Professional Documents
Culture Documents
of
Originated by
MESSER Eutectic Castolin Egypt LLC
As carried out at
Heidelberg Cement
Helwan white cement Plant
El-Minya - Egypt
Dec. 2018
Statement of Liability
We will discuss the procedures, welding materials and methods that have proven
successful at many plants around the world. Specific examples illustrated here is
Helwan Cement company at south of Helwan city ; Tourah Cement at south of Cairo
and Helwan whit cement at east of Samalout city in Minia - Egypt.
The kiln tyres carry all the weight of the kiln, sup- ported between two relatively small-
diameter trunnions, creating rather high ratios of line loading on the surface of the
cast steel tyres.
Due to the high fatigue accumulation rate these stresses can eventually result in
cracks, which form initially under the surface. The fracture mechanism is one of fatigue
and will typically propagate from weaknesses in the original material such as casting
inclusions adjacent to the original riser positions.
Because of the ongoing work hardening and associated strengthening of the tyre
surface, defects or cracks initially form almost invariably below the surface. The
defects or cracks propagate unseen until the cross-sectional area is large enough to
weaken the tyre sufficiently that they cause a sudden and unforeseen break through
the entire section of the tyre.
Although this is not considered an exceptionally difficult grade of steel to weld, it must
be remembered that the part has been subjected to severe mechanical stresses and
some degree of work hardening.
The mass and configuration of the tire must also be taken into consideration as well as
the conditions under which the welding is to be done, and, last but not least, what the
effects of post welding cooling and stresses will be on the base metal, weld metal and
the heat affected zone.
In light of these multiple and varied factors it becomes apparent that any attempt at
repairing a cracked or broken kiln tire successfully will depend on proper preparation
and welding procedure as well as the selection of an absolutely reliable filler metal or
welding alloy with superior characteristics. And the success of the repair operation
relies ultimately on strict adherence to the proper time and temperature parameters
for both preheating and post heating, as well as maintaining proper interpass
temperatures during the continuous welding procedure.
According to the composition analyses that was done for the sample taken from the
kiln tire material is following table: (appendix 1)
Since a broken kiln tire effectively removes a kiln from operation until the tire is either
repaired or replaced, it is readily apparent that time is absolutely of the essence in any
situation where a kiln tire has broken.
Replacing the tire will generally require removal of a section of kiln in order to remove
the broken tire and install the new one, and then the kiln section must be repositioned
and welded back into place.
Also, Large castings are not only expensive, they are tailor made and are never readily
available on site. A large broken part cannot be used anymore and the equipment
becomes idle, there are many different factors for the economical calculation. These
factors include redundant production capability, capital tied up in intermediate stock
during the delivery time of the spare part.
Even if a new tire is on hand or readily available, removal and replacement of the kiln
section can still be time consuming. If no replacement tire is available, repair of the
broken tire may be the only chance of getting the kiln back in operation reasonably
quick, especially since delivery of a new tire may be in the range of four to seven
months.
Therefore, a reliable repair is mandatory, at least to be used during the lead-time for
the spare parts delivery and a time extension to allow the exchange during a scheduled
production stoppage
If the repair route is selected, a number of decisions must be made very quickly, those
include whether to do the repair in-house with existing staff and/or contract welders,
or whether to contract the job out to a company with experience and equipment to do
the entire job. In recent years the latter has increasingly been the most prevalent
choice, especially in light of the reduced welding staff available in most plants today.
This is much more cost effective than ongoing stopping and starting, and minimizes the
difficulties involved in maintaining correct base metal temperatures throughout the
entire repair cycle.
There are generally two alternate routes for selecting the welding alloys and
procedures to be used:
While the Ferritic alloy (OPTION 1) closely matches the chemistry and alloy content of
the base metal, the air harden-ability of the large volumes of weld metal to be
deposited would require rather high preheat requirements, creating both practical and
procedural problems. In addition, post weld heat treatment (PWHT) would be
mandatory. The difficulties associated with these levels of heating, considering the
mass involved and the amount of lost heat through radiation and conduction can be
almost insurmountable.
Another factor that must be considered also is the softening of the work hardened
surface in the welded area, and a severe hardness gradient at the each end of the heat
affected zone.
With respect to the use of non-Ferritic alloys (OPTION 2), one alloy has been widely
accepted as the single most reliable alloy of its type by the major OEMs. Castolin
electrode NucleoTec® 2222 is a high alloy nickel alloy with tensile strengths slightly
higher than that of the cast steel tire, but it has exceptional ductility and impact values,
along with 40–45 percent elongation and exceptional resistance to cracking, even
under continuous thermal cycling.
By using NucleoTec 2222, pre-heat is more easily attainable, and there is no need for
PWHT providing that certain techniques are rigidly adhered to during the welding
operation. The performance of these products in relation to tensile strength and
particularly ductility, even without PWHT, is far in excess of the parent material. When
coupled with good metallurgical integrity at the weld and parent metal interface and
skilled execution, NucleoTec 2222 gives the highest reliability of repair possible. The
concern of surface hardness degradation is also avoided. Naturally, due the high nickel
content there is an economic disadvantage, but bearing in mind the reliability of the
repair and the downtime cost savings involved, the consideration is of no practical
importance.
Table3 : Difference between mechanical properties of the Tyre metal and Xuper
NucleoTec 2222.
When making the final selection of the electrode to be used on a kiln tyre repair, it is
important to remember the severe penalties associated with having the repair fail
again. The cost of the right electrode, then becomes much less important than
knowing it will not only do the job, but will continue to hold up for many years to
come.
Unless the electrode is designed to accommodate the above factors, welding residual
stresses and the presence of hydrogen in hardenable zones will increase the risk of
provoking unexpected “cold cracking” phenomena.
Various materials expand and contract at different rates during the welding process.
Stainless steel alloys, for example, expand and contract much more than the carbon
steel tyre, thereby increasing residual stresses and distorting the joint.
Xuper NucleoTec 2222 has a coefficient of expansion very similar to that of the mild
steel tyre over a very wide temperature range. Only minimal residual stresses can
occur in the joint, either during welding or during subsequent thermal cycling, which
promotes maximum safety margin repairs.
Dilution refers to the percentage of base metal found in the weld deposit. When
conventional stainless steel alloys are used to join or repair carbon steels, the weld
deposit will invariably contain at least 20-30 percent base metal, which creates a weld
deposit prone to embrittlement due to the formation of hard martensite structure.
Xuper NucleoTec 2222 on the other hand will tolerate up to 50 percent dilution with
carbon steels and still retain its tough austenitic structure again promoting maximum
safety margin welds.
Since it has been reject to use of a mild steel electrode because of its lack of
elongation. The next choice is to use an AWS A 5.4 309 electrode as this type of
product is traditionally used for joining wrought or cast steel to ferritic or austenitic
steels.
Although the sigma phase is developed during a heat treatment between 500oC and
900oC, we know that during multi-pass welding, the weld creates, in the preceding
layer, a zone which is subjected to this temperature. This phenomenon will appear in
the bulk of the depost, especially if the weld is overheated during the welding
operation. We are, therefore, confronted with a problem of brittleness, in the
interface and in the deposit.
A special nickel base electrode "Xuper NucleoTec 2222" was developed to eliminate
both problems, the low chromium content does not allow the formation of a sigma
phase, the high nickel content allows a perfect match with most of the iron base
material. The risk of hot cracking associated with high nickel content electrodes, was
first reduced by the addition of molybdenum, which increases, in nickel alloy, the
elevated temperature resistance and secondly by a controlled procedure.
As seen from the Ternary Phase Diagram Xuper NucleoTec 2222 is situated far away
from the critical Sigma Phase zones. Even with dilution, Xuper NucleoTec 2222 remains
immune to the formation of harmful, embrittling Sigma Phases provoked by thermal
cycles either during welding or service conditions.
1. The basic extruded flux coating ensures tough, ductile welds with lowest
diffusible hydrogen contents.
2. The austenitic weld deposit structure is characterised by both a higher
solubility and lower diffusibility for hydrogen than for traditional ferritic
deposits.
This simply means that any errant hydrogen entering the molten weld pool will be
safely dissolved and retained after solidification, allowing very little to diffuse towards
the hardened HAZ steel interface, thus countering the HIC risks.
7
Relative Diffusion rate
6
Ferrite
5
4
Aus te nite
3
1
100 200 300 400 500 600 700 800 900
Temperature °C
6
5
4
Aus te nite
3
2
Fe rrite
1
0
100 200 300 400 500 600 700 800 900
Temperature °C
The comparison of the physical properties of typical cast steel kiln tyre material with
the Xuper NucleoTec 2222 electrode explains the exceptional success and reliability of
this product when repairing kiln tyres and rollers.
Their tensile strength, yield strength and hardness values are almost identical. Both the
impact strength and elongation of the Xuper NucleoTec 2222 electrode, however, are
more than triple those of the base metal. This unique combination of properties
provides tough, ductile welds that are virtually resistant to crack formation when
proper welding techniques and procedures are employed. While initial surface
hardness of the weld metal is lower, it increases rapidly in service by work hardening
effects until it is almost the same as that of the surrounding base metal.
This also helps explain the fact that after more than 12 years, many of the repairs
made with this product worldwide are still operating, with no documented cases of
cracking in the weld deposit or the heat affected zone of the base metal.
While the cost of this specifically developed, high-nickel alloy is considerably higher
than that of standard 7018 low hydrogen electrodes, the reliability of Xuper NucleoTec
2222 in this type repair makes the initial investment negligible when compared to the
cost of potential failure if traditional repair electrodes are used.
The following are the tools and tackles required, has to be arranged before starting the
welding operation.
Soundness of the weld means weld should be free from any form of surface/sub
surface defects. DPT, MPT and UST can be used to ensure this.
After the weld repairs are completed, quality control has to be done using dye
penetrate testing,
• Magnetic particle examination as per ASTM E-709.
• Ultrasonic contact examination as per ASTM E-164.
PWHT may be used for Xuper NucleoTec 2222 repairs but when heavy steel sections
are involved, PWHT is not always a economic in-situ solution. Many E+C case histories
have proven that Xuper NucleoTec 2222 weld repairs without subsequent PWHT have
given totally safe and satisfactory service performance. but to more successfully/safety
job, PWHT is recommended if it's easier possibility.
So, Before gouging/cutting the base metal should be preheated to 200 C°. then cut the
sample to send it to analysis to know the exactly the chemical composition of the base
metal. Then continue the gouging with this condition until decided the preheating
parameters.
once the material composition of the base metal is known, preheat temperature can
be calculated based on the thickness of the work piece and its carbon equivalent%
according to the following equation.
Mn% Cr % + Mo% + V % Ni % + Cu %
Ceq = C % + + +
6 5 15
250 CE=0,50%
200
CE=0,40%
150 CE=0,30%
CE=0,25%
100
CE=0,20%
50
0
۰ ۲۰ ٤۰ ٦۰ ۸۰ ۱۰۰
Thickness mm
Preheating should be done using electrical preheater with the following precautions:
Undercuts are not allowed and, a wash not exceeding 1 mm depth is allowed, in place
welding near flange location.
Laminations and other discontinuities in the weld area should not exceed 3 mm in any
direction. Laminations and other discontinuities greater than 3 mm size shall be
repaired.
100% close visual inspection of the plate after welding is required with special
emphasis on plate edges because of possible appearance of laminations and/or
lamellar tearing. Any visual lamination of lamellar tearing is reject-able. Any of these
defects must be removed and repaired.
6.5.3 Acceptance criteria for Magnetic particle and/or Dye penetrant controls
• Component should be free of any crack after repairing. This will be checked
during the visual inspection, either by magnetic particle or by dye penetrant test.
Both inspections are important to cover the part in its entirety for 100%
inspection. In case of MPT, it will be with a tangential field of 2000 to 3000 A/m.
• Any indications showing the existence of cracks are to be rectified.
• Magnetization should be obtained by passing a current or, with a horseshoe
magnet.
Wet process MPT (fluorescent or black and white) is recommended for better visibility.
5. Remove stop blocks from the tyre pads in crack area and slide tyre pads from under
tyre crack area.
This in turn could significantly increase the amount of welding consumables used and time
scales involved for little benefit.
19. Finish welds and dress if necessary to leave smooth contours, a minimum of inter-bead
craters and undercut or overlap. When all welding and grinding have been completed, allow
the weld to cool slowly. If the welding operation was a major one and added security is
required, a PWHT soaking temperature of 620 °C can used and held for one hour per 3 cm of
thickness. The temperature should then be lowered 20-40°C per hour until ambient
temperature has been reached.
We would strongly recommend that a contractor with experience in welding with 2222 on this
type of application be used. We would also recommend some form of Eutectic supervision be
employed on this type of repair, whether it be full time on site or periodic visits to ensure the
stated methods of repair are adhered to. The most important aspect of this supervision would
be to make the decision whether the surface is ready to be welded and the cut-off point for
excavation, as there are often some small cracks and porosity evident to the surface and edges
of cut out as already explained. A repair following this method should prove successful and a
long lasting repair can be achieved.
Introduction
More than a supplier of consistently high quality products, Eutectic Castolin is a stable
and reliable partner on whom our customers can always rely for the resolution of
technical issues and for ongoing support.
The use of modern welding and surface coatings has been established for many years
as a means of combating wear, breakage and corrosion of components within industry.
The correct choice of process and material is critical to the success of any repair.
Substantial cost savings can, and are being achieved by such reclamation and this can
also impact on inventory, production downtime and can lead to increased service life.
Welding Fumes
• Sources of Fumes
It is often a requirement to remove dirt, grease, paint, rust and scale from the metal’s
surface before welding and brazing can be carried out to produce a defect free weld. It
is also advisable to grind after welding and cutting operations.
1. Eye protection
2. Dust released by the removal method
3. Chemical involving the use of solvents
Unless the welding process, which can only be established by carrying out tests similar
to those that apply in practice, produces any fumes, it will be necessary to take
precautions by way of fume extraction with adequate ventilation and/or personal
protection. Alternatively, by the removal of the coating by means other than burning.
• Eye Protection
Eyes must be protected at all times by the correct type of goggles. This is a goggle of
impact resistance with complete impregnable side protection to BS 2092 1987, eye
protection for industrial and non-industrial uses. See grade 1 and 2 impact.
Where the parent metal has a surface coating such as galvanising, which would
produce an undesirable fume if welded, it may be acceptable to remove this coating by
grinding (taking suitable precautions).
The majority of manual metal arc welding electrodes have a flux coating. These come
in various forms.
Alloying Elements
High levels of chromium and nickel are added to stainless steel electrodes. These
elements may be toxic and be present in the fumes.
MMA electrodes can contain high levels of iron oxide. This can settle in the lungs and
though produces no symptoms of ill health is visible in normal chest radiographs. This
condition is known as Siderosis, or welder lung. This build-up over a period of years, if
exposure is continued, is gradually dispersed if active welding is stopped.
P501 Dispose of contents/container to waste treatment facility in accordance with local and national
regulations. .
2.3. Other hazards
Welding and brazing processes can cause spatter , melting metal and UV/IR heat can cause burns or start fires.
During welding- and brazing processes formed metallic fumes are suspected of being cancer causing agents.
Brazing/welding vapours and fumes from brazing/welding may cause metal fumes fever. Symptoms can appear 4 to 12
hours after. (headache, dizziness, dryness, cough, nausea and fever)
May cause irritation by prolonged inhalation of brazing/welding fumes.
Welding fumes (not otherwise specified) are considered to be carcinogenic with no further categorization by NIOSH
(National Institute for Occupational Safety and Health) and IARC ( International Agency for the Research on Cancer).
IARC - International Agency for Research on Cancer
NIOSH - National Institute for Occupational Safety and Health
Odour: Odourless
pH-Value: n.a.
Initial boiling point and boiling range: n.a.
Flash point: n.a.
9.2. Other information
No data available.
Aspiration hazard
Based on available data, the classification criteria are not met.
Further information
The product was classified on the basis of the calculation procedure of the preparation directive (1999/45/EC).
Advice on disposal
Where possible recycling is preferred to disposal.
Dust and in exhaust systems separated particles dispose of in compliance with local regulations.
Waste disposal number of waste from residues/unused products
160303 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; off-specification batches and unused products;
inorganic wastes containing hazardous substances
Classified as hazardous waste.
Waste disposal number of used product
150202 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE
CLOTHING NOT OTHERWISE SPECIFIED; absorbents, filter materials, wiping cloths and protective clothing;
absorbents, filter materials (including oil filters not otherwise specified), wiping cloths, protective clothing
contaminated by hazardous substances
Classified as hazardous waste.
Waste disposal number of contaminated packaging
150102 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE
CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging
waste); plastic packaging
LD = Lethal dose
LC = Lethal concentration
EC = Effect concentration
IC = Median immobilisation concentration or median inhibitory concentration
Literature:
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)