EXERCISE O-IL Single correct = Q.1 The pH of the solution produced when an aqueous solution of strong acid pH 5 is mixed with equal volume of an aqueous solution of strong acid of pH 3 is :- (log 5.05 = 0.7] A338 (B)3.5 4s (p) 40 fan (Sev 4 10RV Ie" 141 io = = ——— = = foots te = LS xlo7s Soseio 2V 2 > Phe Y- log S08 = 4-072 13-3 Aus.Q2 How many moles of HCI must be removed from 1 litre of aqueous HCI solution to change its pH from 2 to 3 (yl (B) 0.02 4G 0.009 (D) 0.01 + be mt injbag Hts loxle 0-0) ie Give Ht= [5x je 0-001 rade 2 moles & tee rernouek = raitles Of Ht decremed = 0-01-0-001 =Q.3 Which of the following is most soluble in water? (A) Ma (K,,= 810°) (B) ZnS (K,=7*10"'9) (© BisS, (K= P10) SB) Aa(PO)) (K.y= 1.810-) A) ge Sep = [av = [ee 410% mate[e By 8: Ike > Jpxil’s re 158 matele ©) Bossi)

(oe x29 8 > $e Les = (728 x10) Ig | ™ $2 (grey % pode/t .D) Ags P08)

B= Jasna zc (eaanis®)” (6e2)4 x 15 miele Le highs snare” bolubilry, \sQ4 Solubility of AgBr will be minimum in :- (A) Pure water JB) 0.1 M CaBry (©) 0.1 M NaBr (D) 0.1 M AgNO, un (83, L682 0-2M. Higher the Concoutrabion KK Comune FOr Bualley iS the Lolwbi (ty -QS pH ofsolutionat first 1/4" equivalence point of Na,CO, when titrated with HCI will be (for H,CO, K, = 107 ;K, = 10") (Aj 7+ log 3 (B) 7-log3 EFI + logs (D) 11 —log3 Nab, + Hae —~* Nand, + Na. 3 ae a G 34 . cit Paz Pka,+ log ( Pq, >It) Ap > + fog >(O is Lovvett.Q6 — Anacid-base indicator has aK, = 1.0 10°*, The acid form of the indicator is red and the basic form is blue. Calculate the pH change required to change the colour of the indicator from 80% red to 80% blue. [log 2 = 0.3] 1.20 (B) 0.80 (©) 0.20 (D) 1.40 Whom Bol TEA, [Hla = O8 aint [13-02 Phe Ply +log U3 _ cy iog 92. 6-log4 , ie . boat & u BOY blue, fucds 0-8 and [Hed > OD Ply = Slog 28 S+logs A (bn) PH- PA, = Lelogy- 541034 = Dog iT n yxo3- [ 1-2, = 4logz aAssertion /Reason : Q.7 _ Statement-1 pH of 10-7M NaOH solution x exist between 7 to 7.3 at 25°C. —» TUL - Statement-2 Due to common ion effect ionization of water is reduced. -» True - \ANStatement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1. (B) Statement-1istrue, tatement-2is true and statement-2 is NOT the correct explanation for statement-1. (C) Statement-1 is true, statement-2 is false. (D) Statement- is false, statement-2 is true. 4 fo ‘we bane fo Consider inHg Comune Cons, tt = DW Coming (prem twaley atte, ion effect On water told <— ut + ow 2 fer x # (x40) 2164Qs ‘Statement-t In general phenolphthalein is used as an indicator for the titration of weak acid (HA) against strong base (NaOH) Statement-2 At equivalent point solution is basic. (A) Statement-1 is tre, statement2 is true and statement-2 is correct explanation for statement-I (B) Statementel is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1. (©) Statement-1 is true, statement-2 is false. (D) Statement-I is false, statement-2 is true Lol & Newt (m0)Q9 Statement-t : Moles of S* furnished by sparingly soluble substance Sr(OH), decreases due to dilution, Statement-2 : Solubility product constant of S1(OH), is not affected by dilution, (A) Statement- is true, statement-2 is true and statement-2 is corect explanation for statement-1 (B) Statement is true, statement? is true and staement-2 is NOT the comet explanation for statement. (© Statement-1 is tue, statement? is false, (D) Statements alse sttementPistrue. Ou dilubon more Zable ic dissolved, 0 rnvtec bf CPt prmithed by colt wil increme &0 glateinent O 1 a Aut = ()- . fevae que Kep is Que equilitenus i ret: tau iF depends only bo etaliiaont © if warcek:! » Statement-1 : On dilution ofa concentrated solution of CH,COOH , the concentration of [H"] decreases, THe Statement-2 : Increase in volume is more than the increase in degree of ionisation. Tru2 statement- I is true, statement-2 is true and statement-2 is correct explanation for statement-1. (B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1. (C) Statement-1 is true, statement-2 is false. (D) Statement-1 is false, statement-2 is true. On dilution Cl cf And CA=T HI? decremnes..Multiple correct: A) 6) ) » 1) Which of the following is correct for 0.1 M BOH solution (K, = 10 4) JAS pH of solution is 11 \(BYOH- concentration is 10 moV/L (Orit's salt with HCI (i.e. BCI) form the acidic solution in water (D) Phenolphthalein indicator can be used during the titration of BOH with HCI Pons J (Pky- loge) = £ (S-logol) = 3 Pusty-3=II Tow}: 10°H Bee is a salt & (CA+WB) D Acidic At equivalence point PHS 3 PH range & phenelbatralein ic B30 Ww. So Phenslbptralein Can't be waeds12) For weak monobasic acid, HA, the dissociation constant is2 « 10, at 25°C. Which of the following is/are correct regarding this acid? (log2= 0.3] lL - _ ATA + HO SHA + OH; K, = 5 10° 2 Pha = b-logr = S> {By The equilibrium constant for the reaction of HA with ag, NaOH is 2 « 10° MES The pH of 0.1 M, HA solution is 3.35 BJ solution of Ais basic SY <8 ef . - Kw . de? © pwxw = gxlo'. (kh droty tis 3 AW) » ies : ie - 9x08 7 r <¢ De Fa | 28 a1 (inverse R Aytroyets) Kus lt uw I =< & 7 3 (57 -leg oy) = 6, 3-3S C) pHa £ ( Pha~log) D) AT will Aydeotyce fo Give OW, bo its Lalution vvillbebogicQ.13 Select correct statement for 50ml 0.1M H,A(aq) solution : K, = 10%; K, = 10% (A) TH] = 2A) BDH of 0.1M HLA solution is 3 LOPI0 aboww H,A solution when 6 milimolo of NaHA are added then pH increases by 2 units (D) 50 ml of 0.1M NaOH required to neutralised completely 50 ml of 0.1M H,A sotution 10 - pales) ee tan + WALA) o 7 ote m col 5 Se Bi MIO on ie ~3% eis oy > PH (BD's OL gage IBM ek <3 + 16 + A? (08) a) awe > x 8 ihe ALT 9 [AE ot > (ap is rena” u ae Nana > Bubb fe! oangous SME ays Ply tle F 2 omme D (0) ls comert Iba + Nab —> Napa + 24D? ; Emmite— lormmsle jete_nenrolitebrn ts Naon required 6 OO" 2 > (b) it prayQ.14 A solution containing 0.01M each of Pb, Ag* , Zn & Cr°* ion. If solid NaS is added slowly to the solution then correct statement is based on given data - PS AgS ZnS Cr,S, Precipitate 10" 10? 1010" ksp \WarPb* will start precipitating first GCE will start precipitating last (C) Zn will start precipitating before Ag* GPS When Zn just starts precipitating then Pb* ion gets 99.9% precipitated Gr¥] = 0-01M- Grivey : [pert = Legis Laed= 1 10" 1s — / ae [e3- Kee 2 me . Fon We precipitation IF MS > tes _ bo ein Oh ge Me Ww eM " " " Lu! p-ot 4% = fw” (2-00 < 1M. jpitein Be [62d equine ig. minimum 600 Hoe ree wt bw yet will precibiledé » Je comet: (a is meth{ok required ig maximum ber be presipitabon Bp OP, bo OM wll preupilete in (Webs «+ COs is comet ander my presipiranin pet Har gt ten Zoot tbe or. . > ic wee qt slot poor bilebg [rd = 10° 1! yn) IfK, & K, be first and second ionisation constant of HPO, and K, >> K, which is/are incorrect. (A) [H"]=[H,P0;] (©) K, = [HPO,;] kK, Hy00y = Ht & Hp Py Clearky Cutz = Ltn’ Hy POy fe Ht» HeOg” ky Le turopd TH2to 3 ? [Heardek, (T= YK\0HPO,] 2 Kae APT = POF] nae Ee yt pat t= Lee ted [nears 0, Kx ky = Lars [Paps > [wo. Se 1 PaRSi] D) 10 ml. ofa solution contains 0.1 M NH,CI+ 0.01M NH,OH. Which addition would not change the pH of solution SAT Adding 1 ml. water (B) Adding 5 ml. of 0.1 M NH,Cl (©) Adding 5 ml. of 0.1 M NH,OH (D) Adding 10 ml. of 0.1 M NH,CI Lolukion. is a baric buster £01". to (A) will not Change thre ph while (B,(O at (d) will Change the pH by kal amrurt.) » When equal volumes of the following solutions are mixed, precipitation of AgCl(K,, = 1.8 10-19) scur only with: AB) 10-4 M (Ag*) and 104 M (CT) (B) 10-5 M (Ag*) and 10-5 M(CT) (C) 10° M (Ag*) and 10° M (CI) (D) 10°! M (Ag*) and 10-!° M(CT) Cheek fev (A) ionic proBuct = [anit les =f et Lets asriol> & wx s pele = 25H > Nop zp Y D> Precibilabm actu,Paragraph for Q.18to Q20 8 gm weak acid HX (molecular mass = 80) is dissolved is 100 ml water. (K, = 10“) 13) Find pH of solution- (433 2 (23 (D3 19) Ifit is titrated with 0.25 M NaOH find pH at equivalence point (logs = 0.7) (Ayo.1s AB 8.65 (©4065 (D) 4.85 Find [}°] if 10° mol HCIis added to 100 mi original solution (V41= 6.4 ; V5 =2.24) (A) 0.62 * 102 By.02 «102 (©)2.7* 107 (D) 0.27 x 102 Ce [axZ- Sper - | 8px (PP Pre 2 (Pka-loge) = F(4-!9!) TZ] sas (p) let Ve vol & Naot ured tr Got equivalence peint oS OF-HA = 07-RNahH D sy joo 202 xv Ve yoo CeTAT = Boye = 02M. Phe F4d (Plat loge) = 944 (441002) =[84516) (wowak 1 He (ha2 18) Ip? mole Hee -2 - SE lO Sag yx! oe IP Srp YH Thee 2 IP K120? = 15M. . (00 K>® - id a “et lO7SE nya) 2S Htlox) + X (a3) o> = zB . a lek (S40 % x2 18 (224-1) al 7S ; 2 : oie XI) O% 2 0-62 15% ae [Brads [5 pO-kax 65, (ntl [baxterParagraph for Question 21 & 22 {A solution contains one mole each of HA & HBB (both are weak acids) in one lite solution, Now fone mole of NaOH is added to this solution so that both the aids are partially neutralised. Heat of neutralisation of HA & HB are —11.8 and ~12.4keal per mole respectively and eat produced during partial neutralisation of HA & HB is 12.25 keal. Q21 Moletatioof neutralisation of HA & HB is wis (By 1:2 13 Dus um wore Q.22 pllofsoluion containing mixture of| molof HA & | mole of HBin 1 ftxesoaton is K (HA) = 1x 10K (HB) =9 x 105 wz @3 os - . 2) Loa: tned= JM ” lr x mate THA ig neukaltsed -> (re & He pill be newtralited ° , MEMS Tt (190 FIDG = (2 7 che ow =—‘WBX npg thea w, Obx= ott . ols Mm XL Goo " ale De lle 1G? 4 ~ & -)L Required mute rakor we 3 E he2D di a we By cal eodaben Pir Oe Q mike % tvo werk atid s. Hit Piatst Fn’ =02'4 By _ pw <|0 - o fpne2 | raMATCH THE COLUMN : 22) Match the effect ofaddition of | M'NaOH to 100 mL. 1 MCH, COOH (in Column I) with pH (in Column IT) Column-1 Column-It (A) 25mL of NaOH (P) pK, (C) 75 mL of NaOH (8) pK,—log 3 (D) 100 mL of NaOH 1 (8) 51K, + pK, —log 2] A) Chzcoon + Naot = ___» ChzwoNne +H x0 14 (oom? 1M, Bd loomm)o wile | log 5 ts mmb 0 2 mmie. — P= Phat 45, = Pka-log3 BD Pu=Pke 6) PhoPht og, ) pre ged (rtaelegc) Cz ace bm = LPR +Phe!092)Q24 o Column-t PH 3 5 8 9 Ms: A » pre gE (Matlead = 7 Column-tt sotaon Oe eee ye ee ee ee coors oe Hlaemited Kory IO) &) OIMNaHPO, for HPO, K, = 10" | K, = 10%; K, = 10% (S) At *half equivalence point of H,CO, when itated against | a“ 100, O.M NaOH , K, = 10°. K, = 10° MeOH, + K,= 5x10" B+P,SC+R, DT nHyoH + Hee —~ nivie + HD 0.24 Vu, Do2dV mriie 0 [asye] = © = 0.26, Vouk OV mit ° ou vette - O2V .O-1M. Ke “ie ww ? £ (54197) =? “ory = El » CHztoona + Hee > CHzoen + Kol O-2N, VW ov mrile oO 02H Ve | - le 0 oy -2V male) ©) Sts a Cano de Calculation fy bH a weak atid- ae OW Lo. ka pia [ety eoond= C= Tru) 2 OIM. , Bele. 2 L ( Pka-lo49) = £ (E59) -3l D-IM Naz 4 (Araphi pote Qin, woe”) Phat Phas I pie _ b4tlo _ 2 =/2/ Hylog +naon —e Nani, + HD =< P jog = | Plt = Pay t OY, = [s]vp , Kep = 5x0 M4 (OW, os Ma" (ea) 20H (03) £ 2h kep = WPT og” cys ¢ 08% = 4g? alg a; Z 410 x 2 -I6 om 22 (SHO -I8 gr. gs FIO 9) &= sa’ wt Cows= 28= axrro” 21M Pore 1 [Pae4| &‘TABLE TYPE QUESTION : Column-1 Column-Il Column-IIl (solution) (pH of solution) (Introduction about solution) (A) CH,COOHO.2M, 1L)+ —) 13 (1) pH is determined by strong acid NaOH (0.1M, 1L) (B) CH,COOHO.AM,1L)+ @) 7 (2) Buffer solution at its HCI (0.1 M, 1L) maximum buffer capacity (©) CH,COOHO.1M,1L)+ (9 (8) pH is determined by salt NH,OH @.1M, 1L) hydrolysis, (D) NH,C1 (200 ml, 0.1M) © 5 (4) pH is determined by buffer + NaOH (100 ml, 0.1M) solution (Given : Bex,coon= 10" + (Yuan = 10% 106 2= 08 > Phagyssypy= 5 204 Pie oho 2) which ot the towing i incorrectly matched (A-S-4 B)B-P-1 (D-R-2 VAije-Q-1 2) 1f0.15 mole NaOH is added in solution (B) of column-I then which of the following is correct ws-s WIS 4 OR-1 P-3 » If 0.1mole HC! is added in solution (A) of column-I then pH of the resulting solution will be “7 @13 m0 1 aAD Cscooh + Nao ——p CHgcdoNat hho 0024, IL OM, IL 0-2mble o-|mMe Ol ihe o out mile Pas Pkq + (og 2! = Pky zS A~S 2,4 B) CHlooh + Hee Ol . Ot = 3) vim, tL Out IL ChB 2 Usp” 27 2-08 = Sr10 =p Pls 2-legS 2B 2O-lmio 2 0+ mile Bo Pols ©) Grycoot + whyoH —% CHtzcoony + N20 OuHIL O-IM, IL = Ome = O-lnsle ° o O-| mme. Pie +4 (Pha-PK) = 74 (5-5) = C+ AdDD Whyte + NAOH = ——> nag + Who Oo1M, 2000 OI, (00wL 2omnmle lomnle | | lomusle Oo Jommhe — joo, Pons Pky + log 12 to o%, Pons Pre ly-S= 4. Bebter at marcimury D-R--2-4 25) when 9-15 mole NaoH 1s added in solukim @) ben puimtte Naoh will be Comumed by Hi2 Auk 0-05 mite Nanny will eat Wir CrHzCool,Onecwon (03) + Wacnlas) —— CHecoonialas) + hoo O-lmole O-0s whe 0-05 rele D pos mote . > Acidic. bugger Lol Pus PKa t log 228 = 6 2A when Omete Hee is adked fo LolB, toon if will Lowmpterely hoatk wit. Or mile Nate. Retaining Lolubon lil be br mote Czcoey in 2b Solvhim- LonwonS 2c = o, O-1M. Pe fd ( fhy-logo) = 4 ( s-logoi = [3] us.