Aldehyde, Ketone Jee 5 Years MCQ

Physical World, Units and Measurements P-1
Aldehydes, Ketones
and Carboxylic Acids
Numerical
Q.1.
JEE Main 2023 (Online) 12th April Morning Shift

The value of X in compound 'D' is _________.
Q.2. The mass of NH3 produced when 131.8 kg of
cyclohexanecarbaldehyde undergoes Tollen's test is ________ kg.
(Nearest Integer)
Molar Mass of
C = 12g/mol
N = 14g/mol
O = 16g/mol
Q.3.
The ratio x/y on completion of the above reaction is __________.
Q.4. Among the following, the number of compounds which will
give positive iodoform reaction is _________
(a) 1-Phenylbutan-2-one
(b) 2-Methylbutan-2-ol
(c) 3-Methylbutan-2-ol
(d) 1-Phenylethanol
(e) 3,3-dimethylbutan-2-one
(f) 1-Phenylpropan-2-ol
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Q.5. Number of isomeric compounds with molecular

formula C9H10O which (i) do not dissolve in NaOH (ii) do not
dissolve in HCl. (iii) do not give orange precipitate with 2,4-DNP
(iv) on hydrogenation give identical compound with molecular
formula C9H12O is ____________.
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Q.6. The number of molecules which gives the haloform test
among the following molecules is ________.
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Q.7. umber of compounds from the following which will not

dissolve in cold NaHCO3 and NaOH solutions but will dissolve in
hot NaOH solution is ________.
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Q.8. A trisubstituted compound 'A', C10H12O2 gives

neutral FeCl3 test positive. Treatment of compound 'A'
with NaOH and CH3Br gives C11H14O2, with hydroiodic acid gives
methyl iodide and with hot conc. NaOH gives a
compound B,C10H12O2. Compound 'A' also decolorises
alkaline KMnO4. The number of π bond/s present in the
compound 'A' is________.
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Q.9. Number of compounds giving (i) red colouration with ceric

ammonium nitrate and also (ii) positive iodoform test from the
following is ___________
Answer Key & Explanation
1. Ans. Correct answer is 15

Explanation
Explanation
Explanation
For completion of reaction, we need 2 moles of MeMgBr per mole

of reactant
1 mole for nucleophilic addition and 1 mole for acid base reaction.
Explanation
2 possibilities
Explanation
7.Ans. Correct answer is 3

Explanation
will dissolve in hot NaOH solution.

Explanation
Explanation
The compounds which give red colour with ceric ammonium
nitrate and also give positive iodoform test are
MCQ (Single Correct Answer)
Q.1.
'A' formed in the above reaction is

Q.2. In the reaction given below

Q.3.
The products formed in the above reaction are

Q.4.
'A' in the above reaction is:

Q.5. In the following reaction
'A' is
Q.6. The major product 'P' formed in the following sequence of

reactions is
Q.7. The major product formed in the following reaction is
Choose the correct answer from the options given below :

Q.8. Given below are two statements, one is labelled as Assertion

A and the other is labelled as Reason R.
In the light of the above statements, choose the correct answer

from the options given below:
Q.9.
'A' and 'B' in the above reactions are:

Q.10. L-isomer of tetrose X(C4H8O4) gives positive Schiff's test and

has two chiral carbons. On acetylation, 'X' yields triacetate. 'X' also
undergoes following reactions
'X' is
Q.11. In the reaction given below:

The product 'X' is:
Q.12. The major product 'P' formed in the given reaction is

Q.13. Major product 'P' formed in the following reaction is:

Q.14. A compound 'X' when treated with phthalic anhydride in

presence of concentrated H2SO4 yields 'Y'. 'Y' is used as an
acid/base indicator. 'X' and 'Y' are respectively

Q.15. The major product formed in the following reaction is:
Q.16. Match List I with List II:
LIST I LIST II (Compound with

(Reagents Functional group detected)
used)
A. Alkaline I.
solution of
copper
sulphate and
sodium
citrate
B. Neutral FeCl3 II.
C. Alkaline III.
chloroform
solution
D. Potassium IV.
iodide and
sodium
hypochlorite
Choose the correct answer from the options given below:

Q.17. The major products A and B from the following reactions

are:
Q.18. Match List I with List II
Choose the correct answer from the options given below:

Q.19. In a reaction,
reagents 'X' and 'Y' respectively are :
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Q.20. Given below are two statements : one is labelled as

Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : α-halocarboxylic acid on reaction with

dil. NH3 gives good yield of α-amino carboxylic acid whereas the
yield of amines is very low when prepared from alkyl halides.
Reason (R) : Amino acids exist in zwitter ion form in aqueous
medium.

from the options given below :
Q.21. The structures of major products A, B and C in the following

reaction are sequence.
Q.22. Identify the incorrect option from the following
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Q.23. Cyclohexylamine when treated with nitrous acid yields (P).

On treating (P) with PCC results in (Q). When (Q) is heated with
dil. NaOH we get (R) The final product (R) is :
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Q.24. Consider the following reaction
The correct statement for product B is. It is
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Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : Ketoses give Seliwanoff's test faster than Aldoses.
Reason (R) : Ketoses undergo β-elimination followed by

formation of furfural.

Q.26. What is the correct order of acidity of the protons
marked A−D in the given compounds ?
Q.27. Which of the following compounds would give the following

set of qualitative analysis ?
(i) Fehling's Test : Positive
(ii) Na fusion extract upon treatment with sodium nitroprusside

gives a blood red colour but not prussian blue.
Q.28. Find out the major products from the following reaction
sequence.
Q.29. Match List I with List II

Q.30. 'A' in the given reaction is

Q.31. Given below are two statements, one is labelled as Assertion

A and the other is labelled as Reason R
Assertion A : Butylated hydroxy anisole when added to butter

increases its shelf life.
Reason R : Butylated hydroxy anisole is more reactive towards

oxygen than food.
In the light of the above statements, choose the most appropriate

answer from the options given below

Assertion A and the other is labelled as Reason R :
Assertion A : Acetal / Ketal is stable in basic medium.
Reason R : The high leaving tendency of alkoxide ion gives the

stability to acetal/ketal in basic medium.

Q.33. Given below are two statements :

from the options given below:
Q.34. 'R' formed in the following sequence of reactions is :

Q.35. Compound (X) undergoes following sequence of reactions to

give the Lactone (Y).
1. Ans. (A)
Explanation
2. Ans. (D)
Explanation
3. Ans. (B)
Explanation
4. Ans. (C)
Explanation
5. Ans. (D)
Explanation
6. Ans. (D)
Explanation
7. Ans. (B)
Explanation
8. Ans. (B)
Explanation
Wolff-Kishner reduction is not suitable for base sensitive group.
9. Ans. (B)
Explanation
10. Ans. (D)

Explanation
(x) gives positive schiff's test due −CHO group.
(x) is L-tetrose.
11. Ans. (A)
Explanation
12. Ans. (A)

Explanation
KMnO4 oxidises benzylic carbon containing atleast one α-
hydrogen atom to −COOH.
13. Ans. (c)
14. Ans. (B)
Explanation
Phenolphthalein is a commonly used acid/base indicator that can
be synthesized from phthalic anhydride and phenol (carbolic
acid) in the presence of concentrated sulfuric acid (H₂SO₄).
Therefore, compound 'X' is phenol and compound 'Y' is
phenolphthalein.
15. Ans. (D)

Explanation
NaBH4 (Sodium borohydride) is a weak reducing agent, it reduces
aldehydes/ketones but not esters, it produces alcohols through
reduction. ketones reduces to 2∘ alcohol.
Note: Lithium borohydride is commonly used for selective
reduction of esters and lactones to the corresponding alcohol.
16. Ans. (C)
Explanation
(A) Fehling's solution is used to distinguish between aldehyde and
ketone functional groups. Aldehydes oxidize to give a positive
result but ketones won't react to the test (except for α-hydroxy
ketones). Fehling's test is used as a general test for determining
monosaccharides and other reducing sugars.
(B)
(C) This reaction is a chemical test for detection of primary

amines, in which the amine is heated with alcoholic potassium
hydroxide and chloroform. If a primary amine is present, the
isocyanide is formed. The reaction is known as carbylamine
reaction.
(D) When a methyl ketone (even acetaldehyde) is reacted with

halogen in aqueous sodium hydroxide, the ketone gets oxidised to
the sodium salt of acid with one carbon less than ketone and at
the same time haloform (CHX3) also gets formed.
The hydroxide ion acts as a nucleophile and attacks the

electrophilic carbon which is doubly bonded to oxygen. This
carbon-oxygen double bond becomes a single bond making the
oxygen atom anionic.
17. Ans. (B)

18. Ans. (B)
19. Ans. (B)
Explanation
20. Ans. (D)

Explanation
The reaction of α-halocarboxylic acid with dilute ammonia is
known as the haloform reaction. In this reaction, the halogen
atom of α -halocarboxylic acid is replaced by an amino group to
form α -amino carboxylic acid. The yield of α -amino carboxylic
acid is good because the amino group is a better nucleophile than
the halogen atom, and it attacks the carbonyl carbon of the
carboxylic acid to form an intermediate, which is then hydrolyzed
to form the product. On the other hand, when alkyl halides are
reacted with ammonia, the yield of amines is very low because
alkyl halides are less reactive than α -halocarboxylic acids.
The reason (R) is also true. Amino acids exist in the zwitterion
form in an aqueous medium. In this form, the amino group has a
positive charge, and the carboxyl group has a negative charge. The
zwitter ion form is stabilized by the interaction between the
opposite charges, which is known as an electrostatic interaction.
This interaction makes the zwitterion form more stable than the
neutral form.
21. Ans. (A)

Explanation
22. Ans. (C)
Explanation
23. Ans. (B)

Explanation
24. Ans. (C)

Explanation
Racemic mixture effervescence with NaHCO3.
25. Ans. (C)
Explanation
Seliwanoff 's test is a differentiating test for Ketose and aldose.
This test relies on the principle that the keto hexose are more
rapidly dehydrated to form 5-hydroxy methyl furfural when
heated in acidic medium which on condensation with resorcinol,
Cherry red or brown red coloured complex is formed rapidly
indicating a positive test.
26. Ans. (D)
Explanation
Acidity of an acid depends upon the stability of it's conjugate base.
HC > HD > HA > H B
HC is hydrogen of carboxylic acid.
HD removal will lead to stable carbanion.
27. Ans. (A)

Explanation
Aromatic aldehydes do not respond Fehling's test. (B),(C),(D) are
aromatic aldehydes.
If N and S attached with carbon atom give blood red with sodium
nitroprusside gives a blood red colour but not prussian blue.
28. Ans. (B)
Explanation
29. Ans. (A)

Explanation
Correct match is : (A)-III, (B) -IV, (C) -I, (D)-II
30. Ans. (D)
Explanation
31. Ans. (C)

Explanation
Butylated hydroxy anisole is added to butter to increase its shelf
life from months to years as it is more reactive towards oxygen
than food. Therefore, both Assertion and Reason are correct and
Reason is the correct explanation of Assertion.
32. Ans. (D)
Explanation
For Assertion: Acetal and ketals are basically ethers hence they
must be stable in basic medium but should break down in acidic
medium. Hence assertion is correct.
For reason: Alkoxide ion (RO–) is not considered a good leaving

group hence reason must be false.
33. Ans. (C)
Explanation
Statement I is true but statement II is false.

34. Ans. (C)
Explanation
35. Ans. (A)
Explanation
2022
Numerical
Q.1. The number of stereoisomers formed in a reaction of

(±)Ph(C=O)C(OH)(CN)Ph with HCN is ___________.
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Q.2. The spin only magnetic moment of the complex present in Fehling's
reagent is __________ B.M. (Nearest integer).
Q.3. In the given reaction
The number of chiral carbon/s in product A is ___________.

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Q.4. A hydrocarbon 'X' is found to have molar mass of 80. A 10.0 mg of

compound 'X' on hydrogenation consumed 8.40 mL of H2 gas (measured at
STP). Ozonolysis of compound 'X' yields only formaldehyde and
dialdehyde. The total number of fragments/molecules produced from the
ozonolysis of compound 'X' is _____________.
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Q.5. In the given reaction,
The number of π electrons present in the product 'P' is _________.

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Explanation
Number of stereoisomers = 3

Explanation
In the complex present in Fehling's reagent, Cu+2 ion is present.
So, spin only magnetic moment

Explanation
2 chiral carbons are there in product A.

Explanation

Explanation
Q.1. Correct structure of γ-methylcyclohexane carbaldehyde is

Q.2.
Consider the above reaction sequence, the Product 'C' is :

Q.3.
Consider the above reaction, the compound 'A' is :
Q.4. Consider the following reaction sequence:
The product 'B' is :

Q.5.
Find out the major product for the above reaction.

Q.6. The structure of A in the given reaction is :

Q.7. Match List - I with List - II.

List - I List - II
(A) (I) Gatterman Koch reaction
(B) (II) Etard reaction
(C) (III) Stephen reaction
(D) (IV) Rosenmund reaction

Q.8. Hydrolysis of which compound will give carbolic acid?
Q.9.
Q.10. The products formed in the following reaction, A and B are

Q.11. Which reactant will give the following alcohol on reaction with one
mole of phenyl magnesium bromide (PhMgBr) followed by acidic
hydrolysis?

Q.12. What is the major product of the following reaction?
Q.13.
The correct structure of C is

Q.14. Which one of the following reactions does not represent correct
combination of substrate and product under the given conditions?
Q.15. An organic compound 'A' on reaction with NH3 followed by heating

gives compound B. Which on further strong heating gives compound C
(C8H5NO2). Compound C on sequential reaction with ethanolic KOH, alkyl
chloride and hydrolysis with alkali gives a primary amine. The compound A
is :
Q.16. Given below are two statements:

Statement I : On heating with KHSO4, glycerol is dehydrated and acrolein is
formed.
Statement II : Acrolein has fruity odour and can be used to test glycerol's
presence.
Choose the correct option.

Q.17. Consider the given chemical reaction
Identify the product P.

Q.18. Choose the reaction which is not possible:

Q.19. Which among the following will be the major product of the given
reaction?
Q.20.
In the given conversion the compound A is :
Q.21. Given below are two statements :

Statement I : The esterification of carboxylic acid with an alcohol is a
nucleophilic acyl substitution.
Statement II : Electron withdrawing groups in the carboxylic acid will

increase the rate of esterification reaction.
Choose the most appropriate option :

1. Ans. (A)
Explanation
2. Ans. (D)
Explanation
3. Ans. (C)
Explanation
4. Ans. (B)
Explanation
5. Ans. (C)
Explanation
6. Ans. (C)
Explanation
7. Ans. (A)
Explanation
8. Ans. (B)
Explanation
Phenol, is known as Carbolic acid.
Diazonium salt are hydrolysed to phonols.

Benzal chloride on hydrolysis gives benzaldehyde
9. Ans. (A)
Explanation
DIBAL-H reduces both the cyanides and esters to aldehydes.
10. Ans. (C)

Explanation
NaBH4 does not reduce carboxylic acid.
11. Ans. (D)

Explanation
12. Ans. (B)

Explanation
13. Ans. (A)

Explanation
14. Ans. (D)

Explanation
Na2Cr2O7, H2SO4/H2O is the strongest oxidising agent and it will oxidise 1°

alcohol into acids.
15. Ans. (C)

Explanation
Gabriel Pthalimide reaction
16. Ans. (C)

Explanation
Glycerol, on heating with KHSO4, undergoes dehydration to give unsaturated
aldehyde called acrolein. So, the statement I is correct.
Acrolein has a piercing unpleasant smell. So, statement II is incorrect.

17. Ans. (A)
Explanation
Halogenation takes place at α-position in presence of Red Phosphorous. It

is known as Hell-volhard-zelinsky reaction.
18. Ans. (D)

Explanation
Fehling reagent (aq. CuSO4+ alkaline Sodium potassium tartarate) can not
oxidised aromatic aldehydes.
19. Ans. (B)

Explanation
20. Ans. (B)

Explanation
21. Ans. (A)

Explanation
Esterification of carboxylic acid with an alcohol is nucleophilic acyl
substitution and presence of electron withdrawing group in the carboxylic
acid increases the rate of esterification reaction.
2021
Numerical
Q.1
Consider the above reaction where 6.1 g of Benzoic acid is used to get 7.8 g of m-
bromo benzoic acid. The percentage yield of the product is __________
(Round off to the Nearest Integer).
[Given : Atomic masses : C : 12.0 u, H : 1.0 u, O : 16.0 u, Br : 80.0 u]
18th March Evening Shift 2021
Q.2 In Tollen's test for aldehyde, the overall number of electron(s) transferred to
the Tollen's reagent formula [Ag(NH3)2]+ per aldehyde group to form silver mirror is
___________. (Round off to the Nearest Integer).
Q.3 The total number of C-C sigma bond/s in mesityl oxide (C6H10O) is __________.
(Round off to the Nearest Integer).
Numerical Answer Key
1. Ans. (78)
2. Ans. (2)
3. Ans. (5)
Numerical Explanation
Ans 1.
Ans 2.
Total 2e- transfer to Tollen's reagent.

Ans 3. Structure of mesityl oxide is
Number of C–C sigma bonds = 5
Q.1 Given below are two statements :

Statement I : The nucleophilic addition of sodium hydrogen sulphite to an aldehyde
or a ketone involves proton transfer to form a stable ion.
Statement II : The nucleophilic addition of hydrogen cyanide to an aldehyde or a
ketone yields amine as final product.
In the light of the above statements, choose the most appropriate answer from the
options given below :
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Q.2 In the following sequence of reactions,
The compounds B and C respectively are :-

Q.3 In the following sequence of reactions a compound A, (molecular formula

C6H12O2) with a straight chain structure gives a C4 carboxylic acid. A is :
Q.4 For the reaction given below :-
The compound which is not formed as a product in the reaction is a :
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Q.5 The structure of product C, formed by the following sequence of reactions is :
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Q.6 Given below are two statements : one is labelled as Assertion (A) and the other
is labelled as Reason (R) :
Assertion (A) : A simple distillation can be used to separate a mixture of propanol
and propanone.
Reason (R) : Two liquids with a difference of more than 20∘∘ in their boiling points
can be separated by simple distillations.
In the light of the above statements, choose the most appropriate answer from the
options given below :

Q.7 The correct order of reactivity of the given chlorides with acetate in acetic acid
is :
Q.8 Which one of the following tests used for the identification of functional groups
in organic compounds does not use copper reagent?
27th Aug Evening Shift 2021

Q.9 Which one of the following reactions will not yield propionic acid?
Q.10 The structure of the starting compound P used in the reaction given below is :
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Q.11
Consider the given reaction, the product A is :

Q.12 The major product formed in the following reaction is :

Q.13 The major products formed in the following reaction sequence A and B are :
Q.14
Consider the above reaction and identify "Y"
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Q.15 Which one of the following compounds will give orange precipitate when
treated with 2, 4-dinitrophenyl hydrazine?
27th July Morning Shift 2021
Q.16
Consider the above reaction sequence, Product "A" and Product "B" formed
respectively are :

Q.17
Maleic anhydride can prepared by :
Q.18 An organic compound 'A' C4H8 on treatment with KMnO4/H+ yields compound
'B' C3H6O.
Compound 'A' also yields compound 'B' an ozonolysis. Compound 'A' is :
Q.19 Given below are two statements, one is labelled as Assertion (A) and other is
labelled as Reason (R).
Assertion (A) : Gabriel phthalimide synthesis cannot be used to prepare aromatic
primary amines.
Reason (R) : Aryl halides do not undergo nucleophilic substitution reaction.
In the light of the above statements, choose the correct answer from the options
given below :
Q.20
Consider the given reaction, the product 'X' is :
Q.21
Major product P of above reaction, is :

Q.22 The major product (P) in the following reaction is :

Q.23
For above chemical reactions, identify the correct statement from the following :
Q.24
Which among the above compound's does\do not form Silver mirror when treated
with Tollen's reagent?

Q.25
Consider the above reaction, the product 'X' and 'Y' respectively are :
Q.26
Considering the above chemical reaction, identify the product "X" :

18th March Morning Shift 2021
Q.27
Consider the above chemical reaction and identify product "A"

Q.28
In the above reaction, the structural formula of (A), ''X'' and ''Y'' respectively are :
Q.29 Mesityl oxide is a common name of :

Q.30
The product ''A'' in the above reaction is :
Q.31
In the above reaction, the reagent ''A'' is :

Q.32 An unsaturated hydrocarbon X on ozonolysis gives A. Compound A when
warmed with ammonical silver nitrate forms a bright silver mirror along the sides of
the test tube. The unsaturated hydrocarbon X is :
Q.33
The structure of X is :

Q.34 Assertion A : Enol form of acetone [CH3COCH3] exists in < 0.1% quantity.
However, the enol form of acetyl acetone [CH3COCH2OCCH3] exists in approximately
15% quantity.
Reason R : Enol form of acetyl acetone is stabilized by intramolecular hydrogen
bonding, which is not possible in enol form of acetone.
Choose the correct statement :
Q.35
The product ''P'' in the above reaction is :

Q.36 Identify A in the given chemical reaction.
26th Feb Evening Shift 2021
Q.37 2, 4-DNP test can be used to identify :
Q.38 Identify A in the following chemical reaction.

Q.39 The major product of the following reaction is :
Q.40 The major product of the following chemical reaction is :
25th Feb Morning Slot 2021

Q.41 Identify A and B in the chemical reaction.
Q.42 Given below are two statements :

Statement I : CeO2 can be used for oxidation of aldehydes and ketones.
Statement II : Aqueous solution of EuSO4 is a strong reducing agent.
In the light of the above statements, choose the correct answer from the options
given below :

Q.43 Which one of the following reactions will not form acetaldehyde?
Q.44 Match List - I and List - II.
24th Feb Evening Slot 2021

Q.45 Which one of the following carbonyl compounds cannot be prepared by
addition of water on an alkyne in the presence of HgSO4 and H2SO4?
24th Feb Evening Slot 2021
Q.46 Which of the following reagent is used for the following reaction ?

MCQ Answer Key
1. Ans. (B) 17. Ans. (A) 33. Ans. (A)

2. Ans. (D) 18. Ans. (B) 34. Ans. (C)
3. Ans. (C) 19. Ans. (A) 35. Ans. (D)
4. Ans. (C) 20. Ans. (C) 36. Ans. (B)
5. Ans. (A) 21. Ans. (D) 37. Ans. (D)
6. Ans. (D) 22. Ans. (D) 38. Ans. (C)
7. Ans. (D) 23. Ans. (B) 39. Ans. (A)
8. Ans. (B) 24. Ans. (D) 40. Ans. (D)
9. Ans. (D) 25. Ans. (C) 41. Ans. (A)
10. Ans. (A) 26. Ans. (A) 42. Ans. (A)
11. Ans. (C) 27. Ans. (C) 43. Ans. (D)
12. Ans. (C) 28. Ans. (C) 44. Ans. (B)
13. Ans. (A) 29. Ans. (B) 46. Ans. (A)
14. Ans. (C) 30. Ans. (B)
15. Ans. (D) 31. Ans. (D)
16. Ans. (C) 32. Ans. (D)
MCQ Explanation
Ans 1. Statement I : Correct
Statement II : Wrong
Ans 2.
Ans 3.
Ans 4.
Ans 5.
Ans 6. Simple distillation can be used to separate a mixture of propanol and

propanone.
• Two liquid with difference in B.P. around 20°C can be separated by simple
distillation.
• B.P. of propanol is 370 K.
B.P. of acetone is 329 K.
Both assertion & reason are correct & (R) is the correct explanation of (A).
Ans 7. Acetate in acetic acid with R-X cause SN1

Allylic halides undergo faster SN1
∴ Correct order is
Ans 8. In Seliwanoff's reagent, Cu is not present.

In Barfoed, Biuret and in Benediet reagent Cu is present.
Ans 9. All gives propanoic acid as product but option (d) gives butanoic as product
Ans 10.
NaOCl is used in haloform reaction as reagent.

Ans 11.
Ans 12.
Ans 13.
Ans 14.
Ans 15.
Explanation ⇒ 2-4-D.N.P. test is used for carbonyl compound (aldehyde & ketone)
Ans 16.
Ans 17. Cis but 2-enoic acid
Ans 18.
Ans 19. Gabriel phthalimide synthesis
Ans 20.
Ans 21.
Ans 22.
Ans 23.
Ans 24.
Ans 25.
Ans 26.
Ans 27.
Ans 28.
Ans 29.
Ans 30. Ethylene glycol in presence of H+ will convert ketone into cyclic ketal and
the ester group remains intact.
Ans 31.
Ans 32.
Ans 33.
Ans 34.
Acetyl acetone in enol form have intramolecular H-bonding, which is absent in

acetone.
Ans 35.
DIBAL can not reduce the double bond It can reduce cyclic ester.
Ans 36.
Ans 37. 2,4 DNP test is used to identify – (CO) – group. It gives addition reaction
with carbonyl compounds. So, it can be used to identify aldehyde in the given option.
It gives yellow/ orange ppt with carbonyl containing compounds.
Ans 38.
Ans 39.
Ans 40.
Ans 41.
Ans 42. The +3 oxidation state of lanthanide is most stable and therefore lanthanide
in +4 oxidation state has strong tendence to gain e– and converted into +3 and
therefore act as strong oxidizing agent. eg Ce+4
And therefore CeO2 is used to oxidized alcohol aldehyde and ketones.
Lanthanide in +2 oxidation state has strong tendency to loss e– and converted into
+3 oxidation state therefore act as strong reducing agent.
∴ EuSO4 act as a strong reducing agent.
Ans 43.
Ans 45.
Ans 46. Molybdenum oxide (Mo2O3 ) is used for oxidising alkanes to aldehyde. It
used to manufacture molybdenum metal, which serves as an additive to steel and
corrosive resistant alloys.

Aldehyde, Ketone Jee 5 Years MCQ

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Aldehyde, Ketone Jee 5 Years MCQ

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Physical World, Units and Measurements P-1

JEE Main 2023 (Online) 12th April Morning Shift

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Q.5. Number of isomeric compounds with molecular

Q.7. umber of compounds from the following which will not

JEE Main 2023 (Online) 30th January Evening Shift

Q.8. A trisubstituted compound 'A', C10H12O2 gives

Q.9. Number of compounds giving (i) red colouration with ceric

Answer Key & Explanation

1. Ans. Correct answer is 15

For completion of reaction, we need 2 moles of MeMgBr per mole

7.Ans. Correct answer is 3

will dissolve in hot NaOH solution.

'A' formed in the above reaction is

Q.2. In the reaction given below

The products formed in the above reaction are

'A' in the above reaction is:

Q.5. In the following reaction

Q.6. The major product 'P' formed in the following sequence of

Choose the correct answer from the options given below :

Q.8. Given below are two statements, one is labelled as Assertion

In the light of the above statements, choose the correct answer

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'A' and 'B' in the above reactions are:

Q.10. L-isomer of tetrose X(C4H8O4) gives positive Schiff's test and

Q.11. In the reaction given below:

Q.12. The major product 'P' formed in the given reaction is

Q.13. Major product 'P' formed in the following reaction is:

Q.14. A compound 'X' when treated with phthalic anhydride in

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Q.16. Match List I with List II:

LIST I LIST II (Compound with

B. Neutral FeCl3 II.

Choose the correct answer from the options given below:

Q.17. The major products A and B from the following reactions

Q.18. Match List I with List II

Choose the correct answer from the options given below:

reagents 'X' and 'Y' respectively are :

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Q.20. Given below are two statements : one is labelled as

Assertion (A) : α-halocarboxylic acid on reaction with

In the light of the above statements, choose the correct answer

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Q.21. The structures of major products A, B and C in the following

Q.22. Identify the incorrect option from the following

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Q.23. Cyclohexylamine when treated with nitrous acid yields (P).

The correct statement for product B is. It is

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Q.25. Given below are two statements : one is labelled as

Assertion (A) : Ketoses give Seliwanoff's test faster than Aldoses.

Reason (R) : Ketoses undergo β-elimination followed by

In the light of the above statements, choose the correct answer

Q.27. Which of the following compounds would give the following

(i) Fehling's Test : Positive

(ii) Na fusion extract upon treatment with sodium nitroprusside

Choose the correct answer from the options given below :

Q.30. 'A' in the given reaction is

Q.31. Given below are two statements, one is labelled as Assertion

Assertion A : Butylated hydroxy anisole when added to butter

Reason R : Butylated hydroxy anisole is more reactive towards

In the light of the above statements, choose the most appropriate

Q.32. Given below are two statements : one is labelled as