Ch. 11 Worksheet 1)Pairs of liquids that will mix in all proportions are called liquids. ‘A) miscible B)unsaturated C) polar liquids D)saturated E) supersaturated 2) The solubility of oxygen gas in water at 25 °C and 1.0 atm pressure of oxygen is 0.041 g/L. The solubility of oxygen in water at 3.0 atm and 25 °C is gL. A)0.041 B)0.014 ©)0.31 D)0.12 E)3.0 Lo Zo ee A wh CE cl yoees3) The solubility of Arin water at 25 °C is 1.6x10 M when the pressure of the Ar above the solution is 1.0 atm. The solubility of Arat a pressure of 2.5 atm is M A) 16x10 B)6.4x10* |C) 4.0x107 a E) 1.6x107 a & Pear: oe P, a -J M ) 2 4) A solution is prepared by dissolvi Tay ha, Gapyrowe ‘The density of the resulting solution is 1.05 g/mL. The Concentration of CaClis by mass, A)S.94 B)6.32 ©)0.0632 -D)0.0594—E) 6.24 Aw LY as100 so z a ze 8 = «| Video that Explains Z| how to use this Graph 3 wl between minutes 11:00 z x to 14:00 3 0 S10 20 3 050 70 B90 100 Temperature CC) 5) A sample of potassium nitrate (49.0 g) is dissolved in 101 g of water at 100 °C, with precautions taken to avoid evaporation of any water. The solution is cooled to 30.0 °C and no precipitate is observed. This solution is : A)hydrated B)placated C) saturated D) unsaturated E) supersaturated Asolution saturated with potassium dichromate has and elevated boiling point around __. AT =i m Ky= 3 (.272) 0.52 -100 80.0 g K2Cr207|1 mol KCr207_ = 0.272 moles 294.2 g KeCr207 AT = 4.24 so 104.24 °C6) The concentration of nitrate ion in a solution that contains 0.900 M aluminum nitrate is M A) 0.900 B)0.450 €)0.300 1D) 2.70 E)1.80 7) The concentration of KBrin a solution prepared by dissolving 2.21 g of KBrin 897 g ous wooK Baie | ec 119.00,kBr =P DEST Thy D) 2.07x10" E)0.01868) The concentration of a benzene solution prepared by mixing 12.0 g C,H, with 38.0 g CClyis A) 4.04] molal B)0.240 €)0.622 D)0.316 ee \3 Sea, 9) A solution is prepared by dissolving 15.0 g of NH, in 250.0 g of water. The mole fraction of NH, in the solution is A)0.0640 B)0.0597 )0.940 ss eo =Q,1SBb ml Ben ees ee 035 kg10) A solution is prepared by dissolving 15.0 g of NHyin 250.0 g of water. The density of the resulting solution is 0.974 gimL (Use total mass and density to determine the volume). The molarity of NH, in the solution is A) 0.00353 B)0.882 ©) 60.0 [D)3.24 E)353 11) The concentration of HClin a solution that is prepared by dissolving 5.5 g of HCl in 200 g of ethanol is molal. A)275 B)7.5x10* C) 33x10? |D)0.75 E13 a> 15.05 oo pro Tras BS ee 7 35 EL ae 5S )— yy 412) The mole fraction of He in a gaseous solution prepared from 4.0 g of He, 6.5 g of Ar, and 10.0 g of Neis : (A) 0.60 B)15 ©)0.20 D)O.11 E)086 13) The vapor press rvult's Law predicts that a solution prepared be dissolmgsTOU mina naphthalene(onvalatie) 90.0 mmol ethanol will have a vapor pressure of i A)0498 [B)0413] C)0.790 _D)0367 —_—E)0.0918 YP =OADon oe R 8. ao = 2 Mepinect 2 \e ae g oe (uPo~14) The vapor pressure of pure water at 25 °C is 23.8 torr. What is the vapor pressure (tom) of water above a solution prepared by dissolving 18.0 g of glucose (a nonelectrolyte, MW = 180.0 gimol) in 95.0 g of water? A)243 [B)23.4 ©0451) 0.443 rake 8 sig Yonele. tant L>[( 1)A seuions ining 00g ofan unknown St ‘and 90.0 g waterhas a freezing point t Givek Kye Cke= 186°C) Cke= 186°C) ¢Cimifor water, themolar mass of the unknown liquid aioe Cae Ge eon 0 B)333 619 D)161 E)62.1 as 2 Tike = fiers ie a AT>Umk. Sieg Jord Say> eae fan Be =, 6) mal unk stop recording16) The freezing point of ethanol (C,H,OH) is -114.6 °C. The molal freezing point WVhat is the freezing point (*C) of a solution in200.0% of BSE Uke KE 5b depression constant for ethanol prepared by dissolving 50.0 g o: ethanol? A)-115 B)-542 — €)-132.3— [D)-120.0 17) An aqueous solution of a soluble compound (a nonelectrslste)-is prepared by dissolving 33.2 g of the compound in sufficient water to fo he solution has an osmotic pressure of 1.2 atm at 25 °C. What is the molar mass (gmuL) of the compound? A)10x10 [B)27x10] 23x10? D) 68x10? E28 9. o\zzb wl a Ke ie MKT 33% 9 100%s. la nee oe eDL ix i ” alsa( ie =)-° Yo 18) George is making spaghetti for dinner. Heplaces 4.01 kg of wate¥in a pin and brings ittoa boil. Before adding the pasta, he adds 58 g of table sq (NaCI) the water and again brings it toa boil. Kp for water is 0.52 °C'm The temperature EO salty, boiling £C. Assume a pressure of 1.00 atm and no evaporation. €)100.13 D)99.74 ~—-E) 100.00 wateris A)99.87 19) Formation of solutions where the process is endothermic can be spontaneous provided that A) they are accompanied er process that is exothermic |C) they are accompanied AG = AH the E) the solvent is water and the solute is a gas =20) The phrase “like dissolves like” refers to the fact that A) gases can only dissolve other gases B)polar solvents Hissolve polar solutes and nonpolar solvents dissolve nonpolar solutes solvents can only dissolve solutes of similar molar mass D) condensed phases can only dissolve other condensed phases E)polar solvents dissolve nonpolar solutes and vice versa stop recording 21) An unsaturated solution is one that A)has no double bonds B) contains the maximum concentration of solute possible, and is in equilibrium with undissolved solute (C)has a concentration lower than the maximum solubility D) contains more dissolved solute than the solubility allows 2 oN E) contains no solute 22) Which one of the following substances would be the most soluble in CCl, ? \ A)CH,CH,OH = B)H,O =) NH,_—s | D) Gy, | ENaC Ethanol Decane23) Which of the following substances is more likely to dissolve in water? ‘A) HOCH,CH,OB B) CHA, ° i © CHaCH)sCH D) CH,(CH,),CH,OH E) CCl, 24) Which of the following substances is more likely to dissolve in CH,OH ? A)CC, —_B)Kr ON, D)CH,CH,OH| E)H, 25) Which one of the following substances is more likely to dissolve in benzene (C,H,) ? A) CH,CH,OH B) NH, Nach D) cc, E)HBr stop recording 26) Which one of the following is most soluble in water? A) CH,OH B) CH,CH,CH,OH C) CH,CH,OH ‘D) CH,CH,CH,CH,OH E) CH,CH,CH,CH,CH,OH27) Which of the following choices has the compounds comectly atranged in oder of 2 (east soluble to most soluble) A) CCl, < CHCl, < NaNO, B)CH,OH < CH, < LiF ©)CH, < NaNO, < CHG, D)LiF < NaNO, < CHA, E)CH,OH < Cl, < CHCl, 28) A solution contains 28% phosphoric acid by mass. This means that A) 1 mL of this solution contains 28 g of phosphoric acid B)1L ofthis solution has amass of 28 ¢ [C) 100 g of this solution contains 28 g of phosphoric acid D)IL of this solution contains 28 mL of phosphoric acid E) the density of this solution is 2.8 gimL 29) Molality is defined asthe : A)moles solutemoles solvent ___ B) moles solute/Liters solution C)moles solutekg solution [D)moles solutelkg solvent E)none (dimensionless)0 hone of the following concentration units varies with temperature? B)mass percent C)mole fraction D)molality E)all of the above : 31) Which produces the greatest number of ions when one mole dissolves in water? A)NaCl —-B) NH,NO, ©) NH,@_[D) Na,SO, | E)sucrose i32) As the concentration of a solute in a solution increases, the freezing point of the solution and the vapor pressure of the solution A)increases, increases B)increases, decreases C) decreases, increases D) decreases, decreases E) decreases, is unaffected 33) Which of the following liquids will have the lowest freezing point? A) pure H,O B) aqueous glucose (0.050 moles added) C)aqueous Col, (0.030 moles added) —_[D) aqueous Fel, (0.030 moles added) E) aqueous Nal (0.030 moles added) Ge 1.35 m aqueous solution of compound X had a boiling point of 101.4 °C. Which of the following could be compound X? The boiling point elevation constant for wateris 0.52°Cim. A) CH,CH,OH —_B) C,H,,0, fe ©)Na,PO, [DKA E) CaCl, Mole, oma35) The most likely van't Hoff factor for an 0.01 m Cal, sqlution i: s : AQ __B)3.00 ©1227 D)2.69 BN | 36) Colligative properties of solutions include all of the following except ‘A) depression of vapor pressure upon addition of a solute to a solvent B) elevation of the boiling point of a solution upon addition of a solute toa solvent C) depression of the freezing point of a solution upon addition of a solute to a solvent D) an increase in the osmotic pressure of a solution upon the addition of more solute E) the increase of reaction rates with increase in temperature 37) solution is prepared by adding 30.00 g of lactose (milk sugar) to 110.0 g of water 55°C The partial pressure of water above the solution is torr. The vapor pressure of pure water at 55 °C is 118.0 tom The MW of lactose is 342.3 gmol. A)1670—BY94.1 c1694 [D)il63] — E)92.738) A solution is prepared in an evacuated flask by mixing sodium chloride and water. The vapor pressure of pure water at 25 *C is 2.34 kPa. Calculate the total vapor pressure above the solution made by dissolving 10.0°grams of sodium chloride in 900.0 ml of water at 25 °C mom aN at ¥ = © Q = ees) soe _— 2 em ky 2.33 kPa39) A solution is prepared in an evacuated flask by mixing sodium chloride and benzene. The vapor pressure of pure benzene at 20 °C is 10.0 kPa. Calculate the total vapor pressure above the solution made by dissolving 10.0 grams of sodium chloride in 900.0 g Poy w.o(aes) = anal > 9.855 kPa: . Typo below in white. 40) A solution is prepared in ai evacuated flask by mixing benzene and water. The vapor pressure of pure water afQQ}°C is 2.34 kPa. The vapor pressure of pure benzene at 20°C is 10.0 kPa. Calculate the total vapor pressure above the solution made by dissolving 40. grams of benzene (molar mass = 78.0 g'mol) in 40. ml of water at 25 °C. DAsdatla Liqurds : 0 = + Pek ar Xf Benn SIAQau) + 1% Co) 3.78 kPa Pe 379kp,