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MH-CET CELL
Chemistry

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Total Questions : 50 Total Marks : 50
Roll No.
18-Jul-2021
XII - A Div 10:00 AM To 12:00 PM

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This is to certify that, the entry of Roll No. has been correctly written and verified.

Candidate’s Signature MH-CET Chemistry Invigilator’s Signature

Note :
i) All Questions are compulsory

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ii) Darken ( ) the appropriate circle(#) of the most correct option/response with black ball point pen.

1) The following reaction is known as

____________. cl Amines

4) If on acylation, an amine produces only

monoacetyl derivative, then it must be
___________.
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A) primary amine

B) secondary amine
A) Mendius reduction
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C) tertiary amine
B) Hofmann elimination
D) quaternary ammonium salt
C) Hofmanns exhaustive alkylation 5) The products formed, when ethylamine reacts
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with acetic anhydride are N-ethylethanamide

D) Hofmann rearrangement and ____________.
2) Quaternary ammonium hydroxides on strong
heating undergo ___________ to give an alkene. A) CH3 CH2 COOH B) CH3 COOH
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A) β -elimination B) α -elimination C) H3 C − CH2 − NH2 D) CH3 CONH2

6) Gabriel phthalimide synthesis is used for the

C) substitution D) methylation preparation of ___________.
3) Which of the following can be used for
acylation of amines? A) primary aromatic amines
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A) Acetic anhydride B) Benzoyl chloride B) secondary amines

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C) Acetyl chloride D) All of these C) primary aliphatic amines

D) tertiary amines
 7) Ethanamine on acetylation using ethanoyl 12) Ethylamine reacts with HNO2 to form
chloride gives ____________. ___________.

A) N-ethylethanamide A) CH3 − CH2 − O − N = O

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B) N,N-diethylethanamide B) CH3 − CH2 − O − CH2 − CH3

C) N-methylethanamide C) CH3 CH2 OH

D) N,N-dimethylethanamide D) CH3 − CH2 − NO2

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8) Which of the following is FALSE regarding the 13) The gas evolved when aliphatic 1◦ amine reacts
acetylation of amines? with nitrous acid is ___________.

A) Acetylation can be carried out by acid anhydride A) NH3 B) SO2 C) H2 D) N2

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or acetyl chloride.
14) Reaction given below is an example of
___________.
B) Ethylamine on acetylation gives
N-acetylethylamine.

C) Diethylamine on acetylation gives N-acety

ldiethy lamine. clA) addition reaction
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B) displacement reaction
D) Triethylamine on acetylation gives
N,N-Diacetylethylamine.
C) elimination reaction
9) Primary amines give _________ test.
D) rearrangement reaction
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A) iodoform B) Schiff"s
15) Which of the following can be categorised as
Sandmeyer reaction?
C) Lucas D) carbylamine

10) The foul smelling product of carbylamine

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reaction contains which of the following group?

A) −CN B) −NC

C) −O − N = O D) −N+
2X
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16) Identify Gattermann reaction from the following.

11) A nitrogen containing organic compound (X) on
heating with chloroform and alcoholic KOH,
formed foul smelling compound. The
compound (X) could be ___________.

A) N-methylmethanamine
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B) N,N-dimethylmethanamine 17) X is _______________.

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C) aniline

D) N,N-diethylethanamine
 A) benzene B) phenol A) 1 B) 2 C) 3 D) 4

24) Hinsbergs reagent is ____________.

C) benzyl alcohol D) cyclohexanol

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18) Which one is NOT the reaction of diazonium A) diethyl oxalate
salt?
B) benzyl chloride
A) Sandmeyer reaction
C) benzenesulphonyl chloride
B) Gattermann reaction

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D) benzenediazonium salt
C) Orange dye test
25) In Hinsbergs test, ethylamine forms
_____________.
D) Carbylamine reaction

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19) Reaction between diazonium fluoroborate and A) a product which soluble in alkali
sodium nitrite in presence of copper replaces
diazonium group with ____________.

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B) a product which insoluble in alkali

A) −NO3 group B) −NO2 group C) a silver mirror

C) −NO group D) −NO2 group D) an orange dye

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20) X is ____________. 26) Identify the INCORRECT statement from the
following.

A) 1◦ , 2◦ and 3◦ amines can be differentiated

A) benzene B) nitrobenzene using Hinsbergs reagent.
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C) fluorobenzene D) aniline B) 1◦ Amines react with Hinsbergs reagent to form

a product which soluble in alkali.
21) Which of the following is azo group?
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C) 2◦ Amines on reaction with Hinsbergs reagent

A) −N = B) −N = N−
forms a product containing H-atom attached to
nitrogen.
C) −NH− D) −CO − NH−

22) Which of the following reaction involves D) 3◦ Amines do not react with Hinsbergs reagent.
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retention of diazo group?

27) −NH2 group in aniline is __________ group.

A) highly ring activating and o-/p-directing

B) weakly ring activating and o-/p-directing

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C) highly ring deactivating and m-directing

23) Azo coupling reaction with respect to aniline
takes place at position number ___________. D) weakly ring deactivating and m-directing
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28) Aniline reacts with bromine water at room

temperature to give ___________.
 A) bromobenzene A) isomers

B) 2-bromoaniline B) homologous

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C) 4-bromoaniline C) same

D) 2,4,6-tribromoaniline D) different primary amines

29) Direct nitration of aniline yields 33) In amines, the hybridisation state of N is

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_________ nitroaniline. __________.

A) ortho and para-substituted A) sp B) sp2 C) sp3 D) sp2 d

34) Example(s) of primary amine is(are)

B) meta substituted
__________.

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C) para substituted
A) aniline B) isobutylamine
D) o-, m-, p-substituted

30) In order to get p−nitroaniline as major product

from aniline, which of the following sequence
will be effective?
cl C) sec-butylamine D) all of these

35) Secondary amine(s) from the following is/are

___________.
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A) Acetylation → nitration → hydrolysis

B) Nitration → acetylation → hydrolysis

C) Diazotization → nitration → hydrolysis

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D) Diazotization → acetylation → nitration

31) Aniline reacts with conc. H2 SO4 to give X, 36) Match the following.
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which on heating at 453-473 K gives

___________.

A) benzene sulfonic acid

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B) salicylic acid

C) anilinium hydrogen sulfate

A) i - d, ii - c, iii - b, iv - e
D) sulfanilic acid

32) In the reaction, the starting compound and B) i - e, ii - b, iii - d, iv - a

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product C are _____________.

C) i- c, ii - a, iii - b, iv - e
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D) i - e, ii - d, iii - b, iv - a

37) Which of the following is an example of

symmetrical amine?
 A) Methylpropylamine

B) Methylisopropylamine

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C) Diethylamine
A) N,N-dimethylpropan-2-amine
D) Ethyldimethylamine
B) N,N-dimethylaminoisopropane
38) Identify the simple 3◦ amine from the following.

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C) N,N-dimethylaminoethane
A) Ethyldimethylamine
D) N,N-dimethyl-2-aminobutane
B) Trimethylamine
43) The IUPAC name of the compound is
___________.

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C) Ethylmethyln-propylamine

D) Dimethylamine

39) Match the following.

clA) N,N-dimethyl-N-propyl-3-propanamine

B) N-methyl-N-propylbutan-2-amine
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C) N-butylmethyl-n-propylamine
A) i- d, ii - a, iii - b, iv - c
D) N-ethyl-N-propylbutan-2-amine
B) i- b, ii - c, iii - d, iv - a
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44) The IUPAC name for (CH3 )2 NC(CH3 )3 is

_______________
C) i- b, ii - d, iii - a, iv - c
A) N,N-dimethyl-2-methylpropan-1 -amine
D) i- c, ii - d, iii - b, iv - a
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40) C3 H9 N can represent ____________. B) N,N-dimethyl-2-methylpropan-2-amine

A) primary amine B) secondary amine C) N,N-dimethylbutan-2-amine

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C) tertiary amine D) all of these D) N,N-dimethylpropanamine

41) IUPAC name of isopropylamine is ___________. 45) Ethyl bromide when heated with alcoholic NH3
in a sealed tube gives________. (I) ethylamine
A) propan-1-amine (II) diethylamine (III) triethylamine (IV)
tetraethylammonium bromide
B) 2-methylethanamine
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A) only I B) only III

C) 1-methylethanamine
C) I, II and III D) I, II, III and IV
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D) propan-2-amine 46) Triethylamine X is ________.

42) The IUPAC name of the compound given below
is ____________.
 A) nitromethane B) nitroethane

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C) ethyl cyanide D) 1−nitropropane

47) N−Ethyl−N−methylethanamine Identify

compound X .

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A) Nitroethane B) Nitromethane

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C) 1−Nitropropane D) 2−Nitropropane

48) 2−Chloropropane The compound Y is

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____________.

A) (H3 C)2 CH−CH2 −NH2

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B) (H3 C)2 CH−CONH2

C) (H3 C)2 CH−CH3

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D) (H3 C)2 CH−NH−CH3

49) N−Methylethanamine X is ____________.

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A) chloroethane B) chloromethane

C) n−propyl chloride D) isopropylchloride

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50) Indicate which nitrogen containing compound

amongst the following would undergo
Hofmanns reaction (i.e., reaction with Br2 and
conc. KOH) to furnish the primary amine
(R − NH2 ).
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 Answer Sheet

Chemistry : Amines
Total Questions : 50 Total Marks : 50

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1 B 2 A 3 D 4 B 5 B 6 C 7 A 8 D 9 D 10 B 11 C 12 C
13 D 14 B 15 A 16 B 17 B 18 D 19 B 20 C 21 B 22 B 23 D 24 C

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25 A 26 C 27 A 28 D 29 D 30 A 31 D 32 C 33 C 34 D 35 D 36 A
37 C 38 B 39 B 40 D 41 D 42 A 43 B 44 B 45 D 46 B 47 B 48 A
49 A 50 C

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