1. What do mean by molarity.

Calculate the molarity of NaOH in the solution prepared by

dissolving its 4 g in enough water to form 250 mL of the solution.
2. Calcium carbonate reacts with aqueous HCl according to the reaction
CaC03 (s) + 2HCl (aq) ———->CaCl2 (aq) +C02(g) +H2O(l).
What mass of CaC03 is required to react completely with 25 mL of 0.75 M
3. Chlorine is prepared in the laboratory by treating manganese dioxide (Mn02) with aqueous
hydrochloric acid according to the reaction.
4 HCl (aq) + Mn02 (s) ———–> 2 H2O (l) + MnCl2(aq) +Cl2(g)
How many grams of HCl react with 5.0 g of manganese dioxide? (Atomic mass of Mn = 55 u)
5. What is the difference between empirical and molecular formula? A compound contains
4.07 % hydrogen, 24.27 % carbon and 71.65 % chlorine. Its molar mass is 98.96 g. What are
its empirical and molecular formulas?
6. Calculate the number of atoms in each of the following:
(i) 52 moles of Ar (ii) 52 u of He (iii) 52 g of He
7. If the mass percent of various elements of a compound is known, its empirical formula can
be calculated.
a) What is mass percent?
b) A compound contains 4.07% hydrogen, 24.27% carbon and 71.65% chlorine. Its molecular
mass is 98.96. What are the empirical and molecular formulae?

8. Calculate the mass of oxalic acid dihydrate (H2C2O4.2H2O) required to prepare 0.1M, 250
ml of its aqueous solution.

9. Determine the empirical formula of an oxide of iron which has 69.9% iron (Fe) and 30.1%
oxygen (O) by mass.

10. What is the molarity of a solution that was prepared by dissolving 82.0 g of CaCl2 (molar
mass = 111.1 g/mol) in enough water to make 812 mL of solution?

11. How many grams of NaBr (molar mass = 102.9 g/mol) would be needed to prepare 700
ml of 0.230 M NaBr solution?

12. A solution is made by dissolving 25 g of NaCl in enough water to make 1.0 L of solution.
Assume the density of the solution is 1.0 g/cm3 . Calculate the molarity and molality of the
solution.