MM.40 S. S.

1-6=1marks 7-9=2marks 10-12=3marks

Set M CHEMISTRY Date:06 JAN 2023 13-15=5marks 16=4marks

10
1. Equilibrium constant (Kc) for the given cell reaction is 10 . Eocell for reaction
A2+ + B+  A3+ + B is :
(a) 0.0591V (b) 5.91 V (c) 0.00591V (d) 0.0591V
2. What is slope value obtained in the plot of log [Ro] / [R] Vs. time for a
first order reaction.
(a) + k/2.303 (b) 2.303/k (c) – k (d)– k/2.303
3.The oxidation state of Ni in [Ni(CO)4] is
(a) 0 (b) 2 (c) 3 (d) 4
4Total number of unpaired electrons present in Co3+ (Atomic number = 27) is
(A) 2 (B) 7 (C) 3 (D) 5
5. Predict the order of reaction in the given graphs :

(a) First (b) Second (c) Zero (d) Order cannot be determined
6. Assertion (A) : Conductivity of an electrolyte increases with decrease in
concentration.
Reason (R) : Number of ions per unit volume decreases on dilution.
7.Calculate the time to deposit 1.27 g of copper at cathode when a current of 2 A was passed
through the solution of CuSO4. (Molar mass of Cu = 63.5 g mol1, 1 F = 96500 C mol1)
8. Using IUPAC norms write the formulae for the following :
(a) Sodium dicyanidoaurate(I)
(b) Tetraamminechloridonitrito-N-platinum(IV) sulphate

9. Define half-life of a reaction. Write the expression of half-life for

(i) zero order reaction and (ii) first order reaction.
10. (a) Write the IUPAC name of the isomer of the following complex : [Pt(NH3)2Cl2]

(b) Write the formula for the following : Tetraammineaquachloridocobalt(III) nitrate

(c) Write the use of Wilkinson catalyst.
11. In a galvanic cell, the following cell reaction occurs :
Zn (s) + 2 Ag+ (aq) Zn2+ (aq) + 2 Ag (s) Eo cell = + 1·56 V
(a) Is the direction of flow of electrons from zinc to silver or silver to zinc ?
(b) How will concentration of Zn2+ ions and Ag+ ions be affected when cell functions ?
(c) Write Nernst equation for given reaction
12. (a) Write the formula of the following coordination compounds:
Iron(III)Hexacyanoferrate(II)
(b) What type of isomerism is exhibited by the complex [Co(NH3)5Cl]SO4 ?
(c) Write the hybridisation & number of unpaired electrons in the complex [CoF6] 3-
13.(i)Conductivity of 2.5 104 M methanoic acid is 5.25 105 S cm1. Calculate its molar
conductivity and degree of dissociation. Given : 0(H+) = 349.5 S cm2 mol1 and
0(HCOO) = 50.5 S cm2 mol1.

(ii)Calculate e.m.f.& G for the following cell at 298 K : E0 (Mg 2+/Mg)= – 2.37 V
Mg (s) | Mg2+ (0.01 M) || Ag+ (0.0001 M) | Ag (s), E (Ag /Ag )= + 0.80 V.
MM.40 S. S. 1-6=1marks 7-9=2marks 10-12=3marks

Set M CHEMISTRY Date:06 JAN 2023 13-15=5marks 16=4marks

14. (i) A first order reaction takes 30 minutes for 50% completion. Calculate the time
required for 90% completion of this reaction. (Given : log 2 = 0.3010,)
(ii) Write the unit of rate constant (k) : (a) Zero order (b) First order
OR
For the hydrolysis of methyl acetate in aqueous solution, the following results were
obtained :
t/s 0 30 60
[CH3COOH]/mol 0.60 0.30 0.15
L-1
(i) Show that it follows pseudo first order reaction, as the
concentration of water remains constant.
(ii) Calculate the average rate of reaction between the time interval 30
to 60 seconds.
15.(i) Write the IUPAC name of Tollens Reagent
(ii) On the basis of crystal field theory, write the electronic configuration for d 5 ion
if o < P.
(iii)Define enantiomers
.
(iv) Draw the geometrical isomers of complex [Pt(en) 2Cl2]2+
(v) Write the hybridization type and magnetic behaviour of the complex [Ni(CN) 4]2-.
(Atomic number of Ni = 28)
16. Read the passage given below and answer following questions:
 Standard electrode potentials are used for various processes:
(i) It is used to measure relative strengths of various oxidants reductants.
(ii) It is used to calculate standard cell potential.
(iii) It is used to predict possible reactions.
 A set of half-reactions (in acidic medium) along with their standard
reduction potential, Eo (in volt) values are given below
I2+2e−→2I−;E∘=0.54 V 
Cl2+2e−→2Cl−;E∘=1.36 V 
Mn3++e−→Mn2+;E∘=1.50 V 
Fe3++e−⟶Fe2+;E∘=0.77 V 
O2+4H++4e−⟶2H2O;E∘=1.23 V 
The following questions are multiple choice questions. Choose the
most appropriate answer:
(i) Which of the following statements is correct?
(a) CI- is oxidised by O2 (b) Fe2+ is oxidised by iodine
(c) I- is oxidised by chlorine. (d) Mn2+ is oxidised by chlorine
(ii) Mn3+ is not stable in acidic medium, while Fe3+is stable because
(a) O2 oxidises Mn2+ to Mn3+
(b) O2 oxidises both Mn2+ to Mn3+ and Fe2+ to Fe3+
(c) Fe3-oxidises H2O to O2
(d) Mn3+ oxidises H2O to O2
(iii) The strongest reducing agent in the aqueous solution is
(a) I- (b) Cl- (c) Mn2+ (d) Fe2+
(iv) The emf for the following reaction is
I2+KCl⇌2KI+Cl2 
(a) -0.82 V (b) +0.82 V (c) -0.73 V (d) +0.73 V
MM.40 S. S. 1-6=1marks 7-9=2marks 10-12=3marks

Set M CHEMISTRY Date:06 JAN 2023 13-15=5marks 16=4marks