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Manual
GRUNDFOS
DESALINATION
MANUAL
Introduction .........................................................................................5
1. Desalination methods ......................................................................7
a. Multi-Stage Flash (MSF) desalination ..........................................................7
b. Multiple Effect Desalination (MED) ..............................................................9
c. Reverse Osmosis (RO) desalination ............................................................. 10
d. Cost comparison ................................................................................................. 11
2. How Reverse Osmosis (RO) works ...................................................13
a. Spiral wound module ...................................................................................... 14
b. Energy recovery ................................................................................................... 18
c. An example of possible power savings .................................................... 20
3. Water intake ..................................................................................25
a. Beach wells............................................................................................................ 25
4. Intake water treatment ..................................................................27
a. Nanofiltration ...................................................................................................... 28
b. Chlorine .................................................................................................................. 29
5. Brine discharge...............................................................................31
6. Permeate treatment and distribution.............................................33
a. Distribution ........................................................................................................... 33
7. Control systems and water quality control .....................................35
8. Product chart..................................................................................38
Introduction
Why desalination and water treatment? However, desalination offers a potential solution.
Pure water (H2O) is a colourless, odourless and Desalination is the process used to convert
tasteless liquid. It plays a huge part in everyday salt water (seawater, brackish water or saline
life: 70 % of the earth’s surface is covered by groundwater) to fresh water so it is suitable
water in the form of oceans, and the rest of the for human consumption or use. Most interest
planet has large quantities of water in the form in desalination today is focused on developing
of lakes, rivers and watercourses, ice and snow, cost-effective ways of providing fresh water for
and humidity, as well as the principal element human use in regions where the availability
of animal life (> 50 %) and plants (approximately of fresh water is, or is becoming, limited.
80 %). Desalinated water is also used on many seagoing
ships and submarines.
When we talk about water in general, we usually
mean water for some specific purpose, such as Large-scale desalination typically uses extremely
drinking water or process water for industry. This large amounts of energy as well as specialised
is where the term water treatment enters the infrastructure, making it costly comparable
picture, because the available water resources to the use of fresh water from rivers or
provided by nature are not always of a suitable groundwater wells.
quality for immediate use for the specific
purpose.
Almost one-fifth of the world’s population lives Rain clouds
1. Desalination methods
There are different ways to desalinate seawater, excess heat is available from, for example, an oil
and these vary in cost and efficiency, depending or coal heated electric power plant. The Middle
on the purpose. This is a technology-heavy field East has the majority of thermal desalination
in constant development, as attempts are made plants in use today.
to keep costs down, increase efficiency and en-
sure the sustainability of the solution, including
a. Multi-Stage Flash (MSF) desalination
reducing environmental impact.
Multi-Stage Flash (MSF) desalination is the
most common process for turning seawater into
The most common and immediately apparent
drinking water. The process uses the excess heat
desalination process is thermal desalination,
from big thermal power plants. This process is
where seawater (salt water) evaporates and the
widely used in the Middle East.
vapour condenses to clean water.
For producing drinking water, thermal desalina-
Capacity is 200,000 to 800,000 m3/day.
tion uses excess heat and often used where
Sea water
T=112°C
Brine
Feed
Condensate 120°C 110°C 60°C
Liquid Liquid
Concentrate Distillate
A typical RO installation
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Capital
120 114 118 100
investment
Energy related
215 175 140 100
costs
Membrane
--- --- --- 100
replacement
Other remaining
103 89 100 100
costs
Overall product
114 109 107 100
cost
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12
Osmosis is the natural tendency of water with a into the high TDS solution to equalise the
low concentration of total dissolved solids (TDS) concentration levels on both sides. As more
to travel through a semi-permeable membrane water molecules travel through the membrane,
into a solution of higher TDS in order to balance the fluid level in each chamber changes. Once
the solute levels on both sides of the membrane. the TDS concentrations in both chambers have
reached equilibrium, the osmotic process stops,
The illustrations below illustrate how the water as enough pressure has built up to stop the flow
molecules from the low TDS solution migrate of water from one chamber to the other. This
through the semi-permeable membrane pressure is known as osmotic pressure.
Applied
pressure
Reverse Osmosis is a process where pressure
greater than the natural osmotic pressure is
applied on the high concentration side of the
membrane, forcing the water to travel through
the membrane from the higher TDS to lower TDS
chamber, thus ‘reversing’ the natural tendency of
water flow.
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1
9 Concentrate spacer
Inlet for raw water 10 Membrane
4
11 Permeate spacer
Flow direction for
raw water 10 Membrane
5
9 Concentrate spacer
Flow direction for permeate
12 Glue joint of "envelope"
6
External housing
14
Feed
Permeate
Drain
Pressure vessel for ‘spiral wound’ modules Holes
Down
The table shows the different filtration processes according to the relative size of the particle retained
The particle filtration can be achieved with a lot of different technologies, each of them suitable for
different requirements. The filtration of particles of size less than a micrometer is achieved with the use of
membrane filtration, which is a type of filtration over a support.
Membranes is a special type of filtration on support. Relatively thin sheets or thin fibers with an ultrathin
surface layer where the filtration/retention of particles and other pollutants take place. A "filter cake" of
pollutants is build outside the filter during operation, and regeneration of the filter is therefore much
easier and with less water waste. For this reason membrane filters have showed a tremendously fast
growth in market shares on the water purification markets recently.
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When the RO is stopped or in stand-by, natural The CIP station, depending on the plant size,
osmosis will happen between the permeate includes a chemical tank with mechanical or
side and the concentrate side containing manual stirrer, a CIP pump and a fine filter
high salinity brine. This can damage the feed to avoid debris to enter the membranes. The
spacers by creating a vacuum in the permeate chemical tank depends on the number of
line, as water will naturally flow back to the membranes to be cleaned at the same time. H
concentrate side, driven by osmotic pressure. Alkaline and Acid Cleaning solutions are
recirculated around the membranes for at
To avoid this natural damaging osmosis least 30 minutes.
happening, seawater and brine are flushed
off the membranes after service by permeate Routine cleaning, chemicals and procedures
water taken from the permeate tank (before are determined depending on desalination
chlorination) and pushed in the membrane by a plant layout and fouling identification. En
low pressure pump (i.e., feed pump, distribution
pump or specific cleaning pump).
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High pressure
pump
Concentrate
Permeate
Energy recovery
device
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No recovery Product
40/1 bar
Feed
100/63 bar
100/5 bar
CARTRIDGE
FILTER
Brine
60/60 bar
60/0 bar
Feed
100/63 bar
100/5 bar
CARTRIDGE
FILTER
Brine
60/60 bar
60/0 bar
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CHECK VALVES
PRESSURE VESSEL
VALVE
Brine
PRESSURE VESSEL 60/0 bar
60/2 bar
Product
Feed 40/1 bar
100/63 bar
40/63 bar
Brine
60/0 bar
60/2 bar
The particularity of the RO desalination process flow. This is the reason that the HP pump in
lies in the fact that the brine coming from this scheme has to pump only part of the feed
the membranes loses very little from the feed flow equal to permeate. The transfer losses
pressure, and this brine stream contains almost are few, and the circulation pump delivers the
50 % of the energy required for desalination. compensation of pressure difference between
This is why the efficiency with which the energy brine and feed (3-4 bar).
contained in the brine pressure is transferred for
pumping of the feed water is critical. The efficiency of energy recovery in the Pressure
Exchangers group is around 96 %.
The energy transfer in the Pelton group is
indirect, with the brine jet hitting the turbine Good pump efficiency is 85 %, and at the end of
buckets. The efficiency of Pelton turbine itself the retransmission chain, of the 100 kWh energy
is around 87 %. The energy is transferred to the in the brine, only 74 kWh can be transferred to
shaft and from the shaft to the pump. the feed stream again.
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The equipment and maintenance costs in the cost, is shown below. The graph represents
Pressure Exchangers group are higher than in the the case of a 95,000 m3/day desalination
Pelton group. plant, 10-year loan, 7.5 % interest rate. As can
be seen, if the energy cost for large industrial
The merit of implementation of one or other service is above USD 0.0175 (1.75 cents) per kWh,
group depends on several factors such as energy the Pressure Exchangers group can be more
cost, project lifetime, and interest rates. The cost economical than equipment from the Pelton
effectiveness of the Pressure Exchangers group group.
as opposed to the Pelton group, versus energy
$4,000,000
$3,000,000
Saving NPV in US$
$2,000,000
$1,000,000
$0
-$1,000,000 1 1.5 2 2.5 3 4 4.5
- $2,000,000
Saving NPV in USD
Cost effectiveness of Pressure Exchangers group opposed to Pelton group versus
energy cost
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Energy effective but expensive DWEER and ERI Desalination plant costs breakdown
systems cannot be used in conditions where 1pass RO with PX-40 g7L - 40% recovery
the energy cost is low, the interest rate high and - 125 m3/h - 0.08 kWh/m3 - 10 yrs depreciation time
the mortgage period short. The type of energy 1%
11% 14% Investment
recovery device also depends on the condition of 7% Membranes
the brine discharge. The DWEER and ERI systems Consumables
are able to maintain sufficient backpressure for Electricity
41% 26%
long distance brine discharge. Manpower
Spares
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14 m³/h
1 bar
The relationship between energy cost, interest cost, the SWRO designers will implement high
rates, and labour and civil engineering costs membrane fluxes and high recovery in order to
will determine the plant recovery, membrane reduce the physical dimension of the plant and
flux, and even water velocity in the pipelines. increase the energy components of the water
Low power cost and high labour cost, as is cost.
typical in the USA, is unusual for traditional
seawater desalination areas. This combination The tender requirements should define the limits
of economic parameters will challenge plant on several technological parameters to ensure a
designers to push desalination technology to reliable water supply.
its limits. In the effort to reach low overall water
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Seawater feed
23 m³/h; 2 bar 14 m³/h
0 bar
Power consumption per m3 permeate produced on SWRO system with Pelton turbine.
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3. Water intake
CASING
TIDAL WATER
BEACH Well and
Above
pumps CEMENT GROUT
max. storm
tide level
WELL SCREEN
GRAVEL PACK
TO TREATMENT A A
PLANT
PLAN VIEW A A
SECTIONAL VIEW
Well and Well and
pump pump
STORAGE TANK
REVERSE OSMOSIS
DEDALINATED
CASING WATER
PRE-TREATMENT
CEMENT GROUT
WELL SCREEN
INTAKE
GRAVEL PACK
UNDERGROUND
TUNNELS
A A
Overview of seawater desalination concept
SECTIONAL VIEW
OUTLET
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H2SO4 Antiscalant
Multi media Micro R/O Stage
NaOSl
H2SO 4 filter
Multi media Micro filterAntiscalant SBS R/O Stage
NaOSl filter filter SBS
FeCl3
FeCl3
ERT ERT
SEA
SEA WATER Pump
WATER Pump BoosterBooster High pressure Concentrate Concentrate
High pressure Post Post
pump pump pump pump treatment treatment
Sodium RO filtered
hypo chlorite Sodium water RO filtered
hypo chlorite water
R/O Stage
In taked Backwash
water strage tank R/O Stage
pump
In taked Backwash
water strage tank PURE
pump WATER
Concentrated PURE
Pre-filter
feed pump Compressor water Product water WATER
strage tank
Concentrated
Well pump Pre-filter MF Filtered Transfer High
Compressor water Product water
feed pumpmodule water tank pump pressure
pump strage tank
Strainer MF Filtered Transfer High
Well pump module water tank pump pressure Typical SWRO system
pump
with ultra filtration as
Strainer pre-filtration.
The choice of method depends on the water However, it is more and more common that
quality. The most common approach is to pump membranes for ultrafiltration replace the bag
the seawater through multi-media filters with filters or cartridge filter.
layers of sand, pebbles or gravel to remove twigs,
seaweed and other solid particles. The water will
then be filtered through bag filters or cartridge
filters before it is pumped into the membranes.
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a. Nanofiltration
Nanofiltration is a relatively recent membrane
filtration process often used where water has
low total dissolved solids (TDS), such as surface
water and fresh groundwater. With the purpose
of softening (polyvalent cation removal) and
removal of disinfection by-product precursors
such as natural organic matter and synthetic,
nanofiltration is used increasingly as pre-
filtration for SWRO systems.
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b. Chlorine
If necessary, chlorine is added to remove bacteria
or flocculent to separate larger particles from the
water. It can also be necessary to add antiscalant
to prevent scaling deposit in the membranes.
Grundfos Polydos
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5. Brine discharge
When designing a desalination plant, the Seawater desalination plants carry a number of
brine discharge or outfall must be taken into waste products into the coastal environment:
consideration. concentrated salt brine that may also have
The impacts of a desalination plant discharge on an elevated temperature, often containing
the marine environment depend on the physical antifoulant and antiscalant and other
and chemical properties of the desalination substances. Modern, large capacity plants
plant reject streams, and the susceptibility require submerged discharges that ensure a high
of coastal ecosystems to these discharges dilution in order to minimise harmful impacts on
depending on their hydrographical and biological the marine environment.
features. Therefore, a good knowledge of
both the effluent properties and the receiving • There is increased public concern and scientific
environment is required in order to evaluate the awareness on the environmental impact
potential impacts of desalination plants on the of desalination plants. Impacts become key
marine environment. issue for discharge permit (thus influence
plant commissioning date and eventual
The brine flows are of a considerable size, modifications).
generally up to 50-60 % (for membrane based
technologies such as RO and up to 90 % (for • New regulations demand for better pollution
thermal technologies such as MSF, including control at the discharge point (‘effluent
cooling water) of the intake flowrate. The standards’) as well as within the receiving
flows are therefore almost as large as or even water (‘ambient standards’). In order to meet
considerably larger than the required freshwater these regulations, optimised high efficiency
water flow, and salinity and temperature directly mixing designs are needed for the discharges.
influence the density of the effluent. The various
density differences between the brine and the • Discharge designs are often not optimised
receiving water represented by the buoyancy regarding environmental impacts or
flux causes different flow characteristics for the operational needs. Especially for larger plants
discharge. The dense RO effluent flow has the or plant complexes there is a potential for
tendency to fall as negatively buoyant plume recirculation to the plant intake, reducing
and spread as a density current on the sea floor, overall system efficiency. There exists no
whereas a neutral to positive buoyant flux, efficient planning tool to assist desalination
causing the plume to rise and to spread on the plant designers and plant managers about
sea surface, is characteristic for effluent from the importance of good planning for brine
thermal desalination plants. discharges.
DESALINATION
PLANT
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Throughout the whole process, different together all the measured signals from the
measuring and control functions required, using different process steps and regulates the
state of the art technology and providing reliable process to ensure the success of the treatment.
results. Typically, hydraulic parameters such as This is also the point from where the different
flow and pressure, and chemical parameters components and subsystems with its various
like pH, turbidity, conductivity and Total Organic signals are connected to an overall process,
Carbon (TOC) are measured online and put into generally using standard data connection
the process control system. The parameters to systems like Profibus, Ethernet and such like.
be measured and controlled depends on the Total process control can also involve the internal
regulations and requirements of the specific Grundfos communication protocol Genibus,
process. using converters to the communication protocols
mentioned above. Today, cloud solutions are also
Total process control is important for every available for overall process control.
treatment application. Normally a PLC brings
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37
Cleaning Agent
optional Tank
Sitrans F M
MAG 3100 /
MAG 5100 /
MAG 5000 Chemical
Dosing Systems
Dosing Tank
Pressure and Stations Pressure and
Temperature Sensors Temperature Sensors
DPI / RPI DPI / RPI
Polymer
Dosing
VFI Dosing Systems Flow Sensors
Skid
Systems Polydos VFI
Flow Sensors
Multistage TP
Pumps SMART Digital
CR
38
Hypochlorite
alant pH Correction Minerals pH Correction
PX Chlorine
Dioxide
Buffer Tank
Chlorine
Gas
Chemical
Isobaric Pressure Dosing Systems Cl2-Systems VFI
Exchangers Dosing Tank Vaccuperm
Stations Lime Gas
ERD pressure Preparation warning
exchanger Systems device Flow Sensors
DIA-G / DIS-G
Pressure and
KD Booster Temperature
Electro- Systems Sensors
Pelton chlorination
Turbines Dosing Skid
Systems Systems
BMT Hydro MPC
Selcoperm DPI / RPI
NB / NK
BM DME DME
DDI DDI
BMP
SMART Digital SMART Digital
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9069_BM_BMET_manual_2016.indd 40
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25-11-2016 13:12:52