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AIITS-HCT-VI-PCM(Sol)-JEE(Main)/16

Chemistry PART – II

SECTION – A

4. Na 
1s2 2s2 2p6 3s1
3s1 orbitals has n = 3,   0
Number of radial nodes = n  – 1 = 3 – 0 – 1 = 2

rO2 PO2 MCH4 nO2 16 3 16 16 3

6.   =  
rCH4 PCH4 MO2 nCH4 32 32 2 32 4 2

7. Half life t1/2 = 140 days

280  140
Number of half lives in total time = 3
140
R = R0(1/2)n
 3000 = R0(1/2)3, R0 = 24000 dps

9.

58
11. nCl2   1.63
0.082  300
Mass of Al(s)  0.05 101 20  20  61.13  13.56 gm
So mass of Al(s) dissociated = 0.5 moles
So eq is established
3

Al(s)  Cl2(g)  AlCl3(s)
2
3
1.63   0.5 0.5
2
3
 0.88  0.082  300  2

3 3
K p  PCl2   

2 
  2.7 2
 8 
(Volume of the vessel is taken 8 lit approx even after eq is established).
13.
HO OH O CH2
HO CH2 H2C O
B 2 
 B  4H2 O
OH HO CH2 O CH2
HO H2C O

14. (i) Na2 S2 O3  2HCl 

 2NaH  SO2  H2 O  S
(ii) KI3  2Na2S2 O3 
 KI  2NaI  Na 2S4 O6
(iii) 2AgNO3  Na2 S 2O3 
 Ag2 S2 O3  2NaNO3
white


H2O
 Ag2 S  H2 SO4
Black

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AIITS-HCT-VI-PCM(Sol)-JEE(Main)/16

15. Stability of intermediate carbocation increases rate of reaction.

16. CH3 CH3 CH3 CH3

NH2 
 
NH2
NH3
  
H

Cl NH2 NH2

18.

O O

(Aromatic)

19. O
O C
OH

 
KMnO4
H

O O

OH

21.  MgOH2  CH3  C  CH

Mg2 C3  2H2 O 

NH4 Cl 0.1

24. pOH  pKb  log10  4.7  log  5.7
 4 
NH OH 0.01
pH = 14 – 5.7 = 8.3

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website: www.fiitjee.com