2.

Give two points of differences between

electrochemical and electrolytic cells.
(2/5, 2020)(R
Define electrochemical cell. What happens if
external potentialapplied becomes greater than Ecell
of electrochemical cell?
(AI2019, 2/5, Al 2016)U)
 Calculate the emf of the following cell at 298 K:
Fea|Fe*(0.01 M)||HM, lH2g) (1 bar), Ptg
Given Eell=0.44V. (2023)
10. Calculate A,G for the cellreaction at 25°C:
Zn| Zn2||Ca?* | Cd
Given that : E°z,2+Zo =-0.76V,
Eca2+/Cd=0/.40 V, 1 F=96500 Cmol (2023)
11. Write the Nernst equation for the following cell
Nreaction: 2+
Zn + Cua ’ Znoa+
(aq) Cus)
How willthe Erell be affected when concentration of
(i) Cu*ions is increased and
(ii) Zn* ions is increased? (Term I.2021-22)
12. For an electrochemicalcell
+ 2+
N M89 +Ag tag)
(aq) ABs) + Mgoa)
give the cell representation. Also write the Nernst
equation for the above cell at 25°C. (2020)
 2+
NMB) + Ag (aa) ’ABs) + Mgag)
give the cell representation. Also write the Nernst
equation for the above cell at 25°C.
(2020)
13 Calculate the emf of the following cell at 25°C:
Alg |AI* (0-001 M) ||NI* (0.1 M) |Nis)
Given: EN2*/ND=-0-25 \V
EiAI3+/A)= -1-66 V
[log 2= 0-3010, log 3 = 0-4771] (2019) E)
14. Calculate A,G° for the reaction:
2+
M8) + CuaMgaa +Cug
+
Given Eell = +2.71V, 1 F = 96500 Cmol1
(2/3,AI 2014) Ap
15. Equilibrium constant (Ke) for the given cell reaction is
10.Calculate Ecell
Als) B t
+ Bad)
(aq) A(aq) + B(s) (2/3.Foreign 2014)
 Calculate A,G° and log K for the following cell:
174 ¡2+
Nia +2Agog) ’ Nifga+ 2Ag
NNGiven that Eell= 1.05 V,1F= 96,500 Cmol-1
(Term I,2021-22)
OR
Calculate the maximum work and logK,for the given
reaction at 298 K :
Nig+ 2ABiog) Nijag) +2AB)
Given:ENN=-0.25 V, EAgIAg =+0.80 V
1F= 96500 C mol (2020)
OR
For the cell reaction,
Nig |Nifogl|AB)|AB
Calculate the equilibrium constant at 25°C. How
much maximum work would be obtained by
operation of this cell?
E2+=-0.25V andEAg/Ag =0.80V
 18. Calculate the e.m.f. of the following cellat 298K:
N Fe|Fe (0.001 M)||H*(0.01 M) |H2 (1 bar) | Pts
Given that Eell =+0.44 V
[log 2 =0.3010, log 3 = 0.4771, log 10 = 1]
(Term I,2021-22) Ev
OR
Calculate emf of the following cellat 25°C:
Fe|Fe(0.001 M)||H´(0.01 M)IH2(1 bar)|Pt
E(Fe2*/Fe) =-0.44 V, EH*H) =0.00 V (Delhi 2015)
19. Calculate AG° for the reaction,
N Zns +Cuaa)
(aq) ’ Znaa)
(aq) +Cus)
Given: E° for Zn/Zn = -0.76 V and
E° for C"/Cu = +0.34 V
R=8.314JK mol,1F= 96500 Cmol,
(3/5,2020)
20: Calculate e.m.f of the following cell:
N Znl Zn (0.1 M) |Ag* (0.01 M) | Ag
Given:Eznz=-0.76V, EAet/Ag =+0.80V
[Given: log 10 = 1] (3/5, 2020)
21. Calculate A,G° and log Kfor the following reaction.
Cdo +Zns’Znfag) 2+ +
t Cdg)
Given:Eca2tcd=-0.403 V;E2+n =-0.763 V
20: Calculate e.m.f of the followingcell:
Znl|Zn (0.1M) |Ag*(0.01 M)|Ag
Given:Ez2tZn=-0.76V,East/Ag=+0.80 V
[Given : log 10 =1] (3/5, 2020)
21. Calculate A,G° and log K,for the following reaction.
cd aa) +Zng)’Znfo)
(aq) +Cdg)
Given:Eaca=-0.403 V;E2n=-0.763V
(AI2019) Ap
22. Zinc rod is dipped in 0-01 Msolution of zinc sulphate
when temperature is 298 K. Calculate the electrode
potential of zinc.
(Given:E~2tZn = -0-76 V; log 10 =1) (2019C) Ev
23. Write the cell reaction andcalculate the e.m.f. of the
following cell at 298 K.
Snal Sn(0.004 M) || H*(0.020 M) |H2(1 bar)|Ptg
(Given:En/Sn = -0.14 V) (3/5, 2018) U
24. For the reaction,
 2AgCl + H2g) (1 atm)’2Ags +2H*(0.1 M)
+2CI (0.1M)
AG° =- 43600 Jat 25°C.
Calculate the e.m.f. of the cell. (log 10=-n)
(3/5, 2018)
25. Calculate e.m.f. of the following cell at 298 K.
2Cr(s + 3Fe(0.1M) ’ 2Cr(0.01M) +3Fe
Given:Ec3t/C) =-0.74 V,Ee2+/Fe) =-0.44V
(Delhi 2016)
26. Calculate Ecellfor the following reactionat 298 K.
2Ala+3Cu?(0.01M) ’ 2A*(0.01M)+3Cu
Given:Erell =1.98V (3/5,Al2016)
27. Calculate the standard cell potential of the galvanic
N cell in which the following reaction takes place:
Fe2t
(aq))+ Agtag) ’ (aq) -ABs)
Calculate the A,G° and equilibrium constant of the
reaction.

Ag*/Ag =0.80 V:EçFee -0.77V)

(3/5, Delhi 2015C)(U)
28. Calculate the emf of followingcell at 298 K:
M8s) | Mg"(0.1M) || Cu"(0.01 M)|Cus
mol1
(Given: EPl = +2.71 V, 1 F= 96500 C
(3/5, Delhi2014)
 (3/5, Delhi 2015C)U
28. Calculate the emf of following cell at 298 K:
N M8s | Mg"(0.1 M) ||Cu*(0.01 M)|Cus
[Given: Eell =+ 2.71 V,1 F= 96500 Cmol]
(3/5, Delhi 2014)
29. Estimate the minimumpotential difference needed
to reduce Al,O at 500°C. The Gibbs energy change
for the decomposition reaction,
2 4
Al;O3’Al+O,
3 is 960 kJ. (F= 96500Cmol-)
(3/5,Delhi2014C)
LA (5marks)
30. Ecelj for the given redox reaction is 2.71 V.
2+ 2+
MBs+Cu (0.01M)’ Mg (0.001M)+Cus)
Calculate Erel for the reaction. Write the direction of
flowof current when an external opposite potential
applied is
() less than 2.71 V and
(i) greater than 2.71 V (Delhi 2019)
31. Calculate e.m.f and AG for the followingg cell
N MEg Mg (0.001 M) || Cu+(0.0001 M)|Cus)
E
(Mg*Mg) =-2-37 V,Fcukt/=+0.34 V
(NCERT, AI 2015)
 34. Give reason:
Conductivity of CHCOOH decreases on dilution.
(1/5, 2018) (U)
35. Define limiting molar conductivity. Why conductivity
the
of an electrolyte solution decreases with
decrease in concentration? (1/2, Delhi 2015)
OR
Define the follovwing term:
Limiting molar conductivity (1/5, Delhi 2014)
B 36. State Kohirausch's law of independent migration of
ions.Write its one application. (1/2, Foreign 2015)
OR
Define the following term:
Kohlrausch's law of independent migration of ion_.
(1/5, Delhi 2015C)(R
37. Define the following term:
Molar conductivity (Am) (1/5, Delhi2015C)
38. On diluting two electrolytes 'A' and 'B, then A, of 'A'
increases 25 times while that of 'B' increases by 15
times.Which of the two electrolytes is strong? Justify
your answer graphically. (2023)
39. () State Kohlrausch's law of independent migration
of ions.
(ii) Calculate the degree of dissociation () of
CH;COOH if Am and A of CH,COOH are 48
Scmmol and 400 S cm
molrespectively.
(Term lI,2021-22)
40. The conductivity of 0.001 M acetic acid is
7.8x 10S cm,Calculate its degree of dissociation
if A, for aceticacid is 390 Scm² mol
(Term Il, 2021-22) (Ap
41. Inaplot of A against the square root of concentration
(Ce) for strong and weak electrolyte, the value of
limiting molar conductivity of a weak electrolyte
cannot be obtained graphically. Suggest a way to obtain
this value.Also state the related law, if any.
(Term II, 2021-22) (EV
42. Answer the following questions (Any two):
(a) Define molar conductivity (Am).
(b) Write the unit of Am
(c) How does Am vary with concentration?
(TermlI,2021-22 C)
43. Answer the following questions (Any two):
(a) Why is alternating current used instead of
direct current for measuring resistance of an
electrolytic solution ?
(b) State Kohlrausch's law of independent migration
of ion.
(c) Depict the Galvanic cell in which the followine
reaction takes place:
Mg+CuaMgo) +Cuis
(Term II, 2021-220)
44. X and Y are two electrolytes. On dilution molar
conductivity of 'X increases 2.5 times while that
Y increases 25 times. Which of the two is.a weak
electrolyte and why? (2/5, 2020) (Ap)
45. In the plot of molar conductivity (Am) vs square
root of concentration (c),following curves are
obtained for two electrolytes A and B

A
B
c/2
Answer the following:
() Predict the nature of electrolytes A
and B.
(ii) What happens on extrapolation of Nm t0
concentration approaching zero for electrolytes
A and B? (2/5,Delhi 2019) E
46. Explain with a graph, the variation of molar
conductivity of a strong electrolyte with dilution.
(2019)
 46. Explain with a graph, the variation of molar
conductivity of a strong electrolyte with dilution
(2019)
A7. Calculate the degree of dissociation () of acetic acid
if its molar conductivity (Am) is 39.05 S cm mol1
(Given: 2°(H") =349.68S cm²mol and
2°(CH,CO0) =40.9S cm molr) (Delhi 2017)
48.. Define the term degree of dissociation. Write an
expression that relates the molar conductivity of a
weak electrolyte to its degree of dissociation.
(2/5, Delhi 2015C)(C
49. Define conductivity and molar conductivity for the
solution of an electrolyte. Discuss their variation
withconcentration. (NCERT, 2/5, Al2015C)
50. State Kohlrausch law of independent migration
of ions. Why does the conductivity of a solution
decrease with dilution? (AI2014)
51. Define the termsconductivity and molar conductivity
for the solution of an electrolyte. Comment on thelf
variation with temperature.
(Delhi, Al 2014C)(U
52. The resistance of 0.01 M NaCl solution at 25°C IS
200 S2. The cell constant of the conductivity cell
1 used is unity. Calculate the molar conductivity of the
solution. (2/3, AI2014C)
 Calculate Erellfor the reaction.
(Given: 1F = 96500 C moIl)
(b) Calculate mfor MgCl, if ° values for Mg+
jon and CI ion are 106 SS cm mol1 and
76.3 S cm mol respectively. (Term I, 2021-22)
549 The conductivity of 0.001 mol L1 solution of
W
N CHCOOH is 3.905 x 10ScmCalculate its molar
conductivity and degree of dissociation (a).
[Given:2° (H") =349.6 Scm moland2°(CH,CO0)
=40.9 S cm² mol]
(Term II,2021-22C, 3/5, Al2016)
55. Conductivity of 2 x 10 M methanoic acid is
8x 10Scm.Calculate its molar conductivity and
degree of dissociation if A for methanoic acid is
404 S cm mol1 (2020)
56. Out of the following pairs, predict with rason which
pair willallow greater conduction of electricity.
() Silver wire at 30°C or silver wire at 60°C.
(ii) 0.1 M CH,COOH solution or 1 M CHCOOH
solution.
(iii) KCI solution at 20 °Cor KCI solution at 50 °C.
(3/5, 2020)
 M KOH
E7 The electricalresistance of a column of 0.05
solution of length 50 cm and area of cross-section
0 625 Cm is 5 x 10° ohm. Calculate its resistivity,
conductivity and molar conductivity. (3/5,2020)
Following reactiontakes place in the cell:
58. (a) 2+
Zns + AB2O1) +Hz0Znfag) +2A8) +20Hio4)
Calculate A,G°of the reaction..
[Given:Ezn2*/Zn) =-0.76 V,
EAgt/Ag) = 0-80V, 1 F = 96,500 C mol1]
(b) How can you determine limiting molar
conductivity, (A) for strong electrolyte and
weak electrolyte ? (2019)
59. The conductivity -1of 0.20 mol L solution of KCI is
2.48 x 10-S cm Calculate its molar conductivity
and degree of dissociation ().
Given:2 (K)=73.5 S cm mol and
A (CI)= 76.5 S cm² mol1 (AI2015)
60. Resistance of aconductivity cell filled with 0.1 mol L1
KClsolution is 100 Q, If the resistance of the same cell
when filled with 0.02 mol L KCIsolution is 520 S2,
calculate the conductivity and molar conductivity
of 0.02 mol L KCI solution. The conductivity -1
of
0.1 mol L KCI solution is 1.29 x 10*cm
(3/5, AI2014) (Ap)
63. i) The electrical resistance of a column of
0-02 M NaOH solution of diameter 1-40 cm and
length 44 cm is 5-00 x 10 ohm. Calculate its
resistivity, conductivity and molar conductivity.
(i) Depict the galvanic cell in which the reaction
takes place:
Nig +2Agod) ’ ’Ni
Nifog) +2AS)
Further show:
(i) Which of the electrodes is positively charged?
(ii) The carriers of the current in the outer circuit.
(2021C) (An
64. (a) Represent the cellinwhich the following reaction
takes place:
2Al + 3NI (0-1 M) ’ 2A* (0-01 M) +3Ni)
Calculate its emf if Eel =1-41 V.
(b) How does molar conductivity vary with increase
inconcentration for strong electrolyte and weak
electrolyte? How can youobtain limiting molar
conductivity (A) for weakelectrolyte? (2019)
66. Howmuch charge in terms of Faraday is
required to
reduce one mol of MnO, to Mn*?
(2020) Ev
67. HoW many coulombs are reguired for the oxidation
of1 mol of H,0 to O2? (One word, 2020)
68. Give reason:
On the basis of E° values, O, gas should be liberated
at anode but it is Cl, gas which is liberated in the
electrolysis of aqueous NaCl. (1/5, 2018)(U
69. Following reactions oCcur at cathode during the
electrolysis of aqueous silver chloride solution :
Ag" (aq) +e ’Agte EO= +0.80 V
1
H(aa) te ’ Hag),
2
E°= 0.00 V
On the basis of their standard reduction electrode
potential (E) values,which reaction is feasible at the
cathode and why? (AI2017C, 1/2, Delhi 2015)
70. How much charge is required for the reduction of
11mol of Zn toZn? (Delhi2015)
71. Following reactions occur at cathode during the
electrolysis of aqueous copper (ll)chloride solution:
Cufo) t+ 2e’ Cus) i E =+0.34 V
1
Hia) te ’ Hzg) E° =0.00V
2
On the basis of their standard reduction electrode
potential (E°)values, which reaction is feasible at the
cathode and why? (1/2, Foreign 2015) Ev
72. State the Faraday's first law of electrolysis.
{ (Delhi 2015C) (A
73. (i) What should be the signs (positive/negative)
for Ell and AG° for aspontaneOus redox reaction
occurring under standard conditions?
(ii) State Faraday's first law of electrolysis. (2023)
74, Predict the products of electrolysis of an aqueous
< solution of CuCl, with platinum electrodes.
(Given:E cu2t/C, =+0.34 V,
E(v2C1,/CI)=+1.36 V
EH'H Pt =0.00 V,E (V20,/H.0) =+1.23 )
(2/5, 2020)
75. Predict the products of
electrolysis in each of the
following:
(a) An aqueous solution of CuSO, with Pt
(b) An aqueous solution of electrode
AgNO, Wwith Pt electrode
(2020C)
76. How many seconds does it
of Fe to Fe with 2 A require to reduce 3 moles
current?
(Given: 1 F= 96500 Cmol)
77. Folowing (2020C)
reactions may occur at cathode and anode
during electrolysis of aqueous
What products will be held at sodium chloride.
Use given E° values to anode and cathode'
Cathode:Naoa) +e ’Nas) justify youranswer.
1 E° =-2.71 V
Hig) +t e ’H2g) E° = 0.00 V
1
Anode: Cli)’Clzg) +e te E°= + 1-36 V
2H,0(aa)’O2(g) t4H* +4eE° =+1-23 V
(2019) A
 (Given: Molar mass of Ag = 108 g mol,
1F=96500 Cmol) (2/3, Delhi 2017)
79. State Faraday'sfirst lawof electrolysis. Howmuch
N charge in terms of Faraday is required for the
reductionof 1 mol of Cu to Cu? (2/5, Delhi2014)
80. A solution of Ni(NO,) is electrolysed between
N platinum electrodes using a current of 5.0 ampere for
20minutes. What mass of nickel will be deposited at
the cathode?
(Given: At. mass of Ni =58.7 g mo,
1F =96500 Cmol) (Foreign 2014)
81. Predict the products of electrolysis in each of the
following:
(0) An aqueous solution of AgNO3 with platinum
electrodes.
() An aqueous solution of H,SO4 with platinum
electrodes. (2/5, Delhi 2014C)
8 When a steady current of 2A was passed through
two electrolytic cells Aand Bcontaining electrolytes
ZnsO4 and CuSO4 connected in series,2 g of Cu were
deposited at the cathode of cell B. Howlongdid the
current flow ?
What massof Zn was deposited at cathode of cellA?
[Atomic mass: Cu =63.5 g mol,Zn =65gmol 1F
96500 C mol]
(2020)(Ev
83. A steady current of 2 amperes was passed through
two electrolytic cells X and Y connected in series
containing electrolytes FeSO4 and ZnSO4 until
2.8 g of Fe deposited at the çathode of cell X.
How long did the current flow? Calculate the
mass of Zn deposited at the cathode of cell Y.
(Molar mass : Fe = = 56 g mol, Zn ==65.3 g mol,
1F= 96500 Cmol) (3/5, Delhi 2019)
 Asteady current of 2 amperes was passed through
83.
two electrolytic cells X and Y connected in series
containing electrolytes FeSO4 and ZnSO, until
28 gof Fe deposited at the cathode of cell X.
How long did the current flow? Calculate the
mass of Zn deposited at the cathode of cell Y.
(Molar mass : Fe =56 gg mol, Zn =65.3 g mol-1
1F= 96500 Cmol) (3/5, Delhi 2019)
84. Chromium metal is electroplated using an acidic
solution containing CrOz according to the following
equation:
CrO3ag) t óH" +6eCris+ 3H,0
Calculate how many grams of chromium will be
electroplated by 24,000 coulombs. How long will
it take toelectroplate 1.5 g chromium using 12.5 A
current?
[Atomic mass of Cr = 52g mol1F=96500 C mol
(Al2019)
85. (a) The cell in which the following reaction occurs:
2Fe3+(ag) t 21 (aa) ’ 2Fe la) + l2s
cell = 0.236 V at 298 K. Calculate the
has Ecell
standard Gibbs energy of the cell reaction.
(Given: 1 F= 96,500C mol) (NCERT Intext)
(b) How many electrons flow through a metallic
wire if a current of 0.5 A is passed for 2 hours?
(Given: 1 F=96,500 Cmol) (AI 2017)
86. () State Kohlrausch's law of independent migration
of ions. Write an expression for the limiting molar
conductivityof acetic acid according to Kohlrausch's
law.
(ii) Calculate the maximum work and log K for the
given reaction at 298 K:
Ni(s + 2A8 (aq) Ni (aq) ++2Ag)
=+0.8OV
Ni/Ni =-0.25 V, EAgt /Ag
Given: E2+ E.
1F=96500 C mol (2023)
 2015C)(R
87. Define: Secondary batteries (1/5, Delhi
SAI (2 marks)
in
88. Write the name of the cell which is generally used
hearing aids.Write the reactions taking place at the
anode and the cathode of this celI. (AI 2017(R
89. Write the name of the cell which is
generally used
in inverters. Write the reactions taking place at the
anode and .the cathode of thiscell. (AI 2017)
90. Write the name of the cell which is generally used in
transistors. Write the reactions taking place at the
anode and the cathode of this cell. (AI2017)
91. What type of battery is mercury cell? Why is it more
advantageous than dry cell? (2/5, Al2015) (U
LA (5 marks)
92. (a) The conductivity of 0-001 mol L1 acetic
N acid is 4.95 x 10 S cm, Calculate the
dissociation constant if A°m for acetic acid is
390.5 S cm² mol-1
(b) Write Nernst equation for the reaction at 25°C:
2Alg +3Cufan)’ 2Ala0,
(aq) +3Cu9
(c) What are secondary batteries? Give an example.
(2019)
93. Which of the following cell was used in Apollo space
programme?
(a) Mercury cell (b) Daniellcell
(c) H,-0, Fuelcell (d) Dry cell (2023)
VSA (1 mark)
94. Name the celluse in hearing aids and watches.
< (2020)R
95. Name the type of cell which was used in Apollospace
programme. (2020, 1/3, Al 2014)
96. Define: Fuel cell
1 (Delhi 2017, 1/5,Delhi 2015C, 2014)
 Give two advantages of fuel cells. (2/5, 2020)
98. Define fuel celland write its two advantages.
(2/5, 2018) (R
99, From the given cells:
Lead storage cell, Mercury cell, Fuel cell and Dry cell
Answer the follovwing:
(1) Which cellis used in hearing aids?
(i) Which cellwas used in Apollo space
programme?
(iii) Which cell is used in automobiles and
inverters?
(iv) Which cell does not have long life?
(Delhi 2016)( R