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https://doi.org/10.1007/s13538-023-01310-z
STATISTICAL
Abstract
We study in detail the behaviour of a spin-1 model with competing interactions between next and next-nearest neighbours,
biquadratic interactions between nearest neighbours, crystalline and external magnetic fields, on a Bethe lattice in the infinite
coordination limit. We solve this model analytically and investigate its phase diagrams by numerically iterating the recur-
sion relations on the Bethe lattice. The phase diagrams display more than one multiphase points and finite commensurate
modulated phases both at finite and at zero temperature. The ground state of the system is also investigated. We observe rich
phase diagrams with different ordered phases arranged in complex structures. Special attention is dedicated to the peculiar
effects of biquadratic interactions and crystalline field, which in general distort and eventually suppress some of the com-
mensurate ordered phases. The external field behaviour shows differences between 0 ordered phase and the paramagnetic
phase for the first time in these models.
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95 Page 2 of 11 Brazilian Journal of Physics (2023) 53:95
the Lifshitz point for strong enough negative crystal fields the interaction between first and second neighbours spins
( D < 0 ) that favours the S = 0 state. The chaotic attractors are ferromagnetic ( J1 > 0) and antiferromagnetic ( J2 < 0),
are also found in the model. The co-stability of an ordered respectively. In the infinite coordination limit, the coordina-
phase where the spin zero state is predominant and both tion number of the Bethe lattice z → ∞ and the intensity of
ferro and modulated phases is a new feature of the model. the first and second neighbours interaction goes to zero in a
More recently, a preliminary study of the Blume-Emery- way that zJ1, zK and z2 J2 are finite.
Griffiths (BEG) model with competing interactions, named This model can be solved analytically by reaching a set
BEGV (from BEG Vannimenus), attracted some attention of equations, the map associated with the model, which
[14]. The solution of the model in this case was also on a can be used to produce phase diagrams for the system by
Bethe lattice with a finite coordination number. On the other numerical iteration. To reach this set of equations we make
hand, the model has shown strong potential for new kinds of use of the recurrence relations of the Bethe lattice. With
behaviour and stimulated us to go deeper in this direction. these equations, we are able to iterate over a set of shells
In this work we study the BEGV model on the Bethe lat- to determine the properties of the following shell in direc-
tice in the infinite coordination limit. We find a plethora of tion of the centre of the lattice, and so forth. This allows
new aspects of this complex model. We determine many dif- us to determine the order parameters (magnetization and
ferent phase diagrams for different values of biquadratic near- quadrupole moment) of the shells of the Bethe lattice, as it
est neighbour interactions and crystal field, both individually is similarly done in [8]. For simplicity, we will denote the
and jointly. They show new ordered phases co-stable with shells of the Bethe lattice from the surface to the centre, as
ferromagnetic, paramagnetic or modulated phases. Finite illustrated in Fig. 1, with the surface shell denoted as n = 0
regions of modulated phases are present at the ground state. and the centre as n = N in the limit N → ∞.
Many multiphase points at the ground state were also found. In order to obtain the recurrence relations, we will take
A preliminary exploration of the effect of the external field partial traces over the spins, starting at n = 0 and moving
in the BEGV model is also shown, unveiling a great potential in the direction of the centre of the lattice. When we take
for exotic behaviour of the model. the trace over the shell n = 0 , we get effective fields act-
The paper is organized as follows. Section 2 contains ing on shells n = 1 and 2. We can also identify the effec-
the model description, which includes the calculation of tive interactions of the spins of those shells. Denoting
the recurrence relations and the three-dimensional map the r = z − 1 spins of the surface of a single branch as
related to the BEGV model on the Bethe lattice. Character- 𝜎01 , 𝜎02 , ..., 𝜎0r and the spins of the following shells n = 1 and
istic phase diagrams of the BEGV model without external 2 as 𝜎1 and 𝜎2 , and taking the trace over the surface spins
magnetic field are shown in Sect. 3. The nontrivial ground we get, for the 𝜎01 branch:
state of the model is the object of Sect. 4. Finally, Sect. 5 is
devoted to a peculiar external magnetic field behaviour of
the model while in Sect. 6 we draw our conclusions.
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Brazilian Journal of Physics (2023) 53:95 Page 3 of 11 95
From Eqs. (6) and (7) we can identify the expression for the
∑
Tr = exp[(G1 𝜎1 + G2 𝜎2 + GK 𝜎01 (𝜎1 )2
function defined in (8) as:
𝜎01 (2)
GD 𝜎01 B)𝜎01 ],
{
+ + )r
f 𝜎, 𝜎 � = 1 + 2eGD exp 2eGD ×
( ) (
(22)
( )
B2 = B + rU B0 , A0 , G2 , D0 , GK .
we can write the coefficients defined in Eq. (7) as
[ ] The factor r in Eq. (22) appears due to the fact that
1 f (1, 1)f (−1, 1) every spin on shell n = 2 is bound to r spins from shell
U = ln (9)
4 f (1, −1)f (−1, −1) n = 1, each one of those adding to an effective field U.
There is no need to find a relation for the crystalline field
1
[
f (1, 1)f (1, −1)
] in relation to shell n = 2 , for in the original Hamiltonian
V = ln (10) in Eq. (1) there is no biquadratic relation between second
4 f (−1, 1)f (−1, −1)
neighbours. Meanwhile the effective interaction between
[ ] spins from shell n = 1 and n = 2 is:
1 f (1, 1)f (−1, −1)
W = ln (11)
(23)
( )
4 f (1, −1)f (−1, 1) A1 = G1 + W B0 , A0 , G2 , D0 , GK .
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95 Page 4 of 11 Brazilian Journal of Physics (2023) 53:95
(25)
(
D2 = GD + Z B1 , A1 , G2 , D1 , GK
) ) ]/
qn = cosh H + rJ1 Mn−1 + r2 J2 Mn−2 ∕T
[(
{
1 −(D+rKqn−1 )∕T
(26) e +
( )
B3 = B + rU B1 , A1 , G2 , D1 , GK 2 (38)
}
2
[( ) ]
cosh H + rJ1 Mn−1 + r J2 Mn−2 ∕T .
(27)
( )
A2 = G1 + W B1 , A1 , G2 , D1 , GK .
And we can generalize these relations for a shell n, obtain- Now, to deal with the system on the infinite coordination
ing the total magnetic field, the total crystalline field and the limit, we can put rJ1 in evidence in Eqs. (37) and (38) and
effective interaction as redefine the relevant parameters to subsequently use them
( ) to generate the phase diagrams.
Bn = B + V Bn−1 , An−1 , G2 , Dn−1 , GK Then, we define our new finite and dimensionless model
( ) (28)
+ rU Bn−2 , An−2 , G2 , Dn−2 , GK parameters as:
−rJ2 K T
≡p ̃
≡K ̃
≡T (39)
(29)
( )
Dn = GD + Z Bn−1 , An−1 , G2 , Dn−1 , GK J1 J1 rJ1
(30)
( )
An = G1 + W Bn−1 , An−1 , G2 , Dn−1 , GK H ̃ D ̃
rJ1
≡H
rJ1
≡ D, (40)
From those effective fields we obtain the effective Hamil-
tonian for spins at the n shell of the Bethe lattice: where we draw special attention to the parameter p, since
∑ ∑ it measures the relative strength between first and second
Hn = −Bn 𝜎i − Dn 𝜎i2 , (31) neighbour spin-spin interactions, or equivalently, the compe-
i i
tition between ferromagnetic and antiferromagnetic interac-
and from it the average magnetization Mn and quadrupole tions, since we are interested in the case J1 > 0 and J2 < 0.
moment qn for the n-shell: Finally, since in the map defined in (37) and (38) the
magnetization Mn requires two previous iterations to be
−BHn
obtained ( Mn−1 and Mn−2 ), we can define an equivalent
∑
𝜎 𝜎i e 2eDn sinh Bn
Mn = ∑i −BH = , (32) three-dimensional map as:
𝜎i e
n 1 + 2eDn cosh Bn
xn ≡ Mn−1
∑ 2 −BHn
𝜎i (𝜎i ) e 2eDn cosh Bn
qn = = . (33) yn ≡ Mn (41)
e−BHn 1 + 2eDn cosh Bn
∑
𝜎i zn ≡ qn ,
Comparing Eqs. (15), (16) and (17) with Eqs. (32) and (33), and so we finally obtain the map associated with model:
we get the relations
xn+1 =yn (42)
(34)
( )
U Bn , An , G2 , Dn , GK = rG2 Mn ,
[( ) ]/
yn+1 = sinh yn − pxn + H ̃ ∕T
̃
(35)
( )
V Bn , An , G2 , Dn , GK = rG1 Mn ,
( )
1 − D+̃ Kz ̃
̃ n ∕T
{
e + (43)
(36)
( )
Z Bn , An , G2 , Dn , GK = rGK qn . 2 [( ) ]}
cosh yn − pxn + H ̃ ∕T
̃
Comparing Eqs. (28) to (36) and returning, when possible,
to the original Hamiltonian (1) constants, and choosing units [( ) ]/
where we can set kB = 1, we get the recursion relations for the zn+1 = cosh yn − pxn + H ̃ ∕T
̃
order parameters ( )
1 − D+̃ Kz ̃
̃ n ∕T
{
) ]/ e + (44)
Mn = sinh H + rJ1 Mn−1 + r2 J2 Mn−2 ∕T 2 [(
[(
) ]}
{ cosh yn − pxn + H ̃ ∕T
̃ .
1 −(D+rKqn−1 )∕T
e + (37)
2
} The starting parameters of the mapping (x1 , y1 , z1 ) are
cosh H + rJ1 Mn−1 + r2 J2 Mn−2 ∕T
[( ) ] equivalent to the choosing of the starting conditions of mag-
netization and the quadrupole moment on the most external
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Brazilian Journal of Physics (2023) 53:95 Page 5 of 11 95
3 Phase Diagrams
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state. We can also notice that both the ferromagnetic and the Another kind of observation that we can make in this
modulated phases are being “twisted” to the right. model is the effects of the crystalline field D on the T-p
Furthermore, as the parameter K becomes more nega- phase diagram. Similar to what was pointed out earlier for
tive, an antiquadrupolar phase starts to be favoured in the the K case, the nontrivial effects of D are those where D
paramagnetic phase region between the ferromagnetic and takes on negative values, favouring the value 0 for the spins.
the modulated phases, as can be noticed in Fig. 3(b)–(d). Some effects of decreasing the values of D from −0.2 to −0.5
This phase is characterized by a constant zero magnetiza- in the T-p phase diagrams are shown in Fig. 4.
tion and a quadrupolar moment alternating between 0 and The negative values of D show a first effect of widening
2/3. This means that the structure of this phase is composed of the modulated phase 1/6 on the ground state. As can be
a shell with all spins equal to 0, and so both magnetization seen, the phase now extends from a value equal to 1 + D to
and quadrupolar moment equal to 0, alternating with a shell a value equal to 1 − D. This is the same effect observed for
with spins states randomly distributed between values +1, 0 small negative values of K, and is true for 0 ≥ D ≥ −0.5.
and −1, with magnetization still 0 but quadrupolar moment Such widening effects of both parameters are observed more
2/3. For the case where K = −1.25, shown in Fig. 3(c), the clearly in the ground state phase diagrams shown in the next
antiquadrupolar phase becomes prevalent in relation to the section. Another visible effect is the increasing dominance
ferromagnetic phase, but the latter still exists in a small space. of the paramagnetic phase, which starts to take over the
For K = −1.5, Fig. 3(d), the antiquadrupolar phase has com- region of the phase diagram between the ferromagnetic and
pletely taken over the place of the ferromagnetic phase. modulated phases. In this process, the incommensurate mod-
Also, the distortions in the form of the phase boundaries ulated region and commensurate modulated phases close to
in the T-p phase diagram become more prominent as K is ferromagnetic phase, such as the 1/8 phase, becomes pro-
lowered. For K = −1.25, Fig. 3(c), we observe a “bending” gressively suppressed until they disappear for D = −0.5, as
of the ferromagnetic and modulated phases, which are curl- shown in Fig. 4, where we can see a direct transition between
ing on themselves, in a significant increase of the tendency the 1/6 and paramagnetic phases. As the temperature tran-
observed for K = −1.0 . For K = −1.5, Fig. 3(d), there is a sition between the paramagnetic and modulated phases is
greater increase of the “twisting” effect, with the 1/4 phase lowered, the remaining commensurate phases such as 2/10
dominating the ground state and narrowing the remaining become “squeezed”. All of these effects increase with the
commensurate modulated phases. It’s interesting to notice absolute value of D, as should be expected, since this change
that for K < −1.0 we can observe a direct transition from the favours the 0 state of the spins.
ferromagnetic phase to the 1/4 phase, without the phase 1/6 Some distinctions between the effects of the parameters
between them, as would be usual for the K = 0 case. K and D are easier to be observed for higher absolute values
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Brazilian Journal of Physics (2023) 53:95 Page 7 of 11 95
of these parameters, which can be done comparing Fig. 3(d) portions of the phase diagrams shown in Fig. 3 and Fig. 4
and Fig. 4(d). While the former destabilizes completely the with an initial condition M0 ≃ 0 in order to favour spe-
ferromagnetic phase, the latter diminishes it in temperature cially the convergence to disordered phases. We can see
by favouring the paramagnetic phase without shifting the that in the case of negative values of K the antiquadrupolar
modulated phases to lower values of p. In both cases the phase coexists with both ferromagnetic phase and modu-
region between the ferromagnetic and modulated phases lated phases in an intermediate temperature region and for
is occupied by the paramagnetic and/or the antiquadrupo- a small range of values of p. In the case of negative values
lar phases. Nonetheless, specially at low temperatures, for of the D, the paramagnetic phase coexists at low tempera-
higher values of −K there is a clear separation between fer- tures in a wide range of values of p with both ferromagnetic
romagnetic and the modulated phases. phase and modulated phases. The difference in range of
The effects of these parameters are further explored in a these effects lies in the very nature of K and D, while the
set of phase diagrams shown in Fig. 5, showing the results former is a biquadratic interaction between first neighbours,
of a combination of negative values of both D and K. The the last is a local field that promotes explicitly the 0 spin
resulting phase diagrams show a combination of the effects values, and this aspect is also reflected in the ground states
exhibited in Fig. 3 and Fig. 4, varying K and D individually. of the system.
There is the widening of the modulated phase 1/6 on the
ground state, as seen for both negative K and D, a separa-
tion between the paramagnetic and ferromagnetic phases for 4 Ground State
negative K, and a compression of the ferromagnetic phase
for negative D. Comparing the cases where K = −1.25 and To understand the low temperature properties, and hence,
D = −0.3, Fig. 5(d), with K = −1.25 and K = −1.5, both the basic structure of the ordered phases of the model, it is
with D = 0, Fig. 3(c) and (d), we can see that increasing −D important to investigate its ground states. One way to obtain
somewhat enhances effectively the value of −K , but also precise phase diagrams for the ground state of the system is
suppress both the antiquadrupolar phase and the reentrance to analyse the equations for the map (42)–(44) in the limit
of the 1/4 phase around it. of T → 0.
At last, it is important to mention that the map converges Since Eq. (42) for xn+1 is trivial, we need to concentrate on
to a minimum of the free energy of the system, which for the ones for yn+1 and zn+1 — Eqs. (43) and (44) respectively.
some set of parameters can be more than one, indicating For the purpose of clarity, we will first rewrite them in expo-
a coexistence of phases. For instance, in Fig. 6 we show nential form in order to obtain:
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95 Page 8 of 11 Brazilian Journal of Physics (2023) 53:95
xn+1 = yn
B ≡ D + Kzn − yn + pxn − H. (47)
eA∕T − eB∕T
yn+1 =
1 + eA∕T + eB∕T (45) When we take the limit of T → 0, the values of eA∕T and eB∕T
1
zn+1 = )−1 will depend only of the sign of A and B. Given that, there
are 4 possibilities to observe for the initial conditions of the
(
1+ e A∕T + eB∕T
map, corresponding to combinations of positive or negative
where values for A and B. After a simple analysis, we get to these
A ≡ D + Kzn + yn − pxn + H (46) possible correspondences for when T → 0:
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Brazilian Journal of Physics (2023) 53:95 Page 9 of 11 95
A > 0 and B > 0 → yn+1 = 0 and zn+1 = 1 , constant ↑ state across the Bethe lattice shells, the 1/4 ground
A > 0 and B < 0 → yn+1 = 1 and zn+1 = 1 , state that appears for 0 ≥ K > −1 corresponds to a periodic
(48) configuration of ↑↑↓↓. The 1/6 ground state corresponds
A < 0 and B > 0 → yn+1 = −1 and zn+1 = 1 ,
to ↑↑ 0 ↓↓ 0. Finally, the diluted 1/4 phase that appears for
A < 0 and B < 0 → yn+1 = 0 and zn+1 = 0 . K ≤ −1 corresponds to ↑ 0 ↓ 0 . The ground state structure
shown in Fig. 7(a), reflects the role of negative K in promot-
We can then iterate this simplified map, which depends ing 0 states as first neighbours of ±1 states.
only on the signs of A and B, from initial conditions of the Now we turn our attention to the effect of an increas-
system to generate precise phase diagrams for the ground ingly negative value of D on the ground states, shown in
states of the system. It’s interesting to notice that although Fig. 7(b). For D = 0 , we have the expected ferromagnetic
x1 depends on the value of y0 , x2 and beyond will depend on and 1/4 ground states. Increasing the absolute value of a
the values of the previous yn, which in turn depends only on negative D, it’s expected for states 0 to be favoured in all
the sign of A and B. Even so, because A and B also depend positions. As in the case with negative K, the first effect of
on the values of D, K, p and H, the modulated phases can a negative D on the ground state is the gradual appearance
have more than just four possibilities. Using this simplified of the 1/6 ground state between the ferromagnetic and the
map, we can obtain phase diagrams for many sets of param- 1/4 ground states. The main difference is that for D ≤ −0.5
eters on the ground state. Some of the most relevant ones we can notice the appearance of a constant 0 state across the
are presented in Fig. 7. Bethe lattice shells that increasingly dominates the phase
We can observe the effect of an increasingly negative diagram for increasing −D . Furthermore, it is remarkable
value of K on the ground states in Fig. 7(a). For K = 0, we that the diluted 1/4 ground state also appears for D ≤ −1, as
have the expected ferromagnetic and 1/4 phases. Increasing a result of the competition between p (that favours alternat-
the absolute value of K, it is expected for spin states 0 to be ing ±1 periodic states) and negative D (that favours 0 states),
favoured as when the first neighbour spins possess states allowing a transition between the diluted 1/4 phase and the
±1. This causes the 1/6 ground state to appear between fer- 0 ordered phase.
romagnetic and 1/4 ground states, and for higher values of By selecting an interesting value of p, we can observe
−K , a different 1/4 ground state, more diluted than the usual the combined effects of K and D on the ground state. In
one, dominates the phase diagram. To better understand this Fig. 7(c) we show the effect of both parameters in the case
effect, it is important to have a closer look at these ground p = 1.5 where ground states with interleaved +1 and −1 as
states. Let us denote ↑ as the +1 spin state, ↓ as −1, and second neighbours are preferred. It is important to remember
0 otherwise. Apart from symmetry related degenerescen- that negative K favours 0 spin states in vicinity of ±1 spin
cies, while the ferromagnetic ground state corresponds to states, while negative D favours 0 states everywhere. There
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95 Page 10 of 11 Brazilian Journal of Physics (2023) 53:95
and inside the blob represent the 1/6 phase. The lower right
portion of this blob we can see that modulated phases fold
over each another, while the lower left region shows a com-
plex structure that could indicate signatures of chaos with
shrimp structures [16]. This and other effects of the external
field will be the subject of further investigation.
6 Conclusions
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Brazilian Journal of Physics (2023) 53:95 Page 11 of 11 95
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