, rabbit: negative
Skin sensitization:
Skin sensitisation, guinea pig: negative

Safety data sheet
BASE WHI-Z
SECTION 11: TOXICOLOGICAL INFORMATION (continue)
SECTION 12: ECOLOGICAL INFORMATION

Use this product according to good working practices. Avoid littering.
12.1 Toxicity:
Acute aquatic toxicity:

Fish, LC50: >100 mg/l (96 h) (OECD 203)
Chronic aquatic toxicity:

Daphnia, NOEC: >100 mg/l (48 h) (OECD 202)
Algae, NOEC: >100 mg/l (72 h) (OECD 201)
* Acetic acid
Acute aquatic toxicity:

Fish, LC50: >300,82 mg/l (96 h) (OECD 203)
Daphnia, EC50: >300,82 mg/l (48 h) (OECD 202)
Algae, EC50: >300,82 mg/l (72 h)
12.2 Persistence and degradability:

* Acetic acid
Biodegradability: Readily biodegradable

96 %
12.3 Bioaccumulative potential:

Non-applicable.
12.4 Mobility in soil

Non-applicable.
12.5 Results of PBT and vPvB assessment:

vPvB Substances: None
PBT Substances: None
12.6 Other adverse effects:

None.
SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods:
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the
local and national regulations currently in force.
For the manipulation and the provisions in case of accidental dispersion of waste the indications are worth in general furnished to the
sections 6 and 7.
Return the containers to supplier.
Cautions and specific actions must be valued in relationship to the composition of the waste.
* Waste management (disposal and evaluation):

Consult the authorized waste service manager on the assessment and disposal operations, in accordance with Regulation (EU) No.
1357/2014 (for the classification of waste) and Directive 2014/955/UE. We do not recommended disposal down the drain. See
paragraph 6.2.

Safety data sheet
BASE WHI-Z
SECTION 13: DISPOSAL CONSIDERATIONS (continue)

* Regulations related to waste management:
In accordance with Annex II of Regulation (EC) No. 1907/2006 (REACH) the community or state provisions related to waste
management are stated.
- Community legislation:
Directive 2014/955/UE, Regulation (EU) No. 1357/2014
SECTION 14: TRANSPORT INFORMATION

This product is not dangerous for transport (ADR/RID, IMDG, IATA).
SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
Regulation (EC) No. 1907/2006 (REACH)
Regulation (EC) No. 1272/2008 (CLP)
Regulation (EC) No. 790/2009 (ATP 1 CLP) and (UE) N. 758/2013
Regulation (UE) No. 2020/878
Regulation (UE) No. 286/2011 (ATP 2 CLP)
Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII, REACH):
Information not available.
Specific provisions in terms of protecting people or the environment:
It is recommended to use the information included in this safety data sheet as data used in a risk evaluation of the local
circumstances in order to establish the necessary risk prevention measures for the manipulation, use, storage and disposal of this
product.
Other legislation:
Regulation (EC) No. 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and
packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation
(EC) No. 1907/2006.
Chemical safety assessment:
No chemical safety assessment has been processed for the mixture.
A chemical safety assessment has been performed for the following contained substances:
Acetic acid
SECTION 16: OTHER INFORMATION

Legislation related to safety data sheets:
This safety data sheet has been designed in accordance with annex II-Guide to the compilation of safety data sheets of Regulation
(EC) No. 1907/2006 (Regulation (EC) No. 830/2015).
Modifications related to the previous security card which concerns the ways of managing risks:
Texts of the legislative phrases mentioned in sections 2 and 3:

Safety data sheet
BASE WHI-Z
SECTION 16: OTHER INFORMATION (continue)

Flam. Liq. 3: Flammable liquid, category 3
Not classified: Not classified
Skin Corr. 1A: Skin corrosion, category 1A
H226: Flammable liquid and vapour.
H314: Causes severe skin burns and eye damage.
Advice related to training:

Minimal training is recommended to prevent industrial risks for staff using this product, in order to facilitate their comprehension and
interpretation of this safety data sheet, as well as the label on the product.
Principal bibliographical sources:
http://echa.europa.eu
http://eur-lex.europa.eu
Note for users:

The information contained in the present sheet are based on our own knowledge on the date of the last version.
Users must verify the suitability and thoroughness of provided information according to each specific use of the product.
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the
current health and safety laws and regulations.
The producer is relieved from any liability arising from improper uses.
Abbreviations and acronyms:

- ADR: European agreement concerning the international carriage of dangerous goods by road
- IMDG: International maritime dangerous goods code
- IATA: International Air Transport Association
- ICAO: International Civil Aviation Organisation
- COD: Chemical Oxygen Demand
- BOD5: 5-day biochemical oxygen demand
- BCF: Bioconcentration factor
- LD50: Lethal Dose 50
- CL50: Lethal Concentration 50
- EC50: Effective concentration 50
- Log-POW: Octanol–water partition coefficient
- Koc: Partition coefficient of organic carbon
The information contained in this security data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to guarantee its
accuracy. This information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and
conditions for users of this product are not within our awareness or control, and is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements
concerning the manipulation, storage, use and disposal of chemical products. The information on this security data sheet only refers to this product, which should not be used for needs
other than those specified.
- END OF SAFETY DATA SHEET -

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Safety data sheet

according to Regulation (EC) No.1907/2006

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

SECTION 2: HAZARDS IDENTIFICATION

CLP Regulation (EC) No.1272/2008:

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

- CONTINUED ON NEXT PAGE -

Printing date: 30/06/2021 Revised: 06/03/2020 Version: 1 Page 1/10

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS (continue)

Fatty acids, C16-18, reaction products with diethanolamine 70 - < 80 %

Acetic acid 1-<5%

SECTION 4: FIRST AID MEASURES

SECTION 5: FIREFIGHTING MEASURES

UNSUITABLE EXTINGUISHING EQUIPMENT

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SECTION 5: FIREFIGHTING MEASURES (continue)

SECTION 6: ACCIDENTAL RELEASE MEASURES

Suitable material for taking up: absorbing material, organic, sand.

SECTION 7: HANDLING AND STORAGE

Instructions as regards storage premises:

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

TLV-TWA: 10 ppm 25 mg/m³

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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continue)

Short exposure - Systemic:

Short exposure - Local:

Long exposure - Systemic:

Long exposure - Local:

Short exposure - Systemic:

Short exposure - Local:

Long exposure - Systemic:

Long exposure - Local:

Short exposure - Systemic:

Short exposure - Local:

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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continue)

Long exposure - Local:

* Additional emergency measures:

Specific protection for the hands

Ocular and facial protection

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continue)

SECTION 10: STABILITY AND REACTIVITY

SECTION 11: TOXICOLOGICAL INFORMATION

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SECTION 11: TOXICOLOGICAL INFORMATION (continue)

C - Contact with the skin and the eyes:

D - CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):

F - Specific target organ toxicity (STOT) - single exposure:

G - Specific target organ toxicity (STOT) - repeated exposure:

Specific toxicology information on the substances:

* Fatty acids, C16-18, reaction products with diethanolamine

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SECTION 11: TOXICOLOGICAL INFORMATION (continue)

SECTION 12: ECOLOGICAL INFORMATION

Acute aquatic toxicity: