NCERT Solutions For Class 11 Chemistry Chapter 6 Thermodynamics - CBSE Tuts

NCERT Solutions for Class 11 Chemistry Chapter 6 Thermodynamics ... https://www.cbsetuts.
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NCERT Solutions for Class 11 Chemistry

Chapter 6 Thermodynamics
N C E RT S o l u t i o n s f o r C l a s s 1 1 C h e m i s t r y C h a p t e r 6 T h e r m o d y n a m i c s includes all the important
topics with detailed explanation that aims to help students to understand the concepts better. Students who
are preparing for their Class 11 exams must go through NCERT Solutions for C l a s s 1 1 C h e m i s t r y
C h a p t e r 6 T h e r m o d y n a m i c s . Going through the solutions provided on this page will help you to know
how to approach and solve the problems.
Students can also �nd NCERT intext, exercises and back of chapter questions. Also working on C l a s s 1 1
C h e m i s t r y Chapter 6 Thermodynamics NCERT Solutions will be most helpful to the students to solve their
Homeworks and Assignments on time. Students can also download N C E RT S o l u t i o n s f o r C l a s s 1 1
C h e m i s t r y C h a p t e r 6 T h e r m o d y n a m i c s P D F to access them even in o�ine mode.
NCERT Solutions for Class 11 Chemistry Chapter 6

Thermodynamics
NCERT Solutions for Class 11 Chemistry Chapter 6 Thermodynamics are been solved by expert teachers of
CBSETuts.com. All the solutions given in this page are solved based on CBSE Syllabus and NCERT
guidelines.
N C E RT E x e r c i s e s
Question 1.
Choose the correct answer. A thermodynamic state function is a quantity
( a ) used to determine heat changes
( b ) whose value is independent of path
( c ) used toNCERT
determine
6TH
7pressure
8 9volume
10 work
11 12 NCERT MCQ SAMPLE EXTRA ENGLISH
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NCERT Solutions for Class 11 Chemistry Chapter 6 Thermodynamics ... https://www.cbsetuts.com/ncert-solutions-for-class-11-chemistry-chapter-6/
( d ) whose value depends on temperature only.

S o NCERT
l u t i o n . SOLUTIONS TS GREWAL CBSE SAMPLE PAPERS NCERT EXEMPLAR PROBLEMS
( b ) : State function is a property of the system whose value depends only upon the state of the system and
is independent of the path orMCQ
ENGLISH GRAMMAR the manner by which the state is reached.
QUESTIONS
Question 2.
For the process to occur under adiabatic conditions, the correct condition is
( a ) ΔT = 0
( b ) Δp = 0
(c) g = 0
( d ) w=0
Solution.
( c ) : Adiabatic system does not exchange heat with the surroundings.
Question 3.
The enthalpies of all elements in their standard states are
( a ) unity
( b ) zero
( c ) <0
( d ) different for each element.
Solution.
( b ) : By convention, the standard enthalpy of formation of every element in its standard state is zero.
Question 4.
ΔU° of combustion of methane is – X kJ mol-1. The value of ΔH° is
( a ) = ΔU°
( b ) >ΔU°
( c ) <ΔU°
( d ) =0
Solution.
( c ) : CH4(g)+2O2 → CO2(g)+2H2Ol
Δn = 1 – 3 = -2. ‘
ΔH° = ΔU° + ΔnRT = -X- 2RT
Question 5.
The enthalpy of combustion of methane, graphite and dihydrogen at 298 K are, -890.3 kJ mol-1,-393.5 kJ
mol-1 and-285.8 kJ mol-1 respectively. Enthalpy of formation of CH4(g) will be
( a ) -74.8 kJ -1
mol6TH
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( b ) -52.27 kJ mol-1
( c )NCERT SOLUTIONS
+74.8 kJ mol-1 TS GREWAL CBSE SAMPLE PAPERS NCERT EXEMPLAR PROBLEMS
( d ) +52.26 kJ mol-1
S o ENGLISH
l u t i o n . GRAMMAR MCQ QUESTIONS
Question 6.
A reaction, A + B → C + D + q is found to have a positive entropy change. The reaction will be
( a ) possible at high temperature
( b ) possible only at low temperature
( c ) not possible at any temperature
( d ) possible at any temperature
Solution.
( d ) : A + B → C + D + q, ΔS = +ve
Here, ΔH = -ve
ΔG = ΔH – TΔS
For reaction to be spontaneous, ΔG should be -ve. As ΔH = -ve and ΔS is +ve, ΔG will be -ve at any
temperature.
Question 7.
In a process, 701 J of heat is absorbed by a system and 394 S of work is done by the system. What is the
change in internal energy for the process?
Solution.
Heat absorbed by the system (q) = 701 J
Work done by the system (w) = -394 J
According to �rst law of thermodynamics,
ΔU = q + w = 701 + (-394) = 701 – 394 = 307 J
NCERT 6TH NCERT MCQ SAMPLE EXTRA ENGLISH

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Question 8.
TheNCERT SOLUTIONS
reaction of cyanamide, TS
NHGREWAL CBSE SAMPLE PAPERS NCERT EXEMPLAR PROBLEMS
2CN(g), with dioxygen was carried out in a bomb calorimeter, and AU was
found to be -742.7 kJ mol 1 at 298 K. Calculate enthalpy change for the reaction at 298 K.
3
NHENGLISH
2CN(g) + GRAMMAR
O
2 2(g)
→ N2+CO2(g)+H
MCQ 2Ol
QUESTIONS
Solution.
Question 9.
Calculate the number of kJ of heat necessary to raise the temperature of 60.0 g of aluminium from 35°C to
55°C. Molar heat capacity of Al is 24 J mol-1 K-1.
Solution.
Mass of Al = 60 g
Rise in temperature, ΔT = 55 – 35 = 20°C
Molar heat capacity of Al = 24 J mo-1 K-1
Speci�c heat capacity of Al = 24
27
J g −1 K −1
∴ Energy required = m x c x ΔT
28800
= 60 × 24
27
× 20 = 27
= 1066.67 J
= 1.068kJ or 1.07kJ
Question 10.
Calculate the enthalpy change on freezing of 1.0 mol of water at 10.0°C to ice at -10.0°C. ΔfusH = 6.03 kJ
mol-1 at 0°C.
Cp[H2O(l)] = 75.3 J mol-1 K-1,
Cp[H2O(s)] = 36.8 J mol-1 K-1
Solution.

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Question 11.
Enthalpy of combustion of carbon to CO2 is -393.5 kJ mol-1. Calculate the heat released upon formation of
35.2 g of CO2 from carbon and dioxygen gas.
Solution.
C + O2 → CO2; ΔT = -393.5 kJ
∵ When 44 g of COz is formed from carbon and dioxygen gas, heat released = 393.5 kj
∴ When 35.2 g of CO2 is formed from carbon and dioxygen gas, heat released
393.5×35.2 138551.2
= 44
= 44
= 314.8kJ
Thus, ΔH = -314.8 kJ
Question 12.
Enthalpies of formation of CO(g), CO2(g), N2O(g) and N2O4(g) are -110, – 393, 81 and 9.7 kJ mol -1 respectively.
Find the value of Δrf for the reaction
N2O4(g) + 3CO(g) → N2O(g) + 3CO2(g)
Solution.
Question 13.
Given: N2(g) + 3H2(g) → 2NH3(g); ΔrH° = -92.4 kJ mol-1 What is the standard enthalpy of formation of NH3
gas?
Solution.
N2(g) + 3H2(g) → 2NH3(g) ; ΔrH° = -92.4 kJ mol-1
∴ Standard enthalpy of formation of NH3(g)
−92.4
= 2
= −46.2 kJ/mol
Q u e s t i o n NCERT
1 4 . 6TH NCERT MCQ SAMPLE EXTRA ENGLISH
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Calculate the standard enthalpy of formation of CH3OHl from the following data :
Solution.
Question 15.
Calculate the enthalpy change for the process
CCl4(g) → C(g) + 4Cl(g)
and calculate bond enthalpy of C – Cl in CCl4(g).
ΔvapH°(CCl4) = 30.5 kJ mol-1,
ΔfH°(CCl4) = -135.5 kJ mol-1,
ΔaH°(C) = 715.0 kJ mol-1, where ΔaH° is enthalpy of atomisation ΔaH°(Cl2) = 242 kJ mol-1
Solution.

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Question 16.
For an isolated system, ΔU = 0, what will be ΔS?
Solution.
When energy factor has no role to play, for the process to be spontaneous ΔS must be +ve i.e., ΔS > 0.
Question 17.
For the reaction at 298 K, 2A + B → C,
ΔH = 400 kJ mol-1 and ΔS = 0.2 kJ K-1 mol-1 At what temperature will the reaction become spontaneous
considering ΔH and ΔS to be constant over the temperature range.
Solution.
According to Gibbs Helmholtz equation, ΔG = ΔH – TΔS.
Question 18.
For the reaction, 2Cl(g) → Cl2(g), what are the signs of ΔH and ΔS?
Solution.
ΔH is negative because bond energy is released and ΔS is negative because there is less randomness
among the molecules than among the atoms.
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Question 19.
ForNCERT SOLUTIONS
the reaction TS GREWAL CBSE SAMPLE PAPERS NCERT EXEMPLAR PROBLEMS
2A(g) + B(g) → 2D(g), ΔU° = -10.5 kJ and ΔS° = – 44.1 JK-1.

Calculate
ENGLISH ΔG° for the reaction,
GRAMMAR MCQandQUESTIONS
predict whether the reaction may occur spontaneously.
Solution.
ΔH° = ΔU° + Δn(g)RT
Question 20.
The equilibrium constant for a reaction is 10. What will be the value of ΔG° ?
R = 8.314J K-1 mol-1, T= 300 K.
Solution.
We know that ΔG° = – 2.303RT logK
= – 2.303 x 8.314 x 300 x log10
= – 5744.14 J/mol
Question 21.
Comment on the thermodynamic stability of NO(g), given
Solution.
Since Δ(r)H° is +ve, i.e., enthalpy of formation of NO is positive, therefore NO is unstable. But Δ(r)H° is
negative for the formation of NO2. So, NO2 is stable.
Question 22.
Calculate the entropy change in surroundings when 1.00 mol of H2Ol is formed under standard conditions.
NCERT 6TH -1. NCERT MCQ SAMPLE EXTRA ENGLISH
kJ mol7
Δ(r)H° = – SOLUTIONS
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8 of 12 21-12-2022, 16:52
Solution.
Now that you are provided all the necessary information regarding NCERT Solutions for Class 11 Chemistry
Chapter 6 Thermodynamics and we hope this detailed NCERT Solutions are helpful.
NCERT Solutions for Class 11 Chemistry
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