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GRUNDFOS DESALINATION

Manual

GRUNDFOS
DESALINATION
MANUAL

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Contents

Introduction .........................................................................................5
1. Desalination methods ......................................................................7
a. Multi-Stage Flash (MSF) desalination ..........................................................7
b. Multiple Effect Desalination (MED) ..............................................................9
c. Reverse Osmosis (RO) desalination ............................................................. 10
d. Cost comparison ................................................................................................. 11
2. How Reverse Osmosis (RO) works ...................................................13
a. Spiral wound module ...................................................................................... 14
b. Energy recovery ................................................................................................... 18
c. An example of possible power savings .................................................... 20
3. Water intake ..................................................................................25
a. Beach wells............................................................................................................ 25
4. Intake water treatment ..................................................................27
a. Nanofiltration ...................................................................................................... 28
b. Chlorine .................................................................................................................. 29
5. Brine discharge...............................................................................31
6. Permeate treatment and distribution.............................................33
a. Distribution ........................................................................................................... 33
7. Control systems and water quality control .....................................35
8. Product chart..................................................................................38

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Contents Desalination Manual

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INTRODUCTION

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Introduction Desalination Manual

Introduction

Why desalination and water treatment? However, desalination offers a potential solution.
Pure water (H2O) is a colourless, odourless and Desalination is the process used to convert
tasteless liquid. It plays a huge part in everyday salt water (seawater, brackish water or saline
life: 70 % of the earth’s surface is covered by groundwater) to fresh water so it is suitable
water in the form of oceans, and the rest of the for human consumption or use. Most interest
planet has large quantities of water in the form in desalination today is focused on developing
of lakes, rivers and watercourses, ice and snow, cost-effective ways of providing fresh water for
and humidity, as well as the principal element human use in regions where the availability
of animal life (> 50 %) and plants (approximately of fresh water is, or is becoming, limited.
80 %). Desalinated water is also used on many seagoing
ships and submarines.
When we talk about water in general, we usually
mean water for some specific purpose, such as Large-scale desalination typically uses extremely
drinking water or process water for industry. This large amounts of energy as well as specialised
is where the term water treatment enters the infrastructure, making it costly comparable
picture, because the available water resources to the use of fresh water from rivers or
provided by nature are not always of a suitable groundwater wells.
quality for immediate use for the specific
purpose.
Almost one-fifth of the world’s population lives Rain clouds

in areas where freshwater is a physical scarcity.


However, for those living in coastal areas, the
ocean offers a sustainable alternative.
Precipitation
Transpiration
Drinking water must be pure, and should Evaporation
preferably taste good too. It must not contain
substances that could cause problems with daily
use. Process water, which is water that forms a
Ocean
direct and important part of a process or product Soil
in industry, must have a chemical composition
Ground water
and temperature that is precisely suited to the
specific requirements. Thermal desalination is best known from nature’s
own processes in the water cycle
Water availability
With water scarcity increasing, and we
increasingly face the consequences of uneven
global water usage and rapidly depleting
natural water resources. With growing
populations, a rising middle class and booming
industrialisation, the expectation is that world
water consumption will increase substantially
in the future. Only 3 % of all water on earth
is freshwater and accessing these reserves is
sometimes neither practical nor desirable.

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DESALINATION
METHODS

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Desalination Methods Desalination Manual

1. Desalination methods

There are different ways to desalinate seawater, excess heat is available from, for example, an oil
and these vary in cost and efficiency, depending or coal heated electric power plant. The Middle
on the purpose. This is a technology-heavy field East has the majority of thermal desalination
in constant development, as attempts are made plants in use today.
to keep costs down, increase efficiency and en-
sure the sustainability of the solution, including
a. Multi-Stage Flash (MSF) desalination
reducing environmental impact.
Multi-Stage Flash (MSF) desalination is the
most common process for turning seawater into
The most common and immediately apparent
drinking water. The process uses the excess heat
desalination process is thermal desalination,
from big thermal power plants. This process is
where seawater (salt water) evaporates and the
widely used in the Middle East.
vapour condenses to clean water.
For producing drinking water, thermal desalina-
Capacity is 200,000 to 800,000 m3/day.
tion uses excess heat and often used where

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How MSF works and temperature. In a single stage, the feed
MSF distillation is based on condensing water would only warm to an intermediate
low-pressure steam as a heat source for the temperature between the inlet temperature and
evaporation of seawater. It is still considered the the heater, while much of the steam would not
simplest and most common technique in use. condense and the stage would not maintain the
The technique is based on passing seawater lowest pressure and temperature. Such plants
through long, closed pipes passing through a can operate at 23-27 kWh/m3 (approximately 90
series of flash chambers where hot seawater MJ/m3) of distilled water.
allows flashing along the bottom of the
chambers. Vapor from the flash chambers heat Because the colder salt water entering
the feed water flowing in the pipes. More heat the process ‘counter flows’ with the saline
is added in order to increase the temperature of wastewater/distilled water, relatively little heat
the feed water to the initial high temperature, energy leaves in the outflow; most of the heat
around 110 oC. This is done with the use of low is picked up by the colder saline water flowing
pressure steam, usually taken from a back- toward the heater and the energy is recycled.
pressure turbine in a power station. The vapor
condenses on the heating pipes and is pumped In addition, MSF distillation plants, especially
out as product. Usually, the concentrated brine is large ones, are often paired with a power plant
recycled with the feed to improve recovery ratio. configuration. Waste heat from the power plant
Part of it is pumped out to sea. is used to heat the seawater, providing cooling
for the power plant at the same time. This
The energy that makes possible the evaporation reduces the energy needed by half to two-thirds,
is present in the brine as it leaves the which drastically alters the economics of the
heater. There is a good reason for letting the plant, since energy is by far the largest operating
evaporation happen in multiple stages rather cost of MSF plants.
than a single stage at the lowest pressure

Heating steam Air extraction

Sea water

T=112°C

Brine

Condensate return Distillate

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Desalination Methods Desalination Manual

b. Multiple Effect Desalination (MED)


Multiple Effect Desalination (MED) is used in
smaller sized thermal power plants or other
plants with excess heat available.

Capacity is 2000 to 200,000 m3/day.

First Second No. 3


effect effect effect
Vapor Vapor Vapor

Steam 110°C 100°C 50°C Condensator

Feed
Condensate 120°C 110°C 60°C

Liquid Liquid

Concentrate Distillate

How MED works


Consider the plant as a sequence of closed spaces
separated by tube walls, with a heat source at
one end and a heat sink at the other end.

Each space has a lower temperature and pressure


than the previous space. If the pressure is too low
or the temperature too high in the first subspace,
the water evaporates. In the second subspace, the
pressure is too high or the temperature too low
and the vapour condenses. This carries evaporation
energy from the warmer first subspace to the
colder second subspace and so on.

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c. Reverse Osmosis (RO) desalination
Increasingly, Reverse Osmosis (RO) is becoming
the preferred technology for desalination.

RO is in many ways the heart of desalination.


Here, high-pressure pumps force the seawater
through semipermeable membranes to separate
the water molecules from the larger salt
molecules. The membranes allow a permeate
of water to pass through the system, while
expelling a salt concentration called brine.

See Section 2, page 13 for an in-depth look at


how RO works.

A typical RO installation

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Desalination Methods Desalination Manual

d. Cost comparison fact that the environmental standards required


Currently, the best performing membrane for desalination are very high, and the plants
desalination plants achieve energy consumption themselves involve complex intakes and outfalls.
in the region of 3.8-4.2 kWh/m3. This includes In the Unites States, RO desalination is expected
both the pretreatment process and the RO to become expensive for similar reasons.
process. The Affordable Desalination Coalition
has demonstrated that it is possible to Relative operating costs of the main
deliver the SWRO process alone (i.e. without desalination processes
pretreatment and other pumping processes) To work out the capital cost of recent SWRO
for 1.58 kWh/m3. Thermal desalination plants desalination plants, as a rule of thumb the
may use up to 18 kWh/m3. The electrical power current capex figure for an RO project (without
consumption of an MSF plant is around 3.5 site-specific complications) might be USD 1,100/
kWh/m3, even before the water is heated for m3/d, while an MED project might come in
steam.In the figure on the right are shown the at USD 1,500/m3/d, and an MSF plant at USD
relative operating costs of the main desalinatin 1,800/m3/d. The latter two figures are highly
processes. Obviously, energy represents the main dependent on commodities prices – there is
operating cost of a desalination plant and little recent data available to confirm the current
the cost is depending on local electricity prices. state of the EPC (engineering, procurement and
construction) market.
The capital cost of desalination plants varies
according to a number of site-specific issues, as The following chart illustrates the breakdown of
well as the technologies used. E.g. the low bid the capital costs of the three main desalination
that the Dubai Electricity and Water Authority processes:
received for its Hassyan P1 Station in 2008, which
uses MSF technology. And a high prices paid for
the Australian desalination plants reflect the

Cost with relative to RO

Cost component MSF MED MVC RO

Capital
120 114 118 100
investment

Energy related
215 175 140 100
costs

Membrane
--- --- --- 100
replacement

Other remaining
103 89 100 100
costs

Overall product
114 109 107 100
cost

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HOW REVERSE
OSMOSIS (RO) WORKS

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Reverse osmosis Desalination Manual

2. How Reverse Osmosis (RO) works

Osmosis is the natural tendency of water with a into the high TDS solution to equalise the
low concentration of total dissolved solids (TDS) concentration levels on both sides. As more
to travel through a semi-permeable membrane water molecules travel through the membrane,
into a solution of higher TDS in order to balance the fluid level in each chamber changes. Once
the solute levels on both sides of the membrane. the TDS concentrations in both chambers have
reached equilibrium, the osmotic process stops,
The illustrations below illustrate how the water as enough pressure has built up to stop the flow
molecules from the low TDS solution migrate of water from one chamber to the other. This
through the semi-permeable membrane pressure is known as osmotic pressure.

Chamber with Chamber with Equilbrium - TDS is balanced


high TDS low TDS across with chambers

Applied
pressure
Reverse Osmosis is a process where pressure
greater than the natural osmotic pressure is
applied on the high concentration side of the
membrane, forcing the water to travel through
the membrane from the higher TDS to lower TDS
chamber, thus ‘reversing’ the natural tendency of
water flow.

Reverse osmosis membranes used in


desalination operate on this principle, to
draw fresh water through a semi-permeable
membrane from high TDS solutions such as
seawater, brackish water, industrial effluent and
other sources.

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Seal ring between module and pressure vessel
Perforation in central pipe
7 8

2 Outlet for concentrate


3 Outlet for permeate
2 Outlet for concentrate

1
9 Concentrate spacer
Inlet for raw water 10 Membrane
4
11 Permeate spacer
Flow direction for
raw water 10 Membrane
5
9 Concentrate spacer
Flow direction for permeate
12 Glue joint of "envelope"

6
External housing

Cross section of spiral wound module

a. Spiral wound module now resembles a rolled carpet. Finally, a tubular


The spiral wound module is the dominant housing cover, the supporting sleeve, is placed
module available in the drinking water market, around the whole ‘carpet’.
and the most widely used module type.
Modules are installed in series of up to seven in a
The structure is substantially more complicated pressure tube, the ‘pressure vessel’. This is crucial
than other types. The filter consists of a large to ensure the modules withstand the often very
‘envelope’, which is glued tightly together along high system pressure.
three edges, with a porous mesh, ‘the letter’,
inside, and with the actual membrane surface During operation, the raw water is directed
on the two external sides of the envelope. A into the end of the module and flows axially
mat, ‘spacer’, of open mesh is on top of the through the module through the above-
envelope. Another envelope and another mat mentioned spacers. The permeate penetrates
then follow, and so on. Each of the open ends of the membranes and enters the spacers inside
the envelope is glued to a perforated tube, the the ‘envelopes’, where it flows in a spiral until it
permeate tube, so that the openings are right reaches the central permeate pipe, from which
against the rows of perforation. All the layers are the permeate can be drained from the ends.
then rolled up around the permeate tube, which

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Reverse osmosis Desalination Manual

Feed
Permeate

Drain
Pressure vessel for ‘spiral wound’ modules Holes
Down

Electron Microscopy Optical Microscopy Visible to Naked Eye


Macro Molecular
Ionic Range Molecular Range Range Micro Particle Range Macro Particle Range
Micrometers 10-3 10-2 10-1 10 100

Angstrom 10 102 103 104 105 106

Mol. Wt.range 100 200 1000 10000 20000 100000 500000


Latex Emulsions
Oil Emulsions
Sugars Carbon Black Point Pigment
Endotoxins (Pyrogen) Yeast Cells
Virus Bacteria
Soluble Salts
(Ions) Mycoplasm
Red
Colloids Blood Ceels Sand

Metal Ions Proteins / Enzymes Human Hair

Reverse Osmosis Microfiltration


Nanofiltration
Ultrafiltration Particle filtration

Note: 1 Angstrom Unit = 10-10 Meters = 10-4 Micrometers (Microns)

The table shows the different filtration processes according to the relative size of the particle retained

The particle filtration can be achieved with a lot of different technologies, each of them suitable for
different requirements. The filtration of particles of size less than a micrometer is achieved with the use of
membrane filtration, which is a type of filtration over a support.

Membranes is a special type of filtration on support. Relatively thin sheets or thin fibers with an ultrathin
surface layer where the filtration/retention of particles and other pollutants take place. A "filter cake" of
pollutants is build outside the filter during operation, and regeneration of the filter is therefore much
easier and with less water waste. For this reason membrane filters have showed a tremendously fast
growth in market shares on the water purification markets recently.

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Membrane cleaning Normalised values take into account
Reverse Osmosis membranes must be rinsed temperature and salinity variations in feed
and chemically cleaned periodically, when water.
stopped or when performance decreases by In order to ease chronic cleaning, our systems
10-15 %. can be equipped with Cleaning In Place (CIP)
station, readily connected to the membranes
Seawater flows tangentially along the rack.
membrane, creating a salt concentration
gradient along the membrane's length, where
the last element has the most concentrated
brine bulk.

When the RO is stopped or in stand-by, natural The CIP station, depending on the plant size,
osmosis will happen between the permeate includes a chemical tank with mechanical or
side and the concentrate side containing manual stirrer, a CIP pump and a fine filter
high salinity brine. This can damage the feed to avoid debris to enter the membranes. The
spacers by creating a vacuum in the permeate chemical tank depends on the number of
line, as water will naturally flow back to the membranes to be cleaned at the same time. H
concentrate side, driven by osmotic pressure. Alkaline and Acid Cleaning solutions are
recirculated around the membranes for at
To avoid this natural damaging osmosis least 30 minutes.
happening, seawater and brine are flushed
off the membranes after service by permeate Routine cleaning, chemicals and procedures
water taken from the permeate tank (before are determined depending on desalination
chlorination) and pushed in the membrane by a plant layout and fouling identification. En
low pressure pump (i.e., feed pump, distribution
pump or specific cleaning pump).

Membrane chemical cleaning


Seawater flows tangentially along the
membrane, creating a boundary layer on the
membrane surface.

Membranes have to be cleaned typically when:

• Normalised Permeate flow varies by 10-15%


• Normalised Feed pressure varies by 10-15%
• Normalised Permeate conductivity varies by
10-15 %
• Pressure drop between feed and concentrate
varies by 10-15 %

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Reverse osmosis Desalination Manual

High pressure
pump

Concentrate
Permeate
Energy recovery
device

Fine filter CIP pump Chemical tank

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The reverse osmosis membranes filter away In the illustration below, two grouped solutions
everything but water molecules. Therefore, it for energy savings and reuse are shown. In the
is necessary to regulate the pH value and add Pelton group, the entire feed flow is pumped by
essential minerals afterwards, for instance by the high-pressure pump, whereas in the Pressure
letting let the water pass through limestone Exchangers group, only part of the feed flow
filters. Again, precise dosing systems and dosing equal to the product flow is pumped by the high-
pumps are essential to ensure the final product pressure pump.
is perfectly safe to drink.
The main difference between the two groups is
b. Energy recovery therefore the flow pumped by the high-pressure
The brine leaves the system at very high pump. This means that the normal pump and
pressure, and there are different ways of motor losses is applied only to a portion of the
recovering and reusing this energy. In fact, feed flow. This is the first element of power
energy savings of up to 60 % can be achieved savings credited to the Pressure Exchangers
by harvesting this energy with energy recovery group.
devices (ERD).

No recovery Product
40/1 bar

Feed
100/63 bar
100/5 bar
CARTRIDGE
FILTER

Brine
60/60 bar
60/0 bar

Turbine recovery Product


40/1 bar

Feed
100/63 bar
100/5 bar
CARTRIDGE
FILTER

Brine
60/60 bar

60/0 bar

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Reverse osmosis Desalination Manual

Pressure Exchanger group


Product
Feed 40/1 bar
100/63 bar
40/63 bar

100/5 bar 60/63 bar


CARTRIDGE Brine
FILTER 60/60 bar

CHECK VALVES
PRESSURE VESSEL

VALVE
Brine
PRESSURE VESSEL 60/0 bar
60/2 bar

Product
Feed 40/1 bar
100/63 bar
40/63 bar

100/5 bar 60/63 bar


CARTRIDGE Brine
FILTER 60/60 bar

Brine
60/0 bar
60/2 bar

The particularity of the RO desalination process flow. This is the reason that the HP pump in
lies in the fact that the brine coming from this scheme has to pump only part of the feed
the membranes loses very little from the feed flow equal to permeate. The transfer losses
pressure, and this brine stream contains almost are few, and the circulation pump delivers the
50 % of the energy required for desalination. compensation of pressure difference between
This is why the efficiency with which the energy brine and feed (3-4 bar).
contained in the brine pressure is transferred for
pumping of the feed water is critical. The efficiency of energy recovery in the Pressure
Exchangers group is around 96 %.
The energy transfer in the Pelton group is
indirect, with the brine jet hitting the turbine Good pump efficiency is 85 %, and at the end of
buckets. The efficiency of Pelton turbine itself the retransmission chain, of the 100 kWh energy
is around 87 %. The energy is transferred to the in the brine, only 74 kWh can be transferred to
shaft and from the shaft to the pump. the feed stream again.

The form of energy transfer in the Pressure


Exchangers group is direct from brine to feed
water, as in the steam engine, making the
Pressure Exchangers, at the same time, a high-
pressure pump for flow almost equal to brine

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c. An example of possible power savings
Let us assume a desalination plant of 95,000
m3 per day capacity is built using one of two
technological approaches: Pelton turbine or
pressure exchangers.

Common data of design parameters used in both technological groups


Water plant Pressure to Brine Plant recovery HP pump Pelton Circulation Motor
production membrane pressure from efficiency efficiency pump efficiency
membrane efficiency
95,000 m3/day 63 bar 50 % 85 % 87 % 89 % 95 %
Pelton Group
Energy Energy Total energy Specific energy
consumption recovered by consumption consumption
of HP pump Pelton for an hour of per m3
operation
16232 kW 5716 kW 11069 kWh 2.8 kWh
Pressure Exchangers Group
Power of HP Power of Total energy Specific energy The difference in energy
pump circulation consumption consumption consumptin between
pump for one hour of per m3 Pressure Exchangers Group
operation and Pelton Group s 0.5
kWh per m3
8643 kW 405 kW 8948 kWh 2.3 kWh

The equipment and maintenance costs in the cost, is shown below. The graph represents
Pressure Exchangers group are higher than in the the case of a 95,000 m3/day desalination
Pelton group. plant, 10-year loan, 7.5 % interest rate. As can
be seen, if the energy cost for large industrial
The merit of implementation of one or other service is above USD 0.0175 (1.75 cents) per kWh,
group depends on several factors such as energy the Pressure Exchangers group can be more
cost, project lifetime, and interest rates. The cost economical than equipment from the Pelton
effectiveness of the Pressure Exchangers group group.
as opposed to the Pelton group, versus energy

$4,000,000
$3,000,000
Saving NPV in US$

$2,000,000
$1,000,000
$0
-$1,000,000 1 1.5 2 2.5 3 4 4.5
- $2,000,000
Saving NPV in USD
Cost effectiveness of Pressure Exchangers group opposed to Pelton group versus
energy cost

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Reverse osmosis Desalination Manual

The difference between types of equipment in


Cost comparison based on
each group
Energy Recovery Type
There is a major difference in efficiency between
1pass RO with ERT-40 g7L - 40% recovery
Pelton and Francis turbines. The Pelton turbine
- 125 m3/h - 0.08 kWh/m3 - 10 yrs depreciation time
is more efficient and used in the majority of
seawater reverse osmosis (SWRO) desalination 50%
plants. The weak point of Pelton technology is 45% 48%
the formation of a foamy stream that can only be 40%
41%
35%
evacuated by gravity or re-pumped once settled.
30% ERT
The differences between Dual Work Exchange 25% PX
Energy Recovery (DWEER) and isobaric pressure 20%

exchanger (ERI) systems are minor, with both 15%


14%
10% 11%
types of equipment having good reference records 5%
as reliable energy recovery systems. 0%
Investment Electricity

Energy effective but expensive DWEER and ERI Desalination plant costs breakdown
systems cannot be used in conditions where 1pass RO with PX-40 g7L - 40% recovery
the energy cost is low, the interest rate high and - 125 m3/h - 0.08 kWh/m3 - 10 yrs depreciation time
the mortgage period short. The type of energy 1%
11% 14% Investment
recovery device also depends on the condition of 7% Membranes
the brine discharge. The DWEER and ERI systems Consumables
are able to maintain sufficient backpressure for Electricity
41% 26%
long distance brine discharge. Manpower
Spares

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ERI (isobaric pressure exchanger),
used for energy recovery in
Grundfos BMSX systems.

Energy use: 2.5-3.5 kWh/m³

VFD 40% recovery rate


9 m³/h Permeate 9 m³/h
70 bar
RO Concentrate 14 m³/h
Seawater feed
23 m³/h; 2 bar 68 bar
HP pump VFD
14 m ³/h 14 m ³/h; 68 bar
70 bar
Pressure
14 m3/h 2 bar Booster pump exchanger

14 m³/h
1 bar

The relationship between energy cost, interest cost, the SWRO designers will implement high
rates, and labour and civil engineering costs membrane fluxes and high recovery in order to
will determine the plant recovery, membrane reduce the physical dimension of the plant and
flux, and even water velocity in the pipelines. increase the energy components of the water
Low power cost and high labour cost, as is cost.
typical in the USA, is unusual for traditional
seawater desalination areas. This combination The tender requirements should define the limits
of economic parameters will challenge plant on several technological parameters to ensure a
designers to push desalination technology to reliable water supply.
its limits. In the effort to reach low overall water

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Reverse osmosis Desalination Manual

BMT pump driven by Pelton


turbine, used in Grundfos BMST
system.

Energy consumption: 4.5 -5 kWh/m³

VFD 23m³/h 40% recovery rate


Permeate 9 m³/h
70 bar
RO Concentrate 14 m³/h
HP pump 68 bar
14 m ³/h; 68 bar
25bar
Pelton
turbine

Seawater feed
23 m³/h; 2 bar 14 m³/h
0 bar

Power consumption per m3 permeate produced on SWRO system with Pelton turbine.

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WATER INTAKE

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Water intake Desalination Manual

3. Water intake

The first step in desalination is collecting a. Beach wells


seawater for processing. There are many ways to Beach wells are recommended when seawater
design an intake system, and the method chosen quality can vary over the season and/or when
depends on a range of factors, including the high turbidity peaks can occur. One vertical
water demand and the quality of the seawater. beach well can draw up TIDAL
to WATER
200 m3/h. A radial
well can take up to 1000 m3/hour, depending on
Above
BEACH Well and
pumps
For smaller plants, it will often be a good idea to max. storm
the soil layers.
use beach wells fitted with submersible pumps. tide level
This will allow the sand or corals to work as a For larger plants, or plants located near polluted
natural filter, reducing pre-filtration steps in the coastal water, pump houses with dry-installed
plant. pumps and pipelines are often the better choice.
Not only will a pipeline allow a larger intake of
water,TOit TREATMENT
will also enable you to collect
A water
A from
beyond the polluted area.
PLANT
PLAN VIEW

Well and Well and


pump pump

CASING
TIDAL WATER
BEACH Well and
Above
pumps CEMENT GROUT
max. storm
tide level

WELL SCREEN

GRAVEL PACK
TO TREATMENT A A
PLANT
PLAN VIEW A A

SECTIONAL VIEW
Well and Well and
pump pump

STORAGE TANK
REVERSE OSMOSIS

DEDALINATED
CASING WATER

PRE-TREATMENT

CEMENT GROUT

WELL SCREEN

INTAKE

GRAVEL PACK
UNDERGROUND
TUNNELS

A A
Overview of seawater desalination concept
SECTIONAL VIEW

OUTLET

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INTAKE WATER
TREATMENT

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Intake water treatment Desalination Manual

4. Intake water treatment

The next step in the seawater intake process is a


mechanical and possibly chemical pre-treatment.

Typical SWRO system


with multimedia filter
and microfilter

H2SO4 Antiscalant
Multi media Micro R/O Stage
NaOSl
H2SO 4 filter
Multi media Micro filterAntiscalant SBS R/O Stage
NaOSl filter filter SBS
FeCl3
FeCl3

PURE WATER PURE WATER

ERT ERT
SEA
SEA WATER Pump
WATER Pump BoosterBooster High pressure Concentrate Concentrate
High pressure Post Post
pump pump pump pump treatment treatment

Sodium RO filtered
hypo chlorite Sodium water RO filtered
hypo chlorite water

R/O Stage
In taked Backwash
water strage tank R/O Stage
pump
In taked Backwash
water strage tank PURE
pump WATER

Concentrated PURE
Pre-filter
feed pump Compressor water Product water WATER
strage tank
Concentrated
Well pump Pre-filter MF Filtered Transfer High
Compressor water Product water
feed pumpmodule water tank pump pressure
pump strage tank
Strainer MF Filtered Transfer High
Well pump module water tank pump pressure Typical SWRO system
pump
with ultra filtration as
Strainer pre-filtration.

The choice of method depends on the water However, it is more and more common that
quality. The most common approach is to pump membranes for ultrafiltration replace the bag
the seawater through multi-media filters with filters or cartridge filter.
layers of sand, pebbles or gravel to remove twigs,
seaweed and other solid particles. The water will
then be filtered through bag filters or cartridge
filters before it is pumped into the membranes.

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External view of hollow fiber membrane

a. Nanofiltration
Nanofiltration is a relatively recent membrane
filtration process often used where water has
low total dissolved solids (TDS), such as surface
water and fresh groundwater. With the purpose
of softening (polyvalent cation removal) and
removal of disinfection by-product precursors
such as natural organic matter and synthetic,
nanofiltration is used increasingly as pre-
filtration for SWRO systems.

How nanofiltration works


Using nanofiltration as pre-filtration prevents
fouling in the SWRO membranes, and this
increases the efficiency of the desalination
plant. The nanofiltration membranes used for
prefiltration are often hollow fibre membranes.

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Intake water treatment Desalination Manual

b. Chlorine
If necessary, chlorine is added to remove bacteria
or flocculent to separate larger particles from the
water. It can also be necessary to add antiscalant
to prevent scaling deposit in the membranes.

This process relies heavily on precision dosing


pumps to ensure that the exact amount of
chemicals is added.

If chlorine is added, it needs to be removed before


the water is pumped through the membranes.
Potassium metabisulphite is dissolved in the
water to remove chlorine and chloramine.

In this process, feed pumps or end-suction


pumps are essential to maintain the right
pressure and ensure proper filtration. The pumps
are also responsible for delivering sufficient inlet
pressure to the high-pressure pump, which drives Chemical dosing
the RO process.

Grundfos Polydos

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BRINE DISCHARGE

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Brine discharge Desalination Manual

5. Brine discharge

When designing a desalination plant, the Seawater desalination plants carry a number of
brine discharge or outfall must be taken into waste products into the coastal environment:
consideration. concentrated salt brine that may also have
The impacts of a desalination plant discharge on an elevated temperature, often containing
the marine environment depend on the physical antifoulant and antiscalant and other
and chemical properties of the desalination substances. Modern, large capacity plants
plant reject streams, and the susceptibility require submerged discharges that ensure a high
of coastal ecosystems to these discharges dilution in order to minimise harmful impacts on
depending on their hydrographical and biological the marine environment.
features. Therefore, a good knowledge of
both the effluent properties and the receiving • There is increased public concern and scientific
environment is required in order to evaluate the awareness on the environmental impact
potential impacts of desalination plants on the of desalination plants. Impacts become key
marine environment. issue for discharge permit (thus influence
plant commissioning date and eventual
The brine flows are of a considerable size, modifications).
generally up to 50-60 % (for membrane based
technologies such as RO and up to 90 % (for • New regulations demand for better pollution
thermal technologies such as MSF, including control at the discharge point (‘effluent
cooling water) of the intake flowrate. The standards’) as well as within the receiving
flows are therefore almost as large as or even water (‘ambient standards’). In order to meet
considerably larger than the required freshwater these regulations, optimised high efficiency
water flow, and salinity and temperature directly mixing designs are needed for the discharges.
influence the density of the effluent. The various
density differences between the brine and the • Discharge designs are often not optimised
receiving water represented by the buoyancy regarding environmental impacts or
flux causes different flow characteristics for the operational needs. Especially for larger plants
discharge. The dense RO effluent flow has the or plant complexes there is a potential for
tendency to fall as negatively buoyant plume recirculation to the plant intake, reducing
and spread as a density current on the sea floor, overall system efficiency. There exists no
whereas a neutral to positive buoyant flux, efficient planning tool to assist desalination
causing the plume to rise and to spread on the plant designers and plant managers about
sea surface, is characteristic for effluent from the importance of good planning for brine
thermal desalination plants. discharges.

DESALINATION
PLANT

Positive buoyant jet

Brine discharge design must take into account


environmental impact and operational needs, even Negative buoyant jet
where these are not specific in local planning regulations

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PERMEATE TREATMENT
AND DISTRIBUTION

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Permeate treatment and distribution Desalination Manual

6. Permeate treatment and distribution

To finalise the treatment a so-called stabilisation a. Distribution


step is used to balance the water chemistry Finally, all general water treatment processes
again after adding and removing content in the end with the distribution network and the
former steps of the process. This step becomes pumps used. Important again is the choice of
very important, as it is the final step before the materials, corresponding to the water usage in
water goes to the end-user or for use afterwards question. Correct pressure level and flow rate for
in industry. In principle, this step is about pH the distribution system is important.
adjustment, balancing the water with minerals
such as calcium (Ca) or magnesium (Mg), or, even
removing ions to, for example, soften the water.

The reason for balancing the water chemistry is


to avoid corrosion in the pipework or of materials
used in the processes that follow to ensure the
efficiency of disinfection, as the effect of some
chemicals is pH-dependent. The reason can also
be to ensure the water meets the standards and
regulations set for the water usage in question.

Dosing skid system

Hydro MPC system Oxiperm pro for Lime preperation


disenfection system for pH
adjustment

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CONTROL SYSTEMS
AND WATER QUALITY
CONTROL

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Control systems and water quality control Desalination Manual

7. Control systems and water quality control

Throughout the whole process, different together all the measured signals from the
measuring and control functions required, using different process steps and regulates the
state of the art technology and providing reliable process to ensure the success of the treatment.
results. Typically, hydraulic parameters such as This is also the point from where the different
flow and pressure, and chemical parameters components and subsystems with its various
like pH, turbidity, conductivity and Total Organic signals are connected to an overall process,
Carbon (TOC) are measured online and put into generally using standard data connection
the process control system. The parameters to systems like Profibus, Ethernet and such like.
be measured and controlled depends on the Total process control can also involve the internal
regulations and requirements of the specific Grundfos communication protocol Genibus,
process. using converters to the communication protocols
mentioned above. Today, cloud solutions are also
Total process control is important for every available for overall process control.
treatment application. Normally a PLC brings

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PRODUCTS

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Control systems and water quality control Desalination Manual

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8. Product chart

Chlorination Flocculant Dechlorination Anti-Scalant


Cartridge Filter UF
Sand Filter

Cleaning Agent

optional Tank

Sitrans F M
MAG 3100 /
MAG 5100 /
MAG 5000 Chemical
Dosing Systems
Dosing Tank
Pressure and Stations Pressure and
Temperature Sensors Temperature Sensors
DPI / RPI DPI / RPI
Polymer
Dosing
VFI Dosing Systems Flow Sensors
Skid
Systems Polydos VFI

Flow Sensors

Intake Chemical Pretreatment Prefiltration

Submersible Dosing Pumps Feed/ End-Suction Pumps


Pumps Backwash
DMX Pumps
SP
DMH CM
Turbine Pumps End-Suction Pumps
Peerless Vertical NB / NK NB / NK
Turbine Pumps
DME CR
DDI

Multistage TP
Pumps SMART Digital
CR

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Grundfos products Desalination Manual

Hypochlorite
alant pH Correction Minerals pH Correction
PX Chlorine
Dioxide

Buffer Tank
Chlorine
Gas

ClO2 Systems Chemical Dosing Systems


Tank DSS / DTS
Oxiperm Pro ISIA CIO2
Generator Sitrans F M
MAG 3100 /
MAG 5100 /
MAG 5000

Chemical
Isobaric Pressure Dosing Systems Cl2-Systems VFI
Exchangers Dosing Tank Vaccuperm
Stations Lime Gas
ERD pressure Preparation warning
exchanger Systems device Flow Sensors
DIA-G / DIS-G
Pressure and
KD Booster Temperature
Electro- Systems Sensors
Pelton chlorination
Turbines Dosing Skid
Systems Systems
BMT Hydro MPC
Selcoperm DPI / RPI

Reverse Osmosis Remineralisation Disinfection Distribution

Booster High Pressure Dosing Pumps Dosing Pumps End-Suction Pumps


Pumps Pumps
DMX DMX
BMS hs DMH DMH
BMS hp

NB / NK
BM DME DME
DDI DDI

BMP
SMART Digital SMART Digital

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Tel: +45 87 50 14 00
www.grundfos.com
DK-8850 Bjerringbro
Poul Due Jensens Vej 7
GRUNDFOS Holding A/S

9069_BM_BMET_manual_2016.indd 40
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