KENDRIYA VIDYALAYA SANGATHAN, LUCKNOW REGION

II Pre-board Examination, 2022-23 Class 12

CHEMISTRY (Theory)
Time allowed: 3 hours Maximum Marks: 70
MARKING SCHEME
Question Value Points Marks
No.
SECTION A
1. (d) Equivalent weight of electrolyte 1

2. (d) −2.36 V 1

3. (a) 2.5 1

4. (a) 6.25 L2mol−2s−1 1

5. (b) First order reaction 1

(c) It causes the K2Cr2O7 solution to change its color from orange to 1
6.
yellow
7. (d) Oxygen 1

8. (a) 1 1

9. (c) The oxidation state of cobalt in the complex is +1 1

10. (b) Alkyl isocyanide 1

11. (a) Primary 1

12. (b) Oxygen-hydrogen 1

13. (b) III > IV > I > II 1

14. (d) CH3—CH=N—NH2 1

(i) Both Assertion (A) and Reason (R) are correct statements, and 1
15.
the Reason (R) is the correct explanation of the Assertion (A).
(ii) Both Assertion (A) and Reason (R) are correct statements, but 1
16.
the Reason (R) is not the correct explanation of the Assertion (A).
(iv) Assertion (A) is incorrect, but Reason (R) is a correct 1
17.
statement.
(iii) Assertion (A) is correct, but Reason (R) is an incorrect 1
18.
statement.
SECTION B
● At infinite dilution, when dissociation of electrolyte is complete,
each ion makes a definite contribution of its own towards the
19.
molar conductivity of electrolyte, irrespective of
the nature of the other ion with which it is associated. 1
 ● Ωo = ν+ λ˚+ + ν– λ˚– 1
m
OR
● B 1
● Dilution causes the degree of dissociation/ionization of B to
increase, resulting in greater number of ions. 1
● The reactions which have actual order higher than 1, but under
20. certain conditions behave like a first order reactions. 1
● Acidic hydrolysis of ethyl acetate or sucrose. 1
For a first order reaction, k = 0.693 = = 0.693 = 0.01 min−1 ½
0.5
t 69.3
½
k
t = 2.303 log R0
R

= 2.303 log 100 ½

21. 0.01 20

= 2.303 log 5
0.01
= 230.3 × 0.6990 ½
t = 160.9 min
(Half mark to be deducted for not writing or writhing wrong unit)
(a) Ionization isomerism 1
22.
(b) Coordination isomerism 1
An optically inactive mixture of two enantiomers in equal
(a) 1
proportions.
(b) A carbon atom attached to four different atoms or group of atoms. 1
OR
23.
(a) The boiling points of isomeric alkyl halides decrease with
branching because of the weakened van der Waal’s forces. 1
It is because para-isomers fit in the crystal lattice better than
(b) 1
ortho- and meta-isomers.
● Bicarbonate test (treatment with NaHCO3). ½
(a) ● Brisk effervescence of CO2 are formed when benzoic acid is
reacted with HCO3−. ½
24.
● Fehling’s test. ½
(b) ● Formaldehyde gives a red precipitate of Cu2O with Fehling’s
solution. ½
● The coagulation of proteins when it is subjected to change in
25. temperature or pH. 1
● Coagulation of white of an egg on boiling. 1
SECTION C
MB of solute, C6H8O6 = (6×12) + (8×1) + (6×16) ½
= 176 g mol−1
½
26. W B
Kf × 1000
= ∆Tf × MB × WA

= 1.5 ×176 ×75

3.9 ×1000 1
= 5.08 g 1
 The IUPAC name of the complex is tetracyanidonickelate (II). 1
27.
(a) It uses dsp2 hybridization. 1
 The strong CN− ligands cause all d8 electrons to pair in the 3d
(b) 1
orbital (spin-pairing).
OR
(a) Ligands which have two different donor atoms and either of the two
ligates in the complex. 1
The complexes in which the metal is bonded to two or more
(b) 1
different types of ligands.
A series formed when several ligands are arranged in the
(c) 1
increasing or decreasing order of their field strength.

(a) 1

½
28. (b)
½

(c) 1

● Mechanism of dehydration of ethanol:

H2SO4 → H+ + HSO4− ½

29.
½

½1

● Ethoxyethane (diethyl ether).

 (a) 1

30.

R—CONH2 + Br2 + 4NaOH → R—NH2 + Na2CO3 + 2NaBr + 2H2O

(b) 1
Amide 1º amine
R—NH2 + CHCl3 + 3KOH → R—NC + 3KCl + 3 H2O
(c) 1
1º amine alkyl isocyanide
OR
(a) C6H5NH2 < C6H5CH2NH2 < CH3NH2 1
(b) N,N-Dimethylbenzeneamine 1
(c) Aniline, a Lewis base, forms salt with catalyst AlCl3, a Lewis acid. 1
SECTION D
Because the surface has less dissolved oxygen due to less pressure. 1
OR
(a) Nitrogen gas from the cylinder carried by the diver’s combine with his
blood at high pressure deep into the water. 1
31. (b) Y, because it has the least pressure. ½+½
According to Henry’s law, p = KH χ ½
(c) ∴χ = = 760
5
½1
KH 4.27 × 10
∴ χ = 178 × 10−5
32. (a) Insulin. 1
(b) They are not needed to be supplied by food. 1
Because they play an important role in communication between different
cells. 1
(c)
OR
Pituitary gland 1
(d) Adrenaline (or epinephrine) 1
SECTION E
 ½

33. (a)

½
½
 1

½
½
(b)
1

(a) It has fully-filled d10 configuration, so no d-d transition is possible. 1

It has six unpaired electrons, so it forms extensive
(b) 1
metallic/covalent bonds.
It achieves stable noble gas configuration after losing three
(c) 1
electrons.
They have reasonably large void where a small-sized element like
(d) 1
hydrogen, boron or carbon can be trapped.
They don’t have unpaired electrons in their (n−1)d orbital in their
(e) 1
elemental form or in their common oxidation states.
OR
34.
● Lanthanide contraction is the steady decrease in the atomic and
ionic sizes of lanthanide elements. 1
● Its major cause is the inability of inner 4f electrons to screen the
(a)
outer 6s electrons. 1
● Its consequences include comparable atomic sizes of 4d and 5d
series elements and regular decrease in basic strength
from La(OH)3 to Lu(OH)3. ½+½
(b) 4+ 3+ 1
It is because Ce gains one electron to convert to more stable Ce .
2MnO4− + H2O + I− → 2MnO2 + 2OH− + IO3− 1
(c)
(½ marks to be deducted if the reaction is not balanced)
● A : C6H5COCH3 1
● B : C6H5CH2CH3 1
35. ● C : C6H5COOH 1
● D : C6H5COONa 1
● E : CHI3 1
OR
(a) CH4 1
(b) CH3CH(Br)COOH 1
35.
(c) C6H5COCl 1
(d) C6H5COOH 1
(e) CH3CHO 1

*****
 As Per Revised
CBSE Curriculum
2023-24
Classroom Teaching & Animated Videos Playlists

We take immense pleasure in serving you. Now, revel in our

seamless online services completely free of charge. view our animated
and classroom teaching Playlists customized for students from grade 1
to 12,Covering a wide range of subjects to enhance your
comprehension and knowledge. Simply click on the provided playlist
links to access Playlists based on the latest NCERT Syllabus for 2023-
24.
Our content includes Competency-Based Questions,
Assertion-Reason Questions, Previous Year Questions (PYQ), and
Case Study-Based Questions to enhance your learning
experience.For the most up-to-date videos, consider subscribing to
our YouTube channel at
https://www.youtube.com/@PrincipalsHandbookandDiaryadditionall Nageen Group of Schools
y, you're encouraged to join our expanding WhatsApp community
group to stay updated with the latest curriculum-related content and
updates.

We are committed to enriching your educational journey!!!

 ANIMATED & CLASSROM TEACHING VIDEOS PLAYLISTS
(As per revised CBSE Curriculum– 2023-24)

ANIMATED VIDEOSPLAYLISTS (CLASS 1)

Class 1 EVS(EnglishLanguage)(CBSE) Click here for playlist
Class 1 Mathematics (EnglishLanguage)(CBSE) Click here for Playlist
Class 1 EVS (HindiLanguage)(CBSE) Click here for Playlist
Class 1 Mathematics(Hindi Language)(CBSE) Click here for Playlist

ANIMATED VIDEOS PLAYLISTS (CLASS 2)

Class 2 EVS (EnglishLanguage)(CBSE) Click here for Playlist
Class 2 Mathematics (EnglishLanguage)(CBSE) Click here for Playlist
Class 2 EVS(HindiLanguage)(CBSE) Click here for Playlist
Class 2 Mathematics (Hindi Language)(CBSE) Click here for Playlist

ANIMATED VIDEOS PLAYLISTS (CLASS 3)

Class 3 Mathematics (EnglishLanguage)(CBSE) Click here for Playlist
Class 3 EVS (EnglishLanguage)(CBSE) Click here for Playlist
Class 3 EVS (HindiLanguage)(CBSE) Click here for Playlist
Class 3 Mathematics (HindiLanguage)(CBSE) Click here for Playlist

ANIMATED VIDEOS PLAYLISTS (CLASS 4)

Class 4 Mathematics (EnglishLanguage)(CBSE) Click here for Playlist
Class 4 EVS(EnglishLanguage)(CBSE) Click here for Playlist
Class 4 Mathematics (HindiLanguage)(CBSE) Click here for Playlist
Class 4 EVS (HindiLanguage)(CBSE) Click here for Playlist

CLASSROOM TEACHING VIDEOS PLAYLISTS (CLASS 4)

Class 4 General Science (CBSE) Click here for Playlist

ANIMATED VIDEOS PLAYLISTS (CLASS 5)

Class 5 Mathematics (EnglishLanguage)(CBSE) Click here for Playlist
Class 5 Science (EnglishLanguage)(CBSE) Click here for Playlist
Class 5 Mathematics(HindiLanguage)(CBSE) Click here for Playlist
Class 5 Science (HindiLanguage)(CBSE) Click here for Playlist

CLASSROOM TEACHING VIDEOS PLAYLISTS (CLASS 5)

Class 5 General Science (CBSE) Click here for Playlist
Class 5 EVS (CBSE) Click here for Playlist
 ANIMATED VIDEOS PLAYLISTS(CLASS 6)
Class 6 Mathematics (EnglishLanguage)(CBSE) Click here for Playlist
Class 6 Social Science (EnglishLanguage)(CBSE) Click here for Playlist
Class 6 Science (EnglishLanguage) (CBSE) Click here for Playlist
Class 6 Mathematics (Hindi Language)(CBSE) Click here for Playlist
Class 6 Science All Chapters (CBSE) Click here for Playlist

CLASSROOM TEACHING VIDEOS PLAYLISTS (CLASS 6)

Class 6 Mathematics (CBSE) Click here for Playlist
Class 6 Social Science (CBSE) Click here for Playlist
Class 6 Sanskrit (CBSE) Click here for Playlist
Class 6 Hindi (CBSE) Click here for Playlist
Class 6 Science (CBSE) Click here for Playlist

ANIMATED VIDEOS PLAYLISTS (CLASS 7)

Class 7 Science(CBSE) Click here for Playlist
Class 7 Mathematics(CBSE) Click here for Playlist
Class 7 Social Science(CBSE) Click here for Playlist
Class 7 Mathematics(CBSE) Click here for Playlist
Class 7 Science (CBSE) Click here for Playlist

CLASSROOM TEACHING VIDEOS PLAYLISTS (CLASS 7)

Class 7 Science (CBSE) Click here for Playlist
Class 7 Hindi (CBSE) Click here for Playlist
Class 7 Sanskrit (CBSE) Click here for Playlist
Class 7 Social Science (CBSE) Click here for Playlist
Class 7 Mathematics (CBSE) Click here for Playlist

ANIMATED VIDEOS PLAYLISTS (CLASS 8)

Class 8 Science(CBSE) Click here for Playlist
Class 8 Mathematics(CBSE) Click here for Playlist
Class 8 Social Science(CBSE) Click here for Playlist
Class 8 Mathematics(CBSE) Click here for Playlist
Class 8 Science(CBSE) Click here for Playlist

CLASSROOM TEACHING VIDEOS PLAYLISTS (CLASS 8)

Class 8 Hindi (CBSE) Click here for Playlist
Class 8 Sanskrit (CBSE) Click here for Playlist

ANIMATED VIDEOS PLAYLISTS (CLASS 9)

Class 9 Biology(CBSE) Click here for Playlist
Class 9 Physics(CBSE) Click here for Playlist
Class 9 Chemistry(CBSE) Click here for Playlist
Class 9 Social Science (CBSE) Click here for Playlist
Class 9 Mathematics (CBSE) Click here for Playlist
Class 9 Science (CBSE) Click here for Playlist

CLASSROOM TEACHING VIDEOS PLAYLISTS (CLASS 9)

Class 9 Social Science (CBSE) Click here for Playlist
Class 9 Mathematics(CBSE) Click here for Playlist
Class 9 English (CBSE) Click here for Playlist
Class 9 Hindi (CBSE) Click here for Playlist

ANIMATED VIDEOS PLAYLISTS (CLASS 10)

Class 10 Biology (CBSE) Click here for Playlist
Class 10 Physics (CBSE) Click here for Playlist
Class 10 Chemistry (CBSE) Click here for Playlist
Class 10 Social Science (CBSE) Click here for Playlist
Class 10 Mathematics(CBSE) (English Language) Click here for Playlist
Class 10 Mathematics(CBSE) (Hindi Language) Click here for Playlist
Class 10 Science(CBSE) (Hindi Language) Click here for Playlist

CLASSROOM TEACHING VIDEOS PLAYLISTS (CLASS 10)

Class 10 English (CBSE) Click here for Playlist
Class 10 Hindi (CBSE) Click here for Playlist
Class 10 Mathematics (CBSE) Click here for Playlist
Class 10 Social Science (CBSE) Click here for Playlist
Class 10 Magical Science Board Exam Preparation in 1 min (CBSE) Click here for Playlist
Class 10: Science (CBSE) Click here for Playlist

ANIMATED VIDEOS PLAYLISTS (CLASS 11)

Class 11 Physics (CBSE) (English Language) Click here for Playlist
Class 11 Chemistry (CBSE) (English Language) Click here for Playlist
Class 11 Biology (CBSE) (English Language) Click here for Playlist
Class 11 Mathematics(CBSE) (English Language) Click here for Playlist
Class 11 Accountancy (CBSE) (English Language) Click here for Playlist
Class 11 Business Studies (CBSE) (English Language) Click here for Playlist
Class 11 Statistics (CBSE) (English Language) Click here for Playlist
Class 11 Biology (CBSE) (Hindi Language) Click here for Playlist
Class 11 Mathematics (CBSE) (Hindi Language) Click here for Playlist
Class 11 Physics (CBSE) (Hindi Language) Click here for Playlist
Class 11 Chemistry (CBSE) (Hindi Language) Click here for Playlist
Class 11Micro Economy (CBSE) (English Language) Click here for Playlist

CLASSROOM TEACHING VIDEOS PLAYLISTS (CLASS 11)

Class 11Mathematics (CBSE) Click here for Playlist
Class 11 Accounts (CBSE) Click here for Playlist
Class 11 Business Studies (CBSE) Click here for Playlist
Class 11 Hindi (CBSE) Click here for Playlist
Class 11 Psychology (CBSE) Click here for Playlist
Class 11 Economics (CBSE) Click here for Playlist
Class 11 Physics (CBSE) Click here for Playlist
Class 11 Chemistry (CBSE) Click here for Playlist
Class 11 English (CBSE) Click here for Playlist
Class 11 Biology (CBSE) Click here for Playlist
Class 11 Biology Shorts (CBSE) Click here for Playlist

ANIMATED VIDEOS PLAYLISTS (CLASS 12)

Class 12 Physics (CBSE) Click here for Playlist
Class 12 Chemistry (CBSE) Click here for Playlist
Class 12 Biology(CBSE) Click here for Playlist
Class 12 Macro Economy (CBSE) Click here for Playlist
Class 12Economic (CBSE) Click here for Playlist
Class 12 Mathematics (CBSE) Click here for Playlist
Class 12 Accountancy (CBSE) Click here for Playlist
Class 12 Business Studies (CBSE) Click here for Playlist
Class 12 Physics (CBSE) Click here for Playlist
Class 12 Mathematics (CBSE) Click here for Playlist
Class 12 Biology (CBSE) Click here for Playlist
Class 12 Chemistry (CBSE) Click here for Playlist

CLASSROOM TEACHING VIDEOS PLAYLISTS (CLASS 12)

Class 12 CHEMISTRY (CBSE) Click here for Playlist
Class 12 Business Studies (CBSE) Click here for Playlist
Class 12 Hindi (CBSE) Click here for Playlist
NEET Biology in 1 min Click here for Playlist
Class 12 History (CBSE) Click here for Playlist
Class 12 Political Science (CBSE) Click here for Playlist
Class 12 Physics (CBSE) Click here for Playlist
Class 12 Biology (CBSE) Click here for Playlist
Class 12 : Accounts (CBSE) Click here for Playlist