THE SAMHITA ACADEMY Date: 23-01-2023 Annual Examination-2022-23 11 Subject: Chemistry Marks: 70 General Instructions: ‘There are 35 questions in the question paper with internal choice. All questions are compulsory. Section A : Question number 1 to 18 are objective type questions each carrying 1 mark. Section B : Question number 19 to 25 are short answer type questions each carrying 2 marks. Section C : Question number 26 to 30 are short answer type questions each carrying 3 marks. Section D : Question number 31 and 32 are passage based questions each carrying 4 marks. Section E : Question number 33 to 35 are long answer type questions each carrying 5 marks. ‘© Use of calculators and log tables are not permitted. Section-A, 1. Density of 2.05 M solution of acetic acid in water is 1.02 g/mL. The molality of the solution is a)1.14m b)3.28m ) 2.28m, 4)0.44m 2. The amount of CO? produced from combustion of one mole of CaHio on complete combustion is a) 176g b) 44g, ©) 88g d) 132g, 3. 12 LH reacts with 11.2 L of Clzare mixed and exploded, The composition of final mixture is a) 24 Lof HCl b) 0.8 Lof Ch, 20.8 L of HCI ¢) 22.4 Lof HCI, 0.8 Lof He d) 22.4 Lof HCI 4. What is the maximum number of orbitals that can be identified with the following quantum, numbers? n= 3, != 1, m=O a)i b)2 3 d)4 5. Which elements is expected to have lowest ionisation enthalpy? a) Sr b) As xe ds 6. Which of the following does not have zero dipole moment? a) CO, b)CS2 «S02 d) CC 7. The species which has bond angle 120°. a) ClFs b) NC ©) BCs d) Pls The bond order for Of, C; are a)25,2 b)2,3 3,2 15,2010. 1. 14 16. £ ‘The correct thermodynamic conditions for spontaneous reaction at all temperatures is b) AH<0&45<0 a) OH0 ©) OH<08AS=0 _ d)BH> 0&AS<0 1 «6, For the reaction, CO + Chin = COChig, the eS equal to a) VAT b)RT °: iz d)1.0 Which of the following can act as oxidising as well as reducing agent? 1 a) Hy dk ) 202 d) All of these ‘The element which does not undergo disproportionation 1 aa b) Br OF di ‘The order of priority functional groups in IUPAC ‘system 1 a) -CONHa, ~CHO, “SO3H, COOH b) -COOH, -sosH, ~CONH2, -CHO ©) -SOsH, ~COOH, ~CONH2, ~CHO. 4) -CHO, -cooH, ~SOsH, ~CONH2 srw ang ets ted wth ene wih Et (product and select the comet 1 ‘answer using the codes given below the lists, Uist ist 1 Hydrogen in presence of catalyst AT Benzene uw Heat at 600°C B | Acetaldehyde Ai Hydrogen in presence of Pd and CaCO, at a7aK TC Ethene | IV | __Water in presence of H:S0« and HesOe [D| Ethane 2) 18, IC, IED, I-A b) LA, IED, TIC, 1V-B ) FA, 1-0, 1-8, 1v-c. 4) LD, ILA, ILC, 1V-B ‘The correct IUPAC name of the following compound is aN 1 b) S-ethyl-4-propyldecane 4) 4-(I-methylethy)-5-(1-methylpropyl}-decane Solution containing a mixture of acetic acid and sodium acetate maintains 1 Eonstant value of Pon addition of small amounts of acid or alll Reason: A solution containin, 1 a mixture of acetic acid and sodium acetate acts asa buffer solution around P* = 4.75 a) Both Assertion and Reason are true but Reason is not a correct b) Both Assertion and Reason are true and Reason is the correct e ¢) Assertion is false but Reason is true. 4) Assertion is true but Reason is false, explanation of Assertion. -xplanation of Assertion,a7. 18. 19. 20. 21. 22. 23. 24, 25. Assertion: Oxidation number of Cin HCHO is zero. 1 Reason: Formaldehyde is covalent compound. 2) Both Assertion and Reason are true but Reason is not a correct explanation of Assertion. 'b) Both Assertion and Reason are true and Reason is the correct explanation of Assertion. €) Assertion is false but Reason is true. 4d) Assertion is true but Reason is false. Assertion: Nitration of benzene with nitric acid req acid. Reason: The mixture of concentrated sulphui electrophile (NOt). Wires the use of concentrated sulphuric a acid and concentrated Nitric acid produces the a) Both Assertion and Reason are true but Reason is hot a correct explanation of Assertion, ') Both Assertion and Reason are true and Reasons the correct explaniation of Assertion, c) Assertion is false but Reason is true. d) Assertion is true but Reason is false. SECTION -~B {()) Define mole fraction of solute (i) Define limiting reagent. 2 oR Calculate the % of copper in a sample of CuCl (Atomic weights of Cu = 63.5 u, CI= 35.5 u) Calculate wave number of the line having frequency 5 x 10% Hz, 2 oR An element of atomic weight Z consists of two isotopes of mass number 2-1 and Z+2. Calculate the % of the higher isotope. (i) Why is dipole moment of BFs is zero? a (li) Write the resonance structures of CO3-. Explain the shape of the following based on VSEPR theory (a) ClFa (b) XeFs 2 (i) What is meant by electrochemical series? 2 ti Give condensed and bond line structural formula of the following; 2 (a) Cycloocta-1,3,5,7-tetraene (b) 2-(4-isobutylphenyllpropancic acid, What happens when F2 reacts with 420? Write the structure and name of the products obtained by ozonolysis of pent-2-ene. 2 oR How will you convert benzene to acetophenone? 3 oO oy at At Ps » ‘ t See oe EEE26. 27. 29. 30. 31. SECTION -C A compound on analysis found to contain following percentage composition Na= 43.4%, C=11.4% and 0=45,3%, Determine the empirical and molecular formulae. Given Molar mass of the compound is 106 g mot. OR Hydrogen reacts with nitrogen to produce ammonia according to the equation: 3H2q) + Naj—>2NHsig. Determine how much ammonia would be produced if 100 g of Nz reacts? {i) Define uncertainty principle. (ii) Calculate the uncertainty in the position of an electron (mass = 9.1 x 10° kg) moving with velocity of 300 ms”, accurate up to 0.001% (h = 6.626 x 10 Js), oR An ion with mass number 37 possesses one unit of negative charge. If the ion contains 11.1% ‘more neutrons than electrons, find the symbol of the ion. ()An element has atomic number 35. To which group and period does it belong? (ii) Lanthanoids and actinoids belong to which block of the periodic table? (ii) How does ionisation enthalpy vary across the period and down the group? Write molecular orbital electronic configuration of the Nz molecule and comment on its bond ‘order and magnetic behaviour. OR (i) What is the state of hybridisation of nitrogen in NHf ion? (ii) Draw the shape of PHs and SFe according to VSEPR theory. (iii) What is the hybridisation of carbon atoms in CHs~CHO a) Write the structural formulae for compounds name as (i) 1-bromoheptane (ii) S-bromoheptanoic acid b) What are electrophiles? Give one example of electrophilic substitution reaction. SECTION-D Thermodynamics involve energy changes and chemical reactions and other process. Internal energy is the total energy stored in a substance. We can specify absolute value of volume but not absolute value of internal energy. We can measure only change in internal energy (AU). ‘Work done on the system is taken as positive and work done by the system is taken as negative. Q absorbed by the system is positive and heat given output system is narrative. ‘AU=q+w according to first law of thermodynamics. AH(enthalpy change) is measured at constant pressure, AU is measured at constant volume. OH, OS(entropy change), MG(Free energy change) and temperature help to decide spontaneity of the process. 3 3 432. i. Which of the following is true for adiabatic process? (a) a= (b) BU=Wraabave (c) both (a) and (b) (d) None of these fi. 1f 701.4 of heat is absorbed by the system and 394 J of work is done by the system. The value of AU is equal to (a) 3073 (by3945 (700 aq UW. 2 litres of an ideal gas at a pressure of 10 atmosphere expands isothermally into vacuum until its total volume is 10 litres. Which of the following is true? (a) q=0 (b) W= (c) au=0 (4) all of these \v. For an equilibrium H20y) = H204p, which of the following is/are correct? (a)aG=0 — (b) AH>0 ()as>0 (4) all of these OR V. For N20s = 2NOnig, AH-AU is equal to (a) RT (b)-RT ()42RT (d)-2RT Equilibrium can be established for both physical and chemical processes at equilibrium rate of forward and reverse processes or equal. Equilibrium constant Kc is expressed as concentration of products divided by reactants each raise to the power stoichiometric coefficients, Ke has fixed value of constant temperature at this stage concentration, pressure..ete become Constant. Ke is equilibrium constant in terms of partial pressure of gases or vapours. The direction of reaction can be hey predicted by the reaction quotient Qc and Qp. Qc is equal to Ke at equilibrium. Le-chatelier's principle states equilibrium will shift in direction to counter balance the effect of change in temperature pressure and concentration film between ions and unionized molecules in weak electrolyte is called ionic equilibria. 2NOnig;= N2O«, + 60.0 kd, the increase in temperature (2) Favour the formation of N20, (6) Does not affect the eq (b) Favours the decomposition of NOs ibrium, (d) stops the process For the reaction, COig) + Clajg) COCK, the Ko/Ke is equal to (a) VRT (b) RT Oz (d)1.0 {In which condition, the reaction proceeds in the forward direction? (2) Qc=Ke — (b) Qe> Ke (6) Qe< ke (4) Qe # Ke {In the equilibrium, AB = A+ 8, ifthe e equilibrium concentration of 8 will be quilibrium concentration of A is double, then (a) half (b) twice (pth (deh oR ¥. Of the following which change will shift the reaction towards the product at equilibrium? (2) increase in total pressure (b) increase in temperature (c) Decrease in concentration of lz (4) increase in concentration of |SECTION-€ 33, Answer the following: (a)n + /value for the 14" electron in an atom. (b) increasing order of filing electron in 4f, Sp and 6d subshells. (€) mand / value for last electron of Mg{12] atom. (4) subshell in which last electron in Ga[33). (e) sum of spin of all electrons in element having atomic number 14. OR (a) In.a hydrogen atom, an electron jumps from the 5! orbit to the 2"4 orbit. Calculate the wavelength and frequency of the radiation emitted. (b) Calculate the energy of one mole photons from a radiation of frequency 5.8 x 10™ Hz. 34, (a) Give three points of differences between inductive effect and resonance effect. (b) Which of the following compounds will not exist as a resonance hybrid. Give reason for your answer (i) CH30H (ii) R-CONH2 (iii) CHsCH=CHCH2NH2 ‘OR (a) Give condensed and bond line structural formulas and identify the functional group(s) present, if any, for: (i)2,2,4-trimethylpentane (ii) 2-Hydroxy-1,2,3-propanetricarboxylic acid (b) Explain functional isomerism with a suitable example. i) Hexanedial 35. (a) Explain the mechanism for nitration of benzene. (b) Explain Wurtz reaction for the preparation of butane. oR (a) Give the mechanism for chlorination of methane. (b) Classify the following compounds as oO O 0 o ” aromatic/non-aromatic. a « 2fp 6