COSHH Risk Assessment Form

Department

Names/ type of persons involved

Undergraduate group, lab technicians, cleaners secondary
Procedure description
HF beta is first obtained, which is a strong acid. Solution of HF beta and a solvent such as
acetone is prepared with a concentration of HF beta being 1-2 mol/L. The ketone is then
added to the HF beta solution in order to convert it and the mixture is stirred for about 1-2
hours.
Substances used Hazard identification+ the Exposure limit/ toxicity
exposure routes, and the
estimated risk when using
all controls as specified
Hydrogen fluoride (40-60% Harmful by inhalation, can - TWA- 1.8 ppm or
weight) damage respiratory tract. 1.5 mg/m3
Water (40-60% weight) Harmful by ingestion.
Causes sever burns of the
mouth and throat, as well as
danger of perforation of the
oesophagus and stomach.
Can cause serious eye
damage, risk of blindness
Control/ containment measures
- Use only under a chemical fume hood.
- Ensure adequate ventilation , especially in confined spaces.
- Ensure that eyewash stations and safety stations are close to the workstation
location.
- Use light sealing safety goggles and face protection shields.
- Use protective gloves and clothing.
- Use filtered respiratory protection; recommended filter type: filter type ABEK
- Handle in accordance with good industrial hygiene and safety practice.
Emergency procedures (not otherwise covered by Changes to fire risk
departmental good lab practice) assessment
- Soak up with inert, absorbent material. - Ensure that all
- Clean up affected area. flammable materials are
- Do not breathe vapors. stored in a safe and secure
- Avoid substance contact. manner, away from sources
- Ensure adequate ventilation. of ignition.
- Ensure that all fire
protection equipment, such
as fire extinguishers and
sprinkler systems, are
properly maintained and in
good working order.

Health surveillance/ monitoring required

- Conditions such as hypocalcemia, hypomagnesemia and cardiac arrythmias should
be monitored for, since they can occur after exposure.
 - First aiders need to protect themselves.
- Seek medical advice if symptoms persist.
Special training requirements
Post graduates and staff only.
Access restrictions
- Cleaners only to attend to floor and waste bins.
- Auy undergraduate student observers must be supervised at all times.
- Fume cupboard must not be left unattended during reflux period.
Special waste/ decomposition requirements
- Not specified.
Name/signature of assessor
Head of Department/Departmental Safety Advisor/Supervisor Date