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Thermodynamics Project
Thermodynamics Project
A thorough grasp of co-generation technology is required for the preliminary design of a stand-
alone utilities supply system for a new salt factory in a remote salt-affected region of Victoria.
Co-generation, also known as combined heat and power (CHP), has the ability to meet the
facility's electricity and hot water demands in an efficient and sustainable manner. The purpose
of this literature study is to provide an overview of co-generation technology, its applicability in
similar contexts, and its potential benefits for salt factories.
Cogeneration is the sequential generation of two separate types of useable energy from a
single primary energy source, often mechanical and thermal energy. Mechanical energy can be
utilized to power an alternator, which generates electricity, or to power rotating equipment
such as a motor, compressor, pump, or fan, which provides a variety of services. Thermal
energy can be used directly in processes or indirectly to produce steam, hot water, hot air for
dryers, or chilled water for process cooling. Cogeneration offers a diverse set of technologies
for use in a variety of economic activities. In rare circumstances, the overall efficiency of energy
utilization in cogeneration mode could reach 85% or more (Bhatia, 2014).
In the case of the salt factory, electrical power is necessary for processes such as drying,
burning, filtering, and vacuum drying, as well as for smaller equipment that requires continuous
operation. Hot water is largely required for raw salt washing and sterilizing, as well as
extraction, with a desired temperature range of 80°C to 85°C. Co-generation systems may be an
effective way to address both of these goals. The use of a diesel generator for electrical energy
supply, along with the recovery of waste heat to produce hot water, may be a viable solution
for the salt factory's utilities supply system. Co-generation systems have the advantage of
utilizing the thermal energy created during electricity production, hence increasing the total
energy efficiency of the system. Waste heat from the diesel generator can be efficiently
recovered and utilized through heat recovery devices such as heat exchangers to meet the
facility's hot water needs.
The adoption of co-generation systems in industrial settings has shown significant benefits,
including increased energy efficiency, cost savings, and reduced environmental effect. The salt
factory may maximize energy use, reduce reliance on external resources, and lower operating
costs by utilizing waste heat from the diesel generator. Furthermore, because co-generation
systems are less reliant on external utilities like grid electricity and piped gas, they can improve
the facility's stability and resilience.
Finally, co-generation technology presents an appealing approach for meeting the electricity
and hot water demands of the proposed salt factory in a remote area. The literature review has
provided insights into the principles, benefits, and applications of co-generation systems. The
salt factory may achieve high energy efficiency, lower operational costs, and improve
sustainability by using a diesel generator to generate power and collecting waste heat to
provide hot water.
2) Energy analysis
Study the electrical and hot water demand profiles to select suitable Diesel generator and
determine the size of the hot water storage tank needed.
The proposed co-generation system for the salt factory's stand-alone utilities supply intends to
meet the facility's electrical and hot water demands effectively. The system recovers waste
heat from a diesel generator via two heat exchangers, one for heat recovery from engine
coolant and the other for heat recovery from exhaust gases. Figure 2 depicts the proposed co-
generation system schematic.
Assumptions:
1. Heat Exchanger Insulation: Both heat exchangers are assumed to be well-insulated,
resulting in negligible heat transfer between the heat exchangers and the surroundings.
2. Heat Transfer: The bore water receives heat from the coolant first and then is further
heated by the exhaust gas. The total heat gain by the bore water is equal to the sum of
heat lost by the engine coolant and exhaust gases.
3. Negligible Pressure Losses: The engine coolant, exhaust gas, and water experience
negligible pressure losses while flowing through the heat exchangers.
4. Negligible Kinetic and Potential Energy Changes: The engine coolant, exhaust gas, and
water are assumed to have negligible changes in kinetic and potential energy while
flowing through the heat exchangers.
The figure above provide the necessary parameters for the calculation of total electrical power
demand.
To determine the total electrical power demand for each hour, the individual power demands
for all processes during that specific hour are summed up. The calculation for each hour is
performed based on the provided data.
For example, the total electrical power demand from 8 to 9 PM is calculated as follows;
𝑇𝑜𝑡𝑎𝑙 𝑒𝑙𝑒𝑐𝑡𝑟𝑖𝑐𝑎𝑙 𝑝𝑜𝑤𝑒𝑟 = 4.38 + 4.5 + 6.25 = 15.13𝐾𝑊
Calculations for each hour are done and respective values filled in in the table below.
Sum of electrical
Time (duration) power for all
processes (KW)
8 AM to 9 AM 15.13
9 AM to 10 AM 16.35
10 AM to 11 AM 15.13
11 AM to 12 PM 16.15
12 PM to 1 PM 15.08
1 PM to 2 PM 15.78
2 PM to 3 PM 16.75
3 PM to 4 PM 15.38
4 PM to 5 PM 16.55
The X-axis depicts time (from 8 a.m. to 5 p.m.), while the Y-axis represents total hourly
electrical power demand in kW. The area chart depicts the daily variance in electrical power
demand.
b) Determine the total hot water demand in (kg/min) and in (kW) every hour.
The total hot water demand in kg/min and kW for each hour is calculated by adding the hot
water flow rates for the processes that require hot water. "Raw salt washing and sterilization"
and "Extraction" are the operations that require hot water, according to the data presented.
The hourly computation is as follows:
𝑘𝑔⁄
𝐻𝑜𝑡 𝑤𝑎𝑡𝑒𝑟 𝑑𝑒𝑚𝑎𝑛𝑑 ( 𝑚𝑖𝑛) = Raw salt washing flow rate+ 𝐸𝑥𝑡𝑟𝑎𝑥𝑡𝑖𝑜𝑛 𝑓𝑙𝑜𝑤 𝑟𝑎𝑡𝑒
The results of each respective hour are filled in the table below.
Calculation of hot water demand in (kW).
The hot water demand in kW, is calculated by multiply the hot water flow rate in kg/min by the
specific heat capacity of water and converts the units to KW. The specific heat capacity of water
is given as 4.182 J/g°C, which represents the amount of heat energy required to raise the
temperature of 1 gram of water by 1 degree Celsius. However, since the provided hot water
flow rates are given in kg/min, the units need to be converted appropriately.
The correct conversion factor to use is 4.182 kJ/kg·°C, which is the specific heat capacity of
water in kilojoules per kilogram per degree Celsius. The results for each hour are computed and
filled in the table below.
8 AM to 9 AM 5.30 22.1646
9 AM to 10 AM 9.6 40.1472
10 AM to 11 AM 4.3 17.9826
11 AM to 12 PM 5.3 22.1646
12 PM to 1 PM 9.6 40.1472
1 PM to 2 PM 0 0
2 PM to 3 PM 6.95 29.0649
3 PM to 4 PM 8.1 33.8742
4 PM to 5 PM 4.3 17.9826
The chart show the variations in hot water demand in both kW and kg/min throughout the
day.
To determine the average flow rate (kg/min) of hot water
To calculate the average flow rate of hot water (kg/min), add the entire cumulative hot
water flow for all hours and divide it by the nine hours.
5.30 + 9.6 + 4.4 + 5.3 + 9.6 + 6.95 + 8.1 + 4.3
𝑎𝑣𝑒. 𝑓𝑙𝑜𝑤 𝑟𝑎𝑡𝑒 = = 5.94𝑘𝑔/𝑚𝑖𝑛
9
Diesel generator selection
Given:
• Load levels: 50%, 75%, 100%, and 110%
• Fuel consumption and waste heat values corresponding to these load levels.
To use linear interpolation to estimate fuel consumption and waste heat values based on
electrical power demand, the load levels and their corresponding fuel consumption and waste
heat values from the Diesel generator catalogue must be used. These figures serve as a starting
point for estimating the values for intermediate load levels.
The range within which the demand falls can be determined by identifying the closest load level
to the electrical power demand for each hour. This range is made up of two adjacent load
levels, each with its own fuel consumption and waste heat value. Linear interpolation is the
process of computing the values for a certain demand by modifying the values of the two load
levels proportionally based on their proximity to the demand.
Using this method, the fuel consumption and waste heat values for each hour can be estimated
by taking into account the load levels and their corresponding values from the catalogue. Based
on the exact electrical power requirement for each hour, this interpolation technique provides
for a more accurate estimation of the actual fuel consumption and waste heat.
8 AM to 9 AM 15.13 6.6732
9 AM to 10 AM 16.35 7.2136
10 AM to 11 AM 15.13 6.6732
11 AM to 12 PM 16.15 7.1227
12 PM to 1 PM 15.08 6.6512
1 PM to 2 PM 15.78 6.9592
2 PM to 3 PM 16.75 7.3955
3 PM to 4 PM 15.38 6.7832
4 PM to 5 PM 16.55 7.3045
Total waste per hour = waste heat (engine coolant) + waste heat (exhaust). The results are
compared to the total heating demand in the table below.
Total hourly temperature fluctuation of hot water after receiving heat from coolant
(i.e. T2) and the exhaust gas temperature after it leaves the exhaust gas heat recovery
heat exchanger, against time.
8 AM to 9 AM 5.30 5.94
9 AM to 10 AM 9.6 5.94
10 AM to 11 AM 4.3 5.94
11 AM to 12 PM 5.3 5.94
12 PM to 1 PM 9.6 5.94
1 PM to 2 PM 0 5.94
2 PM to 3 PM 6.95 5.94
3 PM to 4 PM 8.1 5.94
4 PM to 5 PM 4.3 5.94
The region above the average flow rate represents the oversupply, while the region below
represents the under supply.
The minimum water storage needed in terms of volume and mass of hot water
storage (in Liters and kg).
Cumulative mass for one hour = 5.94kg/min × 60min = 356.4kg
Total hot water demand per day =356.4 × 9 = 3207.6kg
The minimum volume and mass of hot water storage is given in the table below.
3207.6 3207.6
Tank design
In the calculation of tank dimensions, an increase in the calculated volume of the tank by 5% is
considered. Incorporating a little amount of open space in the design of a storage tank is critical
for various reasons:
• Thermal Expansion: As water heats up, it expands and expands in volume. The addition
of some extra space in the tank enables for thermal expansion of the hot water without
putting too much pressure on the tank walls. This serves to protect the tank from
potential harm and ensures its structural integrity.
• Overflow and Surge Capacity: During periods of high demand or probable overflow, the
additional empty capacity in the tank acts as a buffer. It allows for any abrupt increases
in hot water demand, maintaining a continuous supply without the risk of overflowing
the tank.
• Maintenance and Accessibility: Having some free space in the tank allows for simpler
maintenance, cleaning, and inspection. It enables technicians or operators to do critical
tasks without entirely draining the tank, saving time and effort.
• Flexibility in operation: The extra empty space in the tank allows for future upgrades or
additions. It enables the integration of new components or systems, as well as the
adaptation to changing hot water demand and future improvements.
The system's dependability, safety, and efficiency are improved by including extra space in
the tank design. It effectively manages thermal expansion, ensures surge capacity,
streamlines maintenance operations, and allows for future adjustments. These elements all
contribute to the overall performance and durability of the hot water storage system.
Calculated tank volume in cubic meters =3.2076𝑚3
New volume of the tank = 3.2076 × 1.03 =3.296𝑚3
Note:
The maximum outer diameter and height are limited to 1.6m and 2m respectively.
𝑣𝑜𝑙𝑢𝑚𝑒 = 𝜋𝑟 2 ℎ
Where,
r = radius of the tank
h = height of the tank
To ensure that the outside diameter doesn’t exceed design limitation, the tank height has to
be close to the maximum allowable height. Calculating for the volume = 3.296𝑚3 results in
dimensions that are beyond dimensions limits. It is critical that the tank be designed for this
volume. To meet the design criteria and obtain the intended volume of 3.296𝑚3 , it may be
necessary to exceed the tank's maximum outside diameter and height restrictions with a
stipulated insulation thickness of 0.12m. Although it deviates from the original dimensions,
there is strong reason for exceeding these boundaries.
Meeting the Volume Requirement: The major goal is to ensure that the tank can hold the
requisite volume of hot water (3.296𝑚3 ). The needed storage capacity can be obtained by
exceeding the prescribed dimensions, ensuring an appropriate supply of hot water to fulfill
the client's needs. This assures that no compromises are made in fulfilling demand,
eliminating any potential shortages or interruptions.
Taking the height of the tank as 2.10m
3. .296 = 𝜋𝑟 2 × 2.1
𝑟 = 0.7068𝑚
Tank dimensions Insulated tank dimensions
8 AM to 9 AM 61.6
9 AM to 10 AM 61.6
10 AM to 11 AM 61.6
11 AM to 12 PM 61.6
12 PM to 1 PM 61.6
1 PM to 2 PM 61.6
2 PM to 3 PM 61.6
3 PM to 4 PM 61.6
4 PM to 5 PM 61.6
2. A). Determine the exergy rate of the exhaust gases before they enter the heat recovery
heat exchanger (kW) every hour.
Assumptions
I. The diesel generator is a control volume (cv)
II. No heat loss from the exhaust or engine coolant before it enter the heat
recovery heat exchanger.
Exergy Rate of Exhaust Gases = Heat Rejected to Surroundings × (1 - Tambient / Texhaust)
Exergy rate of exhaust gas = 8.1 × (1 – 20/455) =7.74kW
Since the heat rejected is the same for the generator for every hour, the exergy rate of the
exhaust will remain the same for all the hours.
8 AM to 9 AM 7.74
9 AM to 10 AM 7.74
10 AM to 11 AM 7.74
11 AM to 12 PM 7.74
12 PM to 1 PM 7.74
1 PM to 2 PM 7.74
2 PM to 3 PM 7.74
3 PM to 4 PM 7.74
4 PM to 5 PM 7.74
B). Determine the exergy rate of the engine coolant before it enters the heat recovery
heat exchanger (kW) every hour.
The coolant's exergy rate can be approximated using the following equation:
Exergy rate of coolant = Heat rejected into coolant (kW) × Exergy destruction factor
The exergy destruction factor considers the temperature difference between the coolant and
the surrounding environment and it is calculated as follows:
Exergy destruction factor = 1 - (Tambient / Tcoolant_outlet)
Exergy destruction factor= 1-20/85 =0.765
Exergy rate of coolant = 18.3 × 0.765 = 13.99kW
Since the heat rejected to the coolant is the same, the exergy rate of the coolant is the same for
every hour.
Time (duration) Exergy for engine
coolant in (kW)
8 AM to 9 AM 13.99
9 AM to 10 AM 13.99
10 AM to 11 AM 13.99
11 AM to 12 PM 13.99
12 PM to 1 PM 13.99
1 PM to 2 PM 13.99
2 PM to 3 PM 13.99
3 PM to 4 PM 13.99
4 PM to 5 PM 13.99
3. A). Determine the rate of exergy destruction within the engine (kW) every
hour.
Applying the exergy balance equation to the control volume (cv) of the diesel generator;
Rate of exergy destruction = Exergy input - Exergy output
The exergy input is the exergy delivered by the fuel (diesel) during combustion, which
was previously determined. The electrical power generated by the generator is referred to as
the exergy output.
Therefore,
Rate of exergy destruction = 61.6 – 16 = 45.6kW
Rate of exergy destruction will be the same for every hour.
8 AM to 9 AM 45.6
9 AM to 10 AM 45.6
10 AM to 11 AM 45.6
11 AM to 12 PM 45.6
12 PM to 1 PM 45.6
1 PM to 2 PM 45.6
2 PM to 3 PM 45.6
3 PM to 4 PM 45.6
4 PM to 5 PM 45.6
B). Determine the cost per unit exergy ($/kWh) of the Air + Diesel mixture supplied in
to the Diesel generator every hour.
The cost of air is assumed to be negligible and given the cost of Diesel fuel is $1.42 per liter.
8 AM to 9 AM 0.5148
9 AM to 10 AM 0.5148
10 AM to 11 AM 0.5148
11 AM to 12 PM 0.5148
12 PM to 1 PM 0.5148
1 PM to 2 PM 0.5148
2 PM to 3 PM 0.5148
3 PM to 4 PM 0.5148
4 PM to 5 PM 0.5148
8 AM to 9 AM 3.64
9 AM to 10 AM 3.64
10 AM to 11 AM 3.64
11 AM to 12 PM 3.64
12 PM to 1 PM 3.64
1 PM to 2 PM 3.64
2 PM to 3 PM 3.64
3 PM to 4 PM 3.64
4 PM to 5 PM 3.64
C). Determine the cost per unit exergy ($/kWh) of the electrical energy stream which
is equal to that of the exergy from exhaust stream and the coolant stream from the
Diesel generator every hour.
Assume cost per unit exergy ($/kWh) of electricity and the cost per unit exergy from exhaust
and coolant are equal.
Cost per unit exergy of electricity = Cost per unit exergy from exhaust and coolant
Cost per unit exergy ($/kWh) = 8.2368/16kW = $0.5148/kWh.
8 AM to 9 AM 0.5148
9 AM to 10 AM 0.5148
10 AM to 11 AM 0.5148
11 AM to 12 PM 0.5148
12 PM to 1 PM 0.5148
1 PM to 2 PM 0.5148
2 PM to 3 PM 0.5148
3 PM to 4 PM 0.5148
4 PM to 5 PM 0.5148
The average cost per unit exergy of the electrical energy stream ($/kWh);
Average cost per unit exergy ($/kWh) = Total cost of electrical energy / Total exergy of electrical
energy
Total cost of electrical energy = Electrical power output × Cost per unit exergy of electricity
Total exergy of electrical energy = Exergy rate of exhaust gases + Exergy rate of engine coolant
Total exergy of electrical energy = 7.74 + 13.99 =21.73kW
Total cost of electrical energy = 16 × $0.5148/kWh. = $8.2368/h.
Average cost per unit exergy =8/21.73= 0.379$/kWh
D). Determine the rate of exergy change of the water across the engine coolant heat
recovery heat exchanger (kW) every hour.
The following formula is used compute the rate of exergy change of the water across the engine
coolant heat recovery heat exchanger:
Rate of exergy change = Mass flow rate of water × (Exergy at outlet - Exergy at inlet)
To calculate the exergy of the water at a specific temperature;
Exergy = Mass flow rate × Specific heat × (1 - Reference temperature/ Temperature)
Assuming a reference temperature of 25 degrees; Reference temperature is the reference
temperature at which the exergy is zero.
Exergy at outlet = (5.94 kg/min) × (4.182 kJ/kg·K) × (1 - 25 / 64) =15.13kJ/kg
Exergy at inlet = (5.94 kg/min) × (4.182kJ/kg·K) × (1 - 25 / 20) = -6.21kJ/kg
Rate of exergy change =5.94 /60× (15.13—6.21) = 2.1kW
E). Determine the rate of exergy change of the engine coolant across the engine
coolant heat recovery heat exchanger (kW) every hour.
When the engine coolant enters the heat exchanger, it undergoes a temperature change and
transfers heat to the water). As a result, the engine coolant's exergy decreases. Assuming an
ideal situation, the exergy of engine coolant reach 0. From the previous calculation, the rate of
exergy change of engine coolant was 13.99kW.
Therefore,
Rate of change of engine coolant across =13.99Kw – 0kW = 13.99Kw.
F). Determine the rate of exergy destruction within the engine coolant heat recovery
heat exchanger (kW) every hour.
Rate of exergy destruction = Rate of exergy change of the engine coolant - Rate of exergy
change of the water
Rate of exergy destruction = 13.99 - 2.1 =11.89kW
G). Determine the rate of exergy change of the water across the exhaust gas heat
recovery heat exchanger (kW) every hour.
Rate of exergy change = Mass flow rate of water × (Exergy at outlet - Exergy at inlet)
Using the formulas above and inserting the values and assuming a reference
temperature of 75°C.
Rate of exergy change =5.94/60 × (2.92—4.27) =0.71kW
H). Determine the rate of exergy change of the exhaust gas across the exhaust gas
heat recovery heat exchanger (kW) every hour.
Exhaust gases loses the exergy to the water and reaches 0.
Rate of change of exhaust gases = 7.74kW- 0kW= 7.74kW
I). Determine the rate of exergy destruction within the exhaust gas heat recovery heat
exchanger (kW) every hour.
Rate of exergy destruction = Rate of exergy change of the exhaust gases - Rate of exergy change
of the water
Rate of exergy destruction = 7.74-0.71 =7.03kW
J). Determine the exergetic efficiencies (%) of both the heat recovery heat exchangers
(coolant to water heat exchanger and exhaust gas to water heat exchanger) every
hour.
Exergetic efficiency = (Rate of exergy output / Rate of exergy input) × 100
For the ingine coolant;
Exergetic efficiency =2.1/13.99 × 100 =15%
For the exhaust gases;
Exergetic efficiency =0.71/7.03 × 100 =10%
K). Determine the cost of owning the heat recovery heat exchanger system ($/hour).
Note the rental cost ($/week) of the heat recovery heat exchanger system is $60/week. The salt
factory will operate for 9 hours per day from 8am to 5pm and 5 days a week.
Total operating hours/week = 9hours/day × 5days/week=45hours
Cost/hour = rental cost per week/total operating hours per week=60/45=$1.33/h
L). Determine the cost per unit exergy ($/kWh) of the hot water stream every hour.
Also determine the average cost per unit exergy of the hot water stream ($/kWh).
These had been calculated previously;
Cost per unit exergy ($/kWh) = 8.2368/16kW = $0.5148/kWh.
Average cost per unit exergy =8/21.73= 0.379$/kWh
M). Develop full exergy accounting of planned utilities supply system and prepare a
exergy balance sheet for one sample hour at 2pm.
Power generation system:
Diesel generator:
Fuel consumption rate: 5.8kg/min
Electrical power output: 16kW
Electrical exergy output: 18.93kW
Heat recovery heat exchangers:
Coolant to water heat exchanger
Coolant inlet temperature: 85°C
Coolant outlet temperature: 35°C
Water inlet temperature: 20°C
Water outlet temperature: 64°C
Rate of exergy change of coolant: 13.99 kW
Rate of exergy change of water: 2.1 kW
Exhaust gas to water heat exchanger
Exhaust gas inlet temperature: 455°C
Exhaust gas outlet temperature: 435°C
Water inlet temperature: 64°C
Water outlet temperature: 85°C
Rate of exergy change of exhaust gas: 7.74kW
Rate of exergy change of water: 0.71kW
Hot water production system:
Heat recovery from exhaust gas
Hot water temperature: 85°C
Raw salt washing and sterilization Hot water flow rate: 2.65kg/min
Extraction Hot water 4.3kg/min
Exergy content of hot water: 2.81kW
Electricity consumption:
Total electricity consumption: 16.7kW
Exergy Balance Sheet for the Planned Utilities Supply System at 2pm:
• Exhaust gas emissions: Use powerful exhaust gas treatment systems, such as catalytic
converters and particulate filters, to reduce air pollution and protect employees' and
the surrounding environment's health and safety. Regular maintenance and monitoring
of these systems is critical to their proper operation.
• Noise pollution: Take steps to reduce noise pollution caused by the cogeneration
system, such as erecting soundproof enclosures or using noise barriers. Employees will
be safer and more comfortable as a result of this.
• Develop extensive safety policies and procedures to ensure the cogeneration system's
safe functioning. This involves regular equipment maintenance, employee safety
training, and the development of emergency response plans to reduce possible hazards
and accidents.
• Regulation compliance entails adhering to all necessary health and safety regulations
and standards. Ensure that the co-generation system's design, installation, and
operation adhere to industry and governmental rules.
• Fire and explosion dangers: To reduce the risks associated with fire and explosion
hazards in the cogeneration system, provide fire detection and suppression systems,
conduct regular inspections of fuel storage and handling facilities, and give proper
training to staff.
References:
https://www.sciencedirect.com/topics/engineering/cogeneration
https://www.generatorsource.com/Cogeneration_Technology.aspx
https://energyeducation.ca/encyclopedia/Cogeneration
https://www.mdpi.com/1099-4300/18/11/387
http://home.iitk.ac.in/~suller/lectures/lec24.htm
https://www.sciencedirect.com/topics/engineering/exergy-
analysis#:~:text=Exergy%20analysis%20is%20a%20thermodynamic,and%20systems%20rational
ly%20and%20meaningfully
https://www.researchgate.net/publication/325273785_A_simple_methodology_for_capacity_s
izing_of_cogeneration_and_trigeneration_plants_in_hospitals_A_case_study_for_a_university
_hospital
https://ecourses.ou.edu/cgi-bin/ebook.cgi?topic=th&chap_sec=10.4&page=theory