EXERCISE (O-1D) 2.303RT NOTE : If not given in question use : > = 0.059 GALVANIC CELL A standard hydrogen electrode has zero electrode potential because (A) hydrogen is easier to oxidise \_{BFelectrode potential is assumed to be zero (D) hydrogen is the lighest element. Ltd. Aydeogee~ ofectoode Retertial ic arbitanily ornume +0 be Ze. The thermodynamic efficiency of cell is given by- LL (© hydrogen atom has only one electron AH nFE.,, nFE «a & Hee ea (©) Zero Theremnaby narnic efpicioury = Aer aH _ —nFEcwp On From the following E° values of half cells, (i) Ate >A; E° 0.24 V (ii) B +e > B*; E° =+1.25 V (iii) C+ 2e > Ce; 1.25 V (iv) D+ 2e— D*; E° =+0.68 V What combination of two half cells would result in a cell with the largest potential ? Yi) and (iii) (B) Gi) and (iv) (C) (i) and (iii)(D) (i) and (iv) E: CRY 7 (S2P)y. Pov 6° tp be war” (CRP), mutt be Ajphost => UD Ad (CRP), Mutt be lowest > Ui) . 3) .4. Which of the following will increase the voltage of the cell with following cell reaction n+ 2Ag', > Sn? + 2Ag., (A) Decrease in the concentration of Ag* ions (B) Increase in the concentration of Sn‘? ions increase in the concentration of Ag* ions (D) (A) & (B) both _ _ oee9 Lint? Even = Evew log Tog? Eco Cor be intreared by in creaning Me trcentaf dy Ag The standard electrode potentials for the reactions Ag? (a) + o> ——> Ag(s) Sn* (a) + 2e° ——> Sn (s) at 25 °C are 0.80 volt and -0.14 volt, respectively. The standard emf of the cell n,,|Sn*s,, IM)}Ags, LMD/Ag,, is : (A) 0.66 volt (B) 0.80 volt (C) 1.08 volt er" 0.94 volt Ecce = Engiing ~ Een /en = d-B-(-014) =[OF4V] are. A =~-0.25 volt, E° (Au** | Au) = 1.50 volt. The standard emf of the voltaic cell. Ni, | Ni", (0 M) || Au’, (LOM) | Au,, is : (A) 1.25 Volt (B) -1.75 volt $ey.7s volt (D) 4.0 volt 0 H° Ey : Eun = © rattan ~ EXPN = 16-60%) = [epsu/ Aus —7. E® for F,+2e7 = 2F is 2.8 V, E®° for 4F,+e=F is ? (40 28. V (B) 14V (© 28 V (D) -14V E’ is indeperdent I etaichiometir Copious . 8. If AG? of the cell reaction, AgCl(s) +4H,(g) > Ag(s) + H* +CP is -21.52 KJ then AG? of 2AgCI(s) +H,(g) > 2Ag(s) +2H* 42Ch is: (A) -21.52 KJ (B) -10.76 KJ 4» $eF43.04 KJ (D) 43.04 KJ AGP. 2% (21D = [-4 3-04 eo / 9. The standard emf for the cell reaction, Zn, + Cu, —> Zn*,, + Cu, is 1.10 volt at 25 °C. The emf for the cell reaction when 0.1 M Cu* and 0.1 M Zn* solution are used at 25°C is : er.e volt (B) 0.110 volt (C) -1.10 volt (D) -0.110 volt ° es E cove = Ecoce 7 0.084 log Lett z Lewd? ot [rv] = py —0:087 log as = —— O°! 2 10. Given: E2,,,, =-0.72 V, E%.,,, =~ 0.42V. The potential for the cell Cr, | Cr", O.1 M) || Fe, (0.01 M)|Fe,, is Yr 026V (B) 0.339 V (C) - 0.339 V (D) - 0.26 V Ecoee = Ete - Cotter = -0-42—-(-O-72) = 0:30V -ME Pty ve —> Fels) 3x3 —, Crs) ——» Cf* as) +365 #2 Curate of Ptlasy + DE) —> BFF 2tr"* (a) nzé. a ee Leen? Cece = © cov0 =z ¢ — Tet? > OF Exe, = OB - 0-254 | ex ' Eccee oe —— on" 05 Epp = 0-3 - oes log it - [| 7 = DeB- O:054*4 - [0.26V z 11. What is the potential of the cell containing two hydrogen electrodes as represented below Pt | Hi(g) | Hi(10* M) |) H',,(0.001 M) | H.(g)|Pt (A) = 0.295 V ®)- 0.0591 V(9F0.295 V (D) 0.0591 V Ascume provurt )} Hr gar jn both trde ik tame. Az Aurte- Eigen 2 0-854 log WH Ce Caste: ! Cath, 58 % Econ = — 0.069 lop 2 = Ex0-0S9V12. Consider the cell, CulCu*JAg'|Ag. If the concentration of Cu? and Ag: ions becomes ten times the emf of the cell :— (A) Becomes 10 times (B) Remains same \(Mrcrease by 0.0295 V (D) Decrease by 0.0295 V Me Agtlny 4 O— agls) (42- tA Cent) — Lebtlon) 42€ Dias) + 24919) Ovente Dag" (as) + Cate) > G0 oy Fong Fae = O88 9 Lagtt> Hy ° _ post | tox? w, Eqtr= cow a Cope tant 0-089 Inq 12 LO Loo 7 Ease, Fou, = UF se ee on Evens - Evom2 = a log 4 _ — 0°0L9 TE er = Etever ~ Or — [Ecema = Exevey + 0:029* > jnereares by 0/0295 «13. The standard emf of a galvanic cell involving cell reaction with n = 4 is found to be 0.295 V at 25°C. The equilibrium constant of the reaction would be, or x 10° (B) 2.0 x 10" (©) 4.0x 102 (D) 1.0 x 10° ne Yno-29F 5069 O-oSF Ke Io = (0 20 =/lo Avs 14, The cell Zn | Zi, (1M) || Cu* 499] Cu (Eq = 1.10 V) was allowed to be completely discharged In? at 298 K. The relative concentration of Zn*? to Cu*?, teal is: (A) 9.65 x 10% (B) Antilog (24.08) (C) 37.3 poor 3 Cro = 0 Whe Coumplehny diccharg — 9-069 Jog Le Eaaw= Crow — OT NF 39 Doth Oz lef - 0-054 lo Lu 2 7 Foot! fs, 22 loa Lat {504 poe’ 22 2-3 "1 [aes = re? =/1015. Given the data at 25°C, Agyy + Fag) > Agha + es B° = 0.152V Agi) > Agtaq t&. B® = 0.800 V What is the value of log K,, for Agi 2 (Where K,,= solubility product) (2 20a8t =0. os9v) (A) -8.12 (B) +8.612 (C) -37.83 (YS-16.13 5° _c + + 6:04 k Eriagyag = Engiing tO 9 Meta = 0-054 py —Orlsd = 0-8 + nee log Mena, go, 0-089 10F Kee pay =f 0-8+0-15) 0-952 be, 04 Keenan = 7 OSD _ Eye Ant 5054 : 16. Ina cell that utilises the reaction, Zn(s) + 2H"(A) —> Zn°(aq) + H,(g) addition of H,SO, to cathode compartment, will : \ GF increase the E,,, and shift equilibrium to the right (B) lower the E, and shift equilibrium to the right Az Anabee (© lower the E,,, and shift equilibrium to the left ox Cathe (D) increase the E, , and shift equilibrium to the left & E — 0-059 lo Lut, Pots, © Cone - Cen 109 —_ 4 Late Clearly, additsy Oy Ht will increnne Ere avd wilibsiem will shige to 2eghte. By how much times will potential of half cell Cu|Cu change if, the solution is diluted to 100 times at 298 K :— (A) Increases by 59 mV \ 9 berese by 59 mV (C) Increases by 29.5 mV (D) Decreases by 29.5 mV Cyt +22 —> lw | Ey = Ende. - 0.059 [09 [lu PB b2 DOG yn 2-057 21 > 0 |E= E,-0984 _ , » decremes by easay “1 S4mV.18. The standard reduction electrode potentials of four metal cations are - Bl, =-0250V, El, =-0140V Bo =-0.126V, E),,, =- 0.402 V ‘The metal that displaces A* from its aqueous solution is (A) B (B) C 4) D (D) None of the above whise fA At will he reduced bya metal O-uKV, - ; Har Oo : Oxidlaton potentiol muct be higtey At ep Are” ° ° 6 | Long (0-40) = Dlb2 FO Ee Equa- © ol * e + > D> Gn reduce 19. The reduction potential values are given below: Bj = LO7V 5 By, signe = 234, EP, 0.34V; E), =0.53V Which one is the best reducing agent ? (A) AL Mg (©) Cu (@)1, Higher He value onidaba peteahat date bettev it We Redulivg agent > ic Hy book Predicting AGT «> HeELECTROLYTIC CELL When an electric current is passed through a cell containing an electrolyte, positive ions move towards the cathode and negative ions towards the anode. What will happen if the cathode is pulled out of pal the solution? (A) The positive ions will start moving towards the anode and negative ions will stop moving. (B) The negative ions will continue to move towards the anode and the positive ions will stop moving (C) Both positive and negative ions will move towards the anode. SPI None of these movements will take place. Cirtuil will break, and no Crtutyr loop fo Gon. Lo no maven bf lens: The products formed when an aqueous solution of NaBriselectrolyzed in a cell having inert electrodes are: 2) (a) Na and By (B) Na and 0, fF Hy, Bry and NaOH(D) H, and 0, MC pole) 422 —® tig) + 2H lan) — Ath Deg (a3) —> fo +2€ oe Papdult bound = Hp, Por A solution of sodium sulphate in water is electrolysed using inert electrodes. The products at the cathode and anode are respectively. a te 0, (B) O,, H, (©)0,,Na (D) none Onde NAOH - Nap &Dy (aa) Hrlayt QOH (ag a a ee > Ath foo Pt HHT E -When an aqueous solution of lithium chloride is electrolysed using graphite electrodes we \ WECI, is liberated at the anode. (B) Li is deposited at the cathode (C) as the current flows, pH of the solution remains constant (D)as the current flows, pH of the solution decreases. ices) Hf (a3) e 2 thlaFt 20 MEE, DO +2 ——e tylg) t2e © go py ineremes- At A De = Be on jong Oe fume The Gibbs energy for the decomposition of Al,O, at 500 °C is as follows 2 4 pes ALO; —> 5 Al+ 0, AG = +966 KJ mot! The potential difference needed for electrolytic reduction of Al,O, at 500 °C is at least :- (A) 5.0V (B) 4.5 V ©) 30V OPIS Ne Zrix Gy» Dbz nt Epece <4 7 bbrI000 = YxqesoorE _ 9 beKopP LI ey b= ape Ee! Electrolysis of a CuSO, produces :— wl (A) An increase in pH (BJA decrease in pH (C) Either decrease or increase (D) None Me Leos) + 20 —> Guia) Mtn — pole) —% Orly) + UHTag) + HE Ht ig bowed => Atereane In pH.The amount of an ion discharged during electrolysis is not directly proportional to : AF resistance (B) time (C) current strength (D) electrochemical equivalent of the element We zit Cenly Wee, WxL, eZ Number of electrons involved in the electrodeposition of 63.5 g of Cu from a solution of CuSO, ea is : (N, = 6 x 10®) (A) 6 x 10 (B) 3 x 10% 12 x 108 (D) 6 x 10? Opts 1e—> Gl 625 = |rute Dmolee 13 = 2¥bt0? = [ieee atectons | When one coulomb of electricity is passed through an electrolytic solution the mass deposited on the electrode is equal to : (A) equivalent weight <(OMectrochemical equivalent (B) molecular weight (D) one gram we 22t -wW iw O 2Z>— eZ ‘ dre L When = | Color, ZeW- * Zig pe amount & substaule deposited re liberated vahon I Coulomb J ofectaialy 1 Supplitds Zi6 bed oleckochernital equivaltace Ds He &ubsbank-Electro chemical equivalent of a substance is 0.0006; its equivalent weight. is (45579 (B) 28.95 (D) cannot be calculated (©) 115.8 E=fZ = Fbso0% 0:0006 = [6#2/ The same amount of electricity was passed through two separate electrolytic cells containing solutions a of nickel nitrate [Ni(NO,),]and chromium nitrate [Cr(NO,),] respectively. If 0.3 g of nickel was deposited in the first cell, the amount of chromium deposited is : (at. wt. of Ni = 59, at, wt. of Cr = 52) (A) 0.1 g pen g& (C) 0.3 g (D) 0.6 g Ni* pre —> Ni e2 S49 _ 29-5 Se Crtte Ze ~~ & =o £2 E & Ww & 03 248 — = 6 ? W~ (£7) _ £2703 =|0-17 m Wor Ses aW g of copper deposited in a copper voltameter when an electric current of 2 ampere is passed for 2 hours. If one ampere of electric current is passed for 4 hours in the same voltameter, copper doposited will be + DAW (B) WR (© wis (D) 2W Wr _ byte (or wee 6) wr” = ate mw, W_ 28 = wn” 1 *4 ty h,-W When the same electric current is passed through the solution of different electrolytes in seri amounts of elements deposited on the electrodes are in the ratio of their: (A) atomic number (B) atomic masses (C) specific gravities (Dy equivalent masses Wy. & Wwe Er The amount of electricity that can deposit 108 g. of silver from silver nitrate solution is: (A) 1 ampere (B) 1 coulomb (OA Faraday (D) 2 ampere Agito +e —> AGIA) 108 Z | rate i & LE] ps The ratio of weights of hydrogen and magnesium deposited by the same amount of electricity from aqueous H,SO, and fused MgSO, are : (A) 1:8 ass 12 (1:16 (D) None of these Emre Eng Ye DE Wy — Em : Wy eng Aut:A current of 9.65 amp. flowing for 10 minute deposits 3.0 g of a metal. The equivalent wt. of the metal is (A) 10 (B) 30 O50 (D) 96.5 det We E 96500 ‘ 69 mw B , Tesniere’ z 2 [E= 52] [E= 52] 4m e E 809 1 mole of Al is deposited by X coulomb of electricity passing through aluminium nitrate solution. EI The number of moles of silver deposited by X coulomb of electricity from silver nitrate solution is % (B)4 ©2 1 at +32 a t tle sre & - x 2 34985000: e774 Ag’ (as) + mile zmate | Aunt. The electric charge for electro deposition of 1 equivalent of a substance is : ez (A) one ampere per second (B) 4 faraday (C) one ampere for one hour \ JB) charge on one mole of electrons Itle Fe deposits equivalent Jy a substante- 3.17 g., of a substance was deposited by the flow of 0.1 mole of electrons. The equivalent weight of the substance is : (33) (A) 3.17 (B) 0.317 © 317 6) 31.7 or Oumele @ Aepesic 2179 Ra subshene vd alee BFL app ge & Sabclane‘A current of 9.65 amp. passing for 16 min. 40 sec. through a molten tin salt deposits 5.95 g. of tin The oxidation state of the tin in the salt is : (at. wt of Sn = 119) (A) +4 (B) +3 2 (D) +1 + Gn +ne —? ln é= 14 rn) I ix £ = lbebot 4 EE” 400 = aboryor [000k 119 Gb6500 - ua. Ov, ne the = [EI as. The time required for a current of 3 amp. to decompose electrolytically 18 g of H,O is: 718 hour (B) 36 hour (©) 9 hour (D) 18 seconds Pole) ——> tls» +4 orto) , £95 KN _ WbCxXI000 ogee eee ne Qrroe 2 Eno = Be q 2 Wirt . 18, 2xE 5 4. THOM E° ms00 7 9 ae00 3S oo, t= byZ3Z4ee = IPB tours Za [raAouns |An ion is reduced to the element when it absorbs 6 x 10” electrons. The number of gm equivalents of th : ty O10. . (B) 0.01 <6 0001 (D) 0.0001 no. by Foam equivalent = no- & nutes Be = be? | D-001 €4, bri? 1200 How many coulombs of electric charge are required for the oxidation of 1 mole of H,O to O, ? w (A) 9.65 x 10°C (B) 4.825 x 10°C (PF1.93 x 10°C (D) 1.93 x 10°C Go (0) Hyp ———> M+ $0. iimete h=2(1-o) = 2 mite FE = 2x96500C = 193 007 =[haania ©} Ae The time required to coat ameter surface of 80 cm? with 5 x 10 em thick layer of silver (density GB] 1.08 # em’) with the passage of 9.654 current through a silver nitrate solution is: (A) 10 see. LPF 40 sec. (C) 30 see. (D) 20 sec. Ag lee) + & —> Agip E> '8. ag ' W _ ire . “cin Cw 22th = Hine 5500 x . 2 * ire az sungae area in am om, Ae Lo de deusiy in Glan - e . AeA rLE USED san B60 010 XE? Ata = 7 t= LKE IEEE cu(One gm metal M*? was discharged by the passage of 1.2 x 10°? electrons. What is the atomic weight eal of metal? (A) 25 (B) 50 AO) 100 no- B male; ez bred? = D.oDMmole- brie? ~ (D)75 2 W.o0.02 E ML > |[M=-!l00 w + =00. % o 50? Aut (%) , One mole of electron passes through each of the solution of AgNO,, CuSO, and AICI, when Ag, Cu aS and Al are deposited at cathode. The molar ratio of Ag, Cu and Al deposited are (A) Li 1:l 6:3:2 (C)6:3:1 (D) 1:3:6 Agt+e —» Ag Zt 5 (alee imatAg. M+ 3€ at tale L mole HM. Cotire ea 3 |mble 4 mle Cy ~ pad nor raho F AgiatM= Gt tg - [62322] AY During electrolysis of an aqueous solution of sodium sulphate, 2.4 L of oxygen at STP was liberated at anode. The volume of hydrogen at STP, liberated at cathode would be » (A) L2L (B) 2.4L (C) 2.6L \WI48L Me Mor 2e —» |nls)+ 20W log) ayy LY mmo LU eeeY ET WEL WN xt oa Me -[vat] AA. 2hmo —e +r YHt+ 4! Aus. zy 24 mite 4x Syimle Say DeThe charge required for the oxidation of one mole Mn,O, into MnO3> in presence of alkaline medium is (A) 5 x 96500 C (B) 96500 C rio x 96500 C (D) 2 x 96500 C Mnz0q +8%0 ————> 2Mnoy + l6H*+ (0€ | rte. | lomate & = [lor 9bS00C Resistance of a conductivity cell filled with a solution of an electrolyte of concentration 0.1M is 1002. The conductivity of this solution is 1.29 Sm~!, Resistance of the same cell when filled with 0.02M of the same solution is 520Q. The molar conductivity of 0.02M solution of the electrolyte will be. worts x 10-4 Sm? mol (B) 1240 x 10 Sm? mol! (C) 1.24 x 104 Sm? mol-! (D) 12.4 x 104 Sm? mol-! =| N,<0-1H f= 100% Ks 12959 Gaime th, 42 O°O2H » Ry=S00- Amy § ! Alo 5 Wwe Bb RX D> BK 7 S20 24 -1 - 129. Lem. % Be Bom = Siri00 (009 Am, = ky xlove Mo vz - 24 ing *102%, = xG02 04 C2ntl00 % O02 Kei? | D.oele 1008 =| to SomPog | N o-0152. 53. ‘The resistance of 0.1 N solution of a acetic acid is 250 ohm. When measured in a cell of cell constant 1.15 cm. The equivalent conductance (in ohm! cm? equiv.~') of 0.1 N acetic acid is 46 (B) 9.2 (©) 184 (D) 0.023 OaFok D Ke Gt Hs Lery!. Ne= kK floee = bie ta N 250 ¥ Vel Electrolytic conduction differs from metallic conduction from the fact that in the former (A) The resistance increases with increasing temperature GPF The resistance decreases with increasing temperature (C) The resistance remains constant with increasing temperature (D) The resistance is independent of the length of the conductor le cleebrtyHe Condition Petit FA deems pitt increent |” hemp ‘den rrbile in merollic coubuh : jncreaAe povitrante incresnet with '0 in bere,The highest electrical conducitivity of the following aqueous solution is of (A) 0.1 M fluoroacetic acid BS 0.1 M difluoroacetic acid (C) 0.1 M acetic acid (D) 0.1 M chloroacetic acid Difluoncacche aud i¢ the khwugert acid amboy 55. Which of the following solution of KCI has the lowest value of specific conductance : (A) 1M (B) 01M (C) 0.01 M 50.001 M —> Lpetific Counbutanuie meant CorrBaetivtby —> Cousubvity inereanet bile Nr Poe tonrcard deltremel pit decane nh 4 In une 56. Which of the following solutions of KCI has the lowest value of equivalent conductance ? M @) 01M © 01M (©) .001 M Equivolecr LovPutivity decreanes pity increme in Conc.The limiting molar conductivities A° for NaCl, KBr and KCl are 126,152 and 150Scm? mol B respectively. The A for NaBris: = (A) 278 S cm? mol (B) 176 S em? mol Pir Scm? mol (D) 302 S cm? mol Kp, nate = Am, Nate * Am, Kir ~ An k@ = 1642-160 = Electrolyte ‘A°(S em? mol") Kc 149.9 KNO, 145.0 Hcl 426.2 NaOAC 91.0 Nacl 126.5 Calculate A... using appropriate molar conductances of the electrolytes listed above at infinite dilution in HO at 25°C 93907 (B) 217.5 (©) 517.2 (D) 552.7 00 to 0 he —AN - A + nwo Nate A HoAc = He At. toed “6 = 370% Sunrm = 62441 — 1265 = 97 The molar conductivities, aQ,,, and A°,, at infinite dilution in water at 25°C are 91.0 and €4] 426.2.S cm*jmol respectively. To calculate Af... the additional value required is : (A) KCL (B) NaOH UEP NaCl (D) H,0 oO ° 9 Nuon = Nate + \naoae — Anate - 60. The equivalent conductivity of 0.1 N CH,COOH at 25 °C is 80 S-cm’/eq. and at infinite dilution 400 S-cm*/eq. The degree of dissociation of CH,COOH in the solution is : (A) 1 0.2 (C) 0.1 (D) 0.5 aN a =|O-2 % a7 yoo Ans.Equivalent conductances of Ba’? and Cl-ions are 127 & 76 ohm-' cm? eq respectively. Equivalent conductance of BaCl, at infinite dilution is ~ (A) 379 (B) 139.5 US: 203 (D) 330 00 Ci 00 Ne eac,= Ne por + Ne a = (22426 = [203 Serteq|/ ‘The conductivity of a saturated solution of BaSO, is 3.06 x 10° ohm cnr ‘and its molar conductance jis 1.53 ohm em? mol, The K,, of BaSO, will be : 62s) 2x 10 (B) 4x 10 (4x 108 (A 10° i 0 06 HO 3 An = KxI008 > sae B06 mo #1007 B= 2K10 4 & alte/L. hep peep, = £2 = (2%102) “= Aue.