Professional Documents
Culture Documents
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Content
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1.0 Introduction
The DryEGCS –
an option to comply with
IMO regulations
Couple Systems was founded in Germany in 2007 and focused Very stringent regulations for the reduction of emissions, in par-
on environmental technologies for international maritime ship- ticular for shipping operations in Europe, were compiled and
ping. refined in Marpol Annex VI by the IMO. These, however, are still
moderate compared to regulations on land.
Its’ mission is to become the technology leader for exhaust gas
cleaning systems in the marine industry within the next five In order to conform to legally binding obligations, the use of
years. low sulphur fuel (LSFO) is one of two options. Indeed the avai-
lability of crude oil with a low sulphur content will become
Couple Systems’ business is innovation, development, manu- more and more limited. The desulphurization process of the
facture and marketing of exhaust gas cleaning systems for the crude oil in the refinery is very costly with regard to the process
reduction of emissions of ships. and energy requirements. Therefore low sulphur fuel (LSFO) is
exorbitantly more expensive than heavy fuel oil (HFO).
The company to date has a financial equity of 2.5 mill. Euro. But
much more important is the equity the company has in form of The mineral oil industry has clearly stated that the necessary
its extraordinary team which has more than 25 years of suc- refinery capacity to implement the legislation cannot be crea-
cessful experience in engineering of all kinds of industrial flue ted before 2020. Independently of this, costs of 180 billion US
gas cleaning systems. This is absolutely unique in the shipping dollars are quoted for building such a capacity.
industry!
The question thus is whether the oil industry is willing
The environmental stress from the heavy fuel oil in shipping to invest that kind of money in a product of compara-
(HFO) has captured the media headlines. The focus lies particu- tively very low value? In view of these circumstances
larly on sulphur oxide emissions since the traffic and transport it is legally and economically expedient for the ship
sector shipping is the biggest polluter in absolute numbers. owners to fit exhaust gas cleaning systems.
In order to also effectively reduce the emissions from For this reason IMO has adapted the regulations specifically
shipping operations, IMO, EU and i.e. the California Air with regard to performance, proof, certification, operation and
Resources Board (CARB) have taken action. monitoring, and permitted exhaust gas cleaning systems.
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Couple Systems has developed a very effective ex-
haust gas cleaning system for marine diesel engines,
the DryEGCS.
With the DryEGCS the ship owner can sail anywhere in the
world using the significantly less expensive heavy fuel oil, at the
same time meeting the legal limit values and complying with Successfull
the most stringent environmental regulations! P
Inst
ilo
Dryallation of
t
b us
en
So better be prepared! O
9%
S
red
uction of 9
x
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2.0 Legislation
Shipping is the most important means of transportation today less than 0.1 % sulphur by mass for vessels berthed in ports
and most probably also for the next decades. In addition, com- of the European Community. But also non-EU members of the
pared to other means of transportation (air planes, trucks, rails); European Economic Areas (EEA), which include Norway and
shipping is the most energy-efficient transport system. Approxi- Iceland, have agreed to enact legislation similar to that passed
mately 90 % of the global cargo is moved by vessels powered in the EU for social policy, consumer protection, environment,
by large diesel engines which are fueled with residual fuel oils. company law and statistics. Port authorities have started enfor-
However, the use of residual fuel oils in excess of more than cing the directive by applying severe fines.
300 mill. tons per year causes environmental issues which need
to be solved. The IMO updated the Annex VI of the MARPOL
convention in October 2008 in order to regulate emissions 2.2 IMO MARPOL Annex VI
generated by vessel engines. The focus is now on the global
reduction of pollutants such as nitrogen oxides (NOx), sulphur In some countries, port and local authorities offer a reduction
oxides (SOx) and particulate matter (PM). of port and fairway fees depending on the amount of emissions
produced by vessels, which means that fewer emission leads to
The EU Directive 2005/33/EC stipulates the use of fuel which lower fees. California for example has implemented limitations
contain less than 0.1 % sulphur by mass for vessels berthed for SOx emissions within 24 nautical miles of the coast. Beeing
in ports of the European Community. Both regulations, the in effect from January 1st, 2012 fuel must not exceed a 0.1 %
MARPOL Annex VI and the EU Directive 2005/33/EC specifically sulphur content.
permit the use of emission abatement technologies which pro-
vide emission reductions at least equivalent to, or even greater The goal of limiting the emissions of SOx can be achieved by
than, those achievable using low sulphur fuel. applying primary and secondary actions technology. In order to
meet the legal restraints the usage of low sulphur fuel (primary
action) is an option. However, there is limited availability of na-
2.1 EU Directive 2005/33/EC turally low sulphur fuel and the refinery process for desulphuri-
zation of high sulphur fuel is costly in reference to the process
The EU Directive 2005/33/EC, which came into effect on Ja- itself and its energy consumption. This makes the low sulphur
nuary 1st, 2010, clearly indicates that emissions from shipping fuel more expensive and it is currently unclear if low sulphur
due to the combustion of marine fuels with a high content of fuel is available at the requested volume.
sulphur contribute to air pollution in the form of sulphur di-
oxide and particulate matter, harming human health, dama- Under these conditions it is quite reasonable to specify secon-
ging the environment, public and private property and cultural dary actions, especially as the IMO has recently adopted gui-
heritage, and contributing to acidification. Furthermore, it says delines providing regulations for performance; verification,
that human beings and the environment in coastal areas and in certification, operation and documentation of SOx scrubbers
the vicinity of ports are particularly affected by pollution from (see MEPC184). The SECA Compliance Plan (SCP) describes
ships using fuels high in sulphur. Since January 1st, 2010 the EU methods for compliance by each ship using scrubbers rather
Directive 2005/33/EC regulates the use of fuels which contains than low-sulphur fuel.
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CARB – California Air Resources Board
Particulate Matter
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Sulphur Oxides
Sulphur is a natural compound of crude oil and it appears in Normally, lime based materials such as calcium carbonate
different concentrations depending on the source of the crude (CaCO3), burnt lime (CaO) or hydrated lime [Ca(OH)2] are utilized.
oil. It can be as high 6 vol. %. The sulphur is chemically bound In principal it would be possible to use water as an absorbing
to the hydrocarbons of the oil. The binding energy is quite high agent. But the solubility of SO2 in water is rather low (@ 20°C
which makes it so as difficult and energy consuming to separa- and 1 bar maximum 35 m³ SO2 in 1 m³ water). Because of this
te the sulphur from the hydrocarbons. low physical solubility of SO2 in water, which worsen at lower
pH-values alkaline reacting solutions such as limestone suspen-
During the combustion process inside the engine the sulphur sions are forced to react with acidic components of the flue gas
is oxidized to SO2 (app. 95 to 98 %) and SO3 (app. 2 to 5 %). with the final result of a chemical absorption.
A fraction of the SOx reacts to sulfates and turns into particular
matter but the major part appears as gaseous SO2 and SO3 in Other than limestone based systems desulphurization is also
the exhaust gas. feasable on water based processes. So called Dry Scrubber and
Wet Scrubber are available for operation on board of vessels.
The large-scale proven processes for the desulphurization of
exhaust gases are currently based on absorptive processes.
CARB MDO: 2.0 > 0.5 > 0.1 Global: 4.5 > 3.5 > 0.5
CARB MGO: 1.5 > 1.5 > 0.1 EU Direktive: 0.1
ECA: 1.5 >1.0 > 0.1
5.0
Global Possible
4.5 Reduced initially to 3.50 % (from the current wi
t
4.50 %), effective from 1 January 2012; then pro-
h
gressively to 0.50 %, effective from 1 January 2020, Inst
Dryallation of
4.0
subject to a feasibility review to be completed no
later than 2018.
EGC
3.5
S
3.0 on
CARB MDO you
r sh i p
Sulphur Content in Fuel [% m / m]
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3.0 Dry Exhaust Gas
Cleaning System (DeSOx)
3.1 The DryEGCS
The DryEGCS technology was especially developed for the ma- The chemical reaction is shown in the following equations:
ritime industry to clean the exhaust gas of vessels based on a
dry desulphurization process onboard. This system is adapted Ca(OH)2 SO2 ½ O2 CaSO4 H2O
from land-based applications and calcium hydroxide [Ca(OH)2] Ca(OH)2 SO3 H2O CaSO4 2 H2O
in granulate form is used for the absorptive process.
The absorption of sulphur oxides leads to calcium sulphate,
This proven technology removes more than 99 % of the sulphur which is normally known as gypsum.
oxides (SOx) from the exhaust gas.
page 18
SCR (DeNOx)
Absorber
Bybass Damper
Pneumatic Conveying
Flexible Pipeline
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The DryEGCS is directly integrated downstream the turbo char- The system can also be run at lower temperatures but at the
ger and can be operated at temperatures between 240 - 450°C. cost of a higher consumption of granulate.
As the absorption process is an exothermic reaction, there is no
temperature loss of the exhaust gas. This means that boilers The figure (Schematic design of DryEGCS) shows a schema-
and economizers can be operated while the DryEGCS is in use. tic design of the DryEGCS process. The exhaust gas enters the
absorber and flows horizontally through a packed-bed made
of granulate. A specific design inside the absorber guarantees
the chemical reaction of the exhaust gas with the granulate.
The absorber removes rough sooty particles and other residues
from the exhaust gas and thus acts as particle filter as well.
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3.2 Consumables
Apart from electrical power, the DryEGCS only requires calcium be assigned geographically, close to the global bunker ports
hydroxide in the form of spherical granulate as an operating where the merchant ships are supplied with granulate. Both
resource. A global availability of the granulate is ensured by power plants and lime plants are located worldwide within a
Couple Systems. Production licenses for additional capacity can radius of 200 km from all major ports.
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4.0 Pilot MV Timbus
Braren, the company owning the ship, based in Kollmar, Ger-
many has made a container ship available to Couple Systems
for a pilot project.
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6.0 Selective Catalytic
Reduction – SCR (DeNOx)
6.1 Reduction of Nitrogens (TIER III)
As of January 1st 2016 in ECAs TIER III has to be achieved which which reduce the temperature of the combustion process and
is currently only manageable by applying the SCR Technology thereby also the formation of thermal NOx. With these kinds of
(Selective Catalytic Reduction). Therefore Couple Systems offers engine modifications Tier I and Tier II can be achieved reliably.
the integration of SCR technology as an option.
In a SCR process nitrogen oxides are reacted stoichiometrically
NOx is a generic term for mono-nitrogen oxides (NO and NO2). with ammonia or urea as reducing agent to form nitrogen
These oxides are produced during combustion, especially com- (N2) and water vapour (H2O) which occurs naturally in the
bustion at high temperatures. atmosphere.
The NOx fraction of the exhaust gas of diesel engine usually The SCR process is sensitive to the presents of sulphur oxides
consists of 95 % NO and 5 % NO2. Currently there are several which can react with the NH3 to ammonium hydrogen sulfate
technologies available such as Exhaust Gas Recycling (EGR), (NH4HSO4) which can clog the surface of the SCR and thus
Fuel Water Emulsion (FWE), and Humid Air Motor (HAM) reduce the efficiency of the SCR.
Compressed Air
Dosing Unit
page 10
Dry EGCS
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Therefore the combination of a desulphurization plant such as Additionally, the SCR process is extremely flexible concerning
DryEGCS with a downstream installed SCR is a preferred option flow rates and flue gas compositions with the exception of
both technically and economically. high contents of sulphur oxides, heavy metals and dust load.
The SCR process reliably achieves a reduction level of nitrogen The SCR technology is applied in a couple of thousands of
oxides by means of the reactions shown in a broad temperature combustion processes on land and has proven its long-term
range between about 280 °C and just below 600 °C, depen- efficiency. More than 300 SCR systems are currently operated
ding on exhaust gas conditions and catalyst type. onboard of vessels.
The selection and the combination of metal oxide catalysts such Couple Systems’ R & D program incorporates the optimization
as vanadium pentoxide, titanium dioxide, aluminum oxide and of conventional SCR technology as well as the development of
others secures NOx conversions of well above 90 %. new catalysts meeting the demands of the shipping industry
more effectively.
N2 and H2O
Control Cabinet
Extrudates or
coated ceramic
honeycomb
Urea Tank elements
Mixing Element
Dosing Pump
Urea Injection
NOx
Exhaust Gases
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6.2 DryEGCS in combination with SCR
In case a selective catalytic reduction for the NOx removal of the Beside the benefit of the energy saving for the reheating it is
exhaust gas is required this unit will be installed downstream also possible to operate a smaller and higher active catalyst
the DryEGCS without any additional reheating. and prolong its lifetime significantly.
bypass
sorption material
silo
shut down
fan optional adapter funnel
M discharge
reaction
product
Flow Chart of DryEGCS in combination with a SCR
engine
Effective as of August 1st, 2010, MAN Diesel & Turbo and Emissions of SOx are solely a function of the sulphur content in
Couple Systems agreed to further extend their already existing the fuel burnt and cannot be influenced by the engine builder
development partnership and added a close marketing coope- using primary measures in the combustion chamber. Thus, only
ration partnership to it. secondary measures are available to combat SOx i.e. fuel condi-
tioning and after treatment.
After a three-year-development period the DryEGCS is ready
for the market! The object of the new agreement is the mar- Using heavy fuel oil to benefit from the prize gap to low sulphur
keting and selling of the DryEGCS into the shipping industries. distillates requires an after treatment measure, which is able to
not only meet the legislation but also allows to very economi-
cally operate a vessel. A proven way of after treatment is the
absorption of SOx in reactors using limestone. The DryEGCS is
reaching an efficiency of about 99%. The DryEGCS technique is
neutral to the exhaust gas temperature and allows the operati-
on of the SCR in the cleaned exhaust gas afterwards.
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The constant high temperature level of the DryEGCS permits The discharged residues are disposed of to land-based applica-
the installation at the bottom of the vessel which gives ad- tions i.e. power plants where they are used as valuable consu-
vantages regarding stability and impact on cargo space. The mable additive in the burning process.
reactor itself contains the packed-bed granulate. The exhaust
gas passes through the absorber and the SOx reacts with the MAN Diesel & Turbo offers the DryEGCS which removes the
granulate (limestone) to gypsum. The granulate runs through sulphur permanently from the biosphere.
the system by gravity and is extracted as residue on a frequent
basis. DryEGCS − another important step to a greener future.
The residues can be stored i.e. in spare rooms within the hull
which allows an optimized installation to reduce the impact
on valuable spaces like cargo or passenger areas onboard of
the vessel. In the harbor, the residues will be replaced by fresh
granulate.
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8.0 Logistic of Granulate
8.1 Supply
Lime plants produce the special hydroxide granulate for the • Silo Tuck • Big Bags • Special DryEGCS Containers.
DryEGCS which is then transported by silo trucks to large sto-
rage silos near important harbors. These logistic centers will The ship owning companies will be able to coordinate the sup-
secure adequate supply of the granulate to fill either: ply and disposal of granulate with the Logistic Centers.
Lime Plant
8.2 Disposal
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Residue Recycling
building material
Gypsum
for plaster boards
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9.0 FAQ
9.1 DryEGCS Performance
What is the maximum % of sulphur fuel allowable to What size of engine was DryEGCS fitted to (MW)?
achieve emissions equivalent to a 0.1% sulphur fuel? 3.6 MW main engine of MV Timbus.
Up to 4.5%. In the DryEGCS-Process Ca(OH)2 (Calcuim When were the units fitted and how long have they
hydroxide) reacts with sulphur oxide to gypsum. The higher been operated (h)?
the sulphur content, the higher the consumption of the October 2009, 3000 h operating hours to date and it is still
calcium hydroxide granulate. operating
What % of particulate matter is removed? On what type of vessel and where have they been
80 % of particulate matter is removed. operating?
Freighter, 6389 tdw, Baltic and Northern Sea (ECA)
Can DryEGCS be combind with SCR technology?
DryEGCS can be combined with a SCR-System. The DeNOx What is the maximum and typical % of sulphur fuel
System can remove 90 % of NOx. that has been in use?
Maximum: 1,78 % of sulphur in fuel, typical 0.94 % of
Can boilers and economizers be used in connection sulphur in fuel
with DryEGCS?
Yes, since the loss of temperature is negligible. Has the emissions to air performance of onboard
EGCS units been independently verified and results
Does DryEGCS removed CO2? published?
DryEGCS is able to remove CO2 up to 15 %. Yes, GL emission report, Approval- No. 97248-10 HH
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9.4 Mechanical
What medium is used for scrubbing (e.g. seawater, What is the in-service (i.e. filled) weight of the
freshwater and chemical, dry chemical)? DryEGCS units (t)? Please advise for 1MW and
Ca(OH)2 - calcium hydroxide 20MW units (or biggest in your range).
1 MW: 24 t fill; 9 t light
For the following please assume 2.7 % of residual 20 MW: 294 t fill; 116 t light
sulphur fuel: What is the consumption of dry chemi-
cals (kg/h/MW)? Where are the DryEGCS units normally fitted (e.g. in
With an estimated specific fuel oil consumption of 200 g/ funnel, outside funnel etc)?
kWh and 2.7% sulphur content the calcium hydroxide con- DryEGCS could in variable positions on the vessel.
sumption will be approx. 16 kg/h/MW. The connetion of the system to the engines ductwork directly
after the turbocharger.
Are there any other consumables associated with
the actual process of scrubbing? If so please advise How many exhausts per DryEGCS unit?
what and the consumption rate. Multi stream is possible, i.e. one main engine plus three aux.
There are no other consumables used. engines.
What is the EGC system’s typical power consumption Assuming a 2.7 % sulphur fuel and continuous ope-
(EGC system power consumption kW/ engine MW)? ration over a one month period. What storage capa-
1.5 - 2 kW/engine MW (min. 15 - 20 kW) city/tankage is required (m3/MW) for calcium hydro-
xide granulate?
What is the size range of engines that can be cur- Density of Ca(OH)2 in spherical form is approx. 800 kg/m³
rently scrubbed (MW)? With an estimated operating time of 720 h (30d*24h) there
1 - 36 MW should be a capacity of 14.4 m³/MW.
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9.5 Supply and Installation
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Managing Directors
Jan Hafkemeyer
Olaf Knueppel
www.couple-systems.com
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Why to apply the DryEGCS -
on board of my ships?
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